CN105296023B - A kind of fuel oil additive and preparation method thereof - Google Patents
A kind of fuel oil additive and preparation method thereof Download PDFInfo
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- CN105296023B CN105296023B CN201510643080.7A CN201510643080A CN105296023B CN 105296023 B CN105296023 B CN 105296023B CN 201510643080 A CN201510643080 A CN 201510643080A CN 105296023 B CN105296023 B CN 105296023B
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Abstract
The present invention discloses a kind of fuel oil additive, is made up of the raw material including following parts by weight：50 ~ 80 parts of tourmaline nano powder, 10 ~ 20 parts of ethanol, 30 ~ 50 parts of diisopropyl ether, 10 ~ 20 parts of bio oil, 5 ~ 10 parts of antioxidant, 5 ~ 10 parts of dispersant, 5 ~ 30 parts of water.The preparation method of the fuel oil additive of the present invention produces for all raw materials are stirred at normal temperatures and pressures.The fuel oil additive of the present invention can improve oil, promote fuel oil fully to burn, and improve efficiency of combustion, save fuel oil；Its atomization quality can be improved, fuel oil is fully burnt reduces noxious gas emission, reaches the purpose of energy-saving and emission-reduction.
Description
Technical field
The present invention relates to the preparation method of energy-saving and emission-reduction fuel activating additive, and in particular to a kind of fuel oil additive and its
Preparation method.
Background technology
Energy-saving and emission-reduction are the task of top priority of world today's energy scarcity, and the efficiency of combustion of fuel oil directly affects energy-conservation and subtract
The effect of row, fuel oil additive can improve oil, promote fuel oil fully to burn, and improve efficiency of combustion, save fuel oil；It can carry
Its high atomization quality, fuel oil is fully burnt reduces noxious gas emission, reaches the purpose of energy-saving and emission-reduction.
In field of internal combustion engine, in order to improve fuel economy, increase power output, reduce oil consumption, decarbonizing is reduced
Noxious gas emission, mainly there are two technological approaches at present：First, addition or reforming equipment（Such as various fuel-economizings, reinforcement, purification
Device）, second, putting into additive to fuel oil.First approach investment is big, program is cumbersome, also increases car and boat deadweight and maintenance difficulty,
So second approach more people is received.But one that the fuel oil additive delivered at present has the following disadvantages mostly
It is or several：First, saving fuel oil, the effect of lifting power are undesirable, and some also reduces power performance, and this is that current fuel oil adds
It can not be the generally accepted main cause of users to add agent；2nd, engine noise can not be substantially reduced, some also add hair
Motivation noise；3rd, easily cause " secondary pollution " ----additive to be worked by chemical reaction, playing the same of efficiency
When, may generate some aroused attention or not yet arouse attention, the public hazards thing that is more difficult to natural degradation, so as to turn into business
Family and the hidden danger of the public, such as famous additive MTBE (methyl tertiary butyl ether(MTBE)), its meeting is found after being passed unimpeded in the U.S. 20 years
Increase oxynitride discharge, especially the serious is can permanent polluted source（Even deep phreatic water）, thus made by limitation
With；4th, efficiency is unstable：Because the component of fuel oil is extremely complex, the same label fuel oil of different manufacturers production is in production process
In technique and adding ingredient be different, or even the same label product of same producer, due to the raw material sources of different batches
Difference will also result in the difference of product composition, formally uncertain make it that to rely primarily on that chemical agent works adds due to this
Add agent often to stablize and play efficiency, and easily produce the adverse consequences such as " secondary pollution " and parts corrosion.
Current existing fuel oil anti-knock agent unit cost is too high and addition is excessive when using（Often between 5 ~ 15%）, cause
The price ratio of anti-knock agent in high standard fuel price is set to remain high.In the case where current fuel price increasingly rises violently, reduce
One of effective way of fuel price is to substantially reduce the cost of the additive for lifting gasoline label and diesel cetane-number.
The content of the invention
The purpose of the present invention be exactly in order to overcome above-mentioned prior art to exist the defects of, there is provided a kind of fuel oil additive and its
Preparation method, fuel oil additive of the invention can improve oil, promote fuel oil fully to burn, and improve efficiency of combustion, save combustion
Oil；Its atomization quality can be improved, fuel oil is fully burnt reduces noxious gas emission, reaches the purpose of energy-saving and emission-reduction.
In order to realize foregoing invention purpose, technical scheme is as follows：
The fuel oil additive of the present invention, is made up of the raw material including following parts by weight：50 ~ 80 parts of tourmaline nano powder, second
10 ~ 20 parts of alcohol, 30 ~ 50 parts of diisopropyl ether, 10 ~ 20 parts of bio oil, 5 ~ 10 parts of antioxidant, 5 ~ 10 parts of dispersant, 5 ~ 30 parts of water.
Described antioxidant is the pungent primary alkyl zinc salt of sulphur phosphorus fourth, the double pungent primary alkyl zinc salts of sulphur phosphorus, alkali formula sulphur phosphorus double pungent primary
One or more than one kinds of mixing in the pungent secondary primary alkyl zinc salt of alkyl zinc salt, sulphur phosphorus third, sulphur phosphorus brothers alkyl zinc salt.
Described dispersant is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene calcium alkylbenzenesulfonate, long-chain
Linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, the synthesis of long-chain linear alkyl benzene high base number
Sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutylene succinamide, high score
It is more than son amount polyisobutylene succinamide, one or two kinds of in boronation high molecular weight polyisobutylene base succimide
Mixing.
The water is pure water, mineral water or other clean waters.
The preparation method of described fuel oil additive is：
At normal temperatures and pressures, by described tourmaline nano powder, absolute ethyl alcohol, diisopropyl ether, bio oil, antioxidant,
Dispersant, water are mixed by weight ratio, are stirred, and are produced.
Described mixing speed is 8000 ~ 12000r/min, 10 ~ 90min of mixing time.
The fuel activating agent of the present invention has strong characteristic nmr, and nuclear magnetic resonance makes in fuel containing H atom
Molecule is provided with both positive and negative polarity feature, and molecules align becomes uniform from confusing, and the electric conductivity of fuel greatly reinforces, because
And be uniformly under fire, the ability of synchronousing combustion is strengthened.Two factors all promote fuel synchronously to break out while carried out, and so expect
The inevitable outcome synchronously broken out is that pinking is eliminated, and pinking eliminates, and the in-fighting problem of engine also just solves.Equal to increase
30% useful work, that is, reduce by 30% fuel consumption.It can be seen that tourmaline composition has greatly reinforced the energy-conservation effect of additive
Fruit, the consumption of fuel decline, and the discharge capacity of pernicious gas is also accordingly reduced.
The functioning as of water of the present invention " microexplosion explosive " is used to fried dissipate fuel molecule group, and the water in the presence of tourmaline
Can also Direct Pyrolysis be hydrogen-oxygen, give fuel hydrogenation oxygen supply.With carbon water gas reaction, decarbonizing can also occur for the effect of water.
In the present invention, water is also used as preferable catalyst, and nuclear magnetic resonance delivery agent, and the H atom in water is by, far infrared radiation
Strong nuclear magnetic resonance occurs afterwards, so as to as the outstanding vibration source of fuel nuclear magnetic resonance is triggered, therefore, expand water in the product
Ratio can strengthen its effect and reduce product cost.And the presence of surfactant, water can be promoted to be mixed with the uniform of fuel,
It is helped to play optimal catalytic action.
Ethanol is mixed in fuel oil and burnt as a kind of oxygen-containing bio-fuel in the fuel additive of the present invention, can be with
Reduce the discharge of diesel particulation, reduce smoke intensity, that is, reduce the discharge of diesel engine noxious pollutant.The antioxidant of the present invention can
Block, terminate oxidation, shielding protection effect is played to fuel oil.Bio oil is enriched in china natural resources, has a extensive future, and biology
The pollutant discharge amount of oil is low, has significant environmental benefit, meets the requirement of the strategy of sustainable development.Dispersant can adsorb combustion
Solid particulate matter in oil, is scattered in oil, so that have bigger contact area between solid, liquid and fuel oil,
So that it is uniformly heated.
Beneficial effects of the present invention are as follows：
1st, with tourmaline nano powder etc. for main functional component, a kind of energy-saving fuel additive of significant effect is have developed,
Fuel oil efficiency of combustion can be effectively improved, reduces noxious gas emission, energy-conserving and environment-protective.
2nd, it is theoretical based on nuclear magnetic resonance, additive is transmitted by the use of water as nuclear magnetic resonance, makes uniform atomizing before fuel oil resonance, into
Complicated each component is divided to resonate, fuel oil is disorderly arranged to become orderly, increases the surface area of fuel droplet and air contact, carries
High burning efficiency；Water gas reaction, the oxidation of generation one can also occur water with carbon for high-temperature vapor caused by microexplosion at high temperature
Carbon and hydrogen, decarbonizing further while provide fuel and heat.
3rd, the tourmaline fuel oil additive for preparing the present invention is applied in fuel activating device, has important use value
And economic benefit.
Embodiment
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1
1st, the preparation method of fuel oil additive of the invention, comprises the following steps：
At normal temperatures and pressures, by 50kg tourmaline nano powder, 10kg absolute ethyl alcohols, 30kg diisopropyl ethers, 10kg bio oils,
The double pungent primary alkyl zinc salts of the pungent primary alkyl zinc salt of 2kg sulphur phosphorus fourths, 3kg sulphur phosphorus, 2kg low alkali values synthesized calcium alkyl benzene sulfonate, 3kg are high-alkali
Value linear alkyl benzene calcium alkylbenzenesulfonate, 5kg water are mixed, and are stirred 10min under 8000r/min, are produced.
2nd, by fuel weight than 0.1% by tourmaline fuel oil additive obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows：Often 100 kilometers of row can save gasoline 18.1% to car, reduce CO emission 2.3%, reduce
Hydrocarbon emission amount 7.9%.
Embodiment 2
1st, the preparation method of fuel oil additive of the invention, comprises the following steps：
At normal temperatures and pressures, by 60kg tourmaline nano powder, 12kg absolute ethyl alcohols, 35kg diisopropyl ethers, 12kg bio oils,
2kg alkali formula sulphur phosphorus double pungent primary alkyl zinc salt, the pungent secondary primary alkyl zinc salt of 2kg sulphur phosphorus third, 3kg sulphur phosphorus brothers alkyl zinc salt, 2kg long-chains
Linear alkyl benzene high base number calcium alkylbenzenesulfonate, 3kg high base numbers synthesis dialkyl benzene sulfonic acids calcium, 3kg long-chain linear alkyl benzenes are high-alkali
Value synthesis sulfonic acid magnesium, 10kg water are mixed, and are stirred 20min under 9000r/min, are produced.
2nd, by fuel weight than 0.1% by tourmaline fuel oil additive obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows：Often 100 kilometers of row can save gasoline 21.0% to car, reduce CO emission 2.5%, reduce
Hydrocarbon emission amount 9.0%.
Embodiment 3
1st, the preparation method of fuel oil additive of the invention, comprises the following steps：
At normal temperatures and pressures, by 70kg tourmaline nano powder, 15kg absolute ethyl alcohols, 40kg diisopropyl ethers, 15kg bio oils,
The double pungent primary alkyl zinc salts of 4kg alkali formula sulphur phosphorus, the pungent secondary primary alkyl zinc salt of 4kg sulphur phosphorus third, 3kg SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBERs, 3kg gather
Isobutenyl succimide, 3kg boronations polyisobutylene succinamide, 20kg water are mixed, and are stirred under 8000r/min
30min is mixed, is produced.
2nd, by fuel weight than 0.1% by tourmaline fuel oil additive obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows：Often 100 kilometers of row can save gasoline 22.5% to car, reduce CO emission 3.0%, reduce
Hydrocarbon emission amount 9.1%.
Embodiment 4
1st, the preparation method of fuel oil additive of the invention, comprises the following steps：
At normal temperatures and pressures, by 80kg tourmaline nano powder, 18kg absolute ethyl alcohols, 45kg diisopropyl ethers, 18kg bio oils,
In the pungent primary alkyl zinc salt of 5kg sulphur phosphorus fourths, 5kg sulphur phosphorus brothers alkyl zinc salts, 2kg long-chain linear alkyl benzenes high base number synthesis sulfonic acid
Calcium, 3kg high molecular weight polyisobutylene bases succimide, 7kg boronation high molecular weight polyisobutylene bases succimide, 25kg water
Mixed, stir 60min under 10000r/min, produce.
2nd, by fuel weight than 0.02% by tourmaline fuel oil additive obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows：Often 100 kilometers of row can save gasoline 22.9% to car, reduce CO emission 3.3%, reduce
Hydrocarbon emission amount 9.3%.
Embodiment 5
1st, the preparation method of fuel oil additive of the invention, comprises the following steps：
At normal temperatures and pressures, by 65kg tourmaline nano powder, 20kg absolute ethyl alcohols, 50kg diisopropyl ethers, 20kg bio oils,
The pungent primary alkyl zinc salt of 2kg sulphur phosphorus fourths, 8kg low alkali values synthesized calcium alkyl benzene sulfonate, 30kg water are mixed, under 12000r/min
90min is stirred, is produced.
2nd, by fuel weight than 0.1% by tourmaline fuel oil additive obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows：Often 100 kilometers of row can save gasoline 20.7% to car, reduce CO emission 2.1%, reduce
Hydrocarbon emission amount 8.8%.
Claims (6)
1. a kind of fuel oil additive, it is characterised in that be made up of the raw material of following parts by weight：50 ~ 80 parts of tourmaline nano powder, nothing
10 ~ 20 parts of water-ethanol, 30 ~ 50 parts of diisopropyl ether, 10 ~ 20 parts of bio oil, 5 ~ 10 parts of antioxidant, 5 ~ 10 parts of dispersant, water 5 ~
30 parts.
2. fuel oil additive as claimed in claim 1, it is characterised in that：Described antioxidant is the pungent primary alkyl zinc of sulphur phosphorus fourth
The double pungent primary alkyl zinc salts of salt, sulphur phosphorus, alkali formula sulphur phosphorus double pungent primary alkyl zinc salt, the pungent secondary primary alkyl zinc salt of sulphur phosphorus third, sulphur phosphorus brothers alkane
One or more than one kinds of mixing in base zinc salt.
3. fuel oil additive as claimed in claim 1, it is characterised in that：Described dispersant is low alkali value synthesis of alkyl benzene sulphur
Sour calcium, high base number linear alkyl benzene calcium alkylbenzenesulfonate, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dioxane
Base benzene sulfonic acid calcium, long-chain linear alkyl benzene high base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutenyl succinyl
Imines, boronation polyisobutylene succinamide, high molecular weight polyisobutylene base succimide, boronation high-molecular-weight poly isobutyl
One or more kinds of mixing in alkenyl succimide.
4. fuel oil additive as claimed in claim 1, it is characterised in that：The water is pure water or mineral water.
5. fuel oil additive as claimed in claim 1, it is characterised in that：Its preparation method is at normal temperatures and pressures, by described in
Tourmaline nano powder, absolute ethyl alcohol, diisopropyl ether, bio oil, antioxidant, dispersant, water mixed by weight ratio,
Stir, produce.
6. fuel oil additive as claimed in claim 5, it is characterised in that：Described mixing speed is 8000 ~ 12000r/min,
10 ~ 90min of mixing time.
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| CN106147209A (en) * | 2016-06-30 | 2016-11-23 | 蔡华君 | Method that automobile energy-saving reduces discharging and the object of use and preparation method |
| CN106281489A (en) * | 2016-08-17 | 2017-01-04 | 丘寿勇 | A kind of diesel fuel additives |
| CN106281498A (en) * | 2016-08-18 | 2017-01-04 | 钟磊 | A kind of gasoline additive |
| CN108611135A (en) * | 2018-04-17 | 2018-10-02 | 吉林市石化成润化工助剂有限公司 | A kind of compound antioxygen scale inhibition anti-coagulants |
| CN109609215A (en) * | 2019-01-04 | 2019-04-12 | 顺德职业技术学院 | A kind of diesel motor exhaust purification additive and manufacturing method |
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| GB2438262A (en) * | 2006-05-13 | 2007-11-21 | John William Carson | Reagent for surface calcination of minerals and ashes |
| CN100545245C (en) * | 2007-03-15 | 2009-09-30 | 暨南大学 | A kind of composite gasoline additive and preparation method thereof |
| CN101560419A (en) * | 2008-04-19 | 2009-10-21 | 罗琮贵 | Energy-saving and emission-reduction tourmaline additive |
| CN104232184A (en) * | 2008-04-19 | 2014-12-24 | 罗琮贵 | Tourmaline additive for saving energy and reducing emission |
| CN103980964B (en) * | 2014-04-21 | 2016-08-24 | 丘寿勇 | A kind of preparation method of tourmaline fuel activating agent |
| CN104031722B (en) * | 2014-05-22 | 2016-04-13 | 丘寿勇 | A kind of lubricating oil |
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Effective date of registration: 20171023 Address after: Pass the street 537700 Guangxi Lu Chuan County town of hot springs No. 23 Applicant after: Qiu Haowei Address before: Lu Chuan County, the Guangxi Zhuang Autonomous Region City, Yulin Office of 537700 Street No. 23 Applicant before: Qiu Haowei Applicant before: Qiu Shouyong Applicant before: Qiu Fuquan |
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Application publication date: 20160203 Assignee: Guangxi express Fuel Technology Co., Ltd. Assignor: Qiu Haowei Contract record no.: 2018450000021 Denomination of invention: Fuel oil additive and its preparation Granted publication date: 20171124 License type: Common License Record date: 20180511 |