CN102676249B - High-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel and preparation method thereof - Google Patents
High-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel and preparation method thereof Download PDFInfo
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- CN102676249B CN102676249B CN201210181831.4A CN201210181831A CN102676249B CN 102676249 B CN102676249 B CN 102676249B CN 201210181831 A CN201210181831 A CN 201210181831A CN 102676249 B CN102676249 B CN 102676249B
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Abstract
High-efficiency environment friendly energy-conservation emulsifying agent of the present invention open heavy oil, diesel oil or oil fuel and preparation method thereof, wherein emulsifying agent comprises the agent of A group and the agent of B group that weight ratio is 1:0.67-3; Preparation method is: by the agent of A group and the agent of B group by proportioning stirring reaction 30-90min uniformly solution at 40-80 DEG C, obtain the high-efficiency environment friendly energy-conservation agent of described heavy oil, diesel oil or oil fuel.The high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil of the present invention, diesel oil or oil fuel for emulsifying agent, also comprises composite catalyzing ignition dope with multiple nonionic surface active agent, makes the emulsifying capacity of the emulsifying agent of synthesis strong.Emulsifying agent of the present invention effectively can carry out emulsification to heavy oil, diesel oil or oil fuel, makes the heavy oil after emulsification, diesel oil or oil fuel can more active combustion, after heavy oil adopts emulsifier of the present invention, can fuel-economizing 25%-35%, and reduce SO
2discharge more than 80%, store and there will not be oily water separation in more than 1 year, performance is highly stable.
Description
Technical field
The present invention relates to emulsifying agent, particularly relate to high-efficiency environment friendly energy-conservation emulsifying agent in a kind of heavy oil, diesel oil or oil fuel and preparation method thereof.
Background technology
Heavy oil is a kind of important fuel, generally all use heavy oil as fuel in many places such as refinery, chemical plant, steelworks and power station, but, because heavy oil is oil deep processing surplus materials, no matter adopt the combustion equipment of which kind of high heat effect, direct combusting heavy oil, inevitably cause combustion reactions incomplete, form black smoke, coking and carbon deposit, cause fuel to waste in a large number, also bring the problem of environmental pollution simultaneously.Generally for guarantee sufficient combustion, need excess air be injected, and heat has been taken away in the discharge of these excess airs, caused calorific loss.
Generally at present will carry out after heavy oil emulsive burning to solve the problem, but also do not have and a kind ofly effectively can make the heavy oil active combustion after emulsification, simultaneously can also the emulsifying agent of environmental emission reduction.
Summary of the invention
In order to overcome the deficiencies in the prior art, the object of the present invention is to provide a kind of stable performance, the efficient synthesis of heavy oil of energy, also there is high-efficiency environment friendly energy-conservation emulsifying agent in the heavy oil of effects of energy conservation and environmental protection, diesel oil or oil fuel and preparation method thereof.
Technical scheme of the present invention is: the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel, and it comprises the agent of A group and the agent of B group that weight ratio is 1:0.67-3, and wherein, component and the ratio of weight and number thereof of the agent of A group are:
Sulfomethylated humic acid sodium 0.5-10 part;
Caustic soda 0.5-10 part;
Whiteruss 10-30 part;
Synolac 0.5-30 part;
Alum 0.5-10 part;
Stearic acid 0.5-10 part;
SODIUMNITRATE 0.5-10 part;
Petroleum sodium sulfonate 0.5-10 part;
Saltpetre 0.5-10 part;
Glycerol 0.5-10 part;
Ammoniumper chlorate 10-40 part;
Component and the ratio of weight and number thereof of the agent of B group are:
Cobalt naphthenate 1-30 part;
Calcium naphthenate 1-30 part;
Iron naphthenate 1-30 part;
Manganese naphthenate 1-30 part;
Magnesium naphthenate 1-30 part;
Phthalic anhydride 1-30 part;
Dibasic alcohol 1-30 part;
Quadrol 10-50 part;
Solvent oil 10-50 part.
Preferably, the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil of the present invention, diesel oil or oil fuel, it comprises the agent of A group and the agent of B group that weight ratio is 1:2-3, and wherein, component and the ratio of weight and number thereof of the agent of A group are:
Sulfomethylated humic acid sodium 4-8 part;
Caustic soda 3-7 part;
Whiteruss 15-25 part;
Synolac 15-20 part;
Alum 2-8 part;
Stearic acid 4-6 part;
SODIUMNITRATE 3-7 part;
Petroleum sodium sulfonate 4-7 part;
Saltpetre 3-6 part;
Glycerol 4-8 part;
Ammoniumper chlorate 15-30 part;
Component and the ratio of weight and number thereof of the agent of B group are:
Cobalt naphthenate 10-25 part;
Calcium naphthenate 15-25 part;
Iron naphthenate 10-20 part;
Manganese naphthenate 15-25 part;
Magnesium naphthenate 20-25 part;
Phthalic anhydride 15-25 part;
Dibasic alcohol 15-25 part;
Quadrol 20-40 part;
Solvent oil 20-35 part.
Dibasic alcohol in the agent of described B group is propylene glycol or ethylene glycol.
Solvent oil in the agent of described B group is diesel oil, kerosene or ethanol.
In the present invention, because of the naphthenic compound in the agent of employing B group and suitable charge ratio, have the effect of catalytic combustion-supporting, thus make emulsifying agent of the present invention by after heavy oil emulsive, the discharge of heavy oil combustion greatly reduces, SO
2discharge can reduce more than 80%.
The emulsifying agent such as stearic acid, phthalic anhydride is adopted in the present invention, and reasonable ratio, emulsifying agent of the present invention is made to have very strong emulsifying capacity, heavy oil is when emulsification, the ratio of heavy oil and water can reach 1:1, heavy oil after emulsification is the molecular structure of water-in-oil-type, and the heavy oil after emulsification stores and there will not be oily water separation, stable performance in more than 1 year.
The preparation method of the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil of the present invention, diesel oil or oil fuel is: by the agent of A group and the agent of B group by proportioning stirring reaction 30-90min uniformly solution at 40-80 DEG C, obtain the high-efficiency environment friendly energy-conservation agent of described heavy oil, diesel oil or oil fuel.
Emulsifying agent of the present invention not only can be applicable to emulsification heavy oil, can also be applied to diesel oil emulsification or oil fuel simultaneously.
The high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil of the present invention, diesel oil or oil fuel is made up of multiple compounds compound, with multiple nonionic surface active agent for emulsifying agent, also comprises composite catalyzing ignition dope, makes the emulsifying capacity of the emulsifying agent of synthesis strong.Emulsifying agent of the present invention effectively can carry out emulsification to heavy oil, diesel oil or oil fuel, makes the heavy oil after emulsification, diesel oil or oil fuel can more active combustion, after heavy oil adopts emulsifier of the present invention, can fuel-economizing 25%-35%, and reduce SO
2discharge more than 80%, flue gas reduces 45-85%, and store and there will not be oily water separation in more than 1 year, performance is highly stable.
Embodiment
Below in conjunction with embodiment, the present invention is further detailed explanation.
Technical scheme of the present invention is: the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel, and it comprises the agent of A group and the agent of B group that weight ratio is 1:0.67-3, and wherein, component and the ratio of weight and number thereof of the agent of A group are:
Sulfomethylated humic acid sodium 0.5-10 part;
Caustic soda 0.5-10 part;
Whiteruss 10-30 part;
Synolac 0.5-30 part;
Alum 0.5-10 part;
Stearic acid 0.5-10 part;
SODIUMNITRATE 0.5-10 part;
Petroleum sodium sulfonate 0.5-10 part;
Saltpetre 0.5-10 part;
Glycerol 0.5-10 part;
Ammoniumper chlorate 10-40 part;
Component and the ratio of weight and number thereof of the agent of B group are:
Cobalt naphthenate 1-30 part;
Calcium naphthenate 1-30 part;
Iron naphthenate 1-30 part;
Manganese naphthenate 1-30 part;
Magnesium naphthenate 1-30 part;
Phthalic anhydride 1-30 part;
Propylene glycol 1-30 part;
Quadrol 10-50 part;
Solvent oil 10-50 part.
The preparation method of the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil of the present invention, diesel oil or oil fuel is: by the agent of A group and the agent of B group by proportioning stirring reaction 30-90min uniformly solution at 40-80 DEG C, obtain the high-efficiency environment friendly energy-conservation agent of described heavy oil, diesel oil or oil fuel.
Embodiment 1 prepared by emulsifying agent
The preparation method of the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel is:
1) first take the agent of A group and the agent of B group by weight 1:0.67, wherein, component and the weight thereof of the agent of A group are:
Sulfomethylated humic acid sodium 0.5kg;
Caustic soda 10kg;
Whiteruss 10kg part;
Synolac 0.5kg;
Alum 10kg;
Stearic acid 0.5kg;
SODIUMNITRATE 10kg;
Petroleum sodium sulfonate 0.5kg;
Saltpetre 10kg;
Glycerol 0.5kg;
Ammoniumper chlorate 40kg;
Component and the weight thereof of the agent of B group are:
Cobalt naphthenate 0.4kg;
Calcium naphthenate 12kg;
Iron naphthenate 0.4kg;
Manganese naphthenate 12kg;
Magnesium naphthenate 0.4kg;
Phthalic anhydride 12kg;
Dibasic alcohol 0.4kg;
Quadrol 20kg;
Diesel oil 4kg.
2) at 40 DEG C, by each component mix and blend reaction 90min uniformly solution in the agent of A group and the agent of B group, the high-efficiency environment friendly energy-conservation agent of described heavy oil, diesel oil or oil fuel is obtained.
Embodiment 2 prepared by emulsifying agent
The preparation method of the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel is:
1) first take the agent of A group and the agent of B group by weight 1:3, wherein, component and the weight thereof of the agent of A group are:
Sulfomethylated humic acid sodium 10kg;
Caustic soda 0.5kg;
Whiteruss 30kg;
Synolac 30kg;
Alum 0.5kg;
Stearic acid 10kg;
SODIUMNITRATE 0.5kg;
Petroleum sodium sulfonate 10kg;
Saltpetre 0.5kg;
Glycerol 10kg;
Ammoniumper chlorate 10kg;
Component and the weight thereof of the agent of B group are:
Cobalt naphthenate 55kg;
Calcium naphthenate 1.8kg;
Iron naphthenate 55kg;
Manganese naphthenate 1.8kg;
Magnesium naphthenate 55kg;
Phthalic anhydride 1.8kg;
Ethylene glycol 55kg;
Quadrol 18kg;
Kerosene 91.8kg.
2) at 80 DEG C, by each component mix and blend reaction 30min uniformly solution in the agent of A group and the agent of B group, the high-efficiency environment friendly energy-conservation agent of described heavy oil, diesel oil or oil fuel is obtained.
Embodiment 3 prepared by emulsifying agent
The preparation method of the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel is:
1) first take the agent of A group and the agent of B group by weight 1:2, wherein, component and the weight thereof of the agent of A group are:
Sulfomethylated humic acid sodium 4kg;
Caustic soda 7kg;
Whiteruss 15kg;
Synolac 20kg;
Alum 2kg;
Stearic acid 6kg;
SODIUMNITRATE 3kg;
Petroleum sodium sulfonate 7kg;
Saltpetre 3kg;
Glycerol 8kg;
Ammoniumper chlorate 15kg;
Component and the weight thereof of the agent of B group are:
Cobalt naphthenate 9.5kg;
Calcium naphthenate 23.7kg;
Iron naphthenate 9.5kg;
Manganese naphthenate 23.7kg;
Magnesium naphthenate 19kg;
Phthalic anhydride 23.7kg;
Propylene glycol 14.3kg;
Quadrol 38kg;
Ethanol 19kg.
2) at 60 DEG C, by each component mix and blend reaction 60min uniformly solution in the agent of A group and the agent of B group, the high-efficiency environment friendly energy-conservation agent of described heavy oil, diesel oil or oil fuel is obtained.
Embodiment 4 prepared by emulsifying agent
The preparation method of the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel is:
1) first take the agent of A group and the agent of B group by weight 1:3, wherein, component and the weight thereof of the agent of A group are:
Sulfomethylated humic acid sodium 8kg;
Caustic soda 3kg;
Whiteruss 25kg;
Synolac 15kg;
Alum 8kg;
Stearic acid 4kg;
SODIUMNITRATE 7kg;
Petroleum sodium sulfonate 4kg;
Saltpetre 6kg;
Glycerol 4kg;
Ammoniumper chlorate 30kg;
Component and the weight thereof of the agent of B group are:
Cobalt naphthenate 43.8kg;
Calcium naphthenate 26.3kg;
Iron naphthenate 35kg;
Manganese naphthenate 26.3kg;
Magnesium naphthenate 43.8kg;
Phthalic anhydride 26.3kg;
Ethylene glycol 43.8kg;
Quadrol 35kg;
Diesel oil 61.3kg.
2) at 50 DEG C, by each component mix and blend reaction 70min uniformly solution in the agent of A group and the agent of B group, the high-efficiency environment friendly energy-conservation agent of described heavy oil, diesel oil or oil fuel is obtained.
Application Example 1
Get 540kg heavy oil, be heated to 80 DEG C stir, then add the emulsifying agent that 10kg emulsifying agent prepares the preparation in embodiment 3, through high-speed stirring 5-15min, namely the water mixing and stirring adding 450kg90 DEG C again becomes high-efficiency environment friendly energy-conservation oil in water emulsion, leaves standstill after 24 hours and uses.
Application Example 2
Get 740kg diesel oil, be heated to 80 DEG C stir, then add the emulsifying agent that 10kg emulsifying agent prepares the preparation in embodiment 1, through high-speed stirring 5-15min, namely the water mixing and stirring adding 250kg90 DEG C again becomes high-efficiency environment friendly energy-conservation oil in water emulsion, leaves standstill after 24 hours and uses.
Application Example 3
Get 630kg oil fuel, be heated to 80 DEG C stir, then add the emulsifying agent that 10kg emulsifying agent prepares the preparation in embodiment 4, through high-speed stirring 5-15min, namely the water mixing and stirring adding 360kg90 DEG C again becomes high-efficiency environment friendly energy-conservation oil in water emulsion, leaves standstill after 24 hours and uses.
Claims (3)
1. the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel, is characterized in that: it comprises the agent of A group and the agent of B group that weight ratio is 1:0.67-3, and wherein, component and the ratio of weight and number thereof of the agent of A group are:
Sulfomethylated humic acid sodium 0.5-10 part;
Caustic soda 0.5-10 part;
Whiteruss 10-30 part;
Synolac 0.5-30 part;
Alum 0.5-10 part;
Stearic acid 0.5-10 part;
SODIUMNITRATE 0.5-10 part;
Petroleum sodium sulfonate 0.5-10 part;
Saltpetre 0.5-10 part;
Glycerol 0.5-10 part;
Ammoniumper chlorate 10-40 part;
Component and the ratio of weight and number thereof of the agent of B group are:
Cobalt naphthenate 1-30 part;
Calcium naphthenate 1-30 part;
Iron naphthenate 1-30 part;
Manganese naphthenate 1-30 part;
Magnesium naphthenate 1-30 part;
Phthalic anhydride 1-30 part;
Dibasic alcohol 1-30 part;
Quadrol 10-50 part;
Solvent oil 10-50 part;
Dibasic alcohol in the agent of described B group is propylene glycol or ethylene glycol;
Solvent oil in the agent of described B group is diesel oil or kerosene.
2. the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil according to claim 1, diesel oil or oil fuel, is characterized in that: it comprises the agent of A group and the agent of B group that weight ratio is 1:2-3, and wherein, component and the ratio of weight and number thereof of the agent of A group are:
Sulfomethylated humic acid sodium 4-8 part;
Caustic soda 3-7 part;
Whiteruss 15-25 part;
Synolac 15-20 part;
Alum 2-8 part;
Stearic acid 4-6 part;
SODIUMNITRATE 3-7 part;
Petroleum sodium sulfonate 4-7 part;
Saltpetre 3-6 part;
Glycerol 4-8 part;
Ammoniumper chlorate 15-30 part;
Component and the ratio of weight and number thereof of the agent of B group are:
Cobalt naphthenate 10-25 part;
Calcium naphthenate 15-25 part;
Iron naphthenate 10-20 part;
Manganese naphthenate 15-25 part;
Magnesium naphthenate 20-25 part;
Phthalic anhydride 15-25 part;
Dibasic alcohol 15-25 part;
Quadrol 20-40 part;
Solvent oil 20-35 part.
3. the preparation method of the high-efficiency environment friendly energy-conservation emulsifying agent of heavy oil according to claim 1 and 2, diesel oil or oil fuel, it is characterized in that: described preparation method is: by the agent of A group and the agent of B group by proportioning stirring reaction 30-90min uniformly solution at 40-80 DEG C, obtain the high-efficiency environment friendly energy-conservation agent of described heavy oil, diesel oil or oil fuel.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210181831.4A CN102676249B (en) | 2012-06-05 | 2012-06-05 | High-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel and preparation method thereof |
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| CN201210181831.4A CN102676249B (en) | 2012-06-05 | 2012-06-05 | High-efficiency environment friendly energy-conservation emulsifying agent of heavy oil, diesel oil or oil fuel and preparation method thereof |
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| CN102676249A CN102676249A (en) | 2012-09-19 |
| CN102676249B true CN102676249B (en) | 2016-04-13 |
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| CN103071425A (en) * | 2012-12-14 | 2013-05-01 | 江苏省海安石油化工厂 | Emulsifier |
| CN104479773B (en) * | 2014-11-14 | 2015-12-30 | 山东永泰化工有限公司 | A kind of heavy-oil emulsifying agent and preparation method thereof |
| CN105435841A (en) * | 2015-11-18 | 2016-03-30 | 苏同兴 | Water phase change catalyst and preparation method thereof |
| CN108277052B (en) * | 2016-03-24 | 2019-10-25 | 珠海市三悦石油化工有限公司 | A kind of heavy oil, diesel oil in alcohol group compound emulsifying agent preparation method |
| CN108485735B (en) * | 2016-03-24 | 2019-11-22 | 杭州鼎好新材料有限公司 | A kind of compound emulsifying agent of heavy oil, diesel oil in alcohol group |
| CN105802684B (en) * | 2016-03-24 | 2018-05-04 | 温州极电电子科技有限公司 | A kind of preparation method of environmental protection fuel oil compound emulsifying agent |
| CN108219875A (en) * | 2016-03-24 | 2018-06-29 | 金华知产婺源信息技术有限公司 | A kind of environmental protection fuel oil compound emulsifying agent |
| CN106520229B (en) * | 2016-11-10 | 2018-07-27 | 黑龙江省能源环境研究院 | Composite emulsifying additive for heavy oil and preparation method thereof |
| CN114231325A (en) * | 2021-12-01 | 2022-03-25 | 易信三农(沈阳)石化有限公司 | Preparation and application of new energy multifunctional emulsifier |
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| CN1091769A (en) * | 1994-01-25 | 1994-09-07 | 孙勇 | Efficient diesel or additive for heavy oil |
| CN1107503A (en) * | 1994-12-26 | 1995-08-30 | 黄行声 | Emulsified fuel by blending water with heavy oil- double-base heavy oil |
| CN1153203A (en) * | 1995-12-08 | 1997-07-02 | 刘志强 | Fuel oil emulsifying agent |
| CN1155448A (en) * | 1996-01-24 | 1997-07-30 | 朴万成 | Emulsifier for heavy oil |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1091769A (en) * | 1994-01-25 | 1994-09-07 | 孙勇 | Efficient diesel or additive for heavy oil |
| CN1107503A (en) * | 1994-12-26 | 1995-08-30 | 黄行声 | Emulsified fuel by blending water with heavy oil- double-base heavy oil |
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| CN1155448A (en) * | 1996-01-24 | 1997-07-30 | 朴万成 | Emulsifier for heavy oil |
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