CN107384492A - Anti- haze environmental protection diesel oil combustion improver - Google Patents

Anti- haze environmental protection diesel oil combustion improver Download PDF

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Publication number
CN107384492A
CN107384492A CN201710743182.5A CN201710743182A CN107384492A CN 107384492 A CN107384492 A CN 107384492A CN 201710743182 A CN201710743182 A CN 201710743182A CN 107384492 A CN107384492 A CN 107384492A
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China
Prior art keywords
diesel oil
environmental protection
combustion improver
oil combustion
haze environmental
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CN201710743182.5A
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Chinese (zh)
Inventor
韩建鹏
韩凯
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Qingdao Yongquan Petroleum Co Ltd
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Qingdao Yongquan Petroleum Co Ltd
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Priority to CN201710743182.5A priority Critical patent/CN107384492A/en
Publication of CN107384492A publication Critical patent/CN107384492A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/1802Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • C10L1/1881Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines
    • C10L2270/026Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The present invention proposes a kind of anti-haze environmental protection diesel oil combustion improver, is calculated according to percetage by weight, including following components:O-dinitrobenzene 5~10%, Alkyl nitrate 10~30%, rosin 3~8%, glycerine 4~8%, oleate 5~10%, isooctyl acid potassium 15~30% and organic solvent 20~50%.The diesel oil combustion improver effectively can fully burn each component in diesel oil, and waste gas discharge reduces more than 90%, realizes the ideal effect for controlling haze environmental protection and energy saving.

Description

Anti- haze environmental protection diesel oil combustion improver
Technical field
The invention belongs to diesel fuel additives technical field, and in particular to a kind of anti-haze environmental protection diesel oil combustion improver.
Background technology
The combustion process of diesel engine combustion mixture is an extremely complex physics and chemical process.Diesel oil is inhaled into gas After cylinder, it is impossible to burn immediately, it is necessary to be atomized, absorbed heat by the regular hour, evaporated, spread, mixed with air, decomposed And the set-up procedure such as slow oxidation, until the gaseous mixture and temperature conditionss that form debita spissitudo could spontaneous combustions.Simultaneously because bavin Complexity construction inside oil machine, causes the gaseous mixture composition in diesel engine cylinder to be differed in different time and diverse location Property.Due to the complexity, diversity, randomness of burning, to make diesel oil completely burned is unpractical, the energy of diesel combustion release Amount is also impossible to be fully used, while is exactly these harmful exhausts inevitably along with the appearance of side reaction product Pollutant causes environmental pollution.
Diesel oil combustion improver is that diesel combustion improves additive, and its purpose is to improve the combustion efficiency and heat of diesel oil Efficiency, reduce the consumption of diesel oil, reduce environmental pollution.In terms of the research and development of combustion promoter for diesel oil, foreign countries five, the sixties grind The serial combustion adjuvants such as work(hyperalkaline calcium mahogany sulfonate, hyperalkaline barium mahogany sulfonate are made.The main purpose of these additives is The discharge of visible particle thing is reduced, the numerical value of smoke intensity is reduced, is alternatively arranged as antismoke agent and uses.
With the raising of discharge standard and the enhancing of environmental consciousness, reduce invisible matter and also paid attention to.External phase again After proposing ferrocene, but because ferrocene contains iron and manganese Metal and addition is bigger, metallic iron and manganese are made to environment Cyclopentadienyl compounds and the vulcanization of manganese are added in the fuel that engine uses into pollution, such as United States Patent (USP) 3883320 Alkyl calcium improves combustibility, but because manganese can increase the deposition of sulphur, so as to add the friction of cylinder, United States Patent (USP) 4474580 propose to prepare required combustion adjuvant using the oxygenatedchemicals and methanol of cerium and iron and the solvent of isopropanol, But because its preparation means is complicated, so being not suitable for commercial Application.These current additives can not meet that environment is protected The requirement of shield, anti-haze environmental protection diesel oil combustion improver are the substitute products of diesel antiwear additive, save substantial amounts of petroleum resources.
The content of the invention
The present invention proposes a kind of anti-haze environmental protection diesel oil combustion improver, and the diesel oil combustion improver can be effectively in diesel oil Each component fully burns, and waste gas discharge reduces more than 90%, realizes the ideal effect for controlling haze environmental protection and energy saving.
The technical proposal of the invention is realized in this way:
A kind of anti-haze environmental protection diesel oil combustion improver, is calculated according to percetage by weight, including following components:
O-dinitrobenzene 5~10%, Alkyl nitrate 10~30%, rosin 3~8%, glycerine 4~8%, oleate 5~ 10%th, isooctyl acid potassium 15~30% and organic solvent 20~50%.
Preferably, the organic solvent is the petroleum cuts that benzene, toluene, petroleum ether or boiling range are 140~390 DEG C.
Preferably, calculated according to percetage by weight, including following components:
O-dinitrobenzene 5%, Alkyl nitrate 10%, rosin 8%, glycerine 8%, oleate 10%, isooctyl acid potassium 15% And organic solvent 44%.
Preferably, calculated according to percetage by weight, including following components:
O-dinitrobenzene 8%, Alkyl nitrate 22%, rosin 5%, glycerine 4%, oleate 5%, isooctyl acid potassium 20% with And organic solvent 36%.
Preferably, calculated according to percetage by weight, including following components:
O-dinitrobenzene 10%, Alkyl nitrate 26%, rosin 3%, glycerine 5%, oleate 8%, isooctyl acid potassium 28% And organic solvent 20%.
The preparation method of the anti-haze environmental protection diesel oil combustion improver of the present invention:
Said components are weighed according to proportioning and are well mixed.
Beneficial effects of the present invention:
The anti-haze environmental protection diesel oil combustion improver of the present invention can effectively reduce diesel combustion pollutant, be added to diesel oil Middle use can improve efficiency of combustion, reduce the discharge capacity of pollutant, effectively reduce the discharge such as carbon monoxide, hydrocarbon, subtract Few haze is produced, and diesel oil-saving rate reaches more than 20%-30%, and 5~8 lists of Cetane number are improved by 0.33/1000th additions Position.
The anti-haze environmental protection diesel oil combustion improver of the present invention does not contain manganese and iron, and increasing service life of engine 200,000 is public In more than.
Embodiment
Embodiment 1
A kind of anti-haze environmental protection diesel oil combustion improver, including following components:
O-dinitrobenzene 5kg, Alkyl nitrate 10kg, rosin 8kg, glycerine 8kg, oleate 10kg, isooctyl acid potassium 15kg And petroleum ether 44kg.
Preparation method:Said components are weighed according to proportioning and are well mixed.
Embodiment 2
A kind of anti-haze environmental protection diesel oil combustion improver, including following components:
O-dinitrobenzene 8kg, Alkyl nitrate 22kg, rosin 5kg, glycerine 4kg, oleate 5kg, isooctyl acid potassium 20kg with And No. 90 gasoline 36kg.
Preparation method:Said components are weighed according to proportioning and are well mixed.
Embodiment 3
A kind of anti-haze environmental protection diesel oil combustion improver, including following components:
O-dinitrobenzene 10kg, Alkyl nitrate 26kg, rosin 3kg, glycerine 5kg, oleate 8kg, isooctyl acid potassium 28kg And toluene 20kg.
Preparation method:Said components are weighed according to proportioning and are well mixed.
Embodiment 4
A kind of anti-haze environmental protection diesel oil combustion improver, including following components:
O-dinitrobenzene 6kg, Alkyl nitrate 20kg, rosin 5kg, glycerine 5kg, oleate 6kg, isooctyl acid potassium 25kg with And toluene 33kg.
Preparation method:Said components are weighed according to proportioning and are well mixed.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.

Claims (5)

  1. A kind of 1. anti-haze environmental protection diesel oil combustion improver, it is characterised in that calculated according to percetage by weight, including following components:
    O-dinitrobenzene 5~10%, Alkyl nitrate 10~30%, rosin 3~8%, glycerine 4~8%, oleate 5~10%, Isooctyl acid potassium 15~30% and organic solvent 20~50%.
  2. 2. anti-haze environmental protection diesel oil combustion improver according to claim 1, it is characterised in that the organic solvent be benzene, Toluene, petroleum ether or boiling range are 140~390 DEG C of petroleum cuts.
  3. 3. anti-haze environmental protection diesel oil combustion improver according to claim 1, it is characterised in that according to percent by weight Calculate, including following components:
    O-dinitrobenzene 5%, Alkyl nitrate 10%, rosin 8%, glycerine 8%, oleate 10%, isooctyl acid potassium 15% and Organic solvent 44%.
  4. 4. anti-haze environmental protection diesel oil combustion improver according to claim 1, it is characterised in that according to percent by weight Calculate, including following components:
    O-dinitrobenzene 8%, Alkyl nitrate 22%, rosin 5%, glycerine 4%, oleate 5%, isooctyl acid potassium 20% and have Solvent 36%.
  5. 5. anti-haze environmental protection diesel oil combustion improver according to claim 1, it is characterised in that according to percent by weight Calculate, including following components:
    O-dinitrobenzene 10%, Alkyl nitrate 26%, rosin 3%, glycerine 5%, oleate 8%, isooctyl acid potassium 28% and Organic solvent 20%.
CN201710743182.5A 2017-08-25 2017-08-25 Anti- haze environmental protection diesel oil combustion improver Pending CN107384492A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710743182.5A CN107384492A (en) 2017-08-25 2017-08-25 Anti- haze environmental protection diesel oil combustion improver

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Application Number Priority Date Filing Date Title
CN201710743182.5A CN107384492A (en) 2017-08-25 2017-08-25 Anti- haze environmental protection diesel oil combustion improver

Publications (1)

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CN107384492A true CN107384492A (en) 2017-11-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115707762A (en) * 2021-08-19 2023-02-21 陈文祥 Improved pastille for internal combustion engine oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1766066A (en) * 2005-11-16 2006-05-03 中国石油化工集团公司 Diesel fuel additive and its uses
CN101870892A (en) * 2009-11-20 2010-10-27 济南开发区星火科学技术研究院 Diesel oil combustion improver and preparation method thereof
CN104212503A (en) * 2013-05-31 2014-12-17 湖北航天化学技术研究所 Diesel oil additive

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1766066A (en) * 2005-11-16 2006-05-03 中国石油化工集团公司 Diesel fuel additive and its uses
CN101870892A (en) * 2009-11-20 2010-10-27 济南开发区星火科学技术研究院 Diesel oil combustion improver and preparation method thereof
CN104212503A (en) * 2013-05-31 2014-12-17 湖北航天化学技术研究所 Diesel oil additive

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115707762A (en) * 2021-08-19 2023-02-21 陈文祥 Improved pastille for internal combustion engine oil

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Application publication date: 20171124