CN115707762A - Improved pastille for internal combustion engine oil - Google Patents

Improved pastille for internal combustion engine oil Download PDF

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CN115707762A
CN115707762A CN202110953138.3A CN202110953138A CN115707762A CN 115707762 A CN115707762 A CN 115707762A CN 202110953138 A CN202110953138 A CN 202110953138A CN 115707762 A CN115707762 A CN 115707762A
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oil
rosin
agent
acid
organic
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陈文祥
黄清耀
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Abstract

The invention discloses a lozenge for improving internal combustion engine oil, which comprises, by weight, 20-40% of n-hexadecyl palmitate, 5% of lauric acid, 10-20% of rosin, 10-15% of stearic acid, 20-50% of arrowketone, 4% of borneol and 1% of titanium dioxide, wherein the n-hexadecyl palmitate is a combustion improver and is 20-40%, the lauric acid is a lubricant and a cleaning agent and is 5%, the rosin is a dispersant and a catalyst are 10-20%, the stearic acid is an organic fatty acid and is a synthetic ester and is 10-15%, the arrowketone is an organic ester subliming agent and is 20-50%, the borneol is an organic volatile agent and is a titanium dioxide toxic substance decomposer and is 1%. The invention has stable composition substances, easy acquisition, safety and no toxicity, does not generate secondary pollution, can improve the combustion efficiency of gasoline and diesel oil, increase heat energy and save fuel by more than 15 percent, and can achieve the effect when trace amount of the invention is added.

Description

Improved pastille for internal combustion engine oil
Technical Field
The invention relates to an internal combustion engine oil product improvement pastille, in particular to an environment-friendly and energy-saving formula, which is prepared in a dry pastille state, is different from dangerous liquid olein, is convenient, stable and good in storage, is used for improving the combustion property of gasoline and diesel oil, and meets the requirements of better economy and cleaner environment-friendly performance.
Background
The traditional commercially available pastilles are prepared from chemical synthesis agents such as a surfactant and the like as main agents for the purpose of improving octane number and activity, most of the chemical synthesis agents have unknown components and certain toxicity or corrosiveness, and before the chemical synthesis agents are not effective, equipment such as engines (engines) and the like are probably damaged, and nitrate phosphoric acid or ferrocene and metallic iron ions, \ 8230 \ 8230, and carriers used by the chemical synthesis agents are not completely compatible with fuels such as gasoline, diesel oil and the like. For example, as ferrocene is added into the formula of the fuel-saving pig of the invention patent publication No. CN 103074127B in China, and the main function of ferrocene is to be used as a rocket fast-burning agent, although ferrocene is a good octane number improver, iron oxide is generated after combustion and is attached to the engine chamber, so that the temperature of the engine chamber wall is rapidly increased and exceeds the design value, the heat dissipation is not timely, the interior of the engine is easily damaged, the oil circuit or the nozzle is blocked, the generated iron ions are difficult to remove, the engine runs unsmoothly, and the addition of metal ions such as iron is strictly forbidden in the finished oil standards specified by various countries. Therefore, the addition of ferrocene to the formula of the fuel-saving ingot of the Chinese patent No. CN 103074127B has various disadvantages.
Therefore, there is a need to develop a tablet for improving the oil quality of an internal combustion engine, which can achieve the purposes of high strength, fuel saving and pollution reduction, so as to solve the problems in the prior art.
Disclosure of Invention
The present invention provides a high-grade pastille for internal combustion engine gasoline and diesel oil with improved formula for achieving the purposes of strong force, oil saving and pollution reduction, organic components are mixed and then made into pastille, each pastille is about 2-3 g, the pastille is suitable for 40-50 liters of gasoline and diesel oil, and the pastille is an organic pure plant organic environment-friendly scientific and technological product which is substantially different from the traditional pastille (or additive) sold on the market.
According to the above purpose, the invention provides a lozenge for improving internal combustion engine oil, which comprises, by weight, 20-40% of n-hexadecyl palmitate, 5% of lauric acid, 10-20% of rosin, 10-15% of stearic acid, 20-50% of arrowroot ketone, 4% of borneol and 1% of titanium dioxide, wherein the n-hexadecyl palmitate is a combustion improver and is 20-40%, the lauric acid is a lubricant and a cleaning agent and is 5%, the rosin is a dispersant and a catalyst are 10-20%, the stearic acid is an organic fatty acid and is a synthetic ester and is 10-15%, the arrowroot ketone is an organic ester subliming agent and is an organic volatile agent and is 4%, and the titanium dioxide is a toxic substance decomposer and is 1%.
The invention can achieve the following characteristics through the technology:
the invention relates to an oil product improvement pastille for an internal combustion engine, which is a plant formula, is prepared from organic pure plants, is economical, practical, easy to obtain, safe and nontoxic, does not generate secondary pollution or damage an engine, can be completely compatible with gasoline and diesel after being added, is easy to dissolve quickly and does not generate any sediment.
Detailed Description
The purpose, technical content, features and efficacy of the present invention will be more readily understood by the following detailed description of the combination and use of the structures of the present invention with the accompanying drawings.
The invention provides a lozenge for improving internal combustion engine oil, which comprises, by weight, 20-40% of n-hexadecyl palmitate, 5% of lauric acid, 10-20% of rosin, 10-15% of stearic acid, 20-50% of arrowketone, 4% of borneol and 1% of titanium dioxide, wherein the n-hexadecyl palmitate is a combustion improver and accounts for 20-40%, the lauric acid is a lubricant and a detergent and accounts for 5%, the rosin is a dispersant and a catalyst and accounts for 10-20%, the stearic acid is an organic ester and accounts for 10-15% of a synthetic agent of synthetic ester, the arrowketone is a subliming agent of organic ester and accounts for 20-50%, the borneol is an organic volatile agent and the titanium dioxide is a toxic substance decomposer and accounts for 1%. The invention has stable composition substances, easy obtaining, safety and no toxicity, does not generate secondary pollution, can improve the combustion efficiency of gasoline and diesel oil, increase heat energy and save fuel by more than 15 percent, and can achieve the effect by adding a trace amount of the invention. For example: table one authoritative fixed point constant speed test results, wherein the unit of table one refers to weight percentage, and table two heavy duty forklift test data.
[ TABLE ] A
Figure BDA0003219319760000031
[ TABLE II ]
Test analysis of No. 36 gasoline forklift of factory
Figure BDA0003219319760000032
Test results
1. And when the surface of the stacking machine is lighted with red light, the oil is added until the barrel is full.
Oil was topped up 2.5/09 to 5/20 times (no sample was added) for a total run time of 52.3hr, average 17.4hr per barrel.
The oil (sample) is added in three times of 3.5/24-6/06, the total running time is 62.2hr, and the average time of each barrel is 20.7hr.
4. And (4) conclusion:
after the stacker added this sample, an average of 3.3hr more oil per barrel.
Therefore, the oil saving is fortunately 33hr/17.4hr =19%
5.6/17 of the last oiling is not added with the product, but the oil bottom has partial components, and the oil can be transported out for 19.8hr, which is hard to obtain.
The invention is an environment-friendly and energy-saving formula, is prepared in a dry pastille state, is different from dangerous liquid olein, is convenient, stable and good in storage, is used for improving the combustion property of gasoline and diesel oil, and meets better economical efficiency and cleaner environment-friendly performance. For example: table three emission test results.
[ TABLE III ]
Figure BDA0003219319760000041
And the octane number of the gasoline and the cetane number of the diesel oil are improved, and lubrication is increased to promote combustion. For example: table four SGs test data.
[ TABLE IV ]
And (3) testing results:
test items Unit of Test method Test results
Cetane index --- ASTM D976-06(2016) 53.6
Flash point ASTM D93-18 86.0
Density/15 deg.C g/mL ASTM D4052-18 0.8371
Sulfur ppm ASTM D5453-18 3.1
Copper corrosion (50 ℃,3 pairs) --- ASTM D130-18 1a
Viscosity/40 deg.C mm 2 /s ASTM D445-18 3.256
Lubricity (1.4 wsd60 ℃ C.) μm ASTM D6079-18 330
Polycyclic aromatic hydrocarbon content %(m/m) ASTM D6591-18 1.4
Remarks (1): mgkg = ppm:1wt% =10000ppm
Remarks (2): 1a: slight color change: light orange, almost the same as a freshly polished copper sheet.
The rosin is subjected to sublimation conversion by the arrowketone and the borneol, the molecules of the rosin can be rapidly divided into smaller molecules by the carbon close to fuel oil, the combustible surface area is multiplied, the molecular bond kinetic energy is increased, the rosin is easy to crack into smaller secondary free radicals in the combustion process, the opportunity of fully and uniformly mixing and combusting with oxygen can be increased, the flammability is greatly improved, and the complete combustion effect is achieved.
Lauric dodecanoic acid is used for corrosion resistance and other functions of the lubricant. Especially, lauric dodecanoic acid is the best substitute after lead-free desulfation of the finished oil.
In a closed combustion chamber, where increased flammability is required, the addition of a suitable ester is necessary. And the palmitic acid n-hexadecyl ester is solid and is easy to prepare into a finished product, so that the palmitic acid n-hexadecyl ester is the best choice.
Rosin is a good dispersant which is easy to volatilize and dissolve in gasoline and diesel oil, and the arrowketone is camphor formed after turpentine oil is sublimated, is most easy to sublimate and volatilize in fuel oil, and is easy to be made into pastilles. The rosin oil is sublimated into camphor to form organic acid, and then the ester of the camphor and the stearic acid (fatty acid) is easily formed into ester, so that the optimal combustion improver for the internal combustion engine is obtained.
Stearic acid is widely present in animal and vegetable fats and oils, and belongs to saturated fatty acids. Their advantages are low cost, high detergency and saving oil.
Titanium dioxide is an inorganic component, has excellent chemical stability, and can obviously decompose nitrogen oxides, aromatic hydrocarbons and aldehydes after quantum catalysis.
Borneol is an organic volatile agent, and the octane number of gasoline is improved; secondly, the organic acid and the fatty alcohol are catalyzed to generate ester, and the combustion is promoted.
Palmitic acid n-hexadecyl ester is an ester of palmitic acid with hexadecanol as a main component, and is a white waxy crystalline substance naturally occurring in animals and plants.
The molecular formula is C 32 H 64 O 2
Boiling point: 507.0 +/-18.0 ℃ at760mmHg
Melting point: 55-56 deg.C (lit.)
Lauric acid (Lauric acid), also known as dodecanoic acid, is a saturated fatty acid, and the natural vegetable oils used to make dodecanoic acid are: coconut oil, litsea cubeba kernel oil, palm kernel oil, lindera glauca kernel oil and the like. Dodecanoic acid can be obtained from other plants such as palm kernel oil, semen Lespedezae Cuneatae oil, and lignum Cinnamomi Camphorae seed oil.
The molecular formula is C 12 H 24 O 2
Melting point: 43.8 deg.C (317K)
Boiling point: 297.9 deg.C (571K)
The arrowketone is a white powdery crystal which is prepared by taking turpentine as a raw material through a first-order chemical reaction and is a flammable terpene ketone compound. Colorless or white crystal, granule or easily broken block, pungent aromatic flavor, and slowly volatilize at room temperature.
The molecular formula is C 10 H 16 O
Melting point: 179.75 deg.C
Boiling point: 204 deg.C
Solubility: slightly soluble in water, soluble in ethanol, diethyl ether, chloroform, carbon disulfide, solvent naphtha and volatile or non-volatile oils.
Borneol is prepared from stems and leaves of blumea balsamifera of Compositae or branches and leaves of Cinnamomum camphora of Lauraceae by steam distillation and recrystallization.
Chemical formula is C 10 H 18 O
Molecular weight: 54.25
Melting point: 208 deg.C
Boiling point: 213 deg.C
Titanium dioxide, which is an inorganic component, has excellent chemical stability and can significantly decompose nitrogen oxides, aromatic hydrocarbons and aldehydes.
The molecular formula is TiO 2
Melting point: 1,843 deg.C
Boiling point: 2,972 deg.C
Rosin, a rosin of the oil tree in the family of pines, is the major component of rosin available from pine-like tree species worldwide. Is divided into 3 types of "gum rosin", "wood rosin" and "floating oil rosin".
Chemical formula is C 19 H 29 COOH
Melting point: 110-135 DEG C
Boiling point: 300 deg.C (0.67 kPa)
The invention relates to a lozenge for improving internal combustion engine oil, which comprises the following components by weight percent of 20-40% of hexadecane palmitate, 5% of lauric acid dodecanoic acid serving as a lubricant and a cleaning agent, 20-50% of arrowketone, 10-20% of rosin serving as a dispersing agent and a catalyst, 10-15% of stearic acid serving as a synthetic agent of organic fatty acid synthetic ester, 20-50% of arrowketone sublimating agent of organic ester, 4% of borneol serving as an organic volatile agent, and 1% of titanium dioxide serving as an inorganic component. Mixing evenly, and tabletting into granules to obtain the solid fuel additive. The solid fuel additive disclosed by the invention can effectively reduce harmful substances discharged by tail gas with the minimum additive amount, thereby being beneficial to reducing oil consumption, improving the performance of an engine, improving the reaction speed of an accelerator and increasing power output. According to the material characteristics of the formula, a fuel improvement formula is drawn up, for example: table five (wherein the formulations of table five refer to weight percent).
[ TABLE V ]
According to the characteristics of the substances, a fuel oil improvement formula is drawn up
Figure BDA0003219319760000071
The improved pastille for the internal combustion engine fuel can greatly improve the heat combustion efficiency of the fuel if the improved pastille for the internal combustion engine fuel theoretically can effectively enhance and control the combustion time. After rosin is added and sublimation conversion is carried out on the arrowhead ketone and the borneol, the molecules of the carbon are quickly divided into smaller molecules by the carbon close to fuel oil, the combustible surface area is multiplied, and the complete combustion effect is achieved. So it can save oil and reduce carbon dioxide emission. Since the heat energy contained in the fuel is transferred to the effective part to relatively reduce the heat consumption of the exhaust gas, the temperature of the exhaust gas is not increased, and the nitride NO is suppressed X Is generated. On the other hand, the fuel oil added with the palmitic acid n-hexadecyl ester can be quickly and uniformly combusted, and hydrogen peroxide H can be avoided 2 O 2 The production of transitional products of (2). Hydrogen peroxide is one of the main causes of engine knock, which is equivalent to adding n-hexadecyl palmitate to increase the gasoline octane number or increase the cetane number of diesel fuel for quick combustion.
The present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof, and it should be understood that various changes and modifications can be effected therein by one skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims.

Claims (1)

1. The lozenge for improving the oil quality of the internal combustion engine is characterized by comprising 20-40 wt% of n-hexadecyl palmitate, 5 wt% of lauric acid, 10-20 wt% of rosin, 10-15 wt% of stearic acid, 20-50 wt% of arrowketone, 4 wt% of borneol and 1wt% of titanium dioxide, wherein the n-hexadecyl palmitate is 20-40 wt% of a combustion improver, the lauric acid is 5 wt% of a lubricant and a cleaning agent, the rosin is 10-20 wt% of a dispersant and a catalyst, the stearic acid is 10-15 wt% of a synthetic agent of organic ester, the arrowketone is 20-50 wt% of a subliming agent of organic ester, the borneol is 4 wt% of an organic volatile agent, and the titanium dioxide is 1wt% of a toxic substance decomposer.
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1162626A (en) * 1997-03-31 1997-10-22 孙福刚 Diesel oil combustion adjuvant and its production
CN1888030A (en) * 2005-06-27 2007-01-03 李猛 Nanometer composite fuel oil additive and method of adding the additive to fuel oil
CN103074127A (en) * 2013-01-30 2013-05-01 林大经 Formula for fuel saving ingot
CN104212500A (en) * 2013-06-05 2014-12-17 中国科学院过程工程研究所 Smoke abatement and energy saving additive for fuel oil, preparation method and use method thereof
CN105199792A (en) * 2015-09-01 2015-12-30 徐邦舜 Energy-efficient methanol gasoline additive
CN107384492A (en) * 2017-08-25 2017-11-24 青岛涌泉石油有限公司 Anti- haze environmental protection diesel oil combustion improver
CN111607440A (en) * 2020-05-27 2020-09-01 四川中融雷科汽车科技有限公司 Nano-material diesel combustion improver and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1162626A (en) * 1997-03-31 1997-10-22 孙福刚 Diesel oil combustion adjuvant and its production
CN1888030A (en) * 2005-06-27 2007-01-03 李猛 Nanometer composite fuel oil additive and method of adding the additive to fuel oil
CN103074127A (en) * 2013-01-30 2013-05-01 林大经 Formula for fuel saving ingot
CN104212500A (en) * 2013-06-05 2014-12-17 中国科学院过程工程研究所 Smoke abatement and energy saving additive for fuel oil, preparation method and use method thereof
CN105199792A (en) * 2015-09-01 2015-12-30 徐邦舜 Energy-efficient methanol gasoline additive
CN107384492A (en) * 2017-08-25 2017-11-24 青岛涌泉石油有限公司 Anti- haze environmental protection diesel oil combustion improver
CN111607440A (en) * 2020-05-27 2020-09-01 四川中融雷科汽车科技有限公司 Nano-material diesel combustion improver and preparation method thereof

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