CN113862049A - Safe and environment-friendly water-based fuel and preparation method thereof - Google Patents

Safe and environment-friendly water-based fuel and preparation method thereof Download PDF

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Publication number
CN113862049A
CN113862049A CN202111290324.XA CN202111290324A CN113862049A CN 113862049 A CN113862049 A CN 113862049A CN 202111290324 A CN202111290324 A CN 202111290324A CN 113862049 A CN113862049 A CN 113862049A
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Prior art keywords
water
mixed solution
based fuel
safe
environment
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CN202111290324.XA
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Chinese (zh)
Inventor
张俊红
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Shanxi Hongrunyuan New Energy Technology Co ltd
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Shanxi Hongrunyuan New Energy Technology Co ltd
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Priority to CN202111290324.XA priority Critical patent/CN113862049A/en
Publication of CN113862049A publication Critical patent/CN113862049A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/1802Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters

Abstract

The invention provides a safe and environment-friendly water-based fuel, which comprises the following raw materials: 44% of water, 35% of ethylene glycol, 6% of polyethylene glycol, 5% of glycerol and 10% of palm oil; the preparation method comprises the following steps: (1) treating tap water to prepare ultrapure water; (2) putting 41.8% of ultrapure water and ethylene glycol into a reaction kettle, uniformly stirring, and standing for 24 hours to prepare a mixed solution 1; putting polyethylene glycol and 2.2% of ultrapure water into another reaction kettle, uniformly stirring, and standing for 24 hours to prepare a mixed solution 2; (3) mixing the mixed solution 1 and the mixed solution 2 together, and crushing for 3-5 times to obtain a mixed solution 3; (4) then adding palm oil and glycerol, and crushing for 3-5 times to obtain the water-based fuel; the steps are all carried out at normal temperature and normal pressure; the invention has the advantages of safety, environmental protection and being capable of being used as a fire extinguishing agent and a fuel at the same time, and is suitable for the field of water-based fuels.

Description

Safe and environment-friendly water-based fuel and preparation method thereof
Technical Field
The invention relates to the technical field of water-based fuels, in particular to a safe and environment-friendly water-based fuel and a preparation method thereof.
Background
The fuel is widely applied to industrial and agricultural production and people's life, and can release energy substances through chemical reaction. There are many kinds of fuels, most commonly coal, coke, petroleum, natural gas, methane and the like, and the burning of these fuels discharges floating carbon, hydrocarbons, carbon monoxide, nitrogen oxides, sulfides, solid particles and the like, which cause the environment to deteriorate increasingly, and carbon deposition blockage is easily caused in the burning process, thereby affecting the burning effect, and energy researchers in various countries around the world are actively searching and seeking for environment-friendly alternative fuels.
Disclosure of Invention
Aiming at the defects in the related technology, the technical problem to be solved by the invention is as follows: provides a safe and environment-friendly water-based fuel which can be used as a fire extinguishing agent and a fuel at the same time.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: a safe and environment-friendly water-based fuel comprises the following raw materials in percentage by weight: 44% of water, 35% of ethylene glycol, 6% of polyethylene glycol, 5% of glycerol and 10% of palm oil.
Preferably, the water is ultrapure water.
Preferably, the purity of the ethylene glycol is 99.9%.
The invention also provides a preparation method of the safe and environment-friendly water-based fuel, which comprises the following steps:
(1) treating tap water to prepare ultrapure water;
(2) putting 41.8% of ultrapure water and ethylene glycol into a reaction kettle, uniformly stirring, and standing for 24 hours to prepare a mixed solution 1;
putting polyethylene glycol and 2.2% of ultrapure water into another reaction kettle, uniformly stirring, and standing for 24 hours to prepare a mixed solution 2;
(3) mixing the mixed solution 1 and the mixed solution 2 together, and crushing for 3-5 times to obtain a mixed solution 3;
(4) then adding palm oil and glycerol, and crushing for 3-5 times to obtain the water-based fuel;
the above steps are all carried out at normal temperature and pressure.
Preferably, the method for preparing ultrapure water by treating tap water in step (1) is reverse osmosis water treatment.
Preferably, the molecules of the mixed solution 1 and the mixed solution 2 mixed together in the step (3) are irregularly moved and have a density of 0.01 to 0.05.
Preferably, the molecules in the mixed solution 3 move irregularly, and the density is 0.01-0.03.
The invention has the beneficial technical effects that:
1. the water-based fuel provided by the invention comprises the following raw materials, by weight, 44% of water, 35% of ethylene glycol, 6% of polyethylene glycol, 5% of glycerol and 10% of palm oil.
The water-based fuel provided by the invention is nonflammable and non-explosive, can be safely stored and used as a fire extinguishing agent, and can better guarantee the life and property safety of people; simultaneously in civil and commercial boiler and gas-cooker heat to 280 ~ 300 ℃ through the furnace end and can regard as water-based fuel to use, can burn completely when using as the fuel to realize the effect that no harmful gas discharged and few carbon discharged, environmental protection health more. Can simultaneously realize the dual effects of being used as a fire extinguishing agent and being used as fuel under the heating of the furnace end.
The raw materials adopted in the invention are all non-flammable and non-explosive. The flash point of the polyethylene glycol is high, the structure of the ethylene glycol can be well damaged, and the water and the ethylene glycol can be better fused together; palm oil is pure vegetable oil and has no binding effect, the combustion and separation of the palm oil are beneficial to the full combustion of the aqueous fuel under the heating of a furnace end, and the combined use of the palm oil and water can prevent the aqueous fuel from generating carbon deposit in the combustion process; the glycerol is not a combustion improver, and the water-based fuel is prepared according to the proportion, so that the prepared water-based fuel can be ensured to have the effects of non-flammability and non-explosiveness. The water-based fuel is fully combusted, so that the emission of harmful gas in combustion exhaust gas can be ensured, and the water-based fuel is more environment-friendly and safer.
2. The water in the invention is ultrapure water.
The ultrapure water does not contain bacteria, viruses and mineral trace elements, and only contains hydrogen atoms and oxygen atoms. The use of ultrapure water enables the hydrogen and oxygen in the water to be sufficiently separated during combustion of the produced aqueous fuel without generating carbon deposit.
3. The purity of the ethylene glycol in the invention is 99.9%.
The glycol has low cost, convenient acquisition, non-inflammability with open fire and safety. The heat value generated when the furnace is heated through the furnace end is higher, and the energy is saved.
4. The water-based fuel prepared by the preparation method provided by the invention can realize low-carbon emission, is not flammable or explosive under normal conditions, and is convenient to store safely; the raw materials adopted in the invention are all non-flammable and non-explosive, and the preparation process is safe; meanwhile, a direct combustion improver is not adopted, and the burner is used for heating and atomizing so as to realize the combustion of the water-based fuel. In addition, the water-based fuel prepared by the invention can be used for extinguishing fire, and can better guarantee the life and property safety of people.
The flash point of polyethylene glycol is high, and the structure of destruction ethylene glycol that can be better, mixes back together mixed liquid 1 and mixed liquid 2, and the intermolecular irregular motion, density is 0.01 ~ 0.05. Mix mixed liquid 1 and mixed liquid 2 and be in the same place, then obtain mixed liquid 3 after carrying out broken 3 ~ 5 times, ultrapure water strikes the ethylene glycol in the mixed liquid 3, and the ethylene glycol receives viscosity reduction after strikeing, and ethylene glycol can wrap up ultrapure water during the burning, reaches the effect of abundant burning. The crushing operation promotes the fusion of water and glycol; the addition amount of the polyethylene glycol is small, the polyethylene glycol can be completely fused between the ethylene glycol and water in the preparation process, the molecules of the prepared mixed liquid 3 move irregularly, and the density is 0.01-0.03. Then palm oil and glycerol are added for crushing, and the raw materials are mixed together to better prevent the occurrence of carbon deposit.
5. The method for preparing the ultrapure water by treating the tap water is reverse osmosis water treatment.
Through reverse osmosis treatment, the tap water is treated into ultrapure water, so that the cost is saved, and the treatment effect on the tap water can be ensured.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments, and it is obvious that the described embodiments are some embodiments, but not all embodiments, of the present invention; all other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a safe and environment-friendly water-based fuel, which comprises the following raw materials in percentage by weight: 44% of water, 35% of ethylene glycol, 6% of polyethylene glycol, 5% of glycerol and 10% of palm oil.
The water-based fuel provided by the invention is nonflammable and non-explosive, can be safely stored and used as a fire extinguishing agent, and can better guarantee the life and property safety of people; simultaneously in civil and commercial boiler and gas-cooker heat to 280 ~ 300 ℃ through the furnace end and can regard as water-based fuel to use, can burn completely when using as the fuel to realize the effect that no harmful gas discharged and few carbon discharged, environmental protection health more. Can simultaneously realize the dual effects of being used as a fire extinguishing agent and being used as fuel under the heating of the furnace end.
The raw materials adopted in the invention are all non-flammable and non-explosive. The flash point of the polyethylene glycol is high, the structure of the ethylene glycol can be well damaged, water and the ethylene glycol can be better fused together, and the toxicity of the ethylene glycol is reduced; palm oil is pure vegetable oil and has no binding effect, the combustion and separation of the palm oil are beneficial to the full combustion of the aqueous fuel under the heating of a furnace end, and the combined use of the palm oil and water can prevent the aqueous fuel from generating carbon deposit in the combustion process; the glycerol is not a combustion improver, and the water-based fuel is prepared according to the proportion, so that the prepared water-based fuel can be ensured to have the effects of non-flammability and non-explosiveness. The water-based fuel is fully combusted, so that the emission of harmful gas in combustion exhaust gas can be ensured, and the water-based fuel is more environment-friendly and safer.
Specifically, the water is ultrapure water.
The ultrapure water does not contain bacteria, viruses and mineral trace elements, namely the ultrapure water only contains hydrogen atoms and oxygen atoms. The use of ultrapure water enables the hydrogen and oxygen in the water to be sufficiently separated during combustion of the produced aqueous fuel without generating carbon deposit.
Specifically, the purity of the ethylene glycol is 99.9%.
The glycol has low cost, convenient acquisition, non-inflammability with open fire and safety. The heat value generated when the furnace is heated through the furnace end is higher, and the energy is saved.
The invention also provides a preparation method of the safe and environment-friendly water-based fuel, which comprises the following steps:
(1) treating tap water to prepare ultrapure water;
(2) putting 41.8% of ultrapure water and ethylene glycol into a reaction kettle, uniformly stirring, and standing for 24 hours to prepare a mixed solution 1;
putting polyethylene glycol and 2.2% of ultrapure water into another reaction kettle, uniformly stirring, and standing for 24 hours to prepare a mixed solution 2;
(3) mixing the mixed solution 1 and the mixed solution 2 together, and crushing for 3-5 times to obtain a mixed solution 3;
(4) then adding palm oil and glycerol, and crushing for 3-5 times to obtain the water-based fuel;
the above steps are all carried out at normal temperature and pressure.
Further, when the mixed solution 1 and the mixed solution 2 are mixed together in the step (3), molecules move irregularly, and the density is 0.01-0.05.
Furthermore, the molecules in the mixed solution 3 move irregularly, and the density is 0.01-0.03.
The water-based fuel prepared by the preparation method provided by the invention can realize low-carbon emission, is not flammable or explosive under normal conditions, and is convenient to store safely; the raw materials adopted in the invention are all non-flammable and non-explosive, and the preparation process is safe; meanwhile, a direct combustion improver is not adopted, and the burner is used for heating and atomizing so as to realize the combustion of the water-based fuel. In addition, the water-based fuel prepared by the invention can be used for extinguishing fire, and can better guarantee the life and property safety of people.
The flash point of polyethylene glycol is high, and the structure of destruction ethylene glycol that can be better, mixes back together mixed liquid 1 and mixed liquid 2, and the intermolecular irregular motion, density is 0.01 ~ 0.05. Mix mixed liquid 1 and mixed liquid 2 and be in the same place, then obtain mixed liquid 3 after carrying out broken 3 ~ 5 times, ultrapure water strikes the ethylene glycol in the mixed liquid 3, and the ethylene glycol receives viscosity reduction after strikeing, and ethylene glycol can wrap up ultrapure water during the burning, reaches the effect of abundant burning. The crushing operation promotes the fusion of water and glycol; the addition amount of the polyethylene glycol is small, the polyethylene glycol can be completely fused between the ethylene glycol and water in the preparation process, the molecules of the prepared mixed liquid 3 move irregularly, and the density is 0.01-0.03. Then palm oil and glycerol are added for crushing, and the raw materials are mixed together to better prevent the occurrence of carbon deposit.
Further, the method for preparing ultrapure water by treating tap water in the step (1) is reverse osmosis water treatment.
Through reverse osmosis treatment, the tap water is treated into ultrapure water, so that the cost is saved, and the treatment effect on the tap water can be ensured.
Specifically, the stirring in each step is performed under a sealed condition.
Specifically, the water-based fuel prepared by the invention can be heated through the furnace end, so that the combustion effect is achieved.
The burner comprises an oil path with one inlet and three outlets, when the temperature of the burner reaches 280-300 ℃, a switch of a controller is turned on, so that water-based fuel enters the oil path of the burner, the water-based fuel is heated through the burner, the heated water-based fuel is sprayed out through a combustion nozzle arranged at the bottom of the burner, the atomized water-based fuel is sprayed out through the combustion nozzle, and combustion is realized through an ignition device. The flame during combustion is blue flame, which proves that the water-based fuel prepared by the invention can be fully combusted.
In order to prove that the combustion of the water-based fuel prepared by the invention can achieve the effect of no harmful gas emission, the content detection of sulfur dioxide and carbon monoxide is carried out on the gas generated in the combustion of the water-based fuel prepared by the invention, and the detection method and the detection result are shown in table 1:
TABLE 1 gas detection
Figure BDA0003334659220000051
As can be seen from Table 1, the water-based fuel prepared by the invention can realize the effect of no harmful gas emission in the gas generated during combustion, and is safer and more environment-friendly.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.

Claims (7)

1. A safe and environment-friendly water-based fuel is characterized in that: comprises the following raw materials in percentage by weight: 44% of water, 35% of ethylene glycol, 6% of polyethylene glycol, 5% of glycerol and 10% of palm oil.
2. A safe and environmentally friendly aqueous fuel as claimed in claim 1, wherein: the water is ultrapure water.
3. A safe and environmentally friendly aqueous fuel as claimed in claim 1, wherein: the purity of the ethylene glycol was 99.9%.
4. A method for preparing the safe and environment-friendly water-based fuel as claimed in claim 1, wherein the method comprises the following steps: the method comprises the following steps:
(1) treating tap water to prepare ultrapure water;
(2) putting 41.8% of ultrapure water and ethylene glycol into a reaction kettle, uniformly stirring, and standing for 24 hours to prepare a mixed solution 1;
putting polyethylene glycol and 2.2% of ultrapure water into another reaction kettle, uniformly stirring, and standing for 24 hours to prepare a mixed solution 2;
(3) mixing the mixed solution 1 and the mixed solution 2 together, and crushing for 3-5 times to obtain a mixed solution 3;
(4) then adding palm oil and glycerol, and crushing for 3-5 times to obtain the water-based fuel;
the above steps are all carried out at normal temperature and pressure.
5. The method for preparing the safe and environment-friendly water-based fuel according to claim 4, characterized in that: the method for preparing the ultrapure water by treating the tap water in the step (1) is reverse osmosis water treatment.
6. The method for preparing the safe and environment-friendly water-based fuel according to claim 4, characterized in that: and (3) in the step (3), when the mixed solution 1 and the mixed solution 2 are mixed together, molecules move irregularly, and the density is 0.01-0.05.
7. The method for preparing the safe and environment-friendly water-based fuel according to claim 4, characterized in that: the molecules in the mixed liquid 3 move irregularly, and the density is 0.01-0.03.
CN202111290324.XA 2021-11-02 2021-11-02 Safe and environment-friendly water-based fuel and preparation method thereof Pending CN113862049A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114806658A (en) * 2022-03-18 2022-07-29 赵玉庆 Water-based fuel liquid and preparation method and application thereof
CN115746925A (en) * 2022-12-02 2023-03-07 聚燃(广东)新能源有限公司 Environment-friendly energy-saving water-based fuel and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110289829A1 (en) * 2010-05-25 2011-12-01 New Generation Biofuels Holdings, Inc. Glycerine Based Biofuel Composition and Method
TW201522610A (en) * 2013-12-09 2015-06-16 Meng-Liang Huang Aqueous solution as an alternative energy to reform boiler's fuel oil
CN106967464A (en) * 2017-04-24 2017-07-21 青岛百事德工艺礼品有限公司 A kind of drinking water boiler oil and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110289829A1 (en) * 2010-05-25 2011-12-01 New Generation Biofuels Holdings, Inc. Glycerine Based Biofuel Composition and Method
TW201522610A (en) * 2013-12-09 2015-06-16 Meng-Liang Huang Aqueous solution as an alternative energy to reform boiler's fuel oil
CN106967464A (en) * 2017-04-24 2017-07-21 青岛百事德工艺礼品有限公司 A kind of drinking water boiler oil and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114806658A (en) * 2022-03-18 2022-07-29 赵玉庆 Water-based fuel liquid and preparation method and application thereof
CN114806658B (en) * 2022-03-18 2023-12-08 赵玉庆 Water-based fuel solution and preparation method and application thereof
CN115746925A (en) * 2022-12-02 2023-03-07 聚燃(广东)新能源有限公司 Environment-friendly energy-saving water-based fuel and preparation method thereof

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