CN107434987A - Super diesel oil of environmental protection and energy saving and preparation method thereof - Google Patents

Super diesel oil of environmental protection and energy saving and preparation method thereof Download PDF

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Publication number
CN107434987A
CN107434987A CN201710743183.XA CN201710743183A CN107434987A CN 107434987 A CN107434987 A CN 107434987A CN 201710743183 A CN201710743183 A CN 201710743183A CN 107434987 A CN107434987 A CN 107434987A
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China
Prior art keywords
diesel oil
environmental protection
energy saving
super
haze
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Pending
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CN201710743183.XA
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Chinese (zh)
Inventor
韩建鹏
韩凯
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Qingdao Yongquan Petroleum Co Ltd
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Qingdao Yongquan Petroleum Co Ltd
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Priority to CN201710743183.XA priority Critical patent/CN107434987A/en
Publication of CN107434987A publication Critical patent/CN107434987A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The present invention proposes super diesel oil of a kind of environmental protection and energy saving and preparation method thereof, is calculated according to percetage by weight, including following components：Linear paraffin 50~60%, organic solvent 10~20%, cycloalkane 15~20%, alkylbenzene 8~10%, kerosene 5~10% and anti-haze environmental protection diesel oil combustion improver 0.8%.Preparation method：1) linear paraffin 50~60%, organic solvent 10~20%, cycloalkane 15~20%, alkylbenzene 8~10% and kerosene 5~10% are weighed according to proportioning, then uniformly mixing successively, obtains mixture A；2) under the conditions of lucifuge, anti-haze environmental protection diesel oil combustion improver is added in mixture A according to proportioning and is well mixed.The diesel oil produces a large amount of PM2.5 after solving existing burning, pollutes haze and toxicity problem caused by environment.

Description

Super diesel oil of environmental protection and energy saving and preparation method thereof
Technical field
The invention belongs to biodiesel technology field, and in particular to a kind of super diesel oil of environmental protection and energy saving and preparation method thereof.
Background technology
, in order to improve the Cetane number of diesel oil, ground in diesel oil is produced using external five sixties oil refining enterprise in China The backwardness filtering technique of system ----diesel antiwear additive.This material can produce substantial amounts of polycyclic aromatic hydrocarbons (PAH), be high toxicity carcinogenic substance Matter, substantial amounts of PM2.5 is produced after burning, be the arch-criminal for directly resulting in haze, lung cancer and breathing problem, diesel antiwear additive The Cetane number of diesel oil can be improved, but the component of diesel oil can not be grouped together, causes efficiency of combustion low, waste 20%~ 30% diesel component, aggravate pollution of the vehicle exhaust to air.Can be various bavins using anti-haze environmental protection diesel oil combustion improver Oil ingredient is grouped together abundant burning, fuel-economizing 20%-30%, and waste gas discharge reduces more than 90%, is to administer haze environmental protection section The ideal product of energy emission reduction.
The content of the invention
The present invention proposes a kind of super diesel oil of environmental protection and energy saving, and the diesel oil produces a large amount of PM2.5 after solving existing burning, Pollute haze and toxicity problem caused by environment.
The technical proposal of the invention is realized in this way：
A kind of super diesel oil of environmental protection and energy saving, is calculated according to percetage by weight, including following components：
Linear paraffin 50~60%, organic solvent 10~20%, cycloalkane 15~20%, alkylbenzene 8~10%, kerosene 5 ~10% and anti-haze environmental protection diesel oil combustion improver 0.8%.
Preferably, anti-haze environmental protection diesel oil combustion improver by 5~10wt% of o-dinitrobenzene, Alkyl nitrate 10~ 30wt%, 3~8wt% of rosin, 4~8wt% of glycerine, 5~10wt% of oleate, 15~30wt% of isooctyl acid potassium and solvent 20~50wt% is formed.
Preferably, the kerosene is hyperbranched isoparaffin.
Preferably, the organic solvent is the petroleum cuts that benzene, petroleum ether or boiling range are 140~390 DEG C.
Preferably, the solvent is the petroleum cuts that benzene, toluene, petroleum ether or boiling range are 140~390 DEG C.
It is a further object to provide a kind of preparation method of the super diesel oil of environmental protection and energy saving, comprise the following steps：
1) linear paraffin 50~60%, organic solvent 10~20%, cycloalkane 15~20%, alkylbenzene are weighed according to proportioning 8~10% and kerosene 5~10%, then uniformly mixing successively, obtains mixture A；
2) under the conditions of lucifuge, anti-haze environmental protection diesel oil combustion improver is added in mixture A according to proportioning and is well mixed .
Beneficial effects of the present invention：
1st, the open flash point of diesel oil of the invention is 58 DEG C, and flash-point is high, and this is favourable to storage security.Cetane number is big In 58.On the one hand Cetane number is improved, on the other hand water and steam therein absorbs cylinder and combustion chamber perisporium high temperature zero Heat on part, red-hot position particularly therein, so that the equalizing temperature in cylinder and in combustion chamber, is eliminated easily Cause the incandescent spot of pinking, so as to improve anti-knock properties.
2nd, the fuel economizing rate of diesel oil of the invention reaches more than 15%, and energy-conserving and environment-protective reduce haze and produced.
Embodiment
Embodiment 1
A kind of anti-haze environmental protection diesel oil combustion improver, including following components：
O-dinitrobenzene 5kg, Alkyl nitrate 10kg, rosin 8kg, glycerine 8kg, oleate 10kg, isooctyl acid potassium 15kg And petroleum ether 44kg.
Preparation method：Said components are weighed according to proportioning and are well mixed.
Embodiment 2
A kind of anti-haze environmental protection diesel oil combustion improver, including following components：
O-dinitrobenzene 8kg, Alkyl nitrate 22kg, rosin 5kg, glycerine 4kg, oleate 5kg, isooctyl acid potassium 20kg with And No. 90 gasoline 36kg.
Preparation method：Said components are weighed according to proportioning and are well mixed.
Embodiment 3
A kind of super diesel oil of environmental protection and energy saving, including following components：
Linear paraffin 54kg, petroleum ether 10.2kg, cycloalkane 20kg, alkylbenzene 10kg, kerosene 5kg and embodiment 1 Anti- haze environmental protection diesel oil combustion improver 0.8kg.
Preparation method：
1) linear paraffin, petroleum ether, cycloalkane, alkylbenzene and kerosene are weighed according to proportioning, then uniformly mixing successively, is obtained To mixture A；
2) under the conditions of lucifuge, the anti-haze environmental protection diesel oil combustion improver of embodiment 1 is added in mixture A according to proportioning It is well mixed.
Embodiment 4
A kind of super diesel oil of environmental protection and energy saving, including following components：
Linear paraffin 50kg, petroleum ether 13.2kg, cycloalkane 20kg, alkylbenzene 8kg, kerosene 8kg and embodiment 2 it is anti- Haze environmental protection diesel oil combustion improver 0.8kg.
Preparation method：
1) linear paraffin, petroleum ether, cycloalkane, alkylbenzene and kerosene are weighed according to proportioning, then uniformly mixing successively, is obtained To mixture A；
2) under the conditions of lucifuge, the anti-haze environmental protection diesel oil combustion improver of embodiment 2 is added in mixture A according to proportioning It is well mixed.
Embodiment 5
A kind of super diesel oil of environmental protection and energy saving, including following components：
Linear paraffin 60kg, petroleum ether 11.2kg, cycloalkane 15kg, alkylbenzene 8kg, kerosene 5kg and embodiment 1 it is anti- Haze environmental protection diesel oil combustion improver 0.8kg.
Preparation method：
1) linear paraffin, petroleum ether, cycloalkane, alkylbenzene and kerosene are weighed according to proportioning, then uniformly mixing successively, is obtained To mixture A；
2) under the conditions of lucifuge, the anti-haze environmental protection diesel oil combustion improver of embodiment 1 is added in mixture A according to proportioning It is well mixed.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.

Claims (6)

  1. A kind of 1. super diesel oil of environmental protection and energy saving, it is characterised in that calculated according to percetage by weight, including following components：
    Linear paraffin 50~60%, organic solvent 10~20%, cycloalkane 15~20%, alkylbenzene 8~10%, kerosene 5~ 10% and anti-haze environmental protection diesel oil combustion improver 0.8%.
  2. 2. the super diesel oil of environmental protection and energy saving according to claim 1, it is characterised in that anti-haze environmental protection diesel oil combustion improver by 5~10wt% of o-dinitrobenzene, 10~30wt% of Alkyl nitrate, 3~8wt% of rosin, 4~8wt% of glycerine, oleate 5~ 10wt%, 15~30wt% of isooctyl acid potassium and 20~50wt% of solvent compositions.
  3. 3. the super diesel oil of environmental protection and energy saving according to claim 1, it is characterised in that the kerosene is hyperbranched isomery Alkane.
  4. 4. the super diesel oil of environmental protection and energy saving according to claim 1, it is characterised in that the organic solvent is benzene, petroleum ether Or the petroleum cuts that boiling range is 140~390 DEG C.
  5. 5. the super diesel oil of environmental protection and energy saving according to claim 2, it is characterised in that the solvent is benzene, toluene, petroleum ether Or the petroleum cuts that boiling range is 140~390 DEG C.
  6. 6. the preparation method of the super diesel oil of environmental protection and energy saving as claimed in claim 1, it is characterised in that comprise the following steps：
    1) according to proportioning weigh linear paraffin 50~60%, organic solvent 10~20%, cycloalkane 15~20%, alkylbenzene 8~ 10% and kerosene 5~10%, then uniformly mixing successively, obtains mixture A；
    2) under the conditions of lucifuge, anti-haze environmental protection diesel oil combustion improver is added in mixture A according to proportioning and is well mixed.
CN201710743183.XA 2017-08-25 2017-08-25 Super diesel oil of environmental protection and energy saving and preparation method thereof Pending CN107434987A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710743183.XA CN107434987A (en) 2017-08-25 2017-08-25 Super diesel oil of environmental protection and energy saving and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710743183.XA CN107434987A (en) 2017-08-25 2017-08-25 Super diesel oil of environmental protection and energy saving and preparation method thereof

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Publication Number Publication Date
CN107434987A true CN107434987A (en) 2017-12-05

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1056516A (en) * 1990-05-12 1991-11-27 苌静滨 A kind of diesel-dope and production method thereof
CN1162626A (en) * 1997-03-31 1997-10-22 孙福刚 Diesel oil combustion adjuvant and its production
CN104927943A (en) * 2014-03-19 2015-09-23 荆春芳 High efficient gasoline combustion improver
CN105102588A (en) * 2013-04-02 2015-11-25 芬欧汇川集团 Renewable hydrocarbon composition
CN105102589A (en) * 2013-04-02 2015-11-25 芬欧汇川集团 Renewable hydrocarbon composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1056516A (en) * 1990-05-12 1991-11-27 苌静滨 A kind of diesel-dope and production method thereof
CN1162626A (en) * 1997-03-31 1997-10-22 孙福刚 Diesel oil combustion adjuvant and its production
CN105102588A (en) * 2013-04-02 2015-11-25 芬欧汇川集团 Renewable hydrocarbon composition
CN105102589A (en) * 2013-04-02 2015-11-25 芬欧汇川集团 Renewable hydrocarbon composition
CN104927943A (en) * 2014-03-19 2015-09-23 荆春芳 High efficient gasoline combustion improver

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张广林: "《现代燃料油品手册》", 30 September 2009, 中国石化出版社 *
高大维: "《精细化工概要》", 28 February 1999, 吉林大学出版社 *

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Application publication date: 20171205