CN103642538B - Preparation method of methanol-containing environment-friendly gasoline - Google Patents
Preparation method of methanol-containing environment-friendly gasoline Download PDFInfo
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- CN103642538B CN103642538B CN201310725485.6A CN201310725485A CN103642538B CN 103642538 B CN103642538 B CN 103642538B CN 201310725485 A CN201310725485 A CN 201310725485A CN 103642538 B CN103642538 B CN 103642538B
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- Prior art keywords
- gasoline
- methyl alcohol
- preparation
- methanol
- container
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 165
- 239000003502 gasoline Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000000446 fuel Substances 0.000 claims abstract description 16
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000654 additive Substances 0.000 claims abstract description 14
- 230000000996 additive effect Effects 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 18
- 238000002485 combustion reaction Methods 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 9
- 239000003254 gasoline additive Substances 0.000 claims description 6
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000000295 fuel oil Substances 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 239000006184 cosolvent Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003831 antifriction material Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000005339 levitation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention belongs to the technical field of fuel oil and particularly relates to a preparation method of methanol-containing environment-friendly gasoline. The preparation method of methanol-containing environment-friendly gasoline comprises the following steps: preparing a nano combustion-supporting additive; preparing a cosolvent; preparing denatured methanol; and preparing an environment-friendly methanol gasoline fuel. The method provided by the invention has the beneficial effects that by adding some common raw materials, the problem in intersolubility between methanol and gasoline is solved; due to use of ferrocene and the nano combustion-supporting additive, the thermal efficiency of fuel is greatly improved, the waste of fuel is reduced, the emission of tail gas is reduced, and an aim of environmental protection is really reached.
Description
Technical field
The invention belongs to technical field of fuel oil, be specifically related to a kind of preparation method of the environment protection gasoline containing methyl alcohol.
Background technology
Along with the develop rapidly of China's economy, day by day increase the demand of the energy, especially along with the fast development of automotive industry, the demand of the fuel for motor vehicle caused increases too fast, increases exploitation and the consumption of petroleum resources.Under the requirement of petroleum resources Conception of Sustainable Development, lasting stability, economy are convenient, the exploitation of the vehicle alternative fuel of environment-protecting clean, have special realistic meaning and strategic importance.
A large amount of experimental studies shows, alcohols is except oil, Sweet natural gas, and oil engine can the fuel of substitute.Alcoholic product can reach the discharge more much lower than hydrocarbon products, reduces the pollution to air; When using alcohols-gasoline mixed fuel, the structural modification of engine is little, has good inheritance with traditional engine technology.Because the production of ethanol depends on the food crop such as corn, source receives restriction; By contrast, methyl alcohol wide material sources, adapt to the needs of large-scale industrial production more.
But the popularization of Methanol-gasoline needs to solve a lot of technical matters.The polarity of methyl alcohol is extremely strong, but gasoline is the mixed system of multicomponent, low polarity, both methyl alcohol and gasoline objectionable intermingling within the scope of significant proportion, affects it and stores and safe handling.Therefore, the key that methanol gasoline is applied solves its stability.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of method of preparation of the environment protection gasoline containing methyl alcohol.
The present invention is realized by following technical scheme containing the preparation method of the environment protection gasoline of methyl alcohol:
Containing the preparation method of the environment protection gasoline of methyl alcohol, comprise following step:
Preparation nanometer profit combustion additive; Prepare solubility promoter; Prepare denatured methyl alcohol; Prepare environment-friendly methanol gasoline fuel.
The preparation method of the above-mentioned environment protection gasoline containing methyl alcohol, the method comprises following step:
Raw material is prepared by following parts by weight:
Methyl alcohol 15-65, gasoline 15-55, acetone 1.5-3, formaldehyde 0.8-5, ferrocene 0.5-3.5, nanometer profit combustion additive 10-20;
(1) nanometer profit combustion additive is prepared: stir for subsequent use by nano antiwear agent and nanometer gasoline additive by the weight ratio of 3:15-17;
(2) solubility promoter is prepared: the acetone of above-mentioned weight part, formaldehyde, ferrocene are mixed, for subsequent use;
(3) denatured methyl alcohol is prepared: the solubility promoter of above-mentioned weight part being added weight part is in the methyl alcohol of 15-65, obtains denatured methyl alcohol;
(4) prepare environment-friendly methanol gasoline fuel: the nanometer perfect combustion catalyzer of preparation, denatured methyl alcohol are added successively in the gasoline of 15-55 weight part, fully mix, both obtain environment-friendly methanol gasoline fuel.
Preferably, the parts by weight of above-mentioned raw material are:
Methyl alcohol 15-55, gasoline 15-50, acetone 1.5-2.5, formaldehyde 0.8-4, ferrocene 0.5-3.0, nanometer profit combustion additive 10-20.
Preferred, the parts by weight of above-mentioned raw material are:
Methyl alcohol 20, gasoline 50, acetone 2, formaldehyde 2.5, ferrocene 2.0, nanometer profit combustion additive 15.
Nano antiwear agent be AR nano metal anti-wear agent, ER nano metal anti-wear agent, magnetic levitation nano antiwear agent any one.
The weight ratio of nano antiwear agent and nanometer gasoline additive is 3:17.
Ferrocene is a kind of organo-transition metal compound with aromatic nature.Be orange-yellow powder under normal temperature, have camphor smell.Fusing point 172 degree of-174 degree, boiling point 249 degree, more than 100 DEG C can distil; Water insoluble, be soluble in the organic solvents such as benzene, ether, gasoline, diesel oil.Do not have an effect with acid, alkali, ultraviolet, stable chemical nature, does not decompose within 400 degree.Its molecule presents polarity, has high heat stability, chemical stability and radiation resistance, and it has a wide range of applications in the industry such as industry, agricultural, medicine, space flight, energy-saving and environmental protection.
Nano antiwear agent contains 30 Determination of multiple metal elements.Change the original molecular structure of metal antifriction material by the precious nanotechnology of strength power, diameter generally at 10 ran, be visual inspection less than molecule.After this product is added at machinery position; under metal friction effect; hydrocarbon molecules with cathode charge and metallic surface positive charge attract each other; nano metal eutectic ionic species protective membrane; this protective membrane is the high-strength penetration mechanism by nano metal eutectic ion combination material; be split in metal inside, but not outside adhesion.
Beneficial effect of the present invention is, by adding some common raw materials, solves the mutual solubility problem of methyl alcohol and gasoline on the one hand, the use of ferrocene and nano combustion improver simultaneously considerably increases the thermo-efficiency of fuel, reduce waste of fuel, reduce exhaust emissions, really reach the object of environmental protection.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
The raw material of below embodiment 1(is all weight percentage)
Methyl alcohol 20%
93# home-produced fuel 50%
Acetone 3%
Formaldehyde 2%
Ferrocene 3%
Nanometer profit combustion additive 22%
Preparation process is:
(1) preparation of nano profit combustion additive: extracting container A, mixes nano antiwear agent and nanometer gasoline additive according to the weight ratio of 3:17, for subsequent use;
(2) solubility promoter is prepared: extracting container B, mixes for subsequent use by 3% acetone, 2% formaldehyde, 3% ferrocene;
(3) prepare denatured methyl alcohol: in the container C filling 20% methyl alcohol, the solubility promoter configured is added in container C, stir for subsequent use in (2);
(4) prepare environment-friendly methanol gasoline: the denatured methyl alcohol that the nano combustion improver (1) configured, (3) have configured adds successively and fills in the container D of 50% gasoline, stirring both must this environment-friendly methanol gasoline.
Embodiment 2
Methyl alcohol 35%
93# home-produced fuel 40%
Acetone 3%
Formaldehyde 2%
Ferrocene 2%
Nano combustion improver 18%
Preparation process is:
(1) preparation of nano profit combustion additive: extracting container A, mixes nano antiwear agent and nanometer gasoline additive according to the weight ratio of 3:17, for subsequent use;
(2) solubility promoter is prepared: extracting container B, mixes for subsequent use by 3% acetone, 2% formaldehyde, 2% ferrocene;
(3) prepare denatured methyl alcohol: in the container C filling 35% methyl alcohol, the solubility promoter configured is added in container C, stir for subsequent use in (2);
(4) prepare environment-friendly methanol gasoline: the denatured methyl alcohol that the nano combustion improver (1) configured, (3) have configured adds successively and fills in the container D of 40% gasoline, stirring both must this environment-friendly methanol gasoline.
Embodiment 3
Methyl alcohol 45%
93# home-produced fuel 35%
Acetone 3%
Methyl alcohol 2%
Ferrocene 3%
Nano combustion improver 12%
Preparation process is:
(1) preparation of nano profit combustion additive: extracting container A, mixes nano antiwear agent and nanometer gasoline additive according to the weight ratio of 3:17, for subsequent use;
(2) solubility promoter is prepared: extracting container B, mixes for subsequent use by 3% acetone, 2% formaldehyde, 3% ferrocene;
(3) prepare denatured methyl alcohol: in the container C filling 45% methyl alcohol, the solubility promoter configured is added in container C, stir for subsequent use in (2);
(4) prepare environment-friendly methanol gasoline: the denatured methyl alcohol that the nano combustion improver (1) prepared, (3) have configured adds successively and fills in the container D of 35% gasoline, stirring both must this environment-friendly methanol gasoline.
The environment friendly methanol gasoline prepared by embodiment 1-3 and regular gasoline carry out Performance Detection, shown in result following table:
Claims (1)
1.
containing the preparation method of the environment protection gasoline of methyl alcohol, comprise following step:
Prepare following raw material:
Methyl alcohol 20%
93# home-produced fuel 50%
Acetone 3%
Formaldehyde 2%
Ferrocene 3%
Nanometer profit combustion additive 22%
(1) preparation of nano profit combustion additive: extracting container A, mixes nano antiwear agent and nanometer gasoline additive according to the weight ratio of 3:17, for subsequent use;
(2) solubility promoter is prepared: extracting container B, mixes for subsequent use by 3% acetone, 2% formaldehyde, 3% ferrocene;
(3) prepare denatured methyl alcohol: in the container C filling 20% methyl alcohol, the solubility promoter configured is added in container C, stir for subsequent use in (2);
(4) environment-friendly methanol gasoline is prepared: the nanometer profit (1) configured is fired denatured methyl alcohol that additive, (3) have configured and added successively and fill in the container D of 50% gasoline, and stir to obtain environment-friendly methanol gasoline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310725485.6A CN103642538B (en) | 2013-12-25 | 2013-12-25 | Preparation method of methanol-containing environment-friendly gasoline |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310725485.6A CN103642538B (en) | 2013-12-25 | 2013-12-25 | Preparation method of methanol-containing environment-friendly gasoline |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103642538A CN103642538A (en) | 2014-03-19 |
| CN103642538B true CN103642538B (en) | 2015-05-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310725485.6A Active CN103642538B (en) | 2013-12-25 | 2013-12-25 | Preparation method of methanol-containing environment-friendly gasoline |
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| Country | Link |
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| CN (1) | CN103642538B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327890B (en) * | 2014-09-19 | 2016-04-13 | 金景达(北京)环保动力科技有限公司 | A kind of environment-friendly high-efficiency compound additive for methanol gasoline |
| CN110129104A (en) * | 2019-05-20 | 2019-08-16 | 陈荣钦 | A kind of preparation method of nano-fluid diesel antiwear additive |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418241A (en) * | 2008-12-01 | 2009-04-29 | 石联峰 | Methanol gasoline fuel |
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- 2013-12-25 CN CN201310725485.6A patent/CN103642538B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418241A (en) * | 2008-12-01 | 2009-04-29 | 石联峰 | Methanol gasoline fuel |
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| CN103642538A (en) | 2014-03-19 |
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Effective date of registration: 20160314 Address after: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, No. 2 250100 Patentee after: SHANDONG TAIDE NEW ENERGY Co.,Ltd. Address before: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, 250000 No. 2 Building No. 11 Patentee before: JINAN DEVELOPMENT ZONE XINGHUO SCIENCE AND TECHNOLOGY Research Institute |
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Date of cancellation: 20221017 Granted publication date: 20150527 |
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