CN103642538A - Preparation method of methanol-containing environment-friendly gasoline - Google Patents
Preparation method of methanol-containing environment-friendly gasoline Download PDFInfo
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- CN103642538A CN103642538A CN201310725485.6A CN201310725485A CN103642538A CN 103642538 A CN103642538 A CN 103642538A CN 201310725485 A CN201310725485 A CN 201310725485A CN 103642538 A CN103642538 A CN 103642538A
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- CN
- China
- Prior art keywords
- gasoline
- methyl alcohol
- preparation
- prepare
- nanometer
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 195
- 239000003502 gasoline Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 239000000446 fuel Substances 0.000 claims abstract description 19
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000654 additive Substances 0.000 claims abstract description 16
- 230000000996 additive effect Effects 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 28
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 24
- 238000002485 combustion reaction Methods 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 8
- 239000003254 gasoline additive Substances 0.000 claims description 7
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 5
- 238000005339 levitation Methods 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 239000006184 cosolvent Substances 0.000 abstract 1
- 239000000295 fuel oil Substances 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003831 antifriction material Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention belongs to the technical field of fuel oil and particularly relates to a preparation method of methanol-containing environment-friendly gasoline. The preparation method of methanol-containing environment-friendly gasoline comprises the following steps: preparing a nano combustion-supporting additive; preparing a cosolvent; preparing denatured methanol; and preparing an environment-friendly methanol gasoline fuel. The method provided by the invention has the beneficial effects that by adding some common raw materials, the problem in intersolubility between methanol and gasoline is solved; due to use of ferrocene and the nano combustion-supporting additive, the thermal efficiency of fuel is greatly improved, the waste of fuel is reduced, the emission of tail gas is reduced, and an aim of environmental protection is really reached.
Description
Technical field
The invention belongs to oil fuel technical field, be specifically related to a kind of preparation method of the environment protection gasoline containing methyl alcohol.
background technology
Along with the develop rapidly of China's economy, the demand of the energy is day by day increased, especially along with the fast development of automotive industry, the demand of the fuel for motor vehicle causing increases too fast, the exploitation and the consumption that have strengthened petroleum resources.Under the requirement of petroleum resources Conception of Sustainable Development, the exploitation of the vehicle alternative fuel of lasting stability, economic convenient, environment-protecting clean, has special realistic meaning and strategic importance.
A large amount of experimental studies show, alcohols is except oil, Sweet natural gas, the fuel that oil engine can substitute.Alcoholic product can reach the discharge more much lower than hydrocarbon products, reduces the pollution to atmosphere; When using alcohols-gasoline mixed fuel, the structural modification of engine is little, has good inheritance with traditional engine technology.Because the production of ethanol depends on the food crop such as corn, restriction is received in source; By contrast, methyl alcohol wide material sources, adapt to the needs of large-scale industrial production more.
But the popularization of Methanol-gasoline need to solve a lot of technical matters.The polarity of methyl alcohol is extremely strong, but gasoline is the mixed system of multicomponent, low polarity, and within the scope of significant proportion, the two objectionable intermingling of methyl alcohol and gasoline, affects its storage and safe handling.Therefore the key that, methanol gasoline is applied is to solve its stability.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of method of preparation of the environment protection gasoline containing methyl alcohol.
The present invention realizes by following technical scheme containing the preparation method of the environment protection gasoline of methyl alcohol:
The preparation method who contains the environment protection gasoline of methyl alcohol, comprises following step:
Preparation nanometer profit combustion additive; Prepare solubility promoter; Prepare denatured methyl alcohol; Prepare environment-friendly methanol gasoline fuel.
The preparation method of the above-mentioned environment protection gasoline containing methyl alcohol, the method comprises following step:
By following parts by weight, prepare raw material:
Methyl alcohol 15-65, gasoline 15-55, acetone 1.5-3, formaldehyde 0.8-5, ferrocene 0.5-3.5, nanometer profit combustion additive 10-20;
(1) prepare nanometer profit combustion additive: by nano antiwear agent and nanometer gasoline additive, by the weight ratio of 3:15-17, stir standby;
(2) prepare solubility promoter: the acetone of above-mentioned weight part, formaldehyde, ferrocene are mixed, standby;
(3) prepare denatured methyl alcohol: it is in the methyl alcohol of 15-65 that the solubility promoter of above-mentioned weight part is added to weight part, obtains denatured methyl alcohol;
(4) prepare environment-friendly methanol gasoline fuel: the nanometer perfect combustion catalyzer of preparation, denatured methyl alcohol are added in the gasoline of 15-55 weight part successively, fully mix, both obtained environment-friendly methanol gasoline fuel.
Preferably, the parts by weight of above-mentioned raw material are:
Methyl alcohol 15-55, gasoline 15-50, acetone 1.5-2.5, formaldehyde 0.8-4, ferrocene 0.5-3.0, nanometer profit combustion additive 10-20.
Preferred, the parts by weight of above-mentioned raw material are:
Methyl alcohol 20, gasoline 50, acetone 2, formaldehyde 2.5, ferrocene 2.0, nanometer profit combustion additive 15.
Nano antiwear agent is any of AR nano metal anti-wear agent, ER nano metal anti-wear agent, magnetic levitation nano antiwear agent.
The weight ratio of nano antiwear agent and nanometer gasoline additive is 3:17.
Ferrocene is a kind of organo-transition metal compound with aromatic series character.Under normal temperature, be orange-yellow powder, have camphor smell.Fusing point 172 degree-174 degree, boiling point 249 degree, 100 ℃ of above can distillations; Water insoluble, be soluble in the organic solvents such as benzene, ether, gasoline, diesel oil.Do not have an effect with acid, alkali, ultraviolet ray, stable chemical nature, 400 degree do not decompose with interior.Its molecule presents polarity, has high heat stability, chemical stability and radiation resistance, and it has a wide range of applications in industries such as industry, agricultural, medicine, space flight, energy-saving and environmental protection.
Nano antiwear agent contains 30 Determination of multiple metal elements.By the precious nanotechnology of strength power, changed the original molecular structure of metal antifriction material, diameter is generally in 10 nanometers left and right, be visual inspection less than molecule.Add after this product at machinery position; under metal friction effect; hydrocarbon molecules and metallic surface positive charge with cathode charge attract each other; nano metal eutectic ionic species protective membrane; this protective membrane is by the high-strength penetration mechanism of nano metal eutectic ion combination material; in metal inside, be split into, but not outside adhesion.
Beneficial effect of the present invention is, by adding some common raw materials, has solved on the one hand the mutual solubility problem of methyl alcohol and gasoline, the use of ferrocene and nano combustion improver has simultaneously increased the thermo-efficiency of fuel greatly, reduce waste of fuel, reduce exhaust emissions, really reach the object of environmental protection.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Raw material below embodiment 1(is all weight percentage)
Methyl alcohol 20%
93# home-produced fuel 50%
Acetone 3%
Formaldehyde 2%
Ferrocene 3%
Nanometer profit combustion additive 22%
Preparation process is:
(1) preparation of nano profit combustion additive: extracting container A, nano antiwear agent and nanometer gasoline additive are mixed according to the weight ratio of 3:17, standby;
(2) preparation solubility promoter: extracting container B, mixes standby by 3% acetone, 2% formaldehyde, 3% ferrocene;
(3) preparation denatured methyl alcohol: in filling the container C of 20% methyl alcohol, the solubility promoter having configured in (2) is added in container C, stir standby;
(4) preparation environment-friendly methanol gasoline: the nano combustion improver of (1) configuration, the denatured methyl alcohol that (3) have configured are added in the container D that fills 50% gasoline successively, stir and both obtain this environment-friendly methanol gasoline.
Embodiment 2
Methyl alcohol 35%
93# home-produced fuel 40%
Acetone 3%
Formaldehyde 2%
Ferrocene 2%
Nano combustion improver 18%
Preparation process is:
(1) preparation of nano profit combustion additive: extracting container A, nano antiwear agent and nanometer gasoline additive are mixed according to the weight ratio of 3:17, standby;
(2) preparation solubility promoter: extracting container B, mixes standby by 3% acetone, 2% formaldehyde, 2% ferrocene;
(3) preparation denatured methyl alcohol: in filling the container C of 35% methyl alcohol, the solubility promoter having configured in (2) is added in container C, stir standby;
(4) preparation environment-friendly methanol gasoline: the nano combustion improver of (1) configuration, the denatured methyl alcohol that (3) have configured are added in the container D that fills 40% gasoline successively, stir and both obtain this environment-friendly methanol gasoline.
Embodiment 3
Methyl alcohol 45%
93# home-produced fuel 35%
Acetone 3%
Methyl alcohol 2%
Ferrocene 3%
Nano combustion improver 12%
Preparation process is:
(1) preparation of nano profit combustion additive: extracting container A, nano antiwear agent and nanometer gasoline additive are mixed according to the weight ratio of 3:17, standby;
(2) preparation solubility promoter: extracting container B, mixes standby by 3% acetone, 2% formaldehyde, 3% ferrocene;
(3) preparation denatured methyl alcohol: in filling the container C of 45% methyl alcohol, the solubility promoter having configured in (2) is added in container C, stir standby;
(4) preparation environment-friendly methanol gasoline: the nano combustion improver of (1) preparation, the denatured methyl alcohol that (3) have configured are added in the container D that fills 35% gasoline successively, stir and both obtain this environment-friendly methanol gasoline.
Environment friendly methanol gasoline prepared by embodiment 1-3 and regular gasoline carry out Performance Detection, shown in result following table:
Claims (6)
1. contain the preparation method of the environment protection gasoline of methyl alcohol, comprise following step:
Preparation nanometer profit combustion additive; Prepare solubility promoter; Prepare denatured methyl alcohol; Prepare environment-friendly methanol gasoline fuel.
2. the preparation method of the environment protection gasoline containing methyl alcohol as claimed in claim 1, the method comprises following step:
By following parts by weight, prepare raw material:
Methyl alcohol 15-65, gasoline 15-55, acetone 1.5-3, formaldehyde 0.8-5, ferrocene 0.5-3.5, nanometer profit combustion additive 10-20;
(1) prepare nanometer profit combustion additive: by nano antiwear agent and nanometer gasoline additive, by the weight ratio of 3:15-17, stir standby;
(2) prepare solubility promoter: the acetone of above-mentioned weight part, formaldehyde, ferrocene are mixed, standby;
(3) prepare denatured methyl alcohol: it is in the methyl alcohol of 15-65 that the solubility promoter of above-mentioned weight part is added to weight part, obtains denatured methyl alcohol;
(4) prepare environment-friendly methanol gasoline fuel: the nanometer perfect combustion catalyzer of preparation, denatured methyl alcohol are added in the gasoline of 15-55 weight part successively, fully mix, both obtained environment-friendly methanol gasoline fuel.
3. the preparation method of the environment protection gasoline containing methyl alcohol as claimed in claim 1, is characterized in that, the parts by weight of described raw material are:
Methyl alcohol 15-55, gasoline 15-50, acetone 1.5-2.5, formaldehyde 0.8-4, ferrocene 0.5-3.0, nanometer profit combustion additive 10-20.
4. the preparation method of the environment protection gasoline containing methyl alcohol as claimed in claim 1, is characterized in that, the parts by weight of described raw material are:
Methyl alcohol 20, gasoline 50, acetone 2, formaldehyde 2.5, ferrocene 2.0, nanometer profit combustion additive 15.
5. the preparation method of the environment protection gasoline containing methyl alcohol as claimed in claim 1, is characterized in that, described nano antiwear agent is any of AR nano metal anti-wear agent, ER nano metal anti-wear agent, magnetic levitation nano antiwear agent.
6. the preparation method of the environment protection gasoline containing methyl alcohol as claimed in claim 1, is characterized in that, the weight ratio of described nano antiwear agent and nanometer gasoline additive is 3:17.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310725485.6A CN103642538B (en) | 2013-12-25 | 2013-12-25 | Preparation method of methanol-containing environment-friendly gasoline |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310725485.6A CN103642538B (en) | 2013-12-25 | 2013-12-25 | Preparation method of methanol-containing environment-friendly gasoline |
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| Publication Number | Publication Date |
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| CN103642538A true CN103642538A (en) | 2014-03-19 |
| CN103642538B CN103642538B (en) | 2015-05-27 |
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| CN201310725485.6A Active CN103642538B (en) | 2013-12-25 | 2013-12-25 | Preparation method of methanol-containing environment-friendly gasoline |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327890A (en) * | 2014-09-19 | 2015-02-04 | 金景达(北京)环保动力科技有限公司 | Environmentally-friendly high-efficiency methanol gasoline composite additive |
| CN110129104A (en) * | 2019-05-20 | 2019-08-16 | 陈荣钦 | A kind of preparation method of nano-fluid diesel antiwear additive |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418241A (en) * | 2008-12-01 | 2009-04-29 | 石联峰 | Methanol gasoline fuel |
-
2013
- 2013-12-25 CN CN201310725485.6A patent/CN103642538B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418241A (en) * | 2008-12-01 | 2009-04-29 | 石联峰 | Methanol gasoline fuel |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327890A (en) * | 2014-09-19 | 2015-02-04 | 金景达(北京)环保动力科技有限公司 | Environmentally-friendly high-efficiency methanol gasoline composite additive |
| CN110129104A (en) * | 2019-05-20 | 2019-08-16 | 陈荣钦 | A kind of preparation method of nano-fluid diesel antiwear additive |
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| Publication number | Publication date |
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| CN103642538B (en) | 2015-05-27 |
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Effective date of registration: 20160314 Address after: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, No. 2 250100 Patentee after: SHANDONG TAIDE NEW ENERGY Co.,Ltd. Address before: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, 250000 No. 2 Building No. 11 Patentee before: JINAN DEVELOPMENT ZONE XINGHUO SCIENCE AND TECHNOLOGY Research Institute |
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