A kind of cotton and the processing method of copper alginate mixed yarn
Technical field
The application is related to the processing method of a kind of cotton and copper alginate mixed yarn, belongs to the technology neck of manufacture yarn
Domain.
Background technology
Marine alga, is the ancient low green algae plant of a raw class in ocean.Marine algae resource enriches very much in the world,
Various in style, it is estimated that to have nearly ten thousand kinds, the economic algae for having utilized at present has more than 100 kinds, including brown algae, red algae, green alga
Class and blue algae.The global main grown place of algae concentrates on Asia, especially China, Japan and the Korea peninsula, the yield on three ground
2/3rds of total output have been accounted for, and the output value then accounts for 96% or so.
Acidization or the extractible sodium alginate of calcification are utilized from natural seaweed, as weight prepared by alginic acid fibre
Want raw material.Marine alga Acidity is active, there is good ion exchanging function, can be with many kinds of metal ions such as Ca2+、Cu2+、Fe2 +、Zn2+There is displacement reaction in plasma.From 2000, domestic enterprise and academic institution started to research and develop alginate fiber.
2011, China Textile Science Inst. just completed the alginate fiber production line that an annual production is 10t.The whole nation is same within 2006
Industry leading products sodium alginate production capacity reaches 48750 tons, and You20Duo Jia manufacturing enterprises of Shandong Province, production capacity reaches
41900 tons, account for the 86% of the whole nation.About 34000 tons of the estimation of national sodium alginate actual production in 2006, Shandong Province's alginic acid
About 30000 tons or so of sodium yield, accounts for the whole nation 90%.Alginate fiber is more environmentally friendly harmless compared with chemical fibre preparation process, can
It is widely used in weaving, takes, the field such as medical treatment, wherein copper alginate fiber is with sodium alginate as raw material, with Cu2+By one
Sequence of ion is exchanged, a kind of novel alga silicate fiber being made through wet spinning.Alginate (copper) fiber is because containing a large amount of
Copper ion, with good antibacterial bacteriostatic performance and highly hygroscopic, good biocompatibility, and can be used as anti-electromagnetic radiation, anti-quiet
Electric material, is a kind of new biomass fiber, can be used for dress-goods (such as socks, underwear) exploitation, and its product has
Certain medical functions health care and bacteriostasis, are greatly enlarged textile product diversity, improve added value of product.
But the strength of alginate fibre is relatively low, fragility is larger, and spinnability is poor, at present in the research and development in textile garment field
It is also at starting stage, the rarely seen calcium alginate fibre scribbled of in the market.But calcium alginate fibre, in antibiotic property, fiber is acidproof
The aspects such as alkali, salt stability are not so good as copper alginate fiber, constrain its application on garment industry.At this stage, sea is had no
Alginic acid copper fiber is introduced with the yarn product species of cotton fiber with yarn processing method.Cotton is introduced by by copper alginate fiber
The exploitation of product, on the one hand can solve the shortcoming that cotton Products are also easy to produce mould, on the other hand can lift the antibacterial of product
Bacteria resistance function, so as to lift added value of product.But conventional spinning technique is used, because copper alginate fiber spinnability is poor, cause
Copper alginate fiber is relatively low compared with design content in actual yarn, and yarn can spin the deficiencies such as the dry difference of the low, bar of branch, the application will from into
The reconstruct of yarn operation is set out with technological design angle, copper alginate fiber and the unmanageable problem of cotton blend is solved, with this abundant work(
Can cotton yarn species, lifting yarn product added value, for textile industry transition and upgrade provides technical support and product solution.
Based on this, the application is made.
The content of the invention
For the drawbacks described above existing for existing copper alginate mixed yarn, the application provides a kind of few filoplume, strength height, cotton
Knot less, the processing method of the cotton that bar makes a good job of and copper alginate mixed yarn.
To achieve the above object, the technical scheme that the application takes is as follows:
A kind of cotton and the processing method of copper alginate mixed yarn, by copper alginate fiber and cotton respective pretreatment, mix equal
Opening picking, cotton carding, combing, drafting, rove, spun yarn treatment are carried out after even successively, described opening and cleaning step includes:Will mixing fibre
Dimension sequentially passes through griping cotton machine, mixed cotton slitter, roller card wire opener, vibration feeding hopper and single beater scutcher and is processed,
In processing procedure, closing roller card wire opener, all hired roughneck's bottom drains of single beater scutcher;Strike gauge is gripped using half,
Striking point is 25~45mm with the distance for gripping point, and striking point increases by 40~60% with the distance for gripping point, and maximizing is avoided
Copper alginate fibre damage;The blow speed of the hired roughneck of single beater scutcher is 480~680r/min, and reduction amplitude is to spin cotton
65~75%, reduce too small can formation to marine alga copper fiber and damage, a large amount of short flannels are produced, reduce conference and cause fiber block shredding
It is impermeable, the normal combing in road after influence;Described carding step partly grips licker-in release using controllable type, and cotton carding eedle cloth uses work
Make angle small, and low density pin tooth;Feed plate raises 10~15mm, produces a large amount of short flannels due to gripping shredding to reduce, mistake
Low short fiber content is higher, and too high shredding effect deteriorates;Reduce point a comb part speed, 700~750rpm of licker-in speed, cylinder speed 250
~280rpm, 18~22rpm of doffer speed, too fast short fiber content are higher, and excessively slow shredding effect deteriorates;50~80mm/ of cover plate speed
Min, too fast flat strips amount increases, and too low cotton knot increases.The application carries out technological design to opening picking, carding step, reduces sea
Alginic acid copper fiber overwhelms intensity, and maximizing reduces copper alginate fibre loss, improves copper alginate fiber row yielding.
Further, as preferred:
The preprocessing process of the copper alginate fiber includes:Copper alginate fiber is placed in healthy liquid to be carried out at health
Reason, healthy liquid includes auxiliary agent and water, and auxiliary agent is 1 with the volume proportion of water:4~1:2, preferably 1:3.5~1:2, water be 50~
60 DEG C of warm water, auxiliary agent includes soft finish and hydrophilic infiltration finish, and the volume proportion of soft finish and hydrophilic infiltration finish is
1.5:1~3.5:1, the preferably volume proportion of softness finish and hydrophilic infiltration finish is 2:1~3.5:1;Healthy liquid and alginic acid
The weight ratio of copper fiber raw material is 1:20~1:10, conditioned time is 18~30 hours., there is fibre in the easy brittle failure of copper alginate fiber
Dimension cohesive force, the low, fragility of strength are larger, the problems such as spinnability is poor, processed by the health before spinning, improve the pliability of fiber
And spinnability.Healthy liquid provided herein has good spreadability and permeability, can increase the cohesive force of fiber and soft
Softness, and the coefficient of friction in copper alginate spinning process can be effectively improved, reduce damage of the spinning process combing strike to fiber
Wound.
The preprocessing process of the cotton fiber includes:By raw cotton by, into bar, being broken after opening picking and carding step treatment
Afterwards into bag;Or, by raw cotton by, into bar, breaking Hou Chengbao after the treatment of opening picking, cotton carding and combing process.
Described includes the specific steps that pretreated copper alginate fiber and cotton fiber mix:Will be pretreated
Copper alginate fiber and cotton fiber first mix according to a certain percentage, and the fiber that will be mixed mixes with cotton fiber can so make again
Obtain the distribution of copper alginate fiber more uniform, carrying out case according to the requirement of spun number on bale plucker mixes.Cotton long-staple cotton content
Improved with the raising of the count of yarn.
It is 90~120 that described Roving Frames use roving twist factor, and increase twist factor control is spinned than conventional pure cotton
Twist factor is high by 10%~15%.Copper alginate fibre cohesion is small, and twist factor is too small, easily causes rove unwinding broken end, excessive
" hardhead " easily is produced, drawing-off is difficult.
Described spinning process gathers negative pressure for 2.1kPa~3.1kPa using SEILE textile Yarn spinning method is gathered.The application
Negative pressure will be gathered and improve 10~25%, to improve the collection efficiency of alginic acid fibre yarn.
The cotton is 7tex~20tex, copper alginate fiber in the mixed yarn with copper alginate fiber blend yarn line density
Quality is than content between 3-20%;Cotton and the coefficient on variation CV (%) of copper alginate fiber blend yarn:12~20, filoplume
Index:3.00~4.5, fracture strength (cN/tex):13~22, strength variable coefficient CV (%):9~15;Cotton and copper alginate
Fiber blend yarn is 96 to the bacteriostasis rate of staphylococcus glucose coccus, Escherichia coli, Pseudomonas aeruginosa and Candida albicans~
99.999%.
The application is beneficial in that:
1) spinning equipment based on cotton system is improved, process is simple, and exploitativeness is strong, and process change cost is relatively low.
2) by the transformation for preceding spinning part, solve and copper alginate mixed yarn product process is developed based on cotton system
The more problem of middle copper alginate fibre loss, effectively reduces spinning cost.
3) mixed yarn filoplume is few, and strength is high, and cotton knot is few, and bar makes a good job of, and rove bar does best in quality, in the mistake of production high grade cotton yarn
Cheng Zhong, the production efficiency of spinning frame is high.
4) present application addresses the production difficult problem of branch copper alginate mixed yarn high, by cotton/copper alginate fiber blend
The number of yarn brings up to 80S, meets the demand of production cotton/copper alginate fiber blend high-grade underwear fabric, can be used for socks product, interior
Clothing, the exploitation of high gear shirt fabric.
Specific embodiment
Embodiment 1:The pretreating process of copper alginate fiber
, there is fibre cohesion, low, fragility is larger for strength, spinnability in the easy brittle failure of copper alginate fiber.
Normal practice (such as CN 105012999A) is using copper alginate fiber and the direct blending of absorbent cotton, although Ke Yifu
Give the biocidal property that mixed yarn is good, but intensity, the spinning situation of yarn etc. are not improved, and in other words, it only give only
Scribbled does not assign scribbled processability with the biocidal property of copper alginate fiber.
The present embodiment is pre-processed to copper alginate fiber, to improve its yarn forming performance, the pretreatment of copper alginate fiber
I.e. health treatment major parameter includes ratio, healthy liquid and fiber addition ratio, the conditioned time five of auxiliary agent, water temperature, auxiliary agent and water
The factor of aspect, auxiliary agent is mainly soft finish and is constituted with the mixing ratio of hydrophilic infiltration finish.
(1) it is that soft finish is tested with the volume ratio of hydrophilic infiltration finish auxiliary agent to be constituted, and in 50 DEG C of water temperature, is helped
Agent:Water=1:3rd, healthy liquid:Fiber=1:15th, under the conditions of health 24 hours, hydrophilic infiltration finish is respectively adopted, less than 2:1、2:
1-3.5:1st, higher than 3.5:1 and five classifications of pure soft finish tested, the implementation condition of sequence number 1-9 is as right in table 1
Pure hydrophilic infiltration finish, soft finish are respectively 1 with the volume ratio of hydrophilic infiltration finish:1、1.5:1、2:1、2.5:1、3:1、
3.5:1、4:1 and pure soft oil treatment under concrete technology condition.
(2) in soft finish:Hydrophilic infiltration finish (volume ratio)=2.5:1st, auxiliary agent:Water=1:3rd, healthy liquid:Fiber=
1:15th, under the conditions of health 24 hours, be respectively adopted less than 50 DEG C, 50-60 DEG C, tested higher than 60 DEG C of three intervals, in table 1
The implementation condition of sequence number 10-14 be water temperature be respectively 40 DEG C, 45 DEG C, (50 DEG C referring to the technique corresponding to the sequence number 5 in table 1
Condition), 55 DEG C, 60 DEG C, the concrete technology condition under the conditions of 65 DEG C.
(3) in soft finish:Hydrophilic infiltration finish (volume ratio)=2.5:1st, 50 DEG C of water temperature, healthy liquid:Fiber=1:15、
Under the conditions of health 24 hours, auxiliary agent is respectively adopted and is less than 1 with water volume ratio:2、1:3.5-1:2nd, higher than 1:3.5 3 intervals are entered
Row experiment, the implementation condition of sequence number 15-20 is auxiliary agent and is respectively 1 with water addition volume ratio in table 1:1.5、1:2、1:2.5、
(1:3 referring to the process conditions corresponding to the sequence number 5 in table 1) 1:3.5、1:4、1:Concrete technology condition under the conditions of 4.5.
(4) in soft finish:Hydrophilic infiltration finish (volume ratio)=2.5:1st, 50 DEG C of water temperature, auxiliary agent:Water=1:3rd, health
Under the conditions of 24 hours, healthy liquid is respectively adopted and is less than 1 with fiber volume fraction:10、1:10-1:20th, higher than 1:20 3 intervals are entered
Row experiment, the implementation condition of sequence number 21-26 is healthy liquid and is respectively 1 with fiber addition mass ratio in table 1:8、1:10、1:13、
(1:15 referring to the process conditions corresponding to the sequence number 5 in table 1) 1:20、1:23、1:Concrete technology condition under the conditions of 25.
(5) in soft finish:Hydrophilic infiltration finish (volume ratio)=2.5:1st, 50 DEG C of water temperature, auxiliary agent:Water=1:3rd, health
Liquid:Fiber=1:Under the conditions of 15, be respectively adopted conditioned time less than 18 hours, 18-30 hours, enter higher than 30 hours three intervals
Row experiment, in table 1 implementation condition of sequence number 27-30 be health duration be respectively 12,18, (conditioned time be 24 hours referring to
The process conditions corresponding to sequence number 5 in table 1) concrete technology condition under the conditions of 30,36.
Above-mentioned each concrete technology condition ginseng is shown in Table 1.
The pretreating process condition table of table 1
Comparative example 1
Patent CN 105012999A are that, with sodium alginate as raw material, copper sulfate solution is solidification liquid, prepared by wet spinning
Copper alginate fiber, then degreasing cotton fiber and copper alginate fiber are carried out into blending, raw material and the basic phase of the application of its yarn
Together, distinguishing the main yarn raw material in patent CN 105012999A does not have pretreatment process (mainly copper alginate fiber),
Also particular design is not carried out to opening picking, carding process;And the cotton fiber for using is absorbent cotton, the yarn that rear blending is formed is not
The index of quality is given, the application in gauze and bandage field is only given at, it is impossible to which the application in field is commonly being taken in realization.
By taking 19.44tex cottons/copper alginate fiber 80/20 as an example, contrast table 1 and do not give fiber pretreatment implementation
Journey and finished product effect, referring specifically to shown in table 2.
The yarn main performance index table of comparisons under the different implementation conditions of table 2
Note:D1 in table 2 in comparative example 1 plus any fiber pre-treatment situation.
Be can be seen that with the contrast of table 2 by table 1:
(1) effect of sequence number 1-40 and D1 can be seen that whether under the conditions of what in contrast table 2, pre- using the application
The performance that copper alginate fiber after treatment carries out blending resultant yarn is superior to the technique for being pre-processed.
(2) influence that auxiliary agent is constituted:Whether pure soft finish or pure hydrophilic infiltration finish, its resultant yarn to yarn
Can all have and have some improvement, but pure soft finish is used alone, it is impossible to finish uniformly penetrating is entered copper alginate fine
Dimension aggregate, the stability spun of fiber is bad;Pure hydrophilic infiltration finish is used alone, to the softness lubrication of copper alginate fiber
Performance is not significantly improved, therefore suitable softness finish should be selected to be compounded with hydrophilic infiltration finish.When soft finish with
The volume ratio of hydrophilic infiltration finish is less than 1.5:When 1, soft finish consumption is very few, and the fragility of fiber fails to be changed very well
Kind, yarn forming performance is poor;With soft finish and it is hydrophilic infiltration finish volume ratio gradually increase, when soft finish with it is hydrophilic
The volume ratio for permeating finish is higher than 1.5:When 1, its resultant yarn ultimate strength and evenness fault performance gradually improve, and especially work as softness
Finish is with the hydrophilic volume ratio for permeating finish between 2:1-3.5:When 1, yarn forming performance is stablized relatively;But continue to increase the ratio,
When soft finish is higher than 3.5 with the volume ratio of hydrophilic infiltration finish:When 1, especially when soft finish and hydrophilic infiltration finish
Volume ratio is higher than 4:1, the effect enhancing of soft finish, fiber is excessively soft, easily occurs tacky phenomenon between fiber, deteriorates resultant yarn
Energy.Therefore, when soft finish is controlled 2 with the volume ratio of hydrophilic infiltration finish:1-3.5:When 1, yarn forming performance is optimal.
(3) influence of water temperature:When water temperature is less than 45 DEG C, because the activity of auxiliary molecules is not enough, cause health effect not
It is good;With increasing for temperature, when water temperature is higher than 45 DEG C, especially when water temperature is higher than 50-60 DEG C, the activity of auxiliary agent is with stabilization most
Good, health is worked well, and the fragility of copper alginate fiber is improved very well, resultant yarn fracture strength is higher and evenness fault compared with
It is low;But when temperature continues to raise, when temperature is increased to more than 65 DEG C higher than 60 DEG C, especially temperature, the stability of auxiliary agent
It is affected, so as to reduce this health effect, yarn forming performance reduction.
(4) addition of the composition of healthy liquid and healthy liquid, conditioned time form mutual verifying relationship, and the shadow of healthy liquid
Ring and depend on composition, water temperature and the auxiliary agent of auxiliary agent and the percentage of water again, addressed before the above two influence, this place master
Will be with the percentage of auxiliary agent and water as emphasis is commented, auxiliary agent is Main Function composition in healthy liquid, when its ratio is higher, cost
Higher but not notable to the resultant yarn influential effect of yarn, integrated cost is considered with resultant yarn effect, and auxiliary agent is suitable with the volume ratio of water
Control is 1:Less than 2;But the addition of water is also unsuitable too high, and the concentration of otherwise healthy liquid is too low, health effect on driving birds is not good;Therefore,
Considering for the factors such as integrated treatment cost, process cycle and treatment effect, preferably controls 1 the volume ratio of auxiliary agent and water:4~1:
2nd, water temperature control in 50~60 DEG C, the weight of healthy liquid and copper alginate fibrous raw material than control 1:20~1:10th, during health
Between control at 18~30 hours.
Embodiment 2:The setting of opening picking, carding process
Based on the easy brittle failure of copper alginate fiber, there are problems that fibre cohesion, low, fragility is larger for strength, spinnability,
The present embodiment is tested to the opening picking of yarn material (copper alginate fiber, cotton), carding process, fine to reduce copper alginate
The intensity that overwhelms is tieed up, copper alginate fiber row yielding, opening picking are improved for the purpose of maximization reduction copper alginate fibre loss
The major parameter of technique is striking point and grip the distance of point, factor of both blow speed, the major parameter of cotton carding be to
Cotton plate height, point comb part speed and the aspect of cover plate speed three.
(1) opening and cleaning step includes:Composite fibre is sequentially passed through into griping cotton machine, mixed cotton slitter, roller card wire opener, is shaken
Dynamic feeding hopper and single beater scutcher are processed, in processing procedure, closing roller card wire opener, single beater scutcher
All hired roughneck's bottom drains;Strike gauge is gripped using half, striking point and the distance for gripping point are 25~45mm, striking point and gripping point
Distance increase by 40~60%, maximizing avoids copper alginate fibre damage;The blow speed of the hired roughneck of single beater scutcher
It is 480~680r/min, reduction amplitude is spin cotton 65~75%, reduces too small can formation to marine alga copper fiber and damage, produces
A large amount of short flannels, reduced conference and cause fiber block shredding impermeable, the normal combing in road after influence.
(2) carding step partly grips licker-in release using controllable type, and cotton carding eedle cloth is small and low density using operating angle
Pin tooth;Feed plate raises 10~15mm, and a large amount of short flannels are produced due to gripping shredding to reduce, and too low short fiber content is higher, too high
Shredding effect deteriorates;Reduce point a comb part speed, 700~750rpm of licker-in speed, 250~280rpm of cylinder speed, doffer speed
18~22rpm, too fast short fiber content is higher, and excessively slow shredding effect deteriorates;50~80mm/min of cover plate speed, too fast flat strips amount increases
Plus, too low cotton knot increases.
Be can be seen that using the implementation condition of the application using the implementation result of the application and comparative example, can be very good
Copper alginate fiber is reduced to overwhelm intensity, and maximized reduction copper alginate fibre loss, compared with comparative example, overwhelm
Intensity reduces by 50%, copper alginate fibre loss reduction by 50%, so that copper alginate fiber is fine with the copper alginate of silk/cotton blended yarn
Dimension row yielding increases 50% compared with comparative example.
Embodiment 3:The processing of the high-grade underwear mixed yarn of 7.29tex cottons/copper alginate fiber 97/3
The high-grade underwear mixed yarn of 7.29tex cottons/copper alginate fiber 97/3 of the present embodiment production, raw cotton selects 6800
~7200Nm.Specific implementation process is as follows:By healthy liquid:Copper alginate fiber presses 1:10 carry out the treatment of health in 24 hours, then
With after shredding removal of impurities into bar, break into bag sliver carried out on bale plucker case mix;Opening and cleaning step grips strike using half
Gauge, striking point is 35mm with the distance for gripping point, and the blow speed of the hired roughneck of single beater scutcher is 720r/min;Cotton carding work
Sequence feed plate raises 12mm;Reduce point a comb part speed, licker-in speed 730rpm, cylinder speed 270rpm, doffer speed 22rpm;
Cover plate speed 70mmpm;Roving Frames roving twist factor is 116;Using SEILE textile spinning is gathered, gather negative pressure is spinning process
2.3kPa。
Yarn quality is:Coefficient on variation CV (%):12.5, hairiness index:3.11, details (- 50%, individual/km):
13, slubbing (+50%, individual/km):55, cotton knot (+200%, individual/km):90, fracture strength (cN/tex):21.5, Strength Variance
Coefficient CV (%):9.8;To staphylococcus glucose coccus, Escherichia coli, Pseudomonas aeruginosa bacteriostasis rate up to 97%, to Candida albicans
The bacteriostasis rate of bacterium is up to 95%.
Embodiment 4:The processing of the high-grade underwear mixed yarn of 11.66tex cottons/copper alginate fiber 90/10
The high-grade underwear mixed yarn of 11.66tex cottons/copper alginate fiber 90/10 of production, raw cotton from 6800~
7200Nm.Specific implementation process is as follows:By healthy liquid:Copper alginate fiber presses 1:13 carry out the treatment of health in 24 hours, Ran Houyu
After shredding removal of impurities into bar, break into bag sliver carried out on bale plucker case mix;Opening and cleaning step using half grip strike every
Away from striking point is 32mm with the distance for gripping point, and the blow speed of the hired roughneck of single beater scutcher is 680r/min;Carding step
Feed plate raises 12mm;Reduce point a comb part speed, licker-in speed 720rpm, cylinder speed 255rpm, doffer speed 21rpm;Lid
Plate speed 65mmpm;Roving Frames roving twist factor is 112;Using SEILE textile spinning is gathered, gather negative pressure is spinning process
2.6kPa。
Yarn quality is:Coefficient on variation CV (%):13.9, hairiness index:3.22, details (- 50%, individual/km):
14, slubbing (+50%, individual/km):60, cotton knot (+200%, individual/km):98, fracture strength (cN/tex):19.5, Strength Variance
Coefficient CV (%):10.5;To staphylococcus glucose coccus, Escherichia coli, Pseudomonas aeruginosa bacteriostasis rate up to 99%, to Candida albicans
The bacteriostasis rate of bacterium is up to 97%.
Embodiment 5:The processing of the high-grade underwear mixed yarn of 19.44tex cottons/copper alginate fiber 85/15
The high-grade underwear mixed yarn of 19.44tex cottons/copper alginate fiber 85/15 of production, raw cotton from 6800~
7200Nm.Specific implementation process is as follows:By healthy liquid:Copper alginate fiber presses 1:15 carry out the treatment of health in 36 hours, Ran Houyu
After shredding removal of impurities into bar, break into bag sliver carried out on bale plucker case mix;Opening and cleaning step using half grip strike every
Away from striking point is 30mm with the distance for gripping point, and the blow speed of the hired roughneck of single beater scutcher is 620r/min;Carding step
Feed plate raises 12mm;Reduce point a comb part speed, licker-in speed 700rpm, cylinder speed 260rpm, doffer speed 20rpm;Lid
Plate speed 60mmpm;Roving Frames roving twist factor is 108;Using SEILE textile spinning is gathered, gather negative pressure is spinning process
2.8kPa。
Yarn quality is:Coefficient on variation CV (%):14.0, hairiness index:4.2, details (- 50%, individual/km):15,
Slubbing (+50%, individual/km):60, cotton knot (+200%, individual/km):107, fracture strength (cN/tex):17, strength variable coefficient
CV (%):9.1;To staphylococcus glucose coccus, Escherichia coli, Pseudomonas aeruginosa bacteriostasis rate up to 99.999%, to Candida albicans
The bacteriostasis rate of bacterium is up to 99.9%.