CN108265360A - A kind of antimicrobial yarn - Google Patents

A kind of antimicrobial yarn Download PDF

Info

Publication number
CN108265360A
CN108265360A CN201810262064.7A CN201810262064A CN108265360A CN 108265360 A CN108265360 A CN 108265360A CN 201810262064 A CN201810262064 A CN 201810262064A CN 108265360 A CN108265360 A CN 108265360A
Authority
CN
China
Prior art keywords
fiber
copper
antimicrobial yarn
fibre
alginate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810262064.7A
Other languages
Chinese (zh)
Inventor
杨所平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Silver Mega Mstar Technology Ltd
Original Assignee
Jiangsu Silver Mega Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Silver Mega Mstar Technology Ltd filed Critical Jiangsu Silver Mega Mstar Technology Ltd
Priority to CN201810262064.7A priority Critical patent/CN108265360A/en
Publication of CN108265360A publication Critical patent/CN108265360A/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/12Threads containing metallic filaments or strips
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/20Metallic fibres

Abstract

The invention discloses a kind of antimicrobial yarn, it is characterized in that:Including metal copper fiber of the weight percent for 1 10%, 1 10% copper alginate fiber and 80 98% general fibre, above-mentioned fiber is prepared through blended weave.Gained antimicrobial yarn has very efficiently with lasting antibacterial effect, and repeatedly the bacteriostasis rate to Escherichia coli, gold-coloured staphylococci and Candida albicans after washing is all higher than 99.9%, in addition, also having good antistatic property.

Description

A kind of antimicrobial yarn
Technical field
The present invention relates to a kind of antimicrobial yarns.
Background technology
Textile fiber is the good boarding ground of bacterium, use or wearing process in, particularly those personal are worn Underwear, socks etc., since its specific temperature and humidity is particularly easy to grow bacterium, this can not only generate offending gas Taste, but also pruitus may be caused, it is also possible to intersection either be caused to be felt by contacting transmitted diseases under serious situation Dye.With the improvement of living standards, people become more concerned with health and cleaning problems, the requirement for textile is also no longer only Original function is limited only to, this shows that the demand to functions such as hygiene health cares is continuously improved.It is possible thereby to it predicts anti- The application of bacterium textile and demand can be more and more.
It is a kind of sodium alginate being extract from natural seaweed through wet spinning system for the alginate fibre of textile Make the alginate fiber formed.Wherein seaweed Acidity is active, there is good ion exchanging function, can with various metals from Son such as Ca2+、Cu2+、Zn2+Displacement reaction occurs for plasma.Such as by with Cu2+Ion carries out the seaweed obtained after ion exchange Sour copper fiber, other than having the excellent hygroscopicity of alginate fibre and biocompatibility, also with good antibacterial effect.
Such as Chinese patent CN104947265A and CN106884239A all respectively disclose a kind of copper alginate fiber with The preparation method of cotton fiber blended antibacterial yarn.Although obtained yarn has good antibacterial effect, this antibacterial effect The fruit effect that only yarn has before washing.Actually when copper alginate fiber is after moisture is touched, can by with Cation in water carries out ion exchange and releases copper ion, and copper alginate fiber mainly acts as copper ion herein Carrier, and really play bactericidal effect is copper ion that those are released.This requires copper alginate fibers every time Enough copper ions can be released and just can ensure that enough antibacterial effects.When the fabric containing copper alginate fiber washing when Wait, the loss of a large amount of copper ions is inevitable, therefore with the increase of washing times its antibacterial effect decline therewith be must Right result.Therefore, it can be seen that the antibacterial effect for largely remaining permanent using copper alginate fiber is not simply relied on also not It can finally solve the problems, such as, moreover largely certainly will influence whether the feel of final products and other property using copper alginate fiber Can, so as to limit the scope of application of product.
Invention content
Contain metallic copper with persistent high efficiency antibacterial effect in view of the deficiencies of the prior art, the present invention provides a kind of The antimicrobial yarn of fiber and copper alginate fiber,
To achieve the above object, invention provides following technical solution:
A kind of antimicrobial yarn, including weight percent be the metal copper fiber of 1-10%, 1-10% copper alginate fiber With the general fibre of 80-98%, above-mentioned fiber is prepared through blended weave.
Further setting of the invention:Metallic copper of the metal copper fiber for threadiness.
Further setting of the invention:Copper alloy of the metal copper fiber for threadiness, the weight hundred of copper in the copper alloy Divide than being more than 50%.
Further setting of the invention:The metal copper fiber prepares institute by synthetic fibers by chemical plating or Vacuum Deposition .
Further setting of the invention:The metal copper fiber is staple fiber, and wherein length is 2-6 centimetres, a diameter of 1-60 Micron.
Further setting of the invention:The copper alginate fiber is using water soluble algae hydrochlorate as raw material, in soluble divalent It is prepared in the aqueous solution of mantoquita through wet spinning.
Further setting of the invention:The copper alginate fiber is using alginate fiber as raw material, in soluble cupric It is prepared in the aqueous solution of salt through ion exchange.
Further setting of the invention:The copper alginate fiber is staple fiber, and wherein length is 2-6 centimetres, a diameter of 5-100 Micron.
Further setting of the invention:The general fibre is cotton fiber, regenerated celulose fibre, flaxen fiber, bamboo fibre, shell Glycan fiber, polyester fiber, nylon fibre, acrylic fiber, polypropylene fiber, one kind in vinylon fibre, polyvinyl chloride fibre fiber and wool Or two or more mixture.
Advantageous effect of the present invention:The surface of metallic copper has a kind of special bactericidal mechanism (contact sterilization), to many kinds Pathogen microorganism, bacterium, yeast and virus have good inhibition, for certain bacteriums, several seconds time of contact, number Ten seconds effects that just can reach sterilizing.It is molten in addition to requiring but if being not in contact with and being sterilized just with copper ion Copper ion concentration in liquid reaches except certain value, and required time is also veryer long.In addition, in dry environments, metallic copper Contact sterilization effect is more prominent, and this characteristic is particularly conducive to application on the textile, because can keep constantly in this way Health on textile surface prevents the diffusion and propagation of germ.
Therefore gained yarn not only has very efficient antibacterial effect when coordinating metal copper fiber and copper alginate fiber, But also with very lasting antibacterial effect, mainly there are two aspects for the effect that metal copper fiber here functions as:First, it provides Bactericidal and bacteriostatic effect is played in the surface of one metallic copper by contact sterilization mechanism;Second, copper ion is released in water, is released The copper ion released can both play the role of sterilization combined with bacterium, can also be carried out with neighbouring copper alginate fiber from Son exchanges to supplement the copper ion being lost in copper alginate fiber, so as to maintain the persistence of copper alginate fibre antibacterial, To common several bacteriums after being washed even across 50 times, for example, Escherichia coli, the suppression of gold-coloured staphylococci, Candida albicans Bacterium rate is still up to 99.9%;Since the additive amount of metal copper fiber and copper alginate fiber ratio is relatively low, the feel of gained yarn It is similary with common yarn, do not change significantly.In addition, gained fiber tool also has good antistatic property.
Specific embodiment
The present invention is further elaborated with specific example below,
A kind of antimicrobial yarn, including weight percent be the metal copper fiber of 1-10%, 1-10% copper alginate fiber With the general fibre of 80-98%, above-mentioned fiber is prepared through blended weave, wherein blended weave for the prior art just no longer It repeats.
Wherein metal copper fiber is the metallic copper of threadiness or be fibrous copper alloy, the weight of copper in the copper alloy It measures percentage and is more than 50% either by synthetic fibers by chemical plating or Vacuum Deposition preparation gained.
Wherein described metallic copper fiber is staple fiber, and wherein length is 2-6 centimetres, 1-60 microns a diameter of
Wherein described copper alginate fiber is raw material in soluble divalent with water soluble algae hydrochlorate, such as sodium alginate It is prepared in the aqueous solution of mantoquita through wet spinning;It is raw material either with alginate fiber, such as calcium alginate fibre It is prepared in the aqueous solution of soluble cupric salt through ion exchange.
Wherein the copper alginate fiber is staple fiber, and wherein length is 2-6 centimetres, 5-100 microns a diameter of.
The general fibre is cotton fiber, regenerated celulose fibre, flaxen fiber, bamboo fibre, chitin fiber, terylene are fine The mixing of one or more of dimension, nylon fibre, acrylic fiber, polypropylene fiber, vinylon fibre, polyvinyl chloride fibre fiber and wool Object.
Embodiment 1:
A kind of antimicrobial yarn, including metal copper fiber of the weight percent for 8%, 7% copper alginate fiber and 85% Cotton fiber, above-mentioned fiber is prepared through blended weave, the count of yarn be 32S.
According to national standard《FZ/T73023-2006 (concussion method) appendix C is washed 50 times》Checked, to Escherichia coli, The bacteriostasis rate of gold-coloured staphylococci and Candida albicans is all higher than 99.99%, and gained yarn remains the characteristic of cotton yarn, hand Sense is soft, can be applied in a variety of textiles.
Embodiment 2:
A kind of antimicrobial yarn is 5% metal copper fiber, 5% copper alginate fiber, 45% cotton including weight percent Fiber and 45% polyester fiber, above-mentioned fiber is prepared through blended weave, and the count of yarn is 50S.
According to national standard《FZ/T73023-2006 (concussion method) appendix C is washed 50 times》Checked, to Escherichia coli, The bacteriostasis rate of gold-coloured staphylococci and Candida albicans is all higher than 99.9%.Gained yarn remains the characteristic of polyester, feel Softness can be applied in a variety of textiles.
Embodiment 3:
A kind of antimicrobial yarn is 2% metal copper fiber, 5% copper alginate fiber, 93% cotton including weight percent Above-mentioned fiber is prepared fiber through blended weave, and the count of yarn is 80S.
According to national standard《FZ/T73023-2006 (concussion method) appendix C is washed 50 times》Checked, to Escherichia coli, The bacteriostasis rate of gold-coloured staphylococci and Candida albicans is all higher than 99.9%.Gained yarn remains the characteristic of cotton yarn, and feel is soft It is soft, it can be applied in a variety of textiles.
Particular technique and condition person are not specified in above-described embodiment, according to the described technology of document in the art or item Part is carried out, agents useful for same or instrument by the description of product, and being can be with conventional products that are commercially available.
The above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications It should be regarded as protection scope of the present invention.

Claims (9)

1. a kind of antimicrobial yarn, it is characterized in that:It is the metal copper fiber of 1-10% including weight percent, the alginic acid of 1-10% Above-mentioned fiber is prepared the general fibre of copper fiber and 80-98% through blended weave.
2. a kind of antimicrobial yarn according to claim 1, it is characterized in that:Metallic copper of the metal copper fiber for threadiness.
3. a kind of antimicrobial yarn according to claim 1, it is characterized in that:Copper alloy of the metal copper fiber for threadiness, The weight percent of copper is more than 50% in the copper alloy.
4. a kind of antimicrobial yarn according to claim 1, it is characterized in that:The metal copper fiber is by synthetic fibers by chemistry Plating or Vacuum Deposition prepare gained.
5. according to claims 1 or 2 or a kind of 3 or 4 antimicrobial yarns, it is characterized in that:The metal copper fiber is staple fiber, Wherein length is 2-6 centimetres, 1-60 microns a diameter of.
6. a kind of antimicrobial yarn according to claim 1, it is characterized in that:The copper alginate fiber is with water soluble algae hydrochlorate For raw material, it is prepared in the aqueous solution of soluble cupric salt through wet spinning.
7. a kind of antimicrobial yarn according to claim 1, it is characterized in that:The copper alginate fiber using alginate fiber as Raw material is prepared in the aqueous solution of soluble cupric salt through ion exchange.
8. according to a kind of 1 or 6 or 7 antimicrobial yarn of claim, it is characterized in that:The copper alginate fiber is staple fiber, Middle length is 2-6 centimetres, 5-100 microns a diameter of.
9. a kind of antimicrobial yarn according to claim 1, it is characterized in that:The general fibre is cotton fiber, regenerated cellulose Fiber, flaxen fiber, bamboo fibre, chitin fiber, polyester fiber, nylon fibre, acrylic fiber, polypropylene fiber, vinylon fibre, chlorine The mixture of one or more of synthetic fibre fiber and wool.
CN201810262064.7A 2018-03-27 2018-03-27 A kind of antimicrobial yarn Pending CN108265360A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810262064.7A CN108265360A (en) 2018-03-27 2018-03-27 A kind of antimicrobial yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810262064.7A CN108265360A (en) 2018-03-27 2018-03-27 A kind of antimicrobial yarn

Publications (1)

Publication Number Publication Date
CN108265360A true CN108265360A (en) 2018-07-10

Family

ID=62777828

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810262064.7A Pending CN108265360A (en) 2018-03-27 2018-03-27 A kind of antimicrobial yarn

Country Status (1)

Country Link
CN (1) CN108265360A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109440245A (en) * 2019-01-10 2019-03-08 江苏银兆新材料科技有限公司 A kind of antimicrobial composite yarns and preparation method thereof
CN112359456A (en) * 2020-09-27 2021-02-12 际华三五四二纺织有限公司 Preparation process of copper ion polyester fiber and regenerated cellulose fiber antibacterial high count yarn
CN112981663A (en) * 2021-02-18 2021-06-18 天津市元生泰科技有限公司 Novel magnetic balance garment and production method thereof
CN113718394A (en) * 2021-09-27 2021-11-30 邦威防护科技股份有限公司 Production method of comfortable and soft special protective clothing fabric

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104947265A (en) * 2015-07-09 2015-09-30 厦门百美特生物材料科技有限公司 Low-cost yarn with good antibacterial effect
CN204702874U (en) * 2015-03-26 2015-10-14 上海奥领纺织新材料有限公司 Copper fiber radiation-proof antibacterial functions stocking yarn
CN205711179U (en) * 2016-05-09 2016-11-23 刘春梅 A kind of function antibiotic facing material
CN106884239A (en) * 2017-04-06 2017-06-23 绍兴华通色纺有限公司 A kind of cotton and the processing method of copper alginate mixed yarn

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204702874U (en) * 2015-03-26 2015-10-14 上海奥领纺织新材料有限公司 Copper fiber radiation-proof antibacterial functions stocking yarn
CN104947265A (en) * 2015-07-09 2015-09-30 厦门百美特生物材料科技有限公司 Low-cost yarn with good antibacterial effect
CN205711179U (en) * 2016-05-09 2016-11-23 刘春梅 A kind of function antibiotic facing material
CN106884239A (en) * 2017-04-06 2017-06-23 绍兴华通色纺有限公司 A kind of cotton and the processing method of copper alginate mixed yarn

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109440245A (en) * 2019-01-10 2019-03-08 江苏银兆新材料科技有限公司 A kind of antimicrobial composite yarns and preparation method thereof
CN112359456A (en) * 2020-09-27 2021-02-12 际华三五四二纺织有限公司 Preparation process of copper ion polyester fiber and regenerated cellulose fiber antibacterial high count yarn
CN112981663A (en) * 2021-02-18 2021-06-18 天津市元生泰科技有限公司 Novel magnetic balance garment and production method thereof
CN113718394A (en) * 2021-09-27 2021-11-30 邦威防护科技股份有限公司 Production method of comfortable and soft special protective clothing fabric

Similar Documents

Publication Publication Date Title
CN108265360A (en) A kind of antimicrobial yarn
EP1157158B1 (en) Process for making substrates with biocidal properties
DE102006056977B3 (en) Use of an antimicrobial textile composite as a holder to cause a bacteriostatic effect on the objects and materials to be cleaned in the interior of a washing machine or dishwasher, where the holder comprises fibers with cellulose matrix
CN103170004A (en) Argentiferous antibacterial fiber, fabric, wound dressing and preparation method thereof
EP1208262A1 (en) An article of clothing having antibacterial, antifungal, and antiyeast properties
JP2011052338A (en) Antibacterial textile product and manufacturing method thereof
EP1834030A1 (en) Manufacturing methods and applications of antimicrobial plant fibers having silver particles
KR20130094686A (en) Antimicrobial treatment of synthetic nonwoven textiles
CN108315860A (en) A kind of preparation method of Graphene antibiosis towel
CN106149130B (en) A kind of controllable antibacterial towel and preparation method thereof of argentiferous chelating acrylic fiber
JP2006225785A (en) Blended yarn and antimicrobial woven or knitted fabric using the same
US9907311B2 (en) Anti-odour and antibacterial fabric in textile goods
CN108385397A (en) A kind of Chinese fiber crops blended towel of functional gradient function by and preparation method thereof
CN1306102C (en) Bacteria resistant cotton fiber or cotton fabric and preparation method
JP2006225786A (en) Spun yarn in double layer structure and woven or knitted fabric
JP2011127243A (en) Bacteriostatically treating method
JP2009155732A (en) Anti-microbial fiber product and method for producing the same
CN105887242A (en) Preparation method of chitosan copper fibers
CN106192379B (en) Ozonation prepares the method and its anti-bacterial fibre of multivalent state silver system anti-bacterial fibre
CN101168867A (en) Highly effective acarus-proof cellulose viscose with antibiotic action
KR102184455B1 (en) Method for depositing nano silver with excellent antibacterial power and objects to which the nano silver is deposited
JP2008514827A (en) Silver-containing antibacterial fabric
CN104805697A (en) Novel antibacterial finishing agent composition for cotton fabric
JP6801954B2 (en) Antibacterial and antiviral processing agents and processed products using them
CN102877290A (en) Anti-bacterial treatment agent for textile goods

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180710

RJ01 Rejection of invention patent application after publication