CN106854375A - A kind of fibered wood species and preparation method thereof - Google Patents

A kind of fibered wood species and preparation method thereof Download PDF

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Publication number
CN106854375A
CN106854375A CN201611107378.7A CN201611107378A CN106854375A CN 106854375 A CN106854375 A CN 106854375A CN 201611107378 A CN201611107378 A CN 201611107378A CN 106854375 A CN106854375 A CN 106854375A
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China
Prior art keywords
parts
powder
wood
vinyl acetate
ethylene
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CN201611107378.7A
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Chinese (zh)
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戚炎月
丘泰西
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Qinzhou Hi Tech Industry Service Center
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Qinzhou Hi Tech Industry Service Center
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Priority to CN201611107378.7A priority Critical patent/CN106854375A/en
Publication of CN106854375A publication Critical patent/CN106854375A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of fibered wood species and preparation method thereof, it is made up of following mass fraction formula components:10 20 parts of nanometer carbon crystal, 57 parts of modified zeolite powder, 13 parts of activated carbon powder, 20 40 parts of wood-fibred, 46 parts of oyster shell whiting, 68 parts of pentalyn, 57 parts of lignin, 24 parts of tourmaline powder, 57 parts of ethylene-vinyl acetate copolymer, 6 10 parts of butyl acrylate, 68 parts of zinc stearate, 57 parts of nano zinc oxide powder, 13 parts of fire retardant, present invention effect reduces burst size of methanal, it is the staple fibre timber of kind of novel non-toxic environment-friendly antibacterial, woodwork good mechanical performance of the present invention, can be widely applied to furniture, interior decoration simultaneously.

Description

A kind of fibered wood species and preparation method thereof
Technical field
The present invention relates to field of novel, in particular to a kind of fibered wood species and preparation method thereof.
Background technology
With the improvement of people ' s living standards, people live or handle official business to it, the finishing in the place such as activity it is also proposed more Requirement high, not only require it is elegant in appearance, it is modish fashion, naturally succinct, but also require health environment-friendly.And current, China's life The fiberboard overwhelming majority of product uses Lauxite, and being mixed by certain mol proportion by formaldehyde and urea carries out reaction generation ureaformaldehyde tree Fat.Free formaldehyde is remained in fiberboard sheet material using common Lauxite as adhesive, the body for endangering people is good for Health, formaldehyde has stimulation to the schneiderian membrane of human body, retina, respiratory tract and liver, for a long time in high-concentration formaldehyde content Worked in environment and lived, the formaldehyde poisoning symptom such as allergy, dizziness, fatiguability, vomiting occurs, severe patient can cause a disease, or even It is carcinogenic.Form aldehyde release essentially from:1. the free formaldehyde that end is reacted in Lauxite;2. in resin unstable molecule in hot pressing or Formaldehyde is released during sheet material use again.
The content of the invention
The invention provides a kind of fibered wood species and preparation method thereof, present invention effect reduces burst size of methanal, is to plant new The staple fibre timber of type asepsis environment-protecting antibacterial, while woodwork good mechanical performance of the present invention, can be widely applied to furniture, room Interior trim.
To achieve the above object, the present invention provides following technical scheme:
A kind of fibered wood species and preparation method thereof, are made up of following mass fraction formula components:Nanometer carbon crystal 10-20 parts, Modified zeolite powder 5-7 parts, activated carbon powder 1-3 parts, wood-fibred 20-40 parts, oyster shell whiting 4-6 parts, pentalyn 6-8 parts, Lignin 5-7 parts, tourmaline powder 2-4 parts, ethylene-vinyl acetate copolymer 5-7 parts, butyl acrylate 6-10 parts, zinc stearate 6-8 parts, nano zinc oxide powder 5-7 parts, fire retardant 1-3 parts.
Further:It is made up of following mass fraction formula components:10 parts of nanometer carbon crystal, 5 parts of modified zeolite powder, activated carbon powder 1 part, 20 parts of wood-fibred, 4 parts of oyster shell whiting, 6 parts of pentalyn, 5 parts of lignin, 2 parts of tourmaline powder, ethyl vinyl acetate second 5 parts of alkene copolymer, 6 parts of butyl acrylate, 6 parts of zinc stearate, 5 parts of nano zinc oxide powder, 1 part of fire retardant.
Further:It is made up of following mass fraction formula components:15 parts of nanometer carbon crystal, 6 parts of modified zeolite powder, activated carbon powder 2 parts, 30 parts of wood-fibred, 5 parts of oyster shell whiting, 7 parts of pentalyn, 6 parts of lignin, 3 parts of tourmaline powder, ethyl vinyl acetate second 6 parts of alkene copolymer, 8 parts of butyl acrylate, 7 parts of zinc stearate, 6 parts of nano zinc oxide powder, 2 parts of fire retardant.
Further:It is made up of following mass fraction formula components:20 parts of nanometer carbon crystal, 7 parts of modified zeolite powder, activated carbon powder 3 parts, 40 parts of wood-fibred, 6 parts of oyster shell whiting, 8 parts of pentalyn, 7 parts of lignin, 4 parts of tourmaline powder, ethyl vinyl acetate second 7 parts of alkene copolymer, 10 parts of butyl acrylate, 8 parts of zinc stearate, 7 parts of nano zinc oxide powder, 3 parts of fire retardant.
Further:Preparation method of the present invention has following steps:
Step one, ethylene-vinyl acetate copolymer, polyethyleneimine, NaOH are configured to solution;
Step 2, solution is warming up to 70-80 DEG C, adds pentalyn, butyl acrylate, stirring reaction 30- 60min;30-50 DEG C is cooled to, zinc stearate, nano zinc oxide powder stir 1-2h, obtain mixed liquor;
Step 3, by nanometer carbon crystal in appropriate modified zeolite powder, obtain solution, it is standby;
Step 4, by step (3) prepare solution be added to step (2) preparation mixed liquor in, after stirring, add Surplus stock, stirring reaction 1-3h, obtains final product.
The beneficial effects of the invention are as follows:
1st, present invention effect reduces burst size of methanal, is the staple fibre timber of kind of novel non-toxic environment-friendly antibacterial;
2nd, woodwork good mechanical performance of the present invention, can be widely applied to furniture, interior decoration.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of fibered wood species are made up of following mass fraction formula components:Nanometer carbon crystal 10-20 parts, modified zeolite powder 5-7 Part, activated carbon powder 1-3 parts, wood-fibred 20-40 parts, oyster shell whiting 4-6 parts, pentalyn 6-8 parts, lignin 5-7 parts, electricity 2-4 parts of gas stone flour, ethylene-vinyl acetate copolymer 5-7 parts, butyl acrylate 6-10 parts, zinc stearate 6-8 parts, it is nano oxidized Zinc powder 5-7 parts, fire retardant 1-3 parts.
Embodiment two:
A kind of fibered wood species are made up of following mass fraction formula components:10 parts of nanometer carbon crystal, 5 parts of modified zeolite powder, work 1 part of powdered carbon of property, 20 parts of wood-fibred, 4 parts of oyster shell whiting, 6 parts of pentalyn, 5 parts of lignin, 2 parts of tourmaline powder, ethene- 5 parts of acetate ethylene copolymer, 6 parts of butyl acrylate, 6 parts of zinc stearate, 5 parts of nano zinc oxide powder, 1 part of fire retardant.
Embodiment three:
A kind of fibered wood species are made up of following mass fraction formula components:15 parts of nanometer carbon crystal, 6 parts of modified zeolite powder, work 2 parts of powdered carbon of property, 30 parts of wood-fibred, 5 parts of oyster shell whiting, 7 parts of pentalyn, 6 parts of lignin, 3 parts of tourmaline powder, ethene- 6 parts of acetate ethylene copolymer, 8 parts of butyl acrylate, 7 parts of zinc stearate, 6 parts of nano zinc oxide powder, 2 parts of fire retardant.
Example IV:
A kind of fibered wood species are made up of following mass fraction formula components:20 parts of nanometer carbon crystal, 7 parts of modified zeolite powder, work 3 parts of powdered carbon of property, 40 parts of wood-fibred, 6 parts of oyster shell whiting, 8 parts of pentalyn, 7 parts of lignin, 4 parts of tourmaline powder, ethene- 7 parts of acetate ethylene copolymer, 10 parts of butyl acrylate, 8 parts of zinc stearate, 7 parts of nano zinc oxide powder, 3 parts of fire retardant.
Embodiment five:
A kind of preparation method preparation method of fibered wood species comprises the following steps:
Step one, ethylene-vinyl acetate copolymer, polyethyleneimine, NaOH are configured to solution;
Step 2, solution is warming up to 70-80 DEG C, adds pentalyn, butyl acrylate, stirring reaction 30- 60min;30-50 DEG C is cooled to, zinc stearate, nano zinc oxide powder stir 1-2h, obtain mixed liquor;
Step 3, by nanometer carbon crystal in appropriate modified zeolite powder, obtain solution, it is standby;
Step 4, by step (3) prepare solution be added to step (2) preparation mixed liquor in, after stirring, add Surplus stock, stirring reaction 1-3h, obtains final product.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined May be appreciated other embodiment.

Claims (5)

1. a kind of fibered wood species, it is characterised in that:It is made up of following mass fraction formula components:
Nanometer carbon crystal 10-20 parts, modified zeolite powder 5-7 parts, activated carbon powder 1-3 parts, wood-fibred 20-40 parts, oyster shell whiting 4-6 parts, Pentalyn 6-8 parts, lignin 5-7 parts, tourmaline powder 2-4 parts, ethylene-vinyl acetate copolymer 5-7 parts, acrylic acid Butyl ester 6-10 parts, zinc stearate 6-8 parts, nano zinc oxide powder 5-7 parts, fire retardant 1-3 parts.
2. a kind of fibered wood species according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
10 parts of nanometer carbon crystal, 5 parts of modified zeolite powder, 1 part of activated carbon powder, 20 parts of wood-fibred, 4 parts of oyster shell whiting, rosin pentaerythrite 6 parts of ester, 5 parts of lignin, 2 parts of tourmaline powder, 5 parts of ethylene-vinyl acetate copolymer, 6 parts of butyl acrylate, 6 parts of zinc stearate, 5 parts of nano zinc oxide powder, 1 part of fire retardant.
3. a kind of fibered wood species according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
15 parts of nanometer carbon crystal, 6 parts of modified zeolite powder, 2 parts of activated carbon powder, 30 parts of wood-fibred, 5 parts of oyster shell whiting, rosin pentaerythrite 7 parts of ester, 6 parts of lignin, 3 parts of tourmaline powder, 6 parts of ethylene-vinyl acetate copolymer, 8 parts of butyl acrylate, 7 parts of zinc stearate, 6 parts of nano zinc oxide powder, 2 parts of fire retardant.
4. a kind of fibered wood species according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
20 parts of nanometer carbon crystal, 7 parts of modified zeolite powder, 3 parts of activated carbon powder, 40 parts of wood-fibred, 6 parts of oyster shell whiting, rosin pentaerythrite 8 parts of ester, 7 parts of lignin, 4 parts of tourmaline powder, 7 parts of ethylene-vinyl acetate copolymer, 10 parts of butyl acrylate, zinc stearate 8 Part, 7 parts of nano zinc oxide powder, 3 parts of fire retardant.
5. a kind of a kind of preparation method of fibered wood species according to claim 1, it is characterised in that:Comprise the following steps:
Step one, ethylene-vinyl acetate copolymer, polyethyleneimine, NaOH are configured to solution;
Step 2, solution is warming up to 70-80 DEG C, adds pentalyn, butyl acrylate, stirring reaction 30- 60min;30-50 DEG C is cooled to, zinc stearate, nano zinc oxide powder stir 1-2h, obtain mixed liquor;
Step 3, by nanometer carbon crystal in appropriate modified zeolite powder, obtain solution, it is standby;
Step 4, solution prepared by step (3) is added in the mixed liquor of step (2) preparation, after stirring, added remaining Raw material, stirring reaction 1-3h, obtains final product.
CN201611107378.7A 2016-12-06 2016-12-06 A kind of fibered wood species and preparation method thereof Pending CN106854375A (en)

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Application Number Priority Date Filing Date Title
CN201611107378.7A CN106854375A (en) 2016-12-06 2016-12-06 A kind of fibered wood species and preparation method thereof

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CN106854375A true CN106854375A (en) 2017-06-16

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102492262A (en) * 2011-11-14 2012-06-13 武汉科技大学 Carbon whisker reinforced resin composite material and preparation method thereof
CN105838100A (en) * 2016-05-31 2016-08-10 何松 Fiber wood with formaldehyde purification function and method for preparing fiber wood
CN106009744A (en) * 2016-05-31 2016-10-12 何松 Environment-friendly antibacterial wood product and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102492262A (en) * 2011-11-14 2012-06-13 武汉科技大学 Carbon whisker reinforced resin composite material and preparation method thereof
CN105838100A (en) * 2016-05-31 2016-08-10 何松 Fiber wood with formaldehyde purification function and method for preparing fiber wood
CN106009744A (en) * 2016-05-31 2016-10-12 何松 Environment-friendly antibacterial wood product and preparation method thereof

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Application publication date: 20170616

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