CN107236466A - A kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive and preparation method thereof - Google Patents
A kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive and preparation method thereof Download PDFInfo
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- CN107236466A CN107236466A CN201710479745.4A CN201710479745A CN107236466A CN 107236466 A CN107236466 A CN 107236466A CN 201710479745 A CN201710479745 A CN 201710479745A CN 107236466 A CN107236466 A CN 107236466A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive, include the raw material of following parts by weight：57 parts of vinylacetate, 0.1 0.5 parts of emulsifying agent, 68 parts of waterglass, 15 25 parts of polyvinyl alcohol, 0.3 0.7 parts of antimildew disinfectant, 10 20 parts of thickener, 15 17 parts of filler, 6 10 parts of cellulose ether, 10 20 parts of acrylic resin, 37 parts of starch, 40 60 parts of water.The bonding strength and water resistance of the high-efficiency binder of the present invention are higher, and preferably, the noxious material such as formaldehydeless, benzene, toluene realizes that totally nontoxic is harmless, environmental protection to bin stability, and its hardening time is short in addition, Acceptable life length, permeability are preferable；While the preparation method of the insulating materials of the present invention, its material cost is relatively low, raw material is easy to get and technique concise, it is easy to industrialized production is operated and realize, with higher practical value and good application prospect.
Description
Technical field
The present invention relates to building material technical field, and in particular to a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive and its preparation
Method.
Background technology
The adhesive of current plywood production is still based on formaldehyde system adhesive, and wherein phenolic resin glue is used for production
Outdoor version type Ⅰ plywood, urea-formaldehyde resin adhesive is used for producing the class glued board of indoor type II, due to the production of formaldehyde system adhesive bonding
Product have free formaldehyde release in the production and use process, and harm people's is healthy, increasingly increases in consumer's environmental consciousness
In the case of strong, formaldehyde system adhesive is particularly bonded the production of the urea-formaldehyde resin adhesive of interior products by increasingly stricter
Limitation.By being improved to urea-formaldehyde resin adhesive production technology, or the product being bonded to it can using appropriate post processing means
The release of harmful formaldehyde gas is reduced, but this not only adds cost, and can not thoroughly solve free formaldehyde release problem.
In addition ureaformaldehyde, phenolic aldehyde, melamine formal etc. contain formaldehyde binder, and price good to wood materials bond properties
It is cheap, thus widely applied in timber Wood-based Panel Production.Although adhesive without aldehyde will not cause wood-based panel product, release is free
Formaldehyde, is had a safety feature, but due to reasons such as use cost height and bond properties differences, Wood-based Panel Production should be used less.Exist
Be applied adhesive without aldehyde in plywood production common are isocyanates, acrylic emulsion, double-component waterborne polyurethane
Adhesive, modified soybean glue, glued board PUR etc..
The content of the invention
For the defect of prior art, it is an object of the invention to provide a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive, the height
The bonding strength and water resistance for imitating adhesive are higher, and bin stability preferably, realized by the noxious material such as formaldehydeless, benzene, toluene
Atoxic is harmless, environmental protection, and its hardening time is short in addition, Acceptable life length, permeability are preferable；The present invention's is exhausted simultaneously
The preparation method of edge material, its material cost is relatively low, raw material is easy to get and technique concise, it is easy to operate and realize industrialized production,
With higher practical value and good application prospect.
The present invention solves technical problem and adopted the following technical scheme that：
The invention provides a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive, include the raw material of following parts by weight：
5-7 parts of vinylacetate, 0.1-0.5 parts of emulsifying agent, 6-8 parts of waterglass, 15-25 parts of polyvinyl alcohol, antimildew disinfectant
0.3-0.7 parts, 10-20 parts of thickener, 15-17 parts of filler, 6-10 parts of cellulose ether, 10-20 parts of acrylic resin, starch 3-
7 parts, 40-60 parts of water.
Preferably, the glued board includes the raw material of following parts by weight with Environment-friendlyhigh-efficiency high-efficiency adhesive：
6 parts of vinylacetate, 0.3 part of emulsifying agent, 7 parts of waterglass, 20 parts of polyvinyl alcohol, 0.5 part of antimildew disinfectant, thickener 15
Part, 16 parts of filler, 8 parts of cellulose ether, 15 parts of acrylic resin, 5 parts of starch, 50 parts of water.
Preferably, the emulsifying agent is ten base benzene sulfonic acid sodium salt LAS, NPE OP-10, polyoxyethylene nonyl phenyl second
One kind in alkene ether Tx-10.
Preferably, the waterglass is the aqueous solution of silicate, and its dioxide-containing silica is in 28-34%.
Preferably, the antimildew disinfectant is nano zine oxide, potassium sorbate and antimildew disinfectant KL-303, according to weight
Than 2:1:The mixture of 2 compositions.
Preferably, the thickener is sodium alginate, marine alga propylene glycol ester, sodium carboxymethylcellulose, compares 2 according to weight:
1:The mixture of 3 compositions.
Preferably, the filler is talcum powder, graphite, kaolin, compares 3 according to weight:0.5:The mixture of 1 composition,
The specification of the filler is 300-400 mesh.
The present invention also provides a kind of method of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive, comprises the following steps：
Step one, each component raw material is weighed on request；
Step 2, antimildew disinfectant, filler, starch are mixed and add mixer, is stirred 20-30 minutes, speed of agitator is
200-300r/min, obtains mixture A；
Step 3, distilled water is heated in 85-95 DEG C, mixing pva, waterglass feeding mixer, 10-20 points of stirring
Clock, speed of agitator 400-500r/min, the mixture B of preparation；
Step 4, mixture B prepared by step 3 is sent into reactor, is maintained the temperature at 90-100 DEG C, is sequentially added thickening
Agent, emulsifying agent cellulose ether, acrylic resin, starch, stirring reaction 30-40 minutes add the mixture of step 2 preparation
A, antimildew disinfectant, continue to stir 10-20 minutes, cool down the glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the invention of system.
Preferably, the glued board is with the preparation process of Environment-friendlyhigh-efficiency high-efficiency adhesive：
Step one, each component raw material is weighed on request；
Step 2, antimildew disinfectant, filler, starch are mixed and add mixer, is stirred 25 minutes, speed of agitator is 250r/
Min, obtains mixture A；
Step 3, distilled water is heated in 90 DEG C, mixing pva, waterglass feeding mixer, stirred 15 minutes, stirring
Rotating speed 450r/min, the mixture B of preparation；
Step 4, mixture B prepared by step 3 is sent into reactor, is maintained the temperature at 95 DEG C, is sequentially added thickener, breast
Agent cellulose ether, acrylic resin, starch, stirring reaction 35 minutes add the mixture A of step 2 preparation, mould proof killed
Microbial inoculum, continues to stir 15 minutes, cools down the glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the invention of system.
Compared with prior art, the present invention has following beneficial effect：
（1）A kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the present invention, by being reasonably formulated, it is to avoid make formaldehyde, benzene, toluene etc.
Noxious material, can meet the demand of green building material that people decorate for household and top-grade furniture, the need for being adapted to people, make
The wood-based plate produced with this product can realize that totally nontoxic is harmless, environmental protection, and during the solidification of the adhesive composition
Between it is short, Acceptable life is long.
（2）The present invention a kind of glued board added with Environment-friendlyhigh-efficiency high-efficiency adhesive polyvinyl alcohol, acrylic resin, acetic acid second
Composite network is formed after alkene ester, a few person's synergies, film-forming, the bonding strength and water resistance of adhesive is improved.
（3）A kind of glued board of the present invention with the addition of antimildew disinfectant with Environment-friendlyhigh-efficiency high-efficiency adhesive, predominantly nano oxidized
Zinc, potassium sorbate and antimildew disinfectant KL-303, compound action can have wide spectrum antimicrobial acivity, have to all kinds of moulds compared with
Good inhibitory action, security is preferably, nontoxic to human body, effectively increases the fungus and mildew resistance effect of adhesive.
（4）A kind of glued board of the present invention is with the addition of thickener, cellulose ether and shallow lake in Environment-friendlyhigh-efficiency high-efficiency adhesive raw material
Powder, improves the degree of adhesion of binding agent, improves its penetration, enhances bonding strength.
（5）The bonding strength and water resistance of a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the present invention are higher, and storage is stable
Property preferably, the noxious material such as formaldehydeless, benzene, toluene realizes that totally nontoxic is harmless, environmental protection, and its hardening time is short in addition, have
Imitate service life length, permeability preferable；While the preparation method of the insulating materials of the present invention, its material cost is relatively low, raw material is easy
Obtain and technique is concise, it is easy to industrialized production is operated and realize, with higher practical value and good application prospect.
Embodiment
With reference to specific embodiment, the technical scheme in the embodiment of the present invention is clearly and completely described, shown
So, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the reality in the present invention
Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the present embodiment, includes the raw material of following parts by weight：
5 parts of vinylacetate, 0.1 part of emulsifying agent, 6 parts of waterglass, 15 parts of polyvinyl alcohol, 0.3 part of antimildew disinfectant, thickener 10
Part, 15 parts of filler, 6 parts of cellulose ether, 10 parts of acrylic resin, 3 parts of starch, 40 parts of water.
Emulsifying agent in the present embodiment is ten base benzene sulfonic acid sodium salt LAS.
Waterglass in the present embodiment is the aqueous solution of silicate, and its dioxide-containing silica is in 28-34%.
Antimildew disinfectant in the present embodiment is nano zine oxide, potassium sorbate and antimildew disinfectant KL-303, according to weight
Amount compares 2:1:The mixture of 2 compositions.
Thickener in the present embodiment is sodium alginate, marine alga propylene glycol ester, sodium carboxymethylcellulose, compares 2 according to weight:
1:The mixture of 3 compositions.
Filler in the present embodiment is talcum powder, graphite, kaolin, compares 3 according to weight:0.5:The mixture of 1 composition,
The specification of the filler is 300-400 mesh.
A kind of preparation method of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the present embodiment, comprises the following steps：
Step one, each component raw material is weighed on request；
Step 2, antimildew disinfectant, filler, starch are mixed and add mixer, is stirred 20 minutes, speed of agitator is 200r/
Min, obtains mixture A；
Step 3, distilled water is heated in 85 DEG C, mixing pva, waterglass feeding mixer, stirred 10 minutes, stirring
Rotating speed 400r/min, the mixture B of preparation；
Step 4, mixture B prepared by step 3 is sent into reactor, is maintained the temperature at 90 DEG C, is sequentially added thickener, breast
Agent cellulose ether, acrylic resin, starch, stirring reaction 30 minutes add the mixture A of step 2 preparation, mould proof killed
Microbial inoculum, continues to stir 10 minutes, cools down the glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the invention of system.
Embodiment 2.
A kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the present embodiment, includes the raw material of following parts by weight：
7 parts of vinylacetate, 0.5 part of emulsifying agent, 8 parts of waterglass, 25 parts of polyvinyl alcohol, 0.7 part of antimildew disinfectant, thickener 20
Part, 17 parts of filler, 10 parts of cellulose ether, 20 parts of acrylic resin, 7 parts of starch, 60 parts of water.
Emulsifying agent in the present embodiment is NPE OP-10.
Waterglass in the present embodiment is the aqueous solution of silicate, and its dioxide-containing silica is in 28-34%.
Antimildew disinfectant in the present embodiment is nano zine oxide, potassium sorbate and antimildew disinfectant KL-303, according to weight
Amount compares 2:1:The mixture of 2 compositions.
Thickener in the present embodiment is sodium alginate, marine alga propylene glycol ester, sodium carboxymethylcellulose, compares 2 according to weight:
1:The mixture of 3 compositions.
Filler in the present embodiment is talcum powder, graphite, kaolin, compares 3 according to weight:0.5:The mixture of 1 composition,
The specification of the filler is 300-400 mesh.
A kind of preparation method of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the present embodiment, comprises the following steps：
Step one, each component raw material is weighed on request；
Step 2, antimildew disinfectant, filler, starch are mixed and add mixer, is stirred 30 minutes, speed of agitator is 300r/
Min, obtains mixture A；
Step 3, distilled water is heated in 95 DEG C, mixing pva, waterglass feeding mixer, stirred 20 minutes, stirring
Rotating speed 500r/min, the mixture B of preparation；
Step 4, mixture B prepared by step 3 is sent into reactor, maintains the temperature at 100 DEG C, sequentially add thickener,
Emulsifying agent cellulose ether, acrylic resin, starch, stirring reaction 40 minutes add the mixture A, mould proof of step 2 preparation
Bactericide, continues to stir 20 minutes, cools down the glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the invention of system.
Embodiment 3.
A kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the present embodiment, includes the raw material of following parts by weight：
6 parts of vinylacetate, 0.3 part of emulsifying agent, 7 parts of waterglass, 20 parts of polyvinyl alcohol, 0.5 part of antimildew disinfectant, thickener 15
Part, 16 parts of filler, 8 parts of cellulose ether, 15 parts of acrylic resin, 5 parts of starch, 50 parts of water.
Emulsifying agent in the present embodiment is NPE Tx-10.
Waterglass in the present embodiment is the aqueous solution of silicate, and its dioxide-containing silica is in 28-34%.
Antimildew disinfectant in the present embodiment is nano zine oxide, potassium sorbate and antimildew disinfectant KL-303, according to weight
Amount compares 2:1:The mixture of 2 compositions.
Thickener in the present embodiment is sodium alginate, marine alga propylene glycol ester, sodium carboxymethylcellulose, compares 2 according to weight:
1:The mixture of 3 compositions.
Filler in the present embodiment is talcum powder, graphite, kaolin, compares 3 according to weight:0.5:The mixture of 1 composition,
The specification of the filler is 300-400 mesh.
A kind of preparation method of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the present embodiment, comprises the following steps：
Step one, each component raw material is weighed on request；
Step 2, antimildew disinfectant, filler, starch are mixed and add mixer, is stirred 25 minutes, speed of agitator is 250r/
Min, obtains mixture A；
Step 3, distilled water is heated in 90 DEG C, mixing pva, waterglass feeding mixer, stirred 15 minutes, stirring
Rotating speed 450r/min, the mixture B of preparation；
Step 4, mixture B prepared by step 3 is sent into reactor, is maintained the temperature at 95 DEG C, is sequentially added thickener, breast
Agent cellulose ether, acrylic resin, starch, stirring reaction 35 minutes add the mixture A of step 2 preparation, mould proof killed
Microbial inoculum, continues to stir 15 minutes, cools down the glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the invention of system.
The present invention a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive bonding strength and water resistance it is higher, bin stability compared with
Good, the noxious material such as formaldehydeless, benzene, toluene realizes that totally nontoxic is harmless, environmental protection, its hardening time is short in addition, effectively make
It is preferable with long lifespan, permeability；Simultaneously the present invention insulating materials preparation method, its material cost is relatively low, raw material is easy to get and
Technique is concise, it is easy to industrialized production is operated and realize, with higher practical value and good application prospect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It may be appreciated other embodiment.
Claims (9)
1. a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive, it is characterised in that include the raw material of following parts by weight：
5-7 parts of vinylacetate, 0.1-0.5 parts of emulsifying agent, 6-8 parts of waterglass, 15-25 parts of polyvinyl alcohol, antimildew disinfectant
0.3-0.7 parts, 10-20 parts of thickener, 15-17 parts of filler, 6-10 parts of cellulose ether, 10-20 parts of acrylic resin, starch 3-
7 parts, 40-60 parts of water.
2. a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive according to claim 1, it is characterised in that the glued board ring
Protecting high-efficiency binder includes the raw material of following parts by weight：
6 parts of vinylacetate, 0.3 part of emulsifying agent, 7 parts of waterglass, 20 parts of polyvinyl alcohol, 0.5 part of antimildew disinfectant, thickener 15
Part, 16 parts of filler, 8 parts of cellulose ether, 15 parts of acrylic resin, 5 parts of starch, 50 parts of water.
3. a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive according to claim 1 or 2, it is characterised in that the emulsifying agent
For one kind in ten base benzene sulfonic acid sodium salt LAS, NPE OP-10, NPE Tx-10.
4. a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive according to claim 1 or 2, it is characterised in that the waterglass
For the aqueous solution of silicate, its dioxide-containing silica is in 28-34%.
5. a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive according to claim 1 or 2, it is characterised in that described mould proof to kill
Microbial inoculum is nano zine oxide, potassium sorbate and antimildew disinfectant KL-303, compares 2 according to weight:1:The mixture of 2 compositions.
6. a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive according to claim 1 or 2, it is characterised in that the thickener
For sodium alginate, marine alga propylene glycol ester, sodium carboxymethylcellulose, compare 2 according to weight:1:The mixture of 3 compositions.
7. a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive according to claim 1 or 2, it is characterised in that the filler
For talcum powder, graphite, kaolin, compare 3 according to weight:0.5:The mixture of 1 composition, the specification of the filler is 300-400
Mesh.
8. a kind of method for preparing glued board Environment-friendlyhigh-efficiency high-efficiency adhesive as claimed in claim 1 or 2, it is characterised in that bag
Include following steps：
Step one, each component raw material is weighed on request；
Step 2, antimildew disinfectant, filler, starch are mixed and add mixer, is stirred 20-30 minutes, speed of agitator is
200-300r/min, obtains mixture A；
Step 3, distilled water is heated in 85-95 DEG C, mixing pva, waterglass feeding mixer, 10-20 points of stirring
Clock, speed of agitator 400-500r/min, the mixture B of preparation；
Step 4, mixture B prepared by step 3 is sent into reactor, is maintained the temperature at 90-100 DEG C, is sequentially added thickening
Agent, emulsifying agent cellulose ether, acrylic resin, starch, stirring reaction 30-40 minutes add the mixture of step 2 preparation
A, antimildew disinfectant, continue to stir 10-20 minutes, cool down the glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the invention of system.
9. the preparation method of a kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive according to claim 8, it is characterised in that described
Preparation process is：
Step one, each component raw material is weighed on request；
Step 2, antimildew disinfectant, filler, starch are mixed and add mixer, is stirred 25 minutes, speed of agitator is 250r/
Min, obtains mixture A；
Step 3, distilled water is heated in 90 DEG C, mixing pva, waterglass feeding mixer, stirred 15 minutes, stirring
Rotating speed 450r/min, the mixture B of preparation；
Step 4, mixture B prepared by step 3 is sent into reactor, is maintained the temperature at 95 DEG C, is sequentially added thickener, breast
Agent cellulose ether, acrylic resin, starch, stirring reaction 35 minutes add the mixture A of step 2 preparation, mould proof killed
Microbial inoculum, continues to stir 15 minutes, cools down the glued board Environment-friendlyhigh-efficiency high-efficiency adhesive of the invention of system.
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| CN201710479745.4A CN107236466A (en) | 2017-06-22 | 2017-06-22 | A kind of glued board Environment-friendlyhigh-efficiency high-efficiency adhesive and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977118A (en) * | 2018-06-22 | 2018-12-11 | 安徽索亚装饰材料有限公司 | A kind of filler improving EVA hot-melt adhesive high-temperature capability |
| CN110372307A (en) * | 2019-08-06 | 2019-10-25 | 广州班力仕环保建筑材料有限公司 | A kind of floor heating high thermal conductivity tile binding material and preparation method thereof |
| CN111410438A (en) * | 2020-04-27 | 2020-07-14 | 东莞市嘉镁光学电子有限公司 | Wear-resisting vehicle-mounted glass outer screen |
| CN111635715A (en) * | 2020-07-13 | 2020-09-08 | 江门市豈铭实业有限公司 | Quick-drying carton adhesive and preparation method thereof |
| CN114106740A (en) * | 2021-12-10 | 2022-03-01 | 石家庄正旭环保建材有限公司 | Green and environment-friendly T-series novel water-based special glue and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906278A (en) * | 2010-08-12 | 2010-12-08 | 华南理工大学 | Single-component polyvinylacetate binding agent and preparation method thereof |
| CN104017519A (en) * | 2014-06-17 | 2014-09-03 | 魏根成 | Binding agent for plywood and preparation method thereof |
| CN104592911A (en) * | 2015-02-09 | 2015-05-06 | 金思思 | Adhesive composition for veneer sheets and preparation technique thereof |
| CN104861899A (en) * | 2015-05-30 | 2015-08-26 | 张家港市山牧新材料技术开发有限公司 | Adhesive composition for plywood and preparation process of adhesive composition |
| CN106634714A (en) * | 2016-12-17 | 2017-05-10 | 浦北县建业胶合板有限责任公司 | Adhesive for plywood and preparation method thereof |
| CN106749936A (en) * | 2016-12-06 | 2017-05-31 | 庄爱芹 | Vinyl acetate binder and preparation method thereof |
-
2017
- 2017-06-22 CN CN201710479745.4A patent/CN107236466A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906278A (en) * | 2010-08-12 | 2010-12-08 | 华南理工大学 | Single-component polyvinylacetate binding agent and preparation method thereof |
| CN104017519A (en) * | 2014-06-17 | 2014-09-03 | 魏根成 | Binding agent for plywood and preparation method thereof |
| CN104592911A (en) * | 2015-02-09 | 2015-05-06 | 金思思 | Adhesive composition for veneer sheets and preparation technique thereof |
| CN104861899A (en) * | 2015-05-30 | 2015-08-26 | 张家港市山牧新材料技术开发有限公司 | Adhesive composition for plywood and preparation process of adhesive composition |
| CN106749936A (en) * | 2016-12-06 | 2017-05-31 | 庄爱芹 | Vinyl acetate binder and preparation method thereof |
| CN106634714A (en) * | 2016-12-17 | 2017-05-10 | 浦北县建业胶合板有限责任公司 | Adhesive for plywood and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977118A (en) * | 2018-06-22 | 2018-12-11 | 安徽索亚装饰材料有限公司 | A kind of filler improving EVA hot-melt adhesive high-temperature capability |
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| CN110372307B (en) * | 2019-08-06 | 2021-11-02 | 广州班力仕环保建筑材料有限公司 | High-thermal-conductivity tile adhesive for floor heating and preparation method thereof |
| CN111410438A (en) * | 2020-04-27 | 2020-07-14 | 东莞市嘉镁光学电子有限公司 | Wear-resisting vehicle-mounted glass outer screen |
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Application publication date: 20171010 |