CN107400304A - A kind of ecological wooden of environmental protection and energy saving and preparation method thereof - Google Patents

A kind of ecological wooden of environmental protection and energy saving and preparation method thereof Download PDF

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Publication number
CN107400304A
CN107400304A CN201610328285.0A CN201610328285A CN107400304A CN 107400304 A CN107400304 A CN 107400304A CN 201610328285 A CN201610328285 A CN 201610328285A CN 107400304 A CN107400304 A CN 107400304A
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parts
raw material
stabilizers
foaming agents
cpe135a
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CN201610328285.0A
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Chinese (zh)
Inventor
姜旭光
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Shanghai Sunrise Wood Technology Development Co Ltd
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Shanghai Sunrise Wood Technology Development Co Ltd
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Priority to CN201610328285.0A priority Critical patent/CN107400304A/en
Publication of CN107400304A publication Critical patent/CN107400304A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2497/00Characterised by the use of lignin-containing materials
    • C08J2497/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention discloses a kind of ecological wooden of environmental protection and energy saving and preparation method thereof, it includes 40~55 parts of PVC raw materials, 10~20 parts of wood powder raw material, 20~30 parts of stone flour raw material, 1~3 part of YQ102 stabilizers stabilizer, 1801 0.2~0.5 part of lubricants, 1~2 part of NH213 foaming agents, 4~6 parts of K278P foaming agents, 0.5~1 part of 401K128P blowing promotors, 2~4 parts of CPE135A stabilizers, cured 0.1~0.5 part of PE, 0.8~1.2 part of soybean oil.Its preparation method is:1st, PVC raw materials, wood powder raw material, stone flour raw material are well mixed in mixer;2nd, 120 DEG C are heated to and adds YQ102 stabilizers, 1801 lubricants, NH213 foaming agents, K278P foaming agents, 401K128P blowing promotors, CPE135A stabilizers, is stirred;3rd, add that PE is cured, soybean oil, stirring is bright to lubricating;4th, add extruder and enter mould molding.Ecological wooden protection against the tide of the present invention, anti-deformation, insect prevention, anti acid alkali performance are strong, fire-retardant, weatherability is strong, and ageing resistance is strong, and it makes that simple, cost is low, green, nontoxic.

Description

A kind of ecological wooden of environmental protection and energy saving and preparation method thereof
Technical field
The present invention relates to ecological wooden technical field, more particularly to it is a kind of waterproof, protection against the tide, mould proof, anti-deformation, anti-cracking, anti- Worm, termite-proof, anti acid alkali performance is strong, fire-retardant, weatherability is strong, and ageing resistance is strong, exempts from the ecological wooden and its system of the environmental protection and energy saving of upper dye Preparation Method.
Background technology
Ecological wooden is one kind of Wood-plastic material, and the wood-plastic products of PVC foam technique way are generally called ecological wooden.Ecology Wooden main raw material(s) is to add a kind of new green environment protection material (30%PVC+ that other enhanced auxiliary agents synthesize by wood powder and PVC The colorant formula of 69% wood powder+1%), it is incorporated in each occasion such as house ornamentation, frock extensively, is related to:Indoor and outdoor wallboard, indoor ceiling Each places such as furred ceiling, outdoor flooring, indoor sound absorption plate, cut-off, billboard, are widely used.
Application No. 201310184477.5, patent name are the patent of " a kind of WPC polymer composites ecological wooden " Document, a kind of WPC polymer composites ecological wooden is disclosed, it will original based on string powder and polyvinyl chloride resin powder Material, is formed using PVC fretting map technology extrusion moldings, gluing is free of in the component of the WPC polymer composites ecological wooden Agent.Its good endurance, zero formaldehyde emissions.
Application No. 200610058668.7, patent name is " with can removing pernicious gas and the ecological wooden of energy antibacterial The patent document of plate and preparation method thereof ", disclosing a kind of new can effectively remove pernicious gas and with antibacterial functions Ecological wood floor, the ecological wood floor is from top to bottom successively by multilayers such as abrasion-proof paper, facing paper, high density fiberboard and balance papers Form.Its anti-microbial property is good, can effectively remove pernicious gas.
Although all there is respective advantage in above-mentioned prior art, overall to have the following disadvantages:Ecological wooden waterproof, protection against the tide Poor performance, pest-resistant poor performance,(It is green can wood)Metope is easily deformed, warped, and causes Local Cracking, and weatherability is poor, service life It is short.
The content of the invention
In order to solve the problems of the prior art, it is an object of the invention to provide a kind of ecological wooden of environmental protection and energy saving and its system Preparation Method, the natural texture of its existing natural timber, there is the superiority more prominent than natural timber again:Have waterproof, protection against the tide, Mould proof, anti-deformation, anti-cracking, insect prevention, termite-proof, anti acid alkali performance is strong, fire-retardant, weatherability is strong, and ageing resistance is strong, exempts from the spies such as upper dye Different performance.Can be long-term used in the big outdoor environment of weather metamorphosis, and never degenerate, not brittle, performance does not wane.
To achieve these goals, the technical solution adopted by the present invention is:
A kind of ecological wooden of environmental protection and energy saving, the parts by weight shared by its each component and each component for being included are:PVC raw materials 40~55 Part, 10~20 parts of wood powder raw material, 20~30 parts of stone flour raw material, 1~3 part of YQ102 stabilizers stabilizer, 1801 lubricants 0.2~ 0.5 part, 1~2 part of NH213 foaming agents, 4~6 parts of K278P foaming agents, 0.5~1 part of 401K128P blowing promotors, CPE135A is steady Determine 2~4 parts of agent, cured 0.1~0.5 part of PE, 0.8~1.2 part of soybean oil.
Preferably, 50 parts of PVC raw materials, 15 parts of wood powder raw material, 25 parts of stone flour raw material, 2 parts of YQ102 stabilizers stabilizer, 1801 0.25 part of lubricants, 1.25 parts of NH213 foaming agents, 5 parts of K278P foaming agents, 0.75 part of 401K128P blowing promotors, 3 parts of CPE135A stabilizers, cured 0.3 part of PE, 1 part of soybean oil.
Present invention also offers a kind of preparation method of the ecological wooden of environmental protection and energy saving, it comprises the following steps:
S1, first PVC raw materials, wood powder raw material, stone flour raw material are well mixed in mixer;
S2, mixed raw material is heated to 120 DEG C, then adds YQ102 stabilizers, 1801 lubricants, NH213 hairs by proportioning Infusion, K278P foaming agents, 401K128P blowing promotors, CPE135A stabilizers, are stirred until homogeneous;
S3, it is separately added into mixer that PE is cured, soybean oil, stirring is bright to lubricating;
S4, mixture obtained by S3 added into extruder, after heating, mixture enters mould molding by extruder.
Preferable scheme, the parts by weight shared by each component needed for its preparation process are:40~55 parts of PVC raw materials, wood 10~20 parts of powder raw material, 20~30 parts of stone flour raw material, 1~3 part of YQ102 stabilizers stabilizer, 1,801 0.2~0.5 part of lubricants, 1~2 part of NH213 foaming agents, 4~6 parts of K278P foaming agents, 0.5~1 part of 401K128P blowing promotors, CPE135A stabilizers 2~ 4 parts, cured 0.1~0.5 part of PE, 0.8~1.2 part of soybean oil.
Further preferred scheme, the parts by weight shared by each component needed for its preparation process are:50 parts of PVC raw materials, 15 parts of wood powder raw material, 25 parts of stone flour raw material, 2 parts of YQ102 stabilizers stabilizer, 1,801 0.25 part of lubricants, NH213 foaming agents 1.25 parts, 5 parts of K278P foaming agents, 0.75 part of 401K128P blowing promotors, 3 parts of CPE135A stabilizers, cured 0.3 part of PE, soybean 1 part of oil.
By using above technical scheme, a kind of ecological wooden of environmental protection and energy saving of the present invention and preparation method thereof and prior art Compare, its advantage is:
1st, ecological wooden of the present invention(It is green can wood)It is the composite of wood powder and resin, remains the flesh that natural timber is rich in vitality Texture and beautiful wood grain are managed, possesses waterproof, fire-retardant, anticorrosion, anti-aging, mothproof, anti-mildew, free from extraneous odour, to exempt from paint recyclable The characteristic utilized, the flexible moulding of metope plaque, product can independent assortments.
2nd, ecological wooden of the present invention, it is not only cheap, and there is no formaldehyde, human body injured, the system of the ecological wooden Standby technique is simple, all batch mixing steps can be completed in batch mixer, it is not necessary to secondary operation, be directly entered extruder and save greatly Measure manpower and materials.
3rd, ecological wooden of the present invention can make its service life reach maximization.
Embodiment
To make the object, technical solutions and advantages of the present invention of greater clarity, with reference to instantiation, to the present invention It is further described.It should be understood that these descriptions are merely illustrative, and it is not intended to limit the scope of the present invention.In addition, In illustrating below, the description to known features and technology is eliminated, to avoid unnecessarily obscuring idea of the invention.
A kind of ecological wooden of environmental protection and energy saving of the present invention can be obtained by following examples:
Embodiment one
1st, first 40kgPVC raw materials, 10kg wood powders raw material, 20kg stone flour raw materials are well mixed in mixer;
2nd, mixed raw material is heated to 120 DEG C, then adds 1kg YQ102 stabilizers by proportioning, the 1801 of 0.2kg are moistened Lubrication prescription, 1kg NH213 foaming agents, 4kg K278P foaming agents, 0.5kg 401K128P blowing promotors, 2kg CPE135A are steady Determine agent, be stirred until homogeneous;
3rd, PE from 0.1kg to mixer that be separately added into is cured, 0.8kg soybean oil, and stirring is bright to lubricating;
4th, mixture obtained by S3 is added into extruder, after heating, mixture enters mould molding by extruder.
Embodiment two
1st, first 55kgPVC raw materials, 20kg wood powders raw material, 30kg stone flour raw materials are well mixed in mixer;
2nd, mixed raw material is heated to 120 DEG C, then adds 3kg YQ102 stabilizers by proportioning, the 1801 of 0.5kg are moistened Lubrication prescription, 2kg NH213 foaming agents, 6kg K278P foaming agents, 1kg 401K128P blowing promotors, 4kg CPE135A are stable Agent, it is stirred until homogeneous;
3rd, PE from 0.5kg to mixer that be separately added into is cured, 1.2kg soybean oil, and stirring is bright to lubricating;
4th, mixture obtained by S3 is added into extruder, after heating, mixture enters mould molding by extruder.
Embodiment three
1st, first 50kgPVC raw materials, 15kg wood powders raw material, 25kg stone flour raw materials are well mixed in mixer;
2nd, mixed raw material is heated to 120 DEG C, then adds 2kg YQ102 stabilizers by proportioning, the 1801 of 0.25kg are moistened Lubrication prescription, 1.25kg NH213 foaming agents, 5kg K278P foaming agents, 0.75kg 401K128P blowing promotors, 3kg CPE135A stabilizers, are stirred until homogeneous;
3rd, PE from 0.3kg to mixer that be separately added into is cured, 1kg soybean oil, and stirring is bright to lubricating;
4th, mixture obtained by S3 is added into extruder, after heating, mixture enters mould molding by extruder.
PVC raw materials, wood powder raw material, stone flour raw material are the first component by the present invention, YQ102 stabilizers, 1801 lubricants, NH213 foaming agents, K278P foaming agents, 401K128P blowing promotors, CPE135A stabilizers are the second component, and PE is cured and soybean oil For third component, the first component provides the basic raw material with quite stable, and the second component, third component improve the respectively The performance of one component, the first component, the second component and third component compound, and improve the thermal stability of ecological wooden.
By ecological wooden made from this method, there is preferable waterproof, protection against the tide, mould proof, anti-deformation, anti-cracking, insect prevention, prevent Termite, anti acid alkali performance, and it is preferably fire-retardant, weatherability is strong, and ageing resistance is strong, exempts from upper dye, can be long-term used in weather form Change in big outdoor environment, and never degenerate, not brittle, performance does not wane.And its preparation method is simple, can be completed in batch mixer All batch mixing steps, it is not necessary to secondary operation, be directly entered extruder and save a large amount of manpower and materials;And low manufacture cost, and And there is no formaldehyde, human body is not injured, it can be applicable.
Above-mentioned embodiment is exemplary, is to preferably make skilled artisans appreciate that originally Patent, it is impossible to be not understood as the limitation for including scope to this patent;As long as times made of spirit according to disclosed in this patent How with change or modification, the scope that this patent includes is each fallen within.

Claims (5)

1. a kind of ecological wooden of environmental protection and energy saving, it is characterised in that the parts by weight shared by its each component and each component for being included are: 40~55 parts of PVC raw materials, 10~20 parts of wood powder raw material, 20~30 parts of stone flour raw material, 1~3 part of YQ102 stabilizers stabilizer, 1801 0.2~0.5 part of lubricants, 1~2 part of NH213 foaming agents, 4~6 parts of K278P foaming agents, 401K128P blowing promotors 0.5 ~1 part, 2~4 parts of CPE135A stabilizers, cured 0.1~0.5 part of PE, 0.8~1.2 part of soybean oil.
A kind of 2. ecological wooden of environmental protection and energy saving according to claim 1, it is characterised in that its each component included and each Parts by weight shared by component are:50 parts of PVC raw materials, 15 parts of wood powder raw material, 25 parts of stone flour raw material, YQ102 stabilizers stabilizer 2 Part, 1,801 0.25 part of lubricants, 1.25 parts of NH213 foaming agents, 5 parts of K278P foaming agents, 0.75 part of 401K128P blowing promotors, 3 parts of CPE135A stabilizers, cured 0.3 part of PE, 1 part of soybean oil.
3. a kind of preparation method of the ecological wooden of environmental protection and energy saving, it is characterised in that it comprises the following steps:
S1, first PVC raw materials, wood powder raw material, stone flour raw material are well mixed in mixer;
S2, mixed raw material is heated to 120 DEG C, then adds YQ102 stabilizers, 1801 lubricants, NH213 hairs by proportioning Infusion, K278P foaming agents, 401K128P blowing promotors, CPE135A stabilizers, are stirred until homogeneous;
S3, it is separately added into mixer that PE is cured, soybean oil, stirring is bright to lubricating;
S4, mixture obtained by S3 added into extruder, after heating, mixture enters mould molding by extruder.
A kind of 4. preparation method of the ecological wooden of environmental protection and energy saving according to claim 3, it is characterised in that its preparation process Needed for each component shared by parts by weight be:40~55 parts of PVC raw materials, 10~20 parts of wood powder raw material, stone flour raw material 20~30 Part, 1~3 part of YQ102 stabilizers stabilizer, 1,801 0.2~0.5 part of lubricants, 1~2 part of NH213 foaming agents, K278P foaming agents 4~6 parts, 0.5~1 part of 401K128P blowing promotors, 2~4 parts of CPE135A stabilizers, cured 0.1~0.5 part of PE, soybean oil 0.8 ~1.2 parts.
A kind of 5. preparation method of the ecological wooden of environmental protection and energy saving according to claim 4, it is characterised in that its preparation process Needed for each component shared by parts by weight be:50 parts of PVC raw materials, 15 parts of wood powder raw material, 25 parts of stone flour raw material, YQ102 are stable 2 parts of agent stabilizer, 1,801 0.25 part of lubricants, 1.25 parts of NH213 foaming agents, 5 parts of K278P foaming agents, 401K128P foaming help 0.75 part of agent, 3 parts of CPE135A stabilizers, cured 0.3 part of PE, 1 part of soybean oil.
CN201610328285.0A 2016-05-18 2016-05-18 A kind of ecological wooden of environmental protection and energy saving and preparation method thereof Pending CN107400304A (en)

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CN201610328285.0A CN107400304A (en) 2016-05-18 2016-05-18 A kind of ecological wooden of environmental protection and energy saving and preparation method thereof

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CN201610328285.0A CN107400304A (en) 2016-05-18 2016-05-18 A kind of ecological wooden of environmental protection and energy saving and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181152A (en) * 2018-08-07 2019-01-11 浙江长兴森大竹木制品有限公司 A kind of floor WPC and preparation method thereof
CN109280288A (en) * 2018-08-16 2019-01-29 温州崇奥礼品有限公司 A kind of billboard material and preparation method thereof that uvioresistant effect is good
CN114181538A (en) * 2021-12-16 2022-03-15 鲁山欧文斯工贸有限公司 MCM ecological wood and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101531791A (en) * 2009-01-16 2009-09-16 孙玉武 Composite ecological wood
CN102432959A (en) * 2011-08-17 2012-05-02 无锡天马塑胶制品有限公司 Environmentally-friendly foaming plate
CN103421258A (en) * 2013-07-22 2013-12-04 彭涛 Energy-saving environmental protection wood plastic material and preparation method thereof
CN103980636A (en) * 2014-05-30 2014-08-13 甘肃昱晖新材料有限公司 Wood-plastic foamed composite material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101531791A (en) * 2009-01-16 2009-09-16 孙玉武 Composite ecological wood
CN102432959A (en) * 2011-08-17 2012-05-02 无锡天马塑胶制品有限公司 Environmentally-friendly foaming plate
CN103421258A (en) * 2013-07-22 2013-12-04 彭涛 Energy-saving environmental protection wood plastic material and preparation method thereof
CN103980636A (en) * 2014-05-30 2014-08-13 甘肃昱晖新材料有限公司 Wood-plastic foamed composite material and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181152A (en) * 2018-08-07 2019-01-11 浙江长兴森大竹木制品有限公司 A kind of floor WPC and preparation method thereof
CN109280288A (en) * 2018-08-16 2019-01-29 温州崇奥礼品有限公司 A kind of billboard material and preparation method thereof that uvioresistant effect is good
CN114181538A (en) * 2021-12-16 2022-03-15 鲁山欧文斯工贸有限公司 MCM ecological wood and preparation method thereof

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Application publication date: 20171128