CN107177139A - A kind of ornament materials and preparation method thereof - Google Patents

A kind of ornament materials and preparation method thereof Download PDF

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Publication number
CN107177139A
CN107177139A CN201710565807.3A CN201710565807A CN107177139A CN 107177139 A CN107177139 A CN 107177139A CN 201710565807 A CN201710565807 A CN 201710565807A CN 107177139 A CN107177139 A CN 107177139A
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parts
ornament materials
raw material
preparation
fire retardant
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张玉
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Hefei Xinyada Intelligent Technology Co Ltd
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Hefei Xinyada Intelligent Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The present invention provides a kind of ornament materials and preparation method thereof, is related to building material field, ornament materials includes the raw material of following parts by weight:Magnesium chloride, magnesium sulfate, magnesia, expanded polystyrene (EPS), waste polyvinyl chloride foamed plastics, glass fibre, talcum powder, polyamide, phenolic resin, nanometer silicon carbide, light stabilizer, heat stabilizer, compatilizer, fire retardant and plasticizer;Preparation method comprises the following steps:(1) raw material, (2) are weighed and prepares plastic grain, (3) stirring, (4) heating and extrusion forming.The present invention solve existing ornament materials exist that fire line is poor, effects of energy conservation and environmental protection is poor, low intensity and the problem of high cost.

Description

A kind of ornament materials and preparation method thereof
Technical field
The invention belongs to building material field, and in particular to a kind of ornament materials and preparation method thereof.
Background technology
With social progress and the raising of living standards of the people, requirement more and more higher of the people to construction material, especially Ornament materials in construction material, existing ornament materials has wooden, metal, steel modeling and gypsum, still, the type Ornament materials it is general using non-renewable resources as former material, be unfavorable for the sustainable use of resource, cost is high, for wooden, modeling The problem of also there is inflammable, low intensity in the ornament materials of material class, in addition, existing brand-new building and ornament materials are generally containing organic Volatile materials, such as formaldehyde, aromatic hydrocarbon, severe contamination environment and harm people's is healthy.
The content of the invention
Exist that fire line is poor, effects of energy conservation and environmental protection is poor to solve existing ornament materials, low intensity and cost is high asks Topic, it is an object of the invention to provide a kind of ornament materials and preparation method thereof, obtained ornament materials have fire line it is good, energy-conservation Environment protecting is good, intensity is high and the low advantage of cost.
The invention provides following technical scheme:
A kind of ornament materials, includes the raw material of following parts by weight:26-30 parts of magnesium chloride, 10-18 parts of magnesium sulfate, magnesia 16-20 parts, 8-14 parts of expanded polystyrene (EPS), 10-16 parts of waste polyvinyl chloride foamed plastics, 4-16 parts of glass fibre, talcum powder 6-10 parts, 5-9 parts of polyamide, 9-17 parts of phenolic resin, 16-22 parts of nanometer silicon carbide, 0.2-0.6 parts of light stabilizer, heat 0.3-0.5 parts of 0.1-0.5 parts of stabilizer, 0.3-0.7 parts of compatilizer, 0.4-0.8 parts of fire retardant and plasticizer.
Waste polyvinyl chloride foamed plastics is with the addition of in raw material, the recycling of waste polyvinyl chloride foamed plastics reaches The purpose of energy-conserving and environment-protective has been arrived, production cost is reduced.
Phenolic resin is with the addition of in raw material, phenolic resin belongs to thermosetting resin, it has, and rigidity is big, hardness is high, bond The good, high temperature resistant of property, nonflammable and low-smoke low-toxicity advantage, are favorably improved the intensity and fire resistance of the ornament materials of preparation.
It with the addition of polyamide in raw material, polyamide has that nontoxic, light weight, high mechanical strength, wearability be good, resistance The advantage of the good, good toughness of combustion property and good impact resistance, is favorably improved the toughness and anti-flammability of the ornament materials of preparation.
Nanometer silicon carbide is with the addition of in raw material, nanometer silicon carbide has high high temperature resistant, intensity, good impact resistance and fire resistance Good advantage, is favorably improved the fire resistance and intensity of the electric power protecting pipe of preparation.
Preferably, the raw material of following parts by weight is included:28 parts of magnesium chloride, 14 parts of magnesium sulfate, 18 parts of magnesia, foaming polyphenyl 11 parts of ethene, 13 parts of waste polyvinyl chloride foamed plastics, 10 parts of glass fibre, 8 parts of talcum powder, 7 parts of polyamide, phenolic aldehyde tree 13 parts of fat, 19 parts of nanometer silicon carbide, 0.4 part of light stabilizer, 0.3 part of heat stabilizer, 0.5 part of compatilizer, 0.6 part of fire retardant and increasing Mould 0.4 part of agent.
Preferably, the light stabilizer be nano titanium oxide, can cover or reflect the material of ultraviolet, prevent light from Ornament materials is penetrated, the purpose of protection ornament materials is reached.
Preferably, the heat stabilizer is aluminum stearate, is favorably improved the heat endurance of the ornament materials of preparation.
Preferably, the compatilizer is that maleic anhydride is grafted compatilizer, by intermolecular bonding force, promotes incompatible Two kinds of polymer is combined together, and then reaches the purpose of stabilized blends.
Preferably, the fire retardant is organophosphorous fire retardant, and it is more stable that organic phosphates fire retardant can produce structure when heated Crosslinking shape solid matter or carburization zone, on the one hand the formation of carburization zone can prevent polymer from being further pyrolyzed, another aspect energy Thermal decomposition generation inside preventing enters gas phase and participates in combustion process.
Preferably, the plasticizer is dibutyl phthalate so that the pliability enhancing of ornament materials, is more prone to Processing.
A kind of preparation method of ornament materials, comprises the following steps:
(1) raw material is weighed according to the parts by weight of ornament materials raw material;
(2) waste polyvinyl chloride foamed plastics is added in plastic regenerator, produces plastic grain;
(3) plastic grain in step (2) and other raw materials are added in high-speed mixer, stirs 10-20min, produce Compound;
(4) by the mixed material heating in step (3) to 280-300 DEG C, then it is placed in extruding in the extruder of 5-6 atmospheric pressure It is molded, at normal temperatures timeliness 4-6 days.
The beneficial effects of the invention are as follows:
1st, the present invention solve existing ornament materials exist that fire line is poor, effects of energy conservation and environmental protection is poor, low intensity and cost High the problem of.
2nd, waste polyvinyl chloride foamed plastics, the recovery of waste polyvinyl chloride foamed plastics be with the addition of in raw material of the invention Recycle, reached the purpose of energy-conserving and environment-protective, reduced production cost.
3rd, phenolic resin is with the addition of in raw material of the invention, phenolic resin belongs to thermosetting resin, it has rigidity big, hard Spend height, good caking property, high temperature resistant, nonflammable and low-smoke low-toxicity advantage, be favorably improved preparation ornament materials intensity with Fire resistance.
4th, with the addition of polyamide in raw material of the invention, polyamide have nontoxic, light weight, high mechanical strength, Wearability is good, the advantage of good flame resistance, good toughness and good impact resistance, is favorably improved toughness and the resistance of the ornament materials of preparation Combustion property.
5th, nanometer silicon carbide is with the addition of in raw material of the invention, nanometer silicon carbide has high temperature resistant, intensity height, impact resistance The good and good advantage of fire resistance, is favorably improved the fire resistance and intensity of the electric power protecting pipe of preparation.
6th, heretofore described light stabilizer is nano titanium oxide, can cover or reflect the material of ultraviolet, make light Ornament materials can not be penetrated, the purpose of protection ornament materials is reached.
7th, heretofore described heat stabilizer is aluminum stearate, is favorably improved the heat endurance of the ornament materials of preparation.
8th, heretofore described compatilizer is that maleic anhydride is grafted compatilizer, by intermolecular bonding force, promotes not phase The two kinds of polymer of appearance is combined together, and then reaches the purpose of stabilized blends.
9th, heretofore described fire retardant is organophosphorous fire retardant, and it is more steady that organic phosphates fire retardant can produce structure when heated On the one hand fixed crosslinking shape solid matter or carburization zone, the formation of carburization zone can prevent polymer from being further pyrolyzed, on the other hand Thermal decomposition generation inside preventing enters gas phase and participates in combustion process.
10th, heretofore described plasticizer is dibutyl phthalate so that the pliability enhancing of ornament materials, more It is easily worked.
Embodiment
Embodiment 1
A kind of ornament materials, includes the raw material of following parts by weight:28 parts of magnesium chloride, 14 parts of magnesium sulfate, 18 parts of magnesia, hair 11 parts of foamed polystyrene, 13 parts of waste polyvinyl chloride foamed plastics, 10 parts of glass fibre, 8 parts of talcum powder, 7 parts of polyamide, 13 parts of phenolic resin, 19 parts of nanometer silicon carbide, 0.4 part of light stabilizer, 0.3 part of heat stabilizer, 0.5 part of compatilizer, fire retardant 0.6 0.4 part of part and plasticizer.
Waste polyvinyl chloride foamed plastics is with the addition of in raw material, the recycling of waste polyvinyl chloride foamed plastics reaches The purpose of energy-conserving and environment-protective has been arrived, production cost is reduced.
Phenolic resin is with the addition of in raw material, phenolic resin belongs to thermosetting resin, it has, and rigidity is big, hardness is high, bond The good, high temperature resistant of property, nonflammable and low-smoke low-toxicity advantage, are favorably improved the intensity and fire resistance of the ornament materials of preparation.
It with the addition of polyamide in raw material, polyamide has that nontoxic, light weight, high mechanical strength, wearability be good, resistance The advantage of the good, good toughness of combustion property and good impact resistance, is favorably improved the toughness and anti-flammability of the ornament materials of preparation.
Nanometer silicon carbide is with the addition of in raw material, nanometer silicon carbide has high high temperature resistant, intensity, good impact resistance and fire resistance Good advantage, is favorably improved the fire resistance and intensity of the electric power protecting pipe of preparation.
Light stabilizer is nano titanium oxide, can cover or reflect the material of ultraviolet, prevents light from penetrating decoration material Material, reaches the purpose of protection ornament materials.
Heat stabilizer is aluminum stearate, is favorably improved the heat endurance of the ornament materials of preparation.
Compatilizer is that maleic anhydride is grafted compatilizer, by intermolecular bonding force, promotes incompatible two kinds of polymer It is combined together, and then reaches the purpose of stabilized blends.
Fire retardant is organophosphorous fire retardant, and organic phosphates fire retardant can produce the more stable crosslinking shape solid of structure when heated On the one hand material or carburization zone, the formation of carburization zone can prevent polymer from being further pyrolyzed, on the other hand can prevent inside heat Decompose generation and enter gas phase participation combustion process.
Plasticizer is dibutyl phthalate so that the pliability enhancing of ornament materials, is more prone to processing.
A kind of preparation method of ornament materials, comprises the following steps:
(1) raw material is weighed according to the parts by weight of ornament materials raw material;
(2) waste polyvinyl chloride foamed plastics is added in plastic regenerator, produces plastic grain;
(3) plastic grain in step (2) and other raw materials are added in high-speed mixer, stirs 10-20min, produce Compound;
(4) by the mixed material heating in step (3) to 280-300 DEG C, then it is placed in extruding in the extruder of 5-6 atmospheric pressure It is molded, at normal temperatures timeliness 4-6 days.
Embodiment 2
A kind of ornament materials, includes the raw material of following parts by weight:26 parts of magnesium chloride, 10 parts of magnesium sulfate, 16 parts of magnesia, hair 8 parts of foamed polystyrene, 10 parts of waste polyvinyl chloride foamed plastics, 4 parts of glass fibre, 6 parts of talcum powder, 5 parts of polyamide, phenol 9 parts of urea formaldehyde, 16 parts of nanometer silicon carbide, 0.2 part of light stabilizer, 0.1 part of heat stabilizer, 0.3 part of compatilizer, 0.4 part of fire retardant With 0.3 part of plasticizer.
Waste polyvinyl chloride foamed plastics is with the addition of in raw material, the recycling of waste polyvinyl chloride foamed plastics reaches The purpose of energy-conserving and environment-protective has been arrived, production cost is reduced.
Phenolic resin is with the addition of in raw material, phenolic resin belongs to thermosetting resin, it has, and rigidity is big, hardness is high, bond The good, high temperature resistant of property, nonflammable and low-smoke low-toxicity advantage, are favorably improved the intensity and fire resistance of the ornament materials of preparation.
It with the addition of polyamide in raw material, polyamide has that nontoxic, light weight, high mechanical strength, wearability be good, resistance The advantage of the good, good toughness of combustion property and good impact resistance, is favorably improved the toughness and anti-flammability of the ornament materials of preparation.
Nanometer silicon carbide is with the addition of in raw material, nanometer silicon carbide has high high temperature resistant, intensity, good impact resistance and fire resistance Good advantage, is favorably improved the fire resistance and intensity of the electric power protecting pipe of preparation.
Light stabilizer is nano titanium oxide, can cover or reflect the material of ultraviolet, prevents light from penetrating decoration material Material, reaches the purpose of protection ornament materials.
Heat stabilizer is aluminum stearate, is favorably improved the heat endurance of the ornament materials of preparation.
Compatilizer is that maleic anhydride is grafted compatilizer, by intermolecular bonding force, promotes incompatible two kinds of polymer It is combined together, and then reaches the purpose of stabilized blends.
Fire retardant is organophosphorous fire retardant, and organic phosphates fire retardant can produce the more stable crosslinking shape solid of structure when heated On the one hand material or carburization zone, the formation of carburization zone can prevent polymer from being further pyrolyzed, on the other hand can prevent inside heat Decompose generation and enter gas phase participation combustion process.
Plasticizer is dibutyl phthalate so that the pliability enhancing of ornament materials, is more prone to processing.
A kind of preparation method of ornament materials, comprises the following steps:
(1) raw material is weighed according to the parts by weight of ornament materials raw material;
(2) waste polyvinyl chloride foamed plastics is added in plastic regenerator, produces plastic grain;
(3) plastic grain in step (2) and other raw materials are added in high-speed mixer, stirs 10-20min, produce Compound;
(4) by the mixed material heating in step (3) to 280-300 DEG C, then it is placed in extruding in the extruder of 5-6 atmospheric pressure It is molded, at normal temperatures timeliness 4-6 days.
Embodiment 3
A kind of ornament materials, includes the raw material of following parts by weight:30 parts of magnesium chloride, 18 parts of magnesium sulfate, 20 parts of magnesia, hair 14 parts of foamed polystyrene, 16 parts of waste polyvinyl chloride foamed plastics, 16 parts of glass fibre, 10 parts of talcum powder, polyamide 9 Part, 17 parts of phenolic resin, 22 parts of nanometer silicon carbide, 0.6 part of light stabilizer, 0.5 part of heat stabilizer, 0.7 part of compatilizer, fire retardant 0.8 part and 0.5 part of plasticizer.
Waste polyvinyl chloride foamed plastics is with the addition of in raw material, the recycling of waste polyvinyl chloride foamed plastics reaches The purpose of energy-conserving and environment-protective has been arrived, production cost is reduced.
Phenolic resin is with the addition of in raw material, phenolic resin belongs to thermosetting resin, it has, and rigidity is big, hardness is high, bond The good, high temperature resistant of property, nonflammable and low-smoke low-toxicity advantage, are favorably improved the intensity and fire resistance of the ornament materials of preparation.
It with the addition of polyamide in raw material, polyamide has that nontoxic, light weight, high mechanical strength, wearability be good, resistance The advantage of the good, good toughness of combustion property and good impact resistance, is favorably improved the toughness and anti-flammability of the ornament materials of preparation.
Nanometer silicon carbide is with the addition of in raw material, nanometer silicon carbide has high high temperature resistant, intensity, good impact resistance and fire resistance Good advantage, is favorably improved the fire resistance and intensity of the electric power protecting pipe of preparation.
Light stabilizer is nano titanium oxide, can cover or reflect the material of ultraviolet, prevents light from penetrating decoration material Material, reaches the purpose of protection ornament materials.
Heat stabilizer is aluminum stearate, is favorably improved the heat endurance of the ornament materials of preparation.
Compatilizer is that maleic anhydride is grafted compatilizer, by intermolecular bonding force, promotes incompatible two kinds of polymer It is combined together, and then reaches the purpose of stabilized blends.
Fire retardant is organophosphorous fire retardant, and organic phosphates fire retardant can produce the more stable crosslinking shape solid of structure when heated On the one hand material or carburization zone, the formation of carburization zone can prevent polymer from being further pyrolyzed, on the other hand can prevent inside heat Decompose generation and enter gas phase participation combustion process.
Plasticizer is dibutyl phthalate so that the pliability enhancing of ornament materials, is more prone to processing.
A kind of preparation method of ornament materials, comprises the following steps:
(1) raw material is weighed according to the parts by weight of ornament materials raw material;
(2) waste polyvinyl chloride foamed plastics is added in plastic regenerator, produces plastic grain;
(3) plastic grain in step (2) and other raw materials are added in high-speed mixer, stirs 10-20min, produce Compound;
(4) by the mixed material heating in step (3) to 280-300 DEG C, then it is placed in extruding in the extruder of 5-6 atmospheric pressure It is molded, at normal temperatures timeliness 4-6 days.
Comparative example 1
A kind of ornament materials, includes the raw material of following parts by weight:32.5 parts of waste or used plastics, 37.5 parts of flyash, stone powder 1.1 parts of 20 parts, 10 parts of Corvic, 5 parts of bamboo fibre and fire retardant.
A kind of preparation method of ornament materials, comprises the following steps:
(1) raw material is weighed according to the parts by weight of ornament materials raw material;
(2) waste or used plastics are added in plastic regenerator, produces plastic grain;
(3) plastic grain in step (2) and other raw materials are added in mixer, stirs 30-40min, produce mixing Material;
(4) by the mixed material heating in step (3) to 260-300 DEG C, then it is placed in extruding in the extruder of 4-6 atmospheric pressure It is molded, at normal temperatures timeliness 4-6 days.
Performance test, test result are carried out by ornament materials is made in embodiment 1, embodiment 2, embodiment 3 and comparative example 1 As shown in table 1:
From the data of table 1 compare as can be seen that it is an advantage of the invention that:
1st, a kind of ornament materials and preparation method thereof, from the material loss slip measured as can be seen that embodiment 1-3 Material loss slip is above comparative example 1, illustrates the good energy-conserving effect of ornament materials of the present invention.
2nd, a kind of ornament materials and preparation method thereof, according to national standard《Construction material and product burns grading performance》 GB862, from the flame retardant rating measured as can be seen that embodiment 1-3 flame retardant rating is superior to comparative example 1, illustrates present invention dress The fire resistance of exterior material is good.
3rd, a kind of ornament materials and preparation method thereof, from the rupture strength and compression strength measured as can be seen that embodiment 1-3 rupture strength and compression strength is above comparative example 1, illustrates that the intensity of ornament materials of the present invention is high.
4th, a kind of ornament materials and preparation method thereof, from the data of each index measured as can be seen that embodiment 1 is excellent In embodiment 2, embodiment 3 and comparative example 1, illustrate the composition of raw materials of ornament materials of the present invention and the reasonability of preparation method.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation Technical scheme described in example is modified, or equivalent substitution, all essences in the present invention are carried out to which part technical characteristic God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (8)

1. a kind of ornament materials, it is characterised in that include the raw material of following parts by weight:26-30 parts of magnesium chloride, magnesium sulfate 10-18 Part, 16-20 parts of magnesia, 8-14 parts of expanded polystyrene (EPS), 10-16 parts of waste polyvinyl chloride foamed plastics, glass fibre 4-16 Part, 6-10 parts of talcum powder, 5-9 parts of polyamide, 9-17 parts of phenolic resin, 16-22 parts of nanometer silicon carbide, light stabilizer 0.2- 0.3-0.5 parts of 0.6 part, 0.1-0.5 parts of heat stabilizer, 0.3-0.7 parts of compatilizer, 0.4-0.8 parts of fire retardant and plasticizer.
2. ornament materials according to claim 1, it is characterised in that include the raw material of following parts by weight:28 parts of magnesium chloride, 14 parts of magnesium sulfate, 18 parts of magnesia, 11 parts of expanded polystyrene (EPS), 13 parts of waste polyvinyl chloride foamed plastics, 10 parts of glass fibre, 8 parts of talcum powder, 7 parts of polyamide, 13 parts of phenolic resin, 19 parts of nanometer silicon carbide, 0.4 part of light stabilizer, heat stabilizer 0.3 Part, 0.5 part of compatilizer, 0.6 part of fire retardant and 0.4 part of plasticizer.
3. ornament materials according to claim 1, it is characterised in that:The light stabilizer is nano titanium oxide.
4. ornament materials according to claim 1, it is characterised in that:The heat stabilizer is aluminum stearate.
5. ornament materials according to claim 1, it is characterised in that:The compatilizer is that maleic anhydride is grafted compatilizer.
6. ornament materials according to claim 1, it is characterised in that:The fire retardant is organophosphorous fire retardant.
7. ornament materials according to claim 1, it is characterised in that:The plasticizer is dibutyl phthalate.
8. the preparation method of a kind of ornament materials as described in claim 1-7 any one, it is characterised in that including following Step:
(1) raw material is weighed according to the parts by weight of ornament materials raw material;
(2) waste polyvinyl chloride foamed plastics is added in plastic regenerator, produces plastic grain;
(3) plastic grain in step (2) and other raw materials are added in high-speed mixer, stirs 10-20min, produce mixing Material;
(4) by the mixed material heating in step (3) to 280-300 DEG C, then it is placed in the extruder of 5-6 atmospheric pressure and is squeezed into Type, at normal temperatures timeliness 4-6 days.
CN201710565807.3A 2017-07-12 2017-07-12 A kind of ornament materials and preparation method thereof Withdrawn CN107177139A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108084701A (en) * 2017-12-21 2018-05-29 付主枝 The production technology of a kind of nanometer of construction material and its application
CN108793826A (en) * 2018-07-20 2018-11-13 桐城市景瑞建筑装饰工程有限公司 A kind of building and ornament materials of good flame resistance and preparation method thereof
CN109054423A (en) * 2018-08-08 2018-12-21 苏州利波紧固件有限公司 A kind of fretting map composite polymer material building template and preparation method thereof

Citations (4)

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Application publication date: 20170919