CN106833673A - A kind of straw biomass charcoal soil conditioner containing sludge - Google Patents
A kind of straw biomass charcoal soil conditioner containing sludge Download PDFInfo
- Publication number
- CN106833673A CN106833673A CN201710063213.2A CN201710063213A CN106833673A CN 106833673 A CN106833673 A CN 106833673A CN 201710063213 A CN201710063213 A CN 201710063213A CN 106833673 A CN106833673 A CN 106833673A
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- Prior art keywords
- biomass charcoal
- straw biomass
- soil conditioner
- stalk
- sludge
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
- C09K17/48—Organic compounds mixed with inorganic active ingredients, e.g. polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dentistry (AREA)
- Materials Engineering (AREA)
- Mycology (AREA)
- Plant Pathology (AREA)
- Biotechnology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Organic Chemistry (AREA)
- Microbiology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment Of Sludge (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of straw biomass charcoal soil conditioner containing sludge, it is obtained by the raw material of following weight parts:Vermiculite 23 26, lime stone 25, alum 12, paper mill sludge 12, stalk 130 140, APG 12, diacetyl tartarate monoglyceride 0.2 0.3, phenethyl phenol polyethenoxy ether 0.2 0.4, polyvinyl alcohol 12, stalwart wormwood artemisia 5 10, mulberry tree branch 1.8 3, day name essence 1.4 2.7, calamus 35.
Description
Technical field
Change the present invention relates to soil conditioner technical field, more particularly to a kind of straw biomass charcoal soil containing sludge
Good dose.
Background technology
All physics for being mainly used in improved soil, chemistry and biological property, make it be more suitable for plant growth, rather than master
The material of plant nutrient, referred to as soil conditioner are provided.
The element composition of biomass carbon is main including carbon (generally up to more than 60%), hydrogen, oxygen etc., next to that ash content (including
Potassium, calcium, sodium, magnesium, silicon etc.), it is a kind of carbon containing polymer, Fourier's infrared photoacoustic spectra technical Analysis show biomass carbon table
Contain the oxygen-containing functional groups such as abundant-COOH ,-COH and-OH in face.Biomass carbon not only by stablizing aromatization structure composition, and
Also contain many aliphatic and oxidation state carbon structure material, height aromatization structure makes it have than other any type of organic carbons
There is biochemistry and heat endurance higher, can for a long time be stored in environment and ancient deposit and be difficult to be mineralized.Biomass carbon
With flourishing pore structure, specific surface area high and abundant surface functional group, while have reserves pollution-free, high, can be again
Raw the features such as.The products application can be used as polluter adsorbent, extensive decolouring and deodorizing agent etc. in industry;Being applied to agricultural can
As soil conditioner, organic fertilizer carrier etc.;The industries such as medicine, animal husbandry can be used simultaneously.Imflammable gas it is main into
It is CO to divide, and can be used for generating electricity or is used for industrial and agricultural production or life fuel as piped gas.
With continuing to develop for economic society, the soil resource wretched insufficiency of China, and due to some irrational profits
With, such as a large amount of irrational administration fertilizer, the overspray of agricultural chemicals, excess load are herded etc., cause the serious of soil and move back
Change.It is mainly shown as soil compaction and hardening, erosion, salinization of soil, acidifying, element is unbalance, chemical contamination, Organic Matter Loss and move
Degeneration of flora etc..Meanwhile, with the fast development of today's society industry and mining, heavy metal pollution of soil is increasingly serious,
It is many in nature to exist with compound form, with the exploitation of mankind's heavy metal, smeltings, processing and mulberry leaf manufacture, make much
Heavy metal such as lead, cadmium, mercury enter in air, water body or soil, cause serious heavy metal pollution.Soil be human survival with
The important natural resources of development, the heavy metal pollution of soil will directly affect the healthy and whole terrestrial ecosystems of the mankind.Weight
Gold
Category pollution is different from Organic Pollution, and heavy metal is difficult to be degraded in itself, can not be by micro- life into the heavy metal in soil
Thing is decomposed and accumulated for a long time in soil, and some enter human body after being absorbed by crops eventually through food chain effect, there is one
Fixed ecological risk.
Soil conditioner has multiclass:(1) mineral substance, mainly there is peat, lignite, weathered coal, lime, gypsum, vermiculite, swelling
Soil, zeolite, perlite and sepiolite etc.;(2) natural and semi-synthetic water soluble polymer class, mainly there is stalk, polysaccharide thing
Material, cellulose substances, lignin material and resin glue material;(3) artificial synthesized macromolecular compound, mainly there is polyacrylic acid
Class, vinyl acetate Malaysia acids and polyvinyl alcohol;(4) effective microorganism preparation class etc..
At present, soil conditioner majority is improved at aspect of how building up fertility, and is seldom related to for controlling underground pest
And.And with the development of paper industry, paper mill sludge yield increases year by year.And paper mill sludge(Paper pulp mud, ink slag sludge)
The environmental problem for causing increasingly is revealed, and such as perishable, foul smelling, not readily transportable, disposal difficulty are big, it is therefore necessary to right
Paper mill sludge carries out the treatment such as minimizing, stabilisation, innoxious and resource..
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of straw biomass charcoal soil containing sludge
Earth modifying agent.
The present invention is achieved by the following technical solutions:
A kind of straw biomass charcoal soil conditioner containing sludge, it is obtained by the raw material of following weight parts:Vermiculite 23-
26, lime stone 2-5, alum 1-2, paper mill sludge 1-2, stalk 130-140, APG 1-2, diacetyl tartarate monoglyceride
0.2-0.3, phenethyl phenol polyethenoxy ether 0.2-0.4, polyvinyl alcohol 1-2, stalwart wormwood artemisia 5-10, mulberry tree branch 1.8-3, day name essence 1.4-
2.7th, calamus 3-5.
A kind of described straw biomass charcoal soil conditioner containing sludge,
Preparation method is comprised the following steps:
(1)By soybean stalk, in the case where ultraviolet wavelength is 254-260nm ultraviolet irradiation 30-50 seconds, Pintsch process anaerobic charcoal is carried out
Change, obtain straw biomass charcoal standby;
(2)After stalwart wormwood artemisia, mulberry tree branch, day essence, calamus mix, dry, obtain xeraphium standby;
(3)Straw biomass charcoal adds water mixing, after stirring 0.5-1h at 40-60 DEG C, adds APG, diacetyl tartaric
Sour monoglyceride, phenethyl phenol polyethenoxy ether, polyvinyl alcohol, xeraphium, after stirring, filtering is filtered with distillation water washing
Slag, to filtrate in neutrality, during filter residue is added into concentration for the citric acid solution of 1-2%, stirs under 300-500rpm at 30-50 DEG C
1-2h is mixed, is filtered, with distillation water washing filter residue, to filtrate in neutrality, filter residue obtains final product compounding stalk after being dried at 70-85 DEG C
Biomass carbon is standby;
(4)Paper mill sludge soaks 1-3 hours in concentration is for the citric acid solution of 2-4%, then at 400-500W microwave treatments 20-
30 seconds, filtering, deionized water washing, drying was dried, then was mixed with compounding straw biomass charcoal and remaining raw material, was obtained final product.
It is an advantage of the invention that:(1)The paper mill sludge that the present invention is pre-processed containing acid soak and microwave disinfection, Neng Gouan
Loopful is protected, and is turned waste into wealth, and can be adjusted soil texture, can be loosened the soil, and moisturizing, improved soil physicochemical character is particularly well-suited to gardens
Plant growth.
(2)Compounding straw biomass charcoal used in the present invention, has loaded sterilization and disinsection material, can slowly discharge desinsection
Material, reaches the insect prevention protection effect of the plant to lock plantation, while carrying out sterilized innoxious influence on paper mill sludge.
(3)Using Pintsch process technology, by agriculture and forestry organic waste materials such as agricultural crop straws, imperfect combustion is warm under anoxic conditions
Cracking can be made into straw biomass charcoal.Biomass carbon has flourishing pore structure, specific surface area high and abundant surface official
Can group, while have reserves pollution-free, high, it is renewable the features such as, compounding straw biomass charcoal of the invention contain to crop give birth to
Nutrient and some mineral matter elements such as length favourable nitrogen, phosphorus, potassium, sulphur, carbon content are of a relatively high.It is former after biomass carbonated
There is skeleton structure that more intact reservation has been obtained after charing.Have after straw charring substantially, clearly many Microporous Carbon frame knots
Structure, this abundant pore structure of biomass carbon makes it possess the characteristics such as specific surface area is big, absorption affinity is strong, is manured into soil
Material impact can be produced to the regulation soil water, fertilizer, air and heat environmental condition afterwards, soil organic matter content can also be lifted, to improve
Good structure of matter basis is established in the application of the aspects such as crop production ability.Additionally, can promote during biomass carbon is manured into soil
Enter the breeding of microorganism, carbon surface is generated rhizobium, thus form the soil for being adapted to plant culture, it is to avoid " continuous farming
Obstacle ", and charcoal increases organic matter to cereal, beans and vegetables in length, its quality, color and luster, taste all increase..
Specific embodiment
A kind of straw biomass charcoal soil conditioner containing sludge, it is obtained by the raw material of following weight parts:Vermiculite
23, lime stone 2, alum 1, paper mill sludge 1, stalk 130, APG 1, diacetyl tartarate monoglyceride 0.2, phenethyl phenol
APEO 0.2, polyvinyl alcohol 1, stalwart wormwood artemisia 5, mulberry tree branch 1.8, day name essence 1.4, calamus 3.
A kind of described straw biomass charcoal soil conditioner containing sludge,
Preparation method is comprised the following steps:
(1)By soybean stalk, in the case where ultraviolet wavelength is 254nm, ultraviolet irradiation 30 seconds, carries out Pintsch process anaerobic charing, obtains stalk
Biomass carbon is standby;
(2)After stalwart wormwood artemisia, mulberry tree branch, day essence, calamus mix, dry, obtain xeraphium standby;
(3)Straw biomass charcoal adds water mixing, after stirring 0.5h at 40 DEG C, adds APG, diacetyl tartarate list
Glyceride, phenethyl phenol polyethenoxy ether, polyvinyl alcohol, xeraphium, after stirring, filtering, with water washing filter residue is distilled, extremely
Filtrate in being 1% citric acid solution by filter residue addition concentration, stirs 1h in neutrality under 300rpm at 30 DEG C, filters, with steaming
Distilled water washs filter residue, and to filtrate in neutrality, filter residue obtains final product compounding straw biomass charcoal standby after being dried at 70 DEG C;
(4)Paper mill sludge is soaked 1 hour in the citric acid solution that concentration is 2%, and then at 400W microwave treatments 20 seconds, filtering was gone
Ion water washing, drying is dried, then is mixed with compounding straw biomass charcoal and remaining raw material, is obtained final product.
Claims (2)
1. a kind of straw biomass charcoal soil conditioner containing sludge, it is characterised in that:It is by the raw material of following weight parts
It is obtained:Vermiculite 23-26, lime stone 2-5, alum 1-2, paper mill sludge 1-2, stalk 130-140, APG 1-2, biacetyl wine
Stone acid monoglyceride 0.2-0.3, phenethyl phenol polyethenoxy ether 0.2-0.4, polyvinyl alcohol 1-2, stalwart wormwood artemisia 5-10, mulberry tree branch 1.8-
3rd, day name essence 1.4-2.7, calamus 3-5.
2. a kind of straw biomass charcoal soil conditioner containing sludge according to claim 1, it is characterised in that:
Preparation method is comprised the following steps:
(1)By soybean stalk, in the case where ultraviolet wavelength is 254-260nm ultraviolet irradiation 30-50 seconds, Pintsch process anaerobic charcoal is carried out
Change, obtain straw biomass charcoal standby;
(2)After stalwart wormwood artemisia, mulberry tree branch, day essence, calamus mix, dry, obtain xeraphium standby;
(3)Straw biomass charcoal adds water mixing, after stirring 0.5-1h at 40-60 DEG C, adds APG, diacetyl tartaric
Sour monoglyceride, phenethyl phenol polyethenoxy ether, polyvinyl alcohol, xeraphium, after stirring, filtering is filtered with distillation water washing
Slag, to filtrate in neutrality, during filter residue is added into concentration for the citric acid solution of 1-2%, stirs under 300-500rpm at 30-50 DEG C
1-2h is mixed, is filtered, with distillation water washing filter residue, to filtrate in neutrality, filter residue obtains final product compounding stalk after being dried at 70-85 DEG C
Biomass carbon is standby;
(4)Paper mill sludge soaks 1-3 hours in concentration is for the citric acid solution of 2-4%, then at 400-500W microwave treatments 20-
30 seconds, filtering, deionized water washing, drying was dried, then was mixed with compounding straw biomass charcoal and remaining raw material, was obtained final product.
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CN201710063213.2A CN106833673A (en) | 2017-02-03 | 2017-02-03 | A kind of straw biomass charcoal soil conditioner containing sludge |
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CN201710063213.2A CN106833673A (en) | 2017-02-03 | 2017-02-03 | A kind of straw biomass charcoal soil conditioner containing sludge |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107699244A (en) * | 2017-10-09 | 2018-02-16 | 武汉马腾科技发展有限公司 | A kind of modifying agent for soil remediation and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1762863A (en) * | 2004-10-20 | 2006-04-26 | 吴为中 | Sludge drying and resource disposal process |
CN102728608A (en) * | 2012-06-13 | 2012-10-17 | 广西来宾市天仁生物有机肥有限责任公司 | Leaching device for processing heavy metal in house refuse and sludge by using citric acid |
CN103396809A (en) * | 2013-08-19 | 2013-11-20 | 琼州学院 | Method for producing acid soil modifier by using agricultural waste |
-
2017
- 2017-02-03 CN CN201710063213.2A patent/CN106833673A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1762863A (en) * | 2004-10-20 | 2006-04-26 | 吴为中 | Sludge drying and resource disposal process |
CN102728608A (en) * | 2012-06-13 | 2012-10-17 | 广西来宾市天仁生物有机肥有限责任公司 | Leaching device for processing heavy metal in house refuse and sludge by using citric acid |
CN103396809A (en) * | 2013-08-19 | 2013-11-20 | 琼州学院 | Method for producing acid soil modifier by using agricultural waste |
Non-Patent Citations (1)
Title |
---|
万林等: "《典型区域环境问题及应对策略》", 31 August 2014, 石油工业出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107699244A (en) * | 2017-10-09 | 2018-02-16 | 武汉马腾科技发展有限公司 | A kind of modifying agent for soil remediation and preparation method thereof |
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Application publication date: 20170613 |