CN106833186A - 一种调温控温功能的水性涂料制备方法 - Google Patents
一种调温控温功能的水性涂料制备方法 Download PDFInfo
- Publication number
- CN106833186A CN106833186A CN201611245022.XA CN201611245022A CN106833186A CN 106833186 A CN106833186 A CN 106833186A CN 201611245022 A CN201611245022 A CN 201611245022A CN 106833186 A CN106833186 A CN 106833186A
- Authority
- CN
- China
- Prior art keywords
- parts
- water paint
- phase change
- preparation
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 239000003973 paint Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 19
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 19
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 15
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 15
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000077 silane Inorganic materials 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 14
- 239000010703 silicon Substances 0.000 claims abstract description 14
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 13
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 13
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 12
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical class CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 9
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 29
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 10
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 229940093476 ethylene glycol Drugs 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- 235000019394 potassium persulphate Nutrition 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 5
- 229940068984 polyvinyl alcohol Drugs 0.000 claims 4
- 150000002148 esters Chemical class 0.000 claims 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 150000003022 phthalic acids Chemical class 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000005338 heat storage Methods 0.000 abstract description 2
- 230000027555 hydrotropism Effects 0.000 abstract description 2
- 230000009466 transformation Effects 0.000 abstract description 2
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical compound C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- -1 benzene Diformazan dioctyl phthalate Chemical compound 0.000 description 7
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 239000012782 phase change material Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003094 microcapsule Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
本发明属于水性涂料领域，具体涉及一种调温控温功能的水性涂料的制备方法。该水性涂料由以下重量份数的原料制成：50‑55份水、15‑20份聚乙烯醇、20‑25份丙烯酸树脂、5‑8份邻苯二甲酸二辛酯、10‑15份纳米二氧化钛、1‑3份硅藻土、1‑5份有机硅消泡剂、20‑25份相变介质、10‑12份三乙醇胺、0.2‑0.5份硅烷偶联剂KH570、0.1‑0.5份十二烷基硫酸钠。本发明通过向水性涂料体系中添加相变介质，提高了水性涂料的调温控温能力，该水性涂料的相变焓值可达到21J/g，相变焓损失少，蓄热能力强，力学性能优异，使用寿命长，附着力强。该水性涂料原料绿色环保，减小对环境的污染，制备方法简单，应用范围广，适合推广及大规模生产。
Description
技术领域
本发明属于水性涂料领域，具体涉及一种调温控温功能的水性涂料的制备方法。
背景技术
建筑墙面涂刷涂料不仅可保证墙体美观，同时也是隔热保温的有效方法之一，目前市场上销售的隔热保温材料大多数是在基体中添加了改性剂，而仅通过添加改性剂的方式并不能有效达到控温的目的，且经过长时间的暴晒使用，部分挥发性较强的改性剂会散发出含氯的气体，导致环境污染。在控温材料领域，相变材料是目前研究的热门，而控温调温材料通常由相变介质通过多层纳米粉体共混、乳液聚合、微胶囊等方法来制备。现有技术中也是近年来才将相变材料应用于涂料领域，但目前将相变材料应用于水性涂料领域的技术并不成熟，已有的隔热水性涂料是在基体中加入双层壳体相变控温微胶囊，通过微胶囊达到控温和节能的目的。本发明通过将具有网状结构的相变材料添加至水性基中以获得高性能的水性涂料。
发明内容
为弥补现有技术的不足，提供了一种调温控温功能的水性涂料的制备方法。
本发明采用如下技术方案：一种调温控温功能的水性涂料由以下重量份数的原料制成：50-55份水、15-20份聚乙烯醇、20-25份丙烯酸树脂、5-8份邻苯二甲酸二辛酯、10-15份纳米二氧化钛、1-3份硅藻土、1-5份有机硅消泡剂、20-25份相变介质、10-12份三乙醇胺、0.2-0.5份硅烷偶联剂KH570、0.1-0.5份十二烷基硫酸钠；
所述的相变介质的制备方法为：将纳米二氧化硅、双甲基丙烯酸乙二醇酯、聚乙二醇丙烯酸酯按照质量比3:1:2的比例混合，过硫酸钾占上述物质总量的1％，将原料加入聚乙二醇中，于80℃超声分散器中反应直至生成凝胶，即为相变介质。
所述的调温控温功能的水性涂料的制备方法为：先将丙烯酸树脂加热熔融，缓缓加入聚乙烯醇和相变介质，搅拌1-1.5小时，待混合均匀后将水加入搅拌釜中加热至70-75℃，搅拌速度为800r/min，搅拌0.5-1小时后，加入有机硅消泡剂，搅拌0.5-1小时，降温至35-50℃，加入十二烷基硫酸钠和邻苯二甲酸二辛酯，再继续搅拌1小时后，停止搅拌，向反应釜中加入纳米二氧化钛，超声震荡1-1.5小时后，将反应釜升温至75℃恒温2小时，再次加入三乙醇胺、硅藻土、硅烷偶联剂KH570，恒温5小时，关闭反应釜，即得水性涂料。
作为一个优选的实施例，水性涂料由以下重量份数的原料制成：55份水、20份聚乙烯醇、22份丙烯酸树脂、5份邻苯二甲酸二辛酯、12份纳米二氧化钛、1份硅藻土、1份有机硅消泡剂、23份相变介质、10份三乙醇胺、0.4份硅烷偶联剂KH570、0.2份十二烷基硫酸钠。
进一步的，所述的聚乙烯醇为PVA 1788。
进一步的，超声分散压力为300Pa，频率20KHz。
本发明通过向水性涂料体系中添加相变介质，提高了水性涂料的调温控温能力，该水性涂料的相变焓值可达到21J/g，相变焓损失少，蓄热能力强，力学性能优异，使用寿命长，附着力强。该水性涂料原料绿色环保，减小对环境的污染，制备方法简单，应用范围广，适合推广及大规模生产。
具体实施方式
下面结合具体实施例对本发明的技术方案进一步的说明，但本发明不以任何形式受限于实施例内容。实施例中所述实验方法如无特殊说明，均为常规方法，如无特殊说明，所述化学试剂和材料，均可从商业途径获得。所述PVA 1788聚合度为1700，醇解度为88％。
实施例1
将纳米二氧化硅、双甲基丙烯酸乙二醇酯、聚乙二醇丙烯酸酯按照质量比3:1:2的比例混合，以过硫酸铵为引发剂，过硫酸钾占上述物质总量的1％，将原料加入聚乙二醇中，于80℃超声分散器中反应，超声分散压力为300Pa，频率20KHz。直至反应生成凝胶，即为相变介质。
实施例2
水性涂料由以下重量的原料制成：50g水、15g聚乙烯醇、20g份丙烯酸树脂、5g邻苯二甲酸二辛酯、10g份纳米二氧化钛、3g硅藻土、1g有机硅消泡剂、20g相变介质、10g份三乙醇胺、0.5g硅烷偶联剂KH570、0.1g十二烷基硫酸钠；
所述的调温控温功能的水性涂料的制备方法为：先将丙烯酸树脂加热熔融，缓缓加入聚乙烯醇和相变介质，搅拌1.5小时，待混合均匀后将水加入搅拌釜中加热至75℃，搅拌速度为800r/min，搅拌30分钟后，加入有机硅消泡剂，搅拌0.5小时，降温至50℃，加入十二烷基硫酸钠和邻苯二甲酸二辛酯，再继续搅拌1小时后，停止搅拌，向反应釜中加入纳米二氧化钛，超声震荡1小时后，将反应釜升温至75℃恒温2小时，再次加入三乙醇胺、硅藻土、硅烷偶联剂KH570，恒温5小时，关闭反应釜，即得水性涂料。
实施例3
水性涂料由以下重量的原料制成：55g水、20g聚乙烯醇、22g丙烯酸树脂、5g邻苯二甲酸二辛酯、12g纳米二氧化钛、1g硅藻土、1g有机硅消泡剂、23g相变介质、10g三乙醇胺、0.4g硅烷偶联剂KH570、0.2g十二烷基硫酸钠；
所述的调温控温功能的水性涂料的制备方法为：先将丙烯酸树脂加热熔融，缓缓加入聚乙烯醇和相变介质，搅拌1小时，待混合均匀后将水加入搅拌釜中加热至73℃，搅拌速度为800r/min，搅拌0.5-1小时后，加入有机硅消泡剂，搅拌40分钟，降温至45℃，加入十二烷基硫酸钠和邻苯二甲酸二辛酯，再继续搅拌1小时后，停止搅拌，向反应釜中加入纳米二氧化钛，超声震荡1.5小时后，将反应釜升温至75℃恒温2小时，再次加入三乙醇胺、硅藻土、硅烷偶联剂KH570，恒温5小时，关闭反应釜，即得水性涂料。
实施例4
水性涂料由以下重量的原料制成：55g水、20g聚乙烯醇、25g丙烯酸树脂、8g邻苯二甲酸二辛酯、15g纳米二氧化钛、1g硅藻土、5g有机硅消泡剂、25g相变介质、12g三乙醇胺、0.2g硅烷偶联剂KH570、0.5g十二烷基硫酸钠；
所述的调温控温功能的水性涂料的制备方法为：先将丙烯酸树脂加热熔融，缓缓加入聚乙烯醇和相变介质，搅拌1小时，待混合均匀后将水加入搅拌釜中加热至70℃，搅拌速度为800r/min，搅拌0.5-1小时后，加入有机硅消泡剂，搅拌1小时，降温至35℃，加入十二烷基硫酸钠和邻苯二甲酸二辛酯，再继续搅拌1小时后，停止搅拌，向反应釜中加入纳米二氧化钛，超声震荡1.5小时后，将反应釜升温至75℃恒温2小时，再次加入三乙醇胺、硅藻土、硅烷偶联剂KH570，恒温5小时，关闭反应釜，即得水性涂料。
对比例
水性涂料由以下重量的原料制成：55g水、20g聚乙烯醇、22g丙烯酸树脂、5g邻苯二甲酸二辛酯、12g纳米二氧化钛、1g硅藻土、1g有机硅消泡剂、10g三乙醇胺、0.4g硅烷偶联剂KH570、0.2g十二烷基硫酸钠；
所述的调温控温功能的水性涂料的制备方法为：先将丙烯酸树脂加热熔融，缓缓加入聚乙烯醇，搅拌1小时，待混合均匀后将水加入搅拌釜中加热至73℃，搅拌速度为800r/min，搅拌0.5-1小时后，加入有机硅消泡剂，搅拌40分钟，降温至45℃，加入十二烷基硫酸钠和邻苯二甲酸二辛酯，再继续搅拌1小时后，停止搅拌，向反应釜中加入纳米二氧化钛，超声震荡1.5小时后，将反应釜升温至75℃恒温2小时，再次加入三乙醇胺、硅藻土、硅烷偶联剂KH570，恒温5小时，关闭反应釜，即得水性涂料。
试验例：
将本发明实施例及对比例按照GBT/T 9756-2009、GB1720-79、GB1732-79国家标准进行试验测试，测得的实验数据如表1所示。
表1：
本发明实施例的水性涂料外观无沉淀，无结块，耐水性实验无异常，耐碱性试验无异常，耐洗刷，在室温-50℃热循环20次，相变焓无损失，相变焓最佳可达到21J/g。
Claims (4)
1.一种调温控温功能的水性涂料的制备方法，其特征在于，所述水性涂料由以下重量份数的原料制成：50-55份水、15-20份聚乙烯醇、20-25份丙烯酸树脂、5-8份邻苯二甲酸二辛酯、10-15份纳米二氧化钛、1-3份硅藻土、1-5份有机硅消泡剂、20-25份相变介质、10-12份三乙醇胺、0.2-0.5份硅烷偶联剂KH570、0.1-0.5份十二烷基硫酸钠；
所述的相变介质的制备方法为：将纳米二氧化硅、双甲基丙烯酸乙二醇酯、聚乙二醇丙烯酸酯按照质量比3:1:2的比例混合，过硫酸钾占上述物质总量的1％，将原料加入聚乙二醇中，于80℃超声分散器中反应直至生成凝胶，即为相变介质；
所述的调温控温功能的水性涂料的制备方法为：先将丙烯酸树脂加热熔融，缓缓加入聚乙烯醇和相变介质，搅拌1-1.5小时，待混合均匀后将水加入搅拌釜中加热至70-75℃，搅拌速度为800r/min，搅拌0.5-1小时后，加入有机硅消泡剂，搅拌0.5-1小时，降温至35-50℃，加入十二烷基硫酸钠和邻苯二甲酸二辛酯，再继续搅拌1小时后，停止搅拌，向反应釜中加入纳米二氧化钛，超声震荡1-1.5小时后，将反应釜升温至75℃恒温2小时，再次加入三乙醇胺、硅藻土、硅烷偶联剂KH570，恒温5小时，关闭反应釜，即得水性涂料。
2.根据权利要求1所述的调温控温功能的水性涂料的制备方法，其特征在于，水性涂料由以下重量份数的原料制成：55份水、20份聚乙烯醇、22份丙烯酸树脂、5份邻苯二甲酸二辛酯、12份纳米二氧化钛、1份硅藻土、1份有机硅消泡剂、23份相变介质、10份三乙醇胺、0.4份硅烷偶联剂KH570、0.2份十二烷基硫酸钠。
3.根据权利要求1所述的调温控温功能的水性涂料的制备方法，其特征在于，所述的聚乙烯醇为PVA 1788。
4.根据权利要求1所述的调温控温功能的水性涂料的制备方法，其特征在于，超声分散压力为300Pa，频率20KHz。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611245022.XA CN106833186B (zh) | 2016-12-29 | 2016-12-29 | 一种调温控温功能的水性涂料制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611245022.XA CN106833186B (zh) | 2016-12-29 | 2016-12-29 | 一种调温控温功能的水性涂料制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106833186A true CN106833186A (zh) | 2017-06-13 |
| CN106833186B CN106833186B (zh) | 2019-06-25 |
Family
ID=59114705
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611245022.XA Active CN106833186B (zh) | 2016-12-29 | 2016-12-29 | 一种调温控温功能的水性涂料制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106833186B (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987651A (zh) * | 2017-12-29 | 2018-05-04 | 安徽科邦树脂科技有限公司 | 一种抗腐蚀水性涂料合成方法 |
| CN111349369A (zh) * | 2020-04-08 | 2020-06-30 | 广东梵竹水性涂料有限公司 | 一种调温控温功能的水性涂料的制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206456A (zh) * | 2011-05-26 | 2011-10-05 | 开平市日固力涂料有限公司 | 一种透明玻璃隔热涂料 |
| CN102702457A (zh) * | 2012-04-28 | 2012-10-03 | 东华大学 | 一种可生物降解相变储能材料的制备方法 |
| CN103243406A (zh) * | 2013-05-22 | 2013-08-14 | 东华大学 | 一种熔融纺丝法制备智能调温纤维的方法 |
| CN105481561A (zh) * | 2015-12-23 | 2016-04-13 | 成都新柯力化工科技有限公司 | 一种由温敏性凝胶控释的微生物肥增效剂及其制备方法 |
| US9511566B2 (en) * | 2011-05-13 | 2016-12-06 | Polyglass Usa, Inc. | Building construction material with high solar reflectivity |
-
2016
- 2016-12-29 CN CN201611245022.XA patent/CN106833186B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9511566B2 (en) * | 2011-05-13 | 2016-12-06 | Polyglass Usa, Inc. | Building construction material with high solar reflectivity |
| CN102206456A (zh) * | 2011-05-26 | 2011-10-05 | 开平市日固力涂料有限公司 | 一种透明玻璃隔热涂料 |
| CN102702457A (zh) * | 2012-04-28 | 2012-10-03 | 东华大学 | 一种可生物降解相变储能材料的制备方法 |
| CN103243406A (zh) * | 2013-05-22 | 2013-08-14 | 东华大学 | 一种熔融纺丝法制备智能调温纤维的方法 |
| CN105481561A (zh) * | 2015-12-23 | 2016-04-13 | 成都新柯力化工科技有限公司 | 一种由温敏性凝胶控释的微生物肥增效剂及其制备方法 |
Non-Patent Citations (1)
| Title |
|---|
| 覃忠琼等: "聚双甲基丙烯酸聚乙二醇酯固-固相变储能材料的制备", 《应用化工》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987651A (zh) * | 2017-12-29 | 2018-05-04 | 安徽科邦树脂科技有限公司 | 一种抗腐蚀水性涂料合成方法 |
| CN111349369A (zh) * | 2020-04-08 | 2020-06-30 | 广东梵竹水性涂料有限公司 | 一种调温控温功能的水性涂料的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106833186B (zh) | 2019-06-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105061700B (zh) | 纳米二氧化硅/聚丙烯酸酯有机无机杂化水分散性树脂及其制备方法 | |
| CN106565897B (zh) | 一种具有荷叶效应的外墙弹性乳液及其制备方法 | |
| CN103666159B (zh) | 一种具有相变功能的超疏水涂料的制备方法 | |
| CN105399889A (zh) | 一种相变储能材料的杂化壁材纳米胶囊及其制备方法 | |
| CN103172291B (zh) | 一种常温合成的聚羧酸系减水剂及其制备方法和使用方法 | |
| CN107964297B (zh) | 一种无机材料包覆的相变微胶囊复合的相变涂料及其制备方法和应用 | |
| CN103709885A (zh) | 一种水性环境友好型改性醇酸木器漆 | |
| CN109735192A (zh) | 一种基于磷酸锆和甲基丙烯酸复合改性丙烯酸酯核壳乳液的防火涂料及其制备方法 | |
| CN104087077A (zh) | 基于相变储热的相变储热保温涂料及其制备方法和应用 | |
| CN107365121A (zh) | 一种无机材料包覆的相变微胶囊复合的相变腻子及其制备方法和应用 | |
| CN106833186B (zh) | 一种调温控温功能的水性涂料制备方法 | |
| CN107445574A (zh) | 一种无机材料包覆的相变微胶囊复合的石膏板及其制备方法和应用 | |
| CN108940148A (zh) | 一种温控缓释香精微囊的制备方法 | |
| CN102190754A (zh) | 一种丙烯酸酯乳液、由其制备的耐水丙烯酸酯可再分散乳胶粉及该乳胶粉的制备方法 | |
| CN106189640A (zh) | 一种改性水性丙烯酸树脂涂料的制备方法 | |
| CN107163711A (zh) | 一种水性弹性保温隔热涂料及其制备方法 | |
| CN106146755A (zh) | 一种高固含量硅丙乳液的制备方法 | |
| CN106632876B (zh) | 一种防污涂料用树脂及其制备方法 | |
| CN105131157B (zh) | 一种云母钛原位填充的聚苯乙烯银灰色保温材料的制备方法、其产品及应用 | |
| CN107815296B (zh) | 一种互穿网络杂化定形相变材料制备方法 | |
| CN106565896B (zh) | 一种具有光致亲水效应的外墙弹性乳液及其制备方法 | |
| CN102352164B (zh) | 一种新型隔热保温建筑涂料 | |
| CN104356841A (zh) | 一种自清洁丙烯酸涂料 | |
| CN109762378A (zh) | 负离子涂料及其制备方法 | |
| CN103937315B (zh) | 一种外墙保温基层膏及其制备和应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of water-based coating with temperature regulation and control function Effective date of registration: 20211122 Granted publication date: 20190625 Pledgee: Dalian Economic and Technological Development Zone Xinhui Village Bank Co.,Ltd. Pledgor: DALIAN BLUE CITY ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2021210000083 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20221114 Granted publication date: 20190625 Pledgee: Dalian Economic and Technological Development Zone Xinhui Village Bank Co.,Ltd. Pledgor: DALIAN BLUE CITY ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2021210000083 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method of waterborne paint with temperature regulating and controlling function Effective date of registration: 20221115 Granted publication date: 20190625 Pledgee: Dalian Economic and Technological Development Zone Xinhui Village Bank Co.,Ltd. Pledgor: DALIAN BLUE CITY ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2022210000196 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231108 Granted publication date: 20190625 Pledgee: Dalian Economic and Technological Development Zone Xinhui Village Bank Co.,Ltd. Pledgor: DALIAN BLUE CITY ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2022210000196 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method for water-based coatings with temperature regulation and control function Effective date of registration: 20231110 Granted publication date: 20190625 Pledgee: Dalian Economic and Technological Development Zone Xinhui Village Bank Co.,Ltd. Pledgor: DALIAN BLUE CITY ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2023210000278 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |