CN106800752A - A kind of fast light blast PET color master batch - Google Patents
A kind of fast light blast PET color master batch Download PDFInfo
- Publication number
- CN106800752A CN106800752A CN201611203217.8A CN201611203217A CN106800752A CN 106800752 A CN106800752 A CN 106800752A CN 201611203217 A CN201611203217 A CN 201611203217A CN 106800752 A CN106800752 A CN 106800752A
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- pet
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- color master
- fast light
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of fast light blast PET color master batch, it is made up of the raw material of following weight portion：150 195 parts of PET, 21 25 parts of amino resins, 15 22 parts of ethylene octene block type copolymer, 8 23 parts of nano molybdenum disulfide, 15 28 parts of polytetrafluoroethylwax wax, 8 14 parts of hydroxy silicon oil, 37 parts of AEO, 10 20 parts of nano diatomite, three (2,4 di-tert-butyl-phenyls) 58 parts of phosphite ester, 79 parts of tributyl 2-acetylcitrate, 47 parts of 1,4 butylene glycol.The fast light blast PET color master batch that the present invention is provided has good fast light blast performance, processing cost is low, preparation process is simple, when the coloring of PET products is applied to, with colour stability raising, the less advantage of aberration, the problems such as color is unstable, aberration is larger when existing PET color master batch is coloured is overcome.
Description
Technical field
The invention belongs to technical field of polymer materials, more particularly to a kind of fast light blast PET color master batch.
Background technology
With the improvement of people's living standards, people not only pay close attention to the performance of the product used in various lives, same to time
Its is attractive in appearance for benefit pursuit, and wishes that product of its purchase has good outward appearance.Because there are plastic products raw material sources to enrich, valency
Lattice are cheap, nontoxic, be easy to processing and forming, and rigidity and toughness higher, mechanical strength are good, so being flooded with people's life now
Plastic products miscellaneous, and Masterbatch coloring is the coloring plastic method for most generally using now.Masterbatch is 20th century 60
A kind of plastics, the coloring new product of fiber of age exploitation, it is pigment super quantity to be uniformly attached in resin and is obtained
Polymer compound.With advances in technology, in plastic processes, by adding Masterbatch, so as to play beautification, dress
Adorn, be easy to recognize, improve weatherability, improve mechanical property, improve the effect such as optical property.When being coloured using Masterbatch, pigment
By pre-processing and it is dispersed in vector resin, the dispersive property and coloration efficiency of pigment is substantially increased, with operation
Simply, with low cost, environmentally safe the advantages of.
Polyethylene terephthalate（PET）, exchanged with glycol ester by dimethyl terephthalate (DMT) or with to benzene two
Formic acid first synthesizes bishydroxyethyl terephthalate with ethylene glycol esterification, polycondensation reaction is then carried out again and is obtained.Category crystal type saturation
Polyester, is milky or light yellow, highly crystalline polymer, and surface smooths glossy.Have within the scope of temperature wider
Excellent physical and mechanical properties, long-term use temperature is up to 120 DEG C, and electrical insulating property is excellent, or even under high-temperature high-frequency, its is electrical
Can still preferably, but corona resistance is poor, creep resistance, and fatigue durability, rub resistance, dimensional stability are all fine.
At present, the variety of raw material such as external PET color master batch technical merit country higher, pigment, dispersant are complete, shape
Into seriation and specialized product structure.But domestic PET color master batch product structure is single, the raw material such as pigment, dispersant
Variety matching is not complete, and there is some difference to cause color and luster, and this is totally unfavorable for the coloring of product.Coloured with Masterbatch
When, because carrier flow performance is poor, the problems such as easily there is flow liner, color and luster uneven, aberration whard to control and unitary function.Cause
How this, solve easily to be produced when PET color master batch is coloured that flow liner, color and luster be uneven, aberration is larger and shock resistance is deteriorated etc. asks
Topic, is the problem that need to be urgently solved when PET is coloured.Therefore, we set about from the formula of product, new Masterbatch is developed, there is provided
A kind of PET color master batch.
The content of the invention
It is an object of the invention to provide a kind of fast light blast PET color master batch.
To achieve these goals, the invention provides a kind of fast light blast PET color master batch, by the raw material of following weight portion
It is obtained：PET 150-195 parts, amino resins 21-25 parts, 15-22 parts of ethylene-octene block type copolymer, nano molybdenum disulfide
8-23 parts, polytetrafluoroethylwax wax 15-28 parts, hydroxy silicon oil 8-14 parts, AEO 3-7 parts, nano diatomite 10-
20 parts, phosphite ester 5-8 parts of three (2,4- di-tert-butyl-phenyls), tributyl 2-acetylcitrate 7-9 parts, 1,4- butylene glycols 4-7
Part.
It also includes Graphene 8-23 parts.
It also includes tetraethylammonium tetrafluoroborate 12-18 parts.
It also includes coconut monoethanolamide 6-14 parts.
Beneficial effect：The fast light blast PET color master batch that the present invention is provided has good fast light blast performance, processing cost
It is low, preparation process is simple, when the coloring of PET products is applied to, with colour stability raising, the less advantage of aberration, gram
The problems such as color is unstable, aberration is larger when existing PET color master batch is coloured is taken.
Specific embodiment
Embodiment 1
A kind of fast light blast PET color master batch that the present embodiment is provided, is obtained by the raw material of following weight portion：150 parts of PET, amino
21 parts of resin, 15 parts of ethylene-octene block type copolymer, 8 parts of nano molybdenum disulfide, 15 parts of polytetrafluoroethylwax wax, hydroxy silicon oil 8
Part, 3 parts of AEO, 10 parts of nano diatomite, three 5 parts of (2,4- di-tert-butyl-phenyls) phosphite esters, acetyl lemon
7 parts of tributyl of lemon acid, 4 parts of 1,4- butylene glycols.
Embodiment 2
A kind of fast light blast PET color master batch that the present embodiment is provided, is obtained by the raw material of following weight portion：195 parts of PET, amino
25 parts of resin, 22 parts of ethylene-octene block type copolymer, 23 parts of nano molybdenum disulfide, 28 parts of polytetrafluoroethylwax wax, hydroxy silicon oil
14 parts, 7 parts of AEO, 20 parts of nano diatomite, three 8 parts of (2,4- di-tert-butyl-phenyls) phosphite esters, acetyl
9 parts of ATBC, 7 parts of 1,4- butylene glycols, 23 parts of Graphene.
Embodiment 3
A kind of fast light blast PET color master batch that the present embodiment is provided, is obtained by the raw material of following weight portion：150 parts of PET, amino
21 parts of resin, 15 parts of ethylene-octene block type copolymer, 8 parts of nano molybdenum disulfide, 15 parts of polytetrafluoroethylwax wax, hydroxy silicon oil 8
Part, 3 parts of AEO, 10 parts of nano diatomite, three 5 parts of (2,4- di-tert-butyl-phenyls) phosphite esters, acetyl lemon
7 parts of tributyl of lemon acid, 4 parts of 1,4- butylene glycols, 8 parts of Graphene, 12 parts of tetraethylammonium tetrafluoroborate.
Embodiment 4
A kind of fast light blast PET color master batch that the present embodiment is provided, is obtained by the raw material of following weight portion：195 parts of PET, amino
25 parts of resin, 22 parts of ethylene-octene block type copolymer, 23 parts of nano molybdenum disulfide, 28 parts of polytetrafluoroethylwax wax, hydroxy silicon oil
14 parts, 7 parts of AEO, 20 parts of nano diatomite, three 8 parts of (2,4- di-tert-butyl-phenyls) phosphite esters, acetyl
9 parts of ATBC, 7 parts of 1,4- butylene glycols, 23 parts of Graphene, 18 parts of tetraethylammonium tetrafluoroborate, cocinic acid list second
14 parts of alkylolamides.
The production technology that above-described embodiment 1-4 is used is conventional production process, and its step is：First weighed respectively by said ratio
In raw material input homogenizer, stirring mixing；Then well mixed material is added in double screw extruder and melts, moulds
Change, extrude, granulate, obtain final product.
Claims (4)
1. a kind of fast light blast PET color master batch, it is characterised in that be made up of the raw material of following weight portion：PET 150-195 parts, ammonia
21-25 parts of base resin, 15-22 parts of ethylene-octene block type copolymer, nano molybdenum disulfide 8-23 parts, polytetrafluoroethylwax wax 15-
28 parts, hydroxy silicon oil 8-14 parts, AEO 3-7 parts, nano diatomite 10-20 parts, three (2,4- di-tert-butyls
Base) phosphite ester 5-8 parts, tributyl 2-acetylcitrate 7-9 parts, 4-7 parts of 1,4- butylene glycols.
2. a kind of fast light blast PET color master batch according to claim 1, it is characterised in that：It also includes Graphene 8-23
Part.
3. a kind of fast light blast PET color master batch according to claim 2, it is characterised in that：It also includes tetrafluoro boric acid four
Ethyl ammonium 12-18 parts.
4. a kind of fast light blast PET color master batch according to claim 3, it is characterised in that：It also includes cocinic acid list
Glycollic amide 6-14 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611203217.8A CN106800752A (en) | 2016-12-23 | 2016-12-23 | A kind of fast light blast PET color master batch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611203217.8A CN106800752A (en) | 2016-12-23 | 2016-12-23 | A kind of fast light blast PET color master batch |
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| Publication Number | Publication Date |
|---|---|
| CN106800752A true CN106800752A (en) | 2017-06-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611203217.8A Pending CN106800752A (en) | 2016-12-23 | 2016-12-23 | A kind of fast light blast PET color master batch |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286593A (en) * | 2017-06-13 | 2017-10-24 | 浙江金彩新材料有限公司 | It is a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof |
| CN107903412A (en) * | 2017-11-15 | 2018-04-13 | 苏州博云塑业有限公司 | A kind of Anti-static electricity color master batch that can improve colour stability |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102400236A (en) * | 2011-05-13 | 2012-04-04 | 上海容志材料科技有限公司 | Solid color master batch composite as well as preparation method and application thereof |
| CN104559086A (en) * | 2014-12-29 | 2015-04-29 | 东莞市协创包装材料制品有限公司 | Highlight functional masterbatch as well as preparation method and application thereof |
| CN105291295A (en) * | 2015-11-16 | 2016-02-03 | 东莞市普凯塑料科技有限公司 | Lamelliferous color master batch and manufacturing method thereof |
-
2016
- 2016-12-23 CN CN201611203217.8A patent/CN106800752A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102400236A (en) * | 2011-05-13 | 2012-04-04 | 上海容志材料科技有限公司 | Solid color master batch composite as well as preparation method and application thereof |
| CN104559086A (en) * | 2014-12-29 | 2015-04-29 | 东莞市协创包装材料制品有限公司 | Highlight functional masterbatch as well as preparation method and application thereof |
| CN105291295A (en) * | 2015-11-16 | 2016-02-03 | 东莞市普凯塑料科技有限公司 | Lamelliferous color master batch and manufacturing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286593A (en) * | 2017-06-13 | 2017-10-24 | 浙江金彩新材料有限公司 | It is a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof |
| CN107903412A (en) * | 2017-11-15 | 2018-04-13 | 苏州博云塑业有限公司 | A kind of Anti-static electricity color master batch that can improve colour stability |
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