CN106674869A - Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches - Google Patents
Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches Download PDFInfo
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- CN106674869A CN106674869A CN201611203170.5A CN201611203170A CN106674869A CN 106674869 A CN106674869 A CN 106674869A CN 201611203170 A CN201611203170 A CN 201611203170A CN 106674869 A CN106674869 A CN 106674869A
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- parts
- abs
- antistatic
- antibacterial
- color
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches. The antistatic and antibacterial ABS color masterbatches is prepared from the following raw materials in parts by weight: 140 to 150 parts of ABS, 15 to 25 parts of PBT (Poly Butylene Terephthalate), 2 to 6 parts of nano magnesia, 15 to 19 parts of coumarone indene resin, 6 to 8 parts of antioxidant 1076, 10 to 16 parts of sodium silicate, 8 to 10 parts of lithium trifluoromethanesulfonate, 2 to 6 parts of ferric citrate, 5 to 9 parts of silicon dioxide and 2 to 6 parts of zinc oxide. The antistatic and antibacterial ABS color masterbatches provided by the invention have good antistatic, antibacterial and anti-mold properties, are low in processing cost and simple in preparation technology; when the antistatic and antibacterial ABS color masterbatches are applied to coloring of ABS products, the antistatic and antibacterial ABS color masterbatches have the advantages that the color stability is increased, and the chromatic aberration is smaller; the problems that during coloring of existing ABS color masterbatches, the color is instable, the chromatic aberration is larger, and the like are solved.
Description
Technical field
The invention belongs to technical field of polymer materials, more particularly to a kind of antistatic antibiotic ABS color master batch.
Background technology
With the raising of living standards of the people, people not only pay close attention to the performance of the product used in various lives, same to time
Its is attractive in appearance for benefit pursuit, and wishes that product of its purchase has good outward appearance.Because plastic has abundant raw material source, valency
Lattice are cheap, nontoxic, be easy to processing and forming, higher rigidity and toughness, and mechanical strength is good, so being flooded with people's life now
Plastic miscellaneous, and Masterbatch coloring is the coloring plastic method for most generally adopting now.Masterbatch is 20th century 60
A kind of plastics, the coloring new product of fiber of age exploitation, it is pigment super quantity to be uniformly attached in resin and is obtained
Polymer complex.With the progress of technology, in plastic processes, by adding Masterbatch, so as to play beautification, dress
Adorn, be easy to recognize, improve weatherability, improve mechanical property, improve the effect such as optical property.When being coloured using Masterbatch, pigment
Through pretreatment and it is dispersed in vector resin, the dispersive property and coloration efficiency of pigment is substantially increased, with operation
Simply, the advantages of with low cost, environmentally safe.
ABS（Acrylonitrile-butadiene-styrene copolymer）Resin is one of five big synthetic resin, its impact resistance, heat-resisting
Property, lower temperature resistance, chemical proofing and excellent electrical properties, also with easy processing, product size be stable, lustrous surface property is good
The features such as, easy application, coloring can also carry out the secondary operations such as surface metallization, plating, welding, hot pressing and bonding, extensively
It is general to be applied to the industrial circles such as machinery, automobile, electronic apparatus, instrument and meter, weaving and building, it is a kind of extremely wide thermoplastic of purposes
Property engineering plastics.
At present, the variety of raw material such as the higher country of external ABS color master batch technical merit, pigment, dispersant are complete, shape
Into seriation and specialized product structure.But domestic ABS color master batch product structure is single, the raw material such as pigment, dispersant
Variety matching is not complete, and there is some difference to cause color and luster, and this is totally unfavorable for the coloring of product.Coloured with Masterbatch
When, because carrier flow performance is poor, the problems such as easily there is flow liner, color and luster uneven, wayward aberration and single function.Cause
How this, solve easily to be produced when ABS color master batch is coloured that flow liner, color and luster be uneven, aberration is larger and shock resistance is deteriorated etc. asks
Topic, is the problem that need to urgently solve when ABS is coloured.For this purpose, we set about from the formula of product, new Masterbatch is developed, there is provided
A kind of ABS color master batch.
The content of the invention
It is an object of the invention to provide a kind of antistatic antibiotic ABS color master batch.
To achieve these goals, the invention provides a kind of antistatic antibiotic ABS color master batch, by the original of following weight portion
Material is obtained：ABS 140-150 parts, polybutylene terephthalate (PBT) 15-25 parts, nano magnesia 2-6 parts, coumarone indene resin
15-19 parts, antioxidant 1076 6-8 parts, waterglass 10-16 parts, trifluoromethyl sulfonic acid lithium 8-10 parts, ferric citrate 2-6 parts, two
Silicon oxide 5-9 parts, Zinc Oxide 2-6 part.
It also includes rhenocure CA 8-15 parts.
It also includes triphenyl phosphite 5-9 parts.
It also includes disulfide group 2-ethyl hexyl ethanoate stannous methide 3-5 parts.
Beneficial effect：The antistatic antibiotic ABS color master batch that the present invention is provided has good antistatic and antibacterial and mouldproof
Can, processing cost is low, preparation process is simple, when the coloring of ABS products is applied to, improve with colour stability, aberration compared with
Little advantage, overcomes the problems such as color is unstable, aberration is larger when existing ABS color master batch is coloured.
Specific embodiment
Embodiment 1
A kind of antistatic antibiotic ABS color master batch that the present embodiment is provided, is obtained by the raw material of following weight portion：It is 140 parts of ABS, poly-
15 parts of mutual-phenenyl two acid bromide two alcohol ester, 2 parts of nano magnesia, 15 parts of coumarone indene resin, 6 parts of antioxidant 1076, waterglass 10
Part, 8 parts of trifluoromethyl sulfonic acid lithium, 2 parts of ferric citrate, 5 parts of silicon dioxide, 2 parts of Zinc Oxide.
Embodiment 2
A kind of antistatic antibiotic ABS color master batch that the present embodiment is provided, is obtained by the raw material of following weight portion：It is 150 parts of ABS, poly-
25 parts of mutual-phenenyl two acid bromide two alcohol ester, 6 parts of nano magnesia, 19 parts of coumarone indene resin, 8 parts of antioxidant 1076, waterglass 16
Part, 10 parts of trifluoromethyl sulfonic acid lithium, 6 parts of ferric citrate, 9 parts of silicon dioxide, 6 parts of Zinc Oxide, 15 parts of rhenocure CA.
Embodiment 3
A kind of antistatic antibiotic ABS color master batch that the present embodiment is provided, is obtained by the raw material of following weight portion：It is 140 parts of ABS, poly-
15 parts of mutual-phenenyl two acid bromide two alcohol ester, 2 parts of nano magnesia, 15 parts of coumarone indene resin, 6 parts of antioxidant 1076, waterglass 10
Part, 8 parts of trifluoromethyl sulfonic acid lithium, 2 parts of ferric citrate, 5 parts of silicon dioxide, 2 parts of Zinc Oxide, 8 parts of rhenocure CA, phosphorous acid three
5 parts of phenyl ester.
Embodiment 4
A kind of antistatic antibiotic ABS color master batch that the present embodiment is provided, is obtained by the raw material of following weight portion：It is 150 parts of ABS, poly-
25 parts of mutual-phenenyl two acid bromide two alcohol ester, 6 parts of nano magnesia, 19 parts of coumarone indene resin, 8 parts of antioxidant 1076, waterglass 16
Part, 10 parts of trifluoromethyl sulfonic acid lithium, 6 parts of ferric citrate, 9 parts of silicon dioxide, 6 parts of Zinc Oxide, 15 parts of rhenocure CA, phosphorous acid
9 parts of triphenylmethyl methacrylate, 5 parts of disulfide group 2-ethyl hexyl ethanoate stannous methide.
The production technology that above-described embodiment 1-4 is used is conventional production process, and its step is：First weigh respectively by said ratio
In raw material input homogenizer, stirring mixing；Then the material of mix homogeneously is added to into melting in double screw extruder, modeling
Change, extrusion, pelletize, obtain final product.
Claims (4)
1. a kind of antistatic antibiotic ABS color master batch, it is characterised in that be made up of the raw material of following weight portion：ABS 140-150 parts,
Polybutylene terephthalate (PBT) 15-25 parts, nano magnesia 2-6 parts, coumarone indene resin 15-19 parts, antioxidant 1076 6-8
Part, waterglass 10-16 parts, trifluoromethyl sulfonic acid lithium 8-10 parts, ferric citrate 2-6 parts, silicon dioxide 5-9 parts, Zinc Oxide 2-6
Part.
2. a kind of antistatic antibiotic ABS color master batch according to claim 1, it is characterised in that：It also includes diphenyl sulfur
Urea 8-15 parts.
3. a kind of antistatic antibiotic ABS color master batch according to claim 2, it is characterised in that：It also includes phosphorous acid three
Phenyl ester 5-9 parts.
4. a kind of antistatic antibiotic ABS color master batch according to claim 3, it is characterised in that：It also includes disulfide group second
The different monooctyl ester stannous methide 3-5 parts of acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611203170.5A CN106674869A (en) | 2016-12-23 | 2016-12-23 | Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611203170.5A CN106674869A (en) | 2016-12-23 | 2016-12-23 | Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106674869A true CN106674869A (en) | 2017-05-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611203170.5A Pending CN106674869A (en) | 2016-12-23 | 2016-12-23 | Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches |
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| Country | Link |
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| CN (1) | CN106674869A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722545A (en) * | 2017-10-16 | 2018-02-23 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of high dispersive antibacterial ABS color master batch |
| CN109056099A (en) * | 2018-06-29 | 2018-12-21 | 中润科技股份有限公司 | A kind of super soft highly-elastic power color silk fiber production technology |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040799A (en) * | 2010-12-29 | 2011-05-04 | 深圳市科聚新材料有限公司 | ABS (Acrylonitrile Butadiene Styrene) white master batch and preparation method thereof |
| CN103289298A (en) * | 2013-06-24 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Antistatic and antibacterial ABS color master batch |
| CN106221097A (en) * | 2016-08-31 | 2016-12-14 | 许勤峰 | A kind of ABS color master batch |
-
2016
- 2016-12-23 CN CN201611203170.5A patent/CN106674869A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040799A (en) * | 2010-12-29 | 2011-05-04 | 深圳市科聚新材料有限公司 | ABS (Acrylonitrile Butadiene Styrene) white master batch and preparation method thereof |
| CN103289298A (en) * | 2013-06-24 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Antistatic and antibacterial ABS color master batch |
| CN106221097A (en) * | 2016-08-31 | 2016-12-14 | 许勤峰 | A kind of ABS color master batch |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722545A (en) * | 2017-10-16 | 2018-02-23 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of high dispersive antibacterial ABS color master batch |
| CN109056099A (en) * | 2018-06-29 | 2018-12-21 | 中润科技股份有限公司 | A kind of super soft highly-elastic power color silk fiber production technology |
| CN109056099B (en) * | 2018-06-29 | 2021-08-24 | 中润科技股份有限公司 | Production process of super-soft high-elasticity colored silk fiber |
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Application publication date: 20170517 |