CN106221097A - A kind of ABS color master batch - Google Patents
A kind of ABS color master batch Download PDFInfo
- Publication number
- CN106221097A CN106221097A CN201610762574.1A CN201610762574A CN106221097A CN 106221097 A CN106221097 A CN 106221097A CN 201610762574 A CN201610762574 A CN 201610762574A CN 106221097 A CN106221097 A CN 106221097A
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- China
- Prior art keywords
- master batch
- color master
- abs color
- abs
- parts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to Masterbatch field, particularly to a kind of ABS color master batch.A kind of ABS color master batch, is made up of the component of following parts by weight: carrier 30 as one kind ~ 90 part；Toner 0.01 ~ 50 part；Dispersant 5 ~ 10 parts；Heat stabilizer 0.5 ~ 3 part；Filler 0 ~ 60 part.The ABS color master batch of the present invention is applied to during ABS coloring not only have good colour stability, is also equipped with the advantage that aberration is little the most simultaneously；Cost is relatively low, it is simple to large-scale popularization and application.
Description
Technical field
The present invention relates to Masterbatch field, particularly to a kind of ABS color master batch.
Background technology
And Masterbatch is by a high proportion of pigment or additive and thermoplastic resin, through the coloring plastic of fine dispersion
Agent, its selected resin has good wet and peptizaiton, and has good phase with being colored material coloring agent
Capacitive, therefore, Masterbatch has in purposes widely, especially plastics.But it is as Masterbatch to be widely applied, to Masterbatch
It is also proposed that preferably requirement, when processing and forming, owing to Masterbatch poor heat stability easily causes, color is unstable, aberration is difficult to
The problems such as control.
Summary of the invention
The technical problem to be solved is to provide a kind of ABS color master batch with good thermal stability.
A kind of ABS color master batch, is made up of the component of following parts by weight:
Carrier 30 as one kind ~ 90 part；Toner 0.01 ~ 50 part；Dispersant 5 ~ 10 parts；Heat stabilizer 0.5 ~ 3 part；Filler 0 ~ 60 part.
Further, described carrier is acrylonitritrile-styrene resin, vinyl-acrylate copolymer, ethylene-methyl
At least one in acrylate copolymer.
Further, described toner is inorganic toner or is organic pigment.The present invention can select according to corresponding demand
The inorganic toner of different colours or organic pigment.
Further, described inorganic toner is at least one in titanium dioxide, white carbon black, iron oxide red.
Further, described organic pigment be that phthalocyanine is red, at least one in phthalocyanine blue, phthalocyanine green, azophloxine.
Further, described dispersant is maleic anhydride inoculated polypropylene wax.The dispersant that the present invention uses, contributes to solving
The heat stability agent that certainly present invention is novel dispersion problem in the carrier, preferably plays its performance.
Further, described heat stabilizer chemical formula is (C9H9N3O7)(C16H12N6)Zn；Wherein, C9H9N3O7Urinate for isocyanide
Double (2-carboxyethyl) ester group of acid, C16H12N6For 4,4'-bis-(1H-1,2,4-triazol-1-yl)-1,1'-xenyl；Adsorbent is single
Oblique system,P2/cSpace group, cell parameter isa=17.165 (4),b=15.634 (2),c=19.314 (2),α = γ =90,β =103.815 (5), V=5183.05 (8)3。
Further, at least one during described filler is brucite, calcium carbonate, barium sulfate.
There is advantages that
The ABS color master batch of the present invention is applied to during ABS coloring not only have good colour stability, is also equipped with aberration the most simultaneously
Little advantage；Cost is relatively low, it is simple to large-scale popularization and application.
Accompanying drawing explanation
Fig. 1 is the coordination structure figure of the heat stabilizer of the present invention.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It it not limitation of the invention.
Heat stabilizer preparation method of the present invention is:
By 4,4'-bis-(1H-1,2,4-triazol-1-yl)-1,1'-xenyl, (English is: 4,4'-di (1H-1,2,4-
Triazol-1-yl)-1,1'-biphenyl), (No. CAS is double (2-carboxyethyl) ester of 0.5mmol isocyanuric acid: 2904-40-7)
In the middle of the mixed solvent that 0.5mmol zinc nitrate is dissolved in 10mL methanol, 10mL acetonitrile and 10mL dimethylformamide, use hydroxide
Its pH regulator is 7.5 by sodium water solution, is stirred at room temperature formation mixed liquor A, then described mixed liquor A is transferred to microwave anti-
Answering in bottle and seal, put into by reaction bulb in microwave instrument, set radiant power 500W, the response time is 90 minutes, and reaction temperature is
60 DEG C, reaction obtains mixed liquid B after terminating；Subsequently mixed liquid B is transferred in politef autoclave, place it in
It is down to room temperature after 155 DEG C of baking ovens react 24 hours and is filtrated to get described heat stabilizer.
Then above-mentioned heat stabilizer is carried out monocrystalline sign.
The X ray diffracting data of this heat stabilizer is to visit on diffractometer in Bruker Smart Apex CCD face, uses MoKα
Radiation (λ=0.71073), collects and carries out Lp factor correction with ω scan mode, and absorption correction uses SADABS program.
Use direct method solution structure, then obtain whole non-hydrogen atom coordinate by difference Fourier method, and it is former to obtain hydrogen with theoretical hydrogenation method
Sub-position (C H 1.083), is modified structure with method of least square.Evaluation work uses SHELXTL program on PC
Bag completes.
Resolving after tested and understand, the chemical formula of this heat stabilizer is (C9H9N3O7)(C16H12N6)Zn；Wherein, C9H9N3O7For
Double (2-carboxyethyl) ester group of isocyanuric acid, C16H12N6For 4,4'-bis-(1H-1,2,4-triazol-1-yl)-1,1'-xenyl；Absorption
Agent is monoclinic system,P2/cSpace group, cell parameter isa=17.165 (4),b=15.634 (2),c =19.314(2)
,α =γ =90,β =103.815 (5), V=5183.05 (8)3, Z=8.
The coordination structure figure of this heat stabilizer is as it is shown in figure 1, Zn atom takes the pattern of 4 coordinations, the most each Zn atom
2 O atom coordinations on (2-carboxyethyl) esters double with 2 isocyanuric acids and 2 4,4'-bis-(1H-1,2,4-triazole-1-respectively
Base)-1,1'-xenyl 2 triazole ring on atom N coordination.
Following example if no special instructions, all use said method to prepare the heat stabilizer of gained.
The preparation method that employing the art of the Masterbatch of the present invention is conventional, retouches the most in detail
State.
Embodiment 1
A kind of ABS color master batch, is made up of the component of following parts by weight:
Acrylonitritrile-styrene resin 46 parts；Titanium dioxide 12 parts；6 parts of maleic anhydride inoculated polypropylene wax；Heat stabilizer 2 parts；Water
45 parts of Talcum.
Embodiment 2
A kind of ABS color master batch, is made up of the component of following parts by weight:
Vinyl-acrylate copolymer 85 parts；Phthalocyanine blue 35 parts；9 parts of maleic anhydride inoculated polypropylene wax；Heat stabilizer 2.8 parts；
Calcium carbonate 23 parts.
Embodiment 3
A kind of ABS color master batch, is made up of the component of following parts by weight:
Ethylene-methyl acrylate copolymer 60 parts；White carbon black 2 parts；7 parts of maleic anhydride inoculated polypropylene wax；Heat stabilizer 0.8
Part；50 parts of barium sulfate.
Comparative example 1
A kind of ABS color master batch, is made up of the component of following parts by weight:
Acrylonitritrile-styrene resin 46 parts；Titanium dioxide 12 parts；6 parts of maleic anhydride inoculated polypropylene wax；Brucite 45 parts.
Comparative example 2
A kind of ABS color master batch, is made up of the component of following parts by weight:
Acrylonitritrile-styrene resin 46 parts；Titanium dioxide 12 parts；Heat stabilizer 2 parts；Brucite 45 parts.
Then the Masterbatch of above-described embodiment and comparative example is used for ABS plastic injection, then carries out coloring effect evaluation,
Result is as shown in table 1:
Table 1 coloring effect evaluation table
Embodiment described above only have expressed embodiments of the present invention, therefore it describes more concrete and detailed, but can not be
And it is interpreted as the restriction to the scope of the claims of the present invention, as long as using the technical side that the form of equivalent or equivalent transformation is obtained
Case, all should fall within the scope and spirit of the invention.
Claims (8)
1. an ABS color master batch, it is characterised in that: it is made up of the component of following parts by weight:
Carrier 30 as one kind ~ 90 part；Toner 0.01 ~ 50 part；Dispersant 5 ~ 10 parts；Heat stabilizer 0.5 ~ 3 part；Filler 0 ~ 60 part.
A kind of ABS color master batch the most according to claim 1, it is characterised in that: described carrier is acrylonitrile-styrene copolymerized
At least one in thing, vinyl-acrylate copolymer, ethylene-methyl acrylate copolymer.
A kind of ABS color master batch the most according to claim 1, it is characterised in that: described toner is inorganic toner or for having
Machine pigment.
A kind of ABS color master batch the most according to claim 3, it is characterised in that: described inorganic toner be titanium dioxide, white carbon black,
At least one in iron oxide red.
A kind of ABS color master batch the most according to claim 3, it is characterised in that: described organic pigment is that phthalocyanine is red, phthalocyanine
At least one in indigo plant, phthalocyanine green, azophloxine.
A kind of ABS color master batch the most according to claim 1, it is characterised in that: described dispersant is that maleic anhydride grafting is poly-
Propylene wax.
A kind of ABS color master batch the most according to claim 1, it is characterised in that: described heat stabilizer chemical formula is
(C9H9N3O7)(C16H12N6)Zn；Wherein, C9H9N3O7For double (2-carboxyethyl) ester group of isocyanuric acid, C16H12N6For 4,4'-bis-
(1H-1,2,4-triazol-1-yl)-1,1'-xenyl；Adsorbent is monoclinic system,P2/cSpace group, cell parameter isa=
17.165 (4),b=15.634 (2),c=19.314 (2),α =γ =90,β =103.815 (5), V=5183.05
(8) Å3。
A kind of ABS color master batch the most according to claim 1, it is characterised in that: described filler be brucite, calcium carbonate,
At least one in barium sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610762574.1A CN106221097A (en) | 2016-08-31 | 2016-08-31 | A kind of ABS color master batch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610762574.1A CN106221097A (en) | 2016-08-31 | 2016-08-31 | A kind of ABS color master batch |
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| Publication Number | Publication Date |
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| CN106221097A true CN106221097A (en) | 2016-12-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610762574.1A Pending CN106221097A (en) | 2016-08-31 | 2016-08-31 | A kind of ABS color master batch |
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| Country | Link |
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| CN (1) | CN106221097A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106674869A (en) * | 2016-12-23 | 2017-05-17 | 苏州曙帆信电子科技有限公司 | Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches |
| CN107722545A (en) * | 2017-10-16 | 2018-02-23 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of high dispersive antibacterial ABS color master batch |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101121806A (en) * | 2006-08-11 | 2008-02-13 | 广州市波斯塑胶颜料有限公司 | ABS color master batch with increased color stability and preparation method thereof |
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN103254546A (en) * | 2013-02-07 | 2013-08-21 | 胡君 | ABS color master batch and preparation process thereof |
| CN104403259A (en) * | 2014-12-29 | 2015-03-11 | 苏州钧隆塑胶有限公司 | High-effect ABS (acrylonitrile-butadiene-styrene) color master batch |
| CN105504628A (en) * | 2015-12-21 | 2016-04-20 | 慈溪康氏新材料有限公司 | ABS color master batch and preparing method thereof |
-
2016
- 2016-08-31 CN CN201610762574.1A patent/CN106221097A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101121806A (en) * | 2006-08-11 | 2008-02-13 | 广州市波斯塑胶颜料有限公司 | ABS color master batch with increased color stability and preparation method thereof |
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN103254546A (en) * | 2013-02-07 | 2013-08-21 | 胡君 | ABS color master batch and preparation process thereof |
| CN104403259A (en) * | 2014-12-29 | 2015-03-11 | 苏州钧隆塑胶有限公司 | High-effect ABS (acrylonitrile-butadiene-styrene) color master batch |
| CN105504628A (en) * | 2015-12-21 | 2016-04-20 | 慈溪康氏新材料有限公司 | ABS color master batch and preparing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106674869A (en) * | 2016-12-23 | 2017-05-17 | 苏州曙帆信电子科技有限公司 | Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches |
| CN107722545A (en) * | 2017-10-16 | 2018-02-23 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of high dispersive antibacterial ABS color master batch |
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