CN105504628A - ABS color master batch and preparing method thereof - Google Patents
ABS color master batch and preparing method thereof Download PDFInfo
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- CN105504628A CN105504628A CN201510958236.0A CN201510958236A CN105504628A CN 105504628 A CN105504628 A CN 105504628A CN 201510958236 A CN201510958236 A CN 201510958236A CN 105504628 A CN105504628 A CN 105504628A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses an ABS color master batch and a preparing method thereof. The ABS color master batch comprises, by weight, 50 parts of carriers, 45 parts of toner and 5 parts of dispersing agent, and the dispersing agent is EBFF. The carriers are one or more of acrylonitrile-styrene copolymers, styrene-butadiene copolymers and polystyrene. As the EBFF dispersing agent is adopted, the dispersion effect of the carriers can be greatly promoted, the use quantity of the dispersing agent is decreased, and the application of the ABS color master batch is facilitated.
Description
Technical field
The present invention relates to a kind of Masterbatch, particularly a kind of ABS color master batch and preparation method thereof.
Background technology
Masterbatch is a kind of conventional plastic colorant, and it has the following advantages: 1, make pigment in goods, have better dispersiveness; 2, the chemical stability keeping pigment is conducive to: the words directly using pigment, due to the direct ingress of air of pigment in storage and use procedure, the phenomenons such as pigment can absorb water, oxidation, and after making Masterbatch, because pigment and air, moisture are isolated by resin carrier, the quality of pigment can be made to remain unchanged for a long period of time; 3, the stable of goods color is ensured: Masterbatch is close with resin particle, accurately more convenient in metering, can not adhere on container during mixing, also comparatively even with mixing of resin, therefore can ensure the stable of addition, thus ensure the stable of goods color; 4, protect the health of operator: pigment is generally powdery, easily fly upward when adding and mix, after being sucked by human body, will the health of operator be affected; 5, keep the cleaning of environment, do not stain vessel; 6, operation is simple, and annesl is easy, saves time and starting material.
ABS color master batch is the tinting material of a class large usage quantity, be prepared from primarily of pigment, carrier, dispersion agent and other auxiliary agents, in order to make ABS color master batch, there is good dispersiveness, the content of dispersion agent is generally between 20% ~ 40%, because the content proportion of dispersion agent is high, thus cause the application limitation of this ABS color master batch larger.
Summary of the invention
In order to solve above-mentioned the deficiencies in the prior art, the first object of the present invention is to provide a kind of ABS color master batch.
To achieve these goals, a kind of ABS color master batch designed by the present invention, comprise the component of following weight part: 50 parts, carrier, toner 45 parts, dispersion agent 5 parts, described dispersion agent is EBFF, and described carrier is one or more in acrylonitritrile-styrene resin, styrene-butadiene copolymer, polystyrene.
Also comprise the component of following weight part: nano-tantalum 1.5 parts, chitin 1 part, tea-polyphenol 2 parts, ITO2 part, nano aluminium oxide 1 part, nano zircite 1 part, nano yttrium oxide 1 part, silane coupling agent 2.5 parts and organophosphorous fire retardant 5 parts, the granularity of described nano-tantalum is 50-60nm.
Preferably, described toner is the mixture of fragrant acid amides pigment and benzimidazolone pigment.
The second object of the present invention is to provide a kind of preparation method of above-mentioned ABS color master batch, first by nano-tantalum, nano aluminium oxide, nano zircite, nano yttrium oxide and ITO grind to form the powder that granularity is below 200 orders, then by above-mentioned powder and chitin, tea-polyphenol, silane coupling agent, organophosphorous fire retardant, dispersion agent, toner and carrier are uniformly mixed together in high mixer or Banbury mixer, add after mixing in twin screw extruder, the processing temperature of twin screw extruder: district's temperature 180 DEG C, two district's temperature 180 DEG C, three district's temperature 185 DEG C, four district's temperature 185 DEG C, five district's temperature 190 DEG C, six district's temperature 190 DEG C, seven district's temperature 195 DEG C, eight district's temperature 200 DEG C, nine district's temperature 210 DEG C, extrude rear cooling check rod, air-dry pelletizing obtains Masterbatch of the present invention.
A kind of ABS color master batch that the present invention obtains and preparation method thereof, its technique effect is: 1, adopt EBFF dispersion agent, greatly can promote the dispersion effect of carrier, reduces the usage quantity of dispersion agent, is conducive to the application of ABS color master batch; 2, nano-tantalum is passed through, chitin, tea-polyphenol, ITO, nano aluminium oxide, nano zircite, nano yttrium oxide, silane coupling agent and organophosphorous fire retardant, make the ABS color master batch obtained not only possess high-low temperature resistant, fire-retardant characteristic, but also there is antibacterial effect, make the range of application of this ABS color master batch wider.
Embodiment
Below in conjunction with embodiment, the present invention is further described.
A kind of ABS color master batch provided by the invention, comprise the component of following weight part: 50 parts, carrier, toner 45 parts, dispersion agent 5 parts, nano-tantalum 1.5 parts, chitin 1 part, tea-polyphenol 2 parts, ITO2 part, nano aluminium oxide 1 part, nano zircite 1 part, nano yttrium oxide 1 part, silane coupling agent 2.5 parts and organophosphorous fire retardant 5 parts.
Dispersion agent is the EBFF that Japanese Kao company produces, and carrier is one or more in acrylonitritrile-styrene resin, styrene-butadiene copolymer, polystyrene.
Wherein the granularity of nano-tantalum is 50-60nm.
Toner is the mixture of fragrant acid amides pigment and benzimidazolone pigment.
First by nano-tantalum, nano aluminium oxide, nano zircite, nano yttrium oxide and ITO grind to form the powder that granularity is below 200 orders, then by above-mentioned powder and chitin, tea-polyphenol, silane coupling agent, organophosphorous fire retardant, dispersion agent, toner and carrier are uniformly mixed together in high mixer or Banbury mixer, add after mixing in twin screw extruder, the processing temperature of twin screw extruder: district's temperature 180 DEG C, two district's temperature 180 DEG C, three district's temperature 185 DEG C, four district's temperature 185 DEG C, five district's temperature 190 DEG C, six district's temperature 190 DEG C, seven district's temperature 195 DEG C, eight district's temperature 200 DEG C, nine district's temperature 210 DEG C, extrude rear cooling check rod, air-dry pelletizing obtains Masterbatch of the present invention.
By the ABS color master batch that the method is worth, change original ABS non-refractory, the characteristic that inflammable, weathering resistance is poor, also make ABS color master batch possess certain antibacterial anti-mildew effect, market application foreground is wide simultaneously.
Claims (4)
1. an ABS color master batch, is characterized in that, comprises the component of following weight part: 50 parts, carrier, toner 45 parts, dispersion agent 5 parts, described dispersion agent is EBFF, and described carrier is one or more in acrylonitritrile-styrene resin, styrene-butadiene copolymer, polystyrene.
2. ABS color master batch according to claim 1, it is characterized in that, also comprise the component of following weight part: nano-tantalum 1.5 parts, chitin 1 part, tea-polyphenol 2 parts, ITO2 part, nano aluminium oxide 1 part, nano zircite 1 part, nano yttrium oxide 1 part, silane coupling agent 2.5 parts and organophosphorous fire retardant 5 parts, the granularity of described nano-tantalum is 50-60nm.
3. ABS color master batch according to claim 1, is characterized in that: described toner is the mixture of fragrant acid amides pigment and benzimidazolone pigment.
4. the preparation method of the ABS color master batch described in the claims 2, it is characterized in that: first by nano-tantalum, nano aluminium oxide, nano zircite, nano yttrium oxide and ITO grind to form the powder that granularity is below 200 orders, then by above-mentioned powder and chitin, tea-polyphenol, silane coupling agent, organophosphorous fire retardant, dispersion agent, toner and carrier are uniformly mixed together in high mixer or Banbury mixer, add after mixing in twin screw extruder, the processing temperature of twin screw extruder: district's temperature 180 DEG C, two district's temperature 180 DEG C, three district's temperature 185 DEG C, four district's temperature 185 DEG C, five district's temperature 190 DEG C, six district's temperature 190 DEG C, seven district's temperature 195 DEG C, eight district's temperature 200 DEG C, nine district's temperature 210 DEG C, extrude rear cooling check rod, air-dry pelletizing obtains Masterbatch of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510958236.0A CN105504628A (en) | 2015-12-21 | 2015-12-21 | ABS color master batch and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510958236.0A CN105504628A (en) | 2015-12-21 | 2015-12-21 | ABS color master batch and preparing method thereof |
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| Publication Number | Publication Date |
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| CN105504628A true CN105504628A (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510958236.0A Pending CN105504628A (en) | 2015-12-21 | 2015-12-21 | ABS color master batch and preparing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221097A (en) * | 2016-08-31 | 2016-12-14 | 许勤峰 | A kind of ABS color master batch |
| CN106566102A (en) * | 2016-11-03 | 2017-04-19 | 苏州圣鑫莱新材料有限公司 | Nanometer PS color master batch |
| CN109111678A (en) * | 2018-07-17 | 2019-01-01 | 蓝晓锋 | A kind of ABS resin bloom light tone master batch and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1721474A (en) * | 2005-06-02 | 2006-01-18 | 广州市波斯塑胶颜料有限公司 | Strong dispersion and impact-resistant ABS color concentrates and process for preparing same |
| CN101121806A (en) * | 2006-08-11 | 2008-02-13 | 广州市波斯塑胶颜料有限公司 | ABS color master batch with increased color stability and preparation method thereof |
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN104403259A (en) * | 2014-12-29 | 2015-03-11 | 苏州钧隆塑胶有限公司 | High-effect ABS (acrylonitrile-butadiene-styrene) color master batch |
-
2015
- 2015-12-21 CN CN201510958236.0A patent/CN105504628A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1721474A (en) * | 2005-06-02 | 2006-01-18 | 广州市波斯塑胶颜料有限公司 | Strong dispersion and impact-resistant ABS color concentrates and process for preparing same |
| CN101121806A (en) * | 2006-08-11 | 2008-02-13 | 广州市波斯塑胶颜料有限公司 | ABS color master batch with increased color stability and preparation method thereof |
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN104403259A (en) * | 2014-12-29 | 2015-03-11 | 苏州钧隆塑胶有限公司 | High-effect ABS (acrylonitrile-butadiene-styrene) color master batch |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221097A (en) * | 2016-08-31 | 2016-12-14 | 许勤峰 | A kind of ABS color master batch |
| CN106566102A (en) * | 2016-11-03 | 2017-04-19 | 苏州圣鑫莱新材料有限公司 | Nanometer PS color master batch |
| CN109111678A (en) * | 2018-07-17 | 2019-01-01 | 蓝晓锋 | A kind of ABS resin bloom light tone master batch and preparation method thereof |
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Application publication date: 20160420 |
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