CN103289298A - Antistatic and antibacterial ABS color master batch - Google Patents
Antistatic and antibacterial ABS color master batch Download PDFInfo
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- CN103289298A CN103289298A CN2013102518932A CN201310251893A CN103289298A CN 103289298 A CN103289298 A CN 103289298A CN 2013102518932 A CN2013102518932 A CN 2013102518932A CN 201310251893 A CN201310251893 A CN 201310251893A CN 103289298 A CN103289298 A CN 103289298A
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Abstract
The invention relates to an antistatic and antibacterial ABS color master batch, and belongs to the field of polymer materials. The antistatic and antibacterial ABS color master batch comprises the following raw materials: by weight, 70-120 parts of a carrier, 2-5 parts of tea tree oil, 20-60 portions of an inorganic filler, 30-80 parts of a toner, 10-20 parts of zinc stearate, 1-8 parts of ethoxylated alkylamines, 1-5 parts of dimethyl dimercapto isooctyl acetate tin, and 0.5-2 parts of melamine phosphate. The carrier is one of or a combination of a plurality of substances selected from an acrylonitrile-styrene copolymer, a styrene-butadiene copolymer and polystyrene. When the antistatic and antibacterial ABS color master batch is applied to coloring of ABS products, the antistatic and antibacterial ABS color master batch has advantages of high color-stability, small color-difference, good antistatic and flame retardant properties, and greatly increased safety in the process of production and use. In addition, through addition of a natural antibacterial agent, the antistatic and antibacterial ABS color master batch product has an antibacterial function, and can effectively reduce the possibility that human health may be damaged by bacteria on the surface of ABS products.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of antistatic antibiotic ABS Masterbatch.
Background technology
ABS resin is one of five big synthetic resins, its shock resistance, thermotolerance, lower temperature resistance, chemical proofing and excellent electrical properties, also have characteristics such as easy processing, product size is stable, surface luster property is good, application, painted easily, can also carry out surperficial spraymetal, plating, welding, hot pressing and secondary processing such as bonding, being widely used in industrial circles such as machinery, automobile, electronic apparatus, instrument, weaving and building, is the extremely wide thermoplastic engineering plastic of a kind of purposes.
At present, the colorize method of ABS mainly contain toner painted, dyeing draw the grain the painted and painted three kinds of methods of Masterbatch.The toner colorize method is simple, is easy to generate color dot, aberration is wayward, environmental pollution is bigger shortcoming but exist; It is ABS to be mixed the back adopt mixing facilities to carry out melt blending with toner that dyeing draws grain painted, thereby makes painted ABS micelle, compares with toner is painted, though coloring effect increases to some extent, needs to have improved production cost through second-heating; Masterbatch is painted to be with the pre-treatment of pigment process, and is scattered in uniformly in the vector resin, has improved dispersing of pigments and tinctorial yield greatly, has advantages such as simple to operate, with low cost, environmentally friendly.
Along with the raising of people's living standard, people more and more are concerned about own and household's health except the outward appearance of being concerned about product.Various daily living articles, the harm that has potentiality as the bacterium on the surface of refrigerator, washing machine, televisor etc., so be necessary to produce the antibiotic plastic product, with the control of product surface bacterial number in certain limit.Also because product can produce a large amount of electric charges unavoidably when producing and use, a large amount of electric charges that gather cause fire easily, exist potential danger.Therefore how overcoming the deficiencies in the prior art, is the problem that present technical field of polymer materials is needed solution badly.
Summary of the invention
The objective of the invention is in order to solve the deficiencies in the prior art, a kind of antistatic antibiotic ABS Masterbatch is provided, and product of the present invention has added static inhibitor and halogen-free flame retardants, makes this product have higher safety coefficient, adopt natural antibacterial agent simultaneously, made this product have antibacterial.
The technical solution used in the present invention is as follows:
A kind of antistatic antibiotic ABS Masterbatch is characterized in that comprising the following raw material according to the parts by weight meter: 70 ~ 120 parts in carrier, 2 ~ 5 parts of tea tree oil, 21 ~ 60 parts of mineral fillers, 30 ~ 80 parts of toners, 10 ~ 20 parts of Zinic stearass, 1 ~ 8 part of ethoxylated alkylamine, 1 ~ 5 part in dimethyl dimercapto 2-ethyl hexyl ethanoate tin, trimeric cyanamide phosphoesterase 30 .5 ~ 2 parts;
Described carrier is one or more the combination in acrylonitritrile-styrene resin, styrene-butadiene copolymer, the polystyrene.
Further preferably mineral filler is that diatomite and tourmaline powder mass ratio are the mixture of 2:1.
Further preferably described toner is one or more mixture in pigment dyestuff, mineral dye or the dyestuff.
Preparation method of the present invention: above-mentioned each component joined successively mix 10 ~ 15min in the high-speed mixer, adopt twin screw extruder or Banbury mixer to carry out melt blending, be uniformly dispersed at carrier by the shearing of screw rod or rotor, the mixing pigment that makes then, carry out granulation then, drying makes product of the present invention.
The present invention compared with prior art, its beneficial effect is:When (1) the present invention is applied to ABS goods painted, have advantages such as colour stability height, aberration be less; (2) added static inhibitor and halogen-free flame retardants in the products material of the present invention, made this product have good antistatic performance and flame retardant properties, increase to produce greatly and use in security; (3) add natural antibacterial disinfectant---tea tree oil simultaneously, made this product have antibacterial, can reduce the possibility of ABS product surface bacterium damage HUMAN HEALTH effectively; (4) use tourmaline powder among the present invention, made product of the present invention have negative ion-releasing function.
Specific embodiment
The present invention is described in further detail below in conjunction with embodiment.
Embodiment 1
A kind of antistatic antibiotic ABS Masterbatch comprises the following raw material according to the parts by weight meter: 70 parts of acrylonitritrile-styrene resins, 2 parts of tea tree oil, 14 parts in diatomite, 7 parts of tourmaline powders, 30 parts of permanent violets, 10 parts of Zinic stearass, 1 part of ethoxylated alkylamine, 1 part in dimethyl dimercapto 2-ethyl hexyl ethanoate tin, trimeric cyanamide phosphoesterase 30 .5 part.
Embodiment 2
A kind of antistatic antibiotic ABS Masterbatch comprises the following raw material according to the parts by weight meter: 70 parts of acrylonitritrile-styrene resins, 50 parts of styrene butadienes, 5 parts of tea tree oil, 22 parts in diatomite, 11 parts of tourmaline powders, 80 parts of titanium dioxides, 20 parts of Zinic stearass, 8 parts of ethoxylated alkylamines, 5 parts in dimethyl dimercapto 2-ethyl hexyl ethanoate tin, 2 parts of trimeric cyanamide phosphoric acid ester.
Embodiment 3
A kind of antistatic antibiotic ABS Masterbatch comprises the following raw material according to the parts by weight meter: 40 parts of acrylonitritrile-styrene resins, 30 parts of styrene-butadiene copolymers, 10 parts of polystyrene, 4 parts of tea tree oil, 40 parts in diatomite, 20 parts of tourmaline powders, 60 parts of carbon blacks, 15 parts of Zinic stearass, 6 parts of ethoxylated alkylamines, 3 parts in dimethyl dimercapto 2-ethyl hexyl ethanoate tin, 1 part of trimeric cyanamide phosphoric acid ester;
The embodiment of the invention 1 ~ 3 product performance detected result is as shown in table 1.
The Performance Detection data of table 1 embodiment of the invention 1 ~ 3 product
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Fire-retardant rank (thickness 0.25mm) | VTM-0 | VTM-0 | VTM-0 |
| Surface resistivity Ω/sq | 10 8 | 10 8 | 10 8 |
| Flow liner | Do not have | Do not have | Do not have |
| Aberration | ≤0.3 | ≤0.3 | ≤0.3 |
Simultaneously the anti-microbial property of present embodiment 1 ~ 3 product is tested:
Adopt conventional microbial disinfection power to detect, its data results is as shown in table 2.
The sterilizing power of table 2 embodiment of the invention 1 ~ 3 product detects data
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Streptococcus aureus | 82% | 85% | 88% |
| Intestinal bacteria | 85% | 83% | 87% |
| Candida albicans | 87% | 86% | 90% |
Claims (3)
1. an antistatic antibiotic ABS Masterbatch is characterized in that comprising the following raw material according to the parts by weight meter: 70 ~ 120 parts in carrier, 2 ~ 5 parts of tea tree oil, 21 ~ 60 parts of mineral fillers, 30 ~ 80 parts of toners, 10 ~ 20 parts of Zinic stearass, 1 ~ 8 part of ethoxylated alkylamine, 1 ~ 5 part in dimethyl dimercapto 2-ethyl hexyl ethanoate tin, trimeric cyanamide phosphoesterase 30 .5 ~ 2 parts;
Described carrier is one or more the combination in acrylonitritrile-styrene resin, styrene-butadiene copolymer, the polystyrene.
2. antistatic ABS Masterbatch according to claim 1 is characterized in that described mineral filler is that diatomite and tourmaline powder mass ratio are the mixture of 2:1.
3. antistatic ABS Masterbatch according to claim 1 is characterized in that described toner is one or more mixture in pigment dyestuff, mineral dye or the dyestuff.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310251893.2A CN103289298B (en) | 2013-06-24 | 2013-06-24 | A kind of antistatic antibiotic ABS color master batch |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310251893.2A CN103289298B (en) | 2013-06-24 | 2013-06-24 | A kind of antistatic antibiotic ABS color master batch |
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| CN103289298A true CN103289298A (en) | 2013-09-11 |
| CN103289298B CN103289298B (en) | 2015-08-19 |
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| CN201310251893.2A Expired - Fee Related CN103289298B (en) | 2013-06-24 | 2013-06-24 | A kind of antistatic antibiotic ABS color master batch |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104962030A (en) * | 2015-07-12 | 2015-10-07 | 陆思烨 | Natural antibacterial and aging-resistant ABS (acrylonitrile butadiene styrene copolymer) material and preparation method thereof |
| CN105936696A (en) * | 2016-07-19 | 2016-09-14 | 丁飞鹏 | Functional plastic master batch for tea bran making |
| CN106674869A (en) * | 2016-12-23 | 2017-05-17 | 苏州曙帆信电子科技有限公司 | Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches |
| CN107722545A (en) * | 2017-10-16 | 2018-02-23 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of high dispersive antibacterial ABS color master batch |
| CN110079182A (en) * | 2019-04-29 | 2019-08-02 | 深圳市兴盛迪新材料有限公司 | A kind of permanent anti-static exempts to spray ABS material |
| CN112831132A (en) * | 2021-01-29 | 2021-05-25 | 湖南省升阳新材料有限公司 | Flame-retardant color master batch for XPS (extruded polystyrene) foaming insulation board and preparation method thereof |
| CN113186615A (en) * | 2021-05-15 | 2021-07-30 | 浙江世纪晨星纤维科技有限公司 | Environment-friendly antibacterial polyamide composite coated yarn and preparation method thereof |
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| WO2010009471A2 (en) * | 2008-07-18 | 2010-01-21 | Quick-Med Technologies, Inc. | Polyelectrolyte complex for imparting antimicrobial properties to a substrate |
| CN102344619A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Antistatic PVC plastic floor |
| CN102558680A (en) * | 2011-12-29 | 2012-07-11 | 海尔科化工程塑料国家工程研究中心股份有限公司 | Antibacterial masterbatch |
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- 2013-06-24 CN CN201310251893.2A patent/CN103289298B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010009471A2 (en) * | 2008-07-18 | 2010-01-21 | Quick-Med Technologies, Inc. | Polyelectrolyte complex for imparting antimicrobial properties to a substrate |
| CN102344619A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Antistatic PVC plastic floor |
| CN102558680A (en) * | 2011-12-29 | 2012-07-11 | 海尔科化工程塑料国家工程研究中心股份有限公司 | Antibacterial masterbatch |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104962030A (en) * | 2015-07-12 | 2015-10-07 | 陆思烨 | Natural antibacterial and aging-resistant ABS (acrylonitrile butadiene styrene copolymer) material and preparation method thereof |
| CN105936696A (en) * | 2016-07-19 | 2016-09-14 | 丁飞鹏 | Functional plastic master batch for tea bran making |
| CN106674869A (en) * | 2016-12-23 | 2017-05-17 | 苏州曙帆信电子科技有限公司 | Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches |
| CN107722545A (en) * | 2017-10-16 | 2018-02-23 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of high dispersive antibacterial ABS color master batch |
| CN110079182A (en) * | 2019-04-29 | 2019-08-02 | 深圳市兴盛迪新材料有限公司 | A kind of permanent anti-static exempts to spray ABS material |
| CN112831132A (en) * | 2021-01-29 | 2021-05-25 | 湖南省升阳新材料有限公司 | Flame-retardant color master batch for XPS (extruded polystyrene) foaming insulation board and preparation method thereof |
| CN113186615A (en) * | 2021-05-15 | 2021-07-30 | 浙江世纪晨星纤维科技有限公司 | Environment-friendly antibacterial polyamide composite coated yarn and preparation method thereof |
| CN113186615B (en) * | 2021-05-15 | 2023-08-29 | 浙江世纪晨星纤维科技有限公司 | Environment-friendly antibacterial nylon composite coated yarn and preparation method thereof |
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| Publication number | Publication date |
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| CN103289298B (en) | 2015-08-19 |
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