CN103289298B - A kind of antistatic antibiotic ABS color master batch - Google Patents
A kind of antistatic antibiotic ABS color master batch Download PDFInfo
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- CN103289298B CN103289298B CN201310251893.2A CN201310251893A CN103289298B CN 103289298 B CN103289298 B CN 103289298B CN 201310251893 A CN201310251893 A CN 201310251893A CN 103289298 B CN103289298 B CN 103289298B
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Abstract
The present invention relates to a kind of antistatic antibiotic ABS color master batch, belong to polymeric material field, it is characterized in that comprising the following raw material according to weight parts: 70 ~ 120 parts, carrier, tea tree oil 2 ~ 5 parts, mineral filler 20 ~ 60 parts, toner 30 ~ 80 parts, Zinic stearas 10 ~ 20 parts, ethoxylated alkylamine 1 ~ 8 part, 1 ~ 5 part, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, melamine phosphate 0.5 ~ 2 part; Described carrier is the combination of one or more in acrylonitritrile-styrene resin, styrene-butadiene copolymer, polystyrene.When the present invention is applied to ABS goods painted, there is the advantages such as colour stability is high, aberration is less, and there is good static resistance and flame retardant properties, greatly increase the security of producing and in use procedure.With the addition of natural antibacterial agent simultaneously, make this product have antibacterial, effectively can reduce the possibility of ABS product surface bacterium damage HUMAN HEALTH.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of antistatic antibiotic ABS color master batch.
Background technology
ABS resin is one of five large synthetic resins, its shock resistance, thermotolerance, lower temperature resistance, chemical proofing and excellent electrical properties, also there is the features such as easy processing, product size is stable, surface luster property is good, easy application, painted, surface metallization, plating, welding, hot pressing and the secondary processing such as bonding can also be carried out, being widely used in the industrial circles such as machinery, automobile, electronic apparatus, instrument, weaving and building, is the thermoplastic engineering plastic that a kind of purposes is extremely wide.
At present, the colorize method of ABS mainly contains that toner is painted, the painted and painted three kinds of methods of Masterbatch of grain are drawn in dyeing.Toner colorize method is simple, but exists and easily produce color dot, aberration is wayward, environmental pollution is larger shortcoming; It is adopt mixing facilities to carry out melt blending after being mixed with toner by ABS that dyeing draws grain painted, thus obtained painted ABS micelle, compared with painted with toner, although coloring effect increases to some extent, need, through second-heating, to improve production cost; Masterbatch is painted is by pigment through pre-treatment, and is scattered in uniformly in vector resin, substantially increases dispersiveness and the tinctorial yield of pigment, has the advantages such as simple to operate, with low cost, environmentally friendly.
Along with the raising of people's living standard, people, except being concerned about the outward appearance of product, are more and more concerned about the health of oneself and household.Various daily living article, the bacterium as the surface of refrigerator, washing machine, televisor etc. has the harm of potentiality, so be necessary to produce antibiotic plastic product, controls product surface bacterial number in certain limit.Also because product can produce a large amount of electric charge unavoidably when producing and use, a large amount of electric charges gathered hold fire hazardous, there is potential danger.Therefore how overcoming the deficiencies in the prior art, is the problem that current technical field of polymer materials needs solution badly.
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, there is provided a kind of antistatic antibiotic ABS color master batch, product of the present invention with the addition of static inhibitor and halogen-free flame retardants, makes this product have higher safety coefficient, have employed natural antibacterial agent simultaneously, make this product have antibacterial.
The technical solution used in the present invention is as follows:
A kind of antistatic antibiotic ABS color master batch, is characterized in that comprising the following raw material according to weight parts: 70 ~ 120 parts, carrier, tea tree oil 2 ~ 5 parts, mineral filler 21 ~ 60 parts, toner 30 ~ 80 parts, Zinic stearas 10 ~ 20 parts, ethoxylated alkylamine 1 ~ 8 part, 1 ~ 5 part, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, melamine phosphate 0.5 ~ 2 part;
Described carrier is the combination of one or more in acrylonitritrile-styrene resin, styrene-butadiene copolymer, polystyrene.
Further preferably mineral filler is diatomite and tourmaline powder mass ratio is the mixture of 2:1.
Further preferably described toner is one or more mixture in pigment dyestuff, mineral dye or dyestuff.
Preparation method of the present invention: above-mentioned each component is joined successively in high-speed mixer and mix 10 ~ 15min, twin screw extruder or Banbury mixer is adopted to carry out melt blending, then be uniformly dispersed on carrier by screw rod or the shearing of rotor, the mixing pigment that makes, then carry out granulation, dry obtained product of the present invention.
compared with prior art, its beneficial effect is in the present invention:(1), when the present invention is applied to ABS goods painted, there is the advantages such as colour stability is high, aberration is less; (2) with the addition of static inhibitor and halogen-free flame retardants in products material of the present invention, make this product have good antistatic property and flame retardant properties, greatly increase produce and use procedure in security; (3) with the addition of natural antibacterial disinfectant simultaneously---tea tree oil, makes this product have antibacterial, effectively can reduce the possibility of ABS product surface bacterium damage HUMAN HEALTH; (4) be employed herein tourmaline powder, make product of the present invention have negative ion-releasing function.
Specific embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
A kind of antistatic antibiotic ABS color master batch, comprises the following raw material according to weight parts: acrylonitritrile-styrene resin 70 parts, tea tree oil 2 parts, 14 parts, diatomite, tourmaline powder 7 parts, permanent violet 30 parts, Zinic stearas 10 parts, ethoxylated alkylamine 1 part, 1 part, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, melamine phosphate 0.5 part.
Embodiment 2
A kind of antistatic antibiotic ABS color master batch, comprises the following raw material according to weight parts: acrylonitritrile-styrene resin 70 parts, styrene butadiene 50 parts, tea tree oil 5 parts, 22 parts, diatomite, tourmaline powder 11 parts, titanium dioxide 80 parts, Zinic stearas 20 parts, ethoxylated alkylamine 8 parts, 5 parts, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, melamine phosphate 2 parts.
Embodiment 3
A kind of antistatic antibiotic ABS color master batch, comprises the following raw material according to weight parts: acrylonitritrile-styrene resin 40 parts, styrene-butadiene copolymer 30 parts, polystyrene 10 parts, tea tree oil 4 parts, 40 parts, diatomite, tourmaline powder 20 parts, carbon black 60 parts, Zinic stearas 15 parts, ethoxylated alkylamine 6 parts, 3 parts, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, melamine phosphate 1 part;
The embodiment of the present invention 1 ~ 3 product performance detected result is as shown in table 1.
The performance detection data of table 1 embodiment of the present invention 1 ~ 3 product
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Fire-retardant rank (thickness 0.25mm) | VTM-0 | VTM-0 | VTM-0 |
| Surface resistivity Ω/sq | 10 8 | 10 8 | 10 8 |
| Flow liner | Nothing | Nothing | Nothing |
| Aberration | ≤0.3 | ≤0.3 | ≤0.3 |
The anti-microbial property of the present embodiment 1 ~ 3 product is tested simultaneously:
Adopt conventional microbiological sterilizing power to detect, its data results is as shown in table 2.
The sterilizing power of table 2 embodiment of the present invention 1 ~ 3 product detects data
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Streptococcus aureus | 82% | 85% | 88% |
| Intestinal bacteria | 85% | 83% | 87% |
| Candida albicans | 87% | 86% | 90% |
Claims (3)
1. an antistatic antibiotic ABS color master batch, is characterized in that comprising the following raw material according to weight parts: 70 ~ 120 parts, carrier, tea tree oil 2 ~ 5 parts, mineral filler 21 ~ 60 parts, toner 30 ~ 80 parts, Zinic stearas 10 ~ 20 parts, ethoxylated alkylamine 1 ~ 8 part, 1 ~ 5 part, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, melamine phosphate 0.5 ~ 2 part; Described carrier is the combination of one or more in acrylonitritrile-styrene resin, styrene-butadiene copolymer, polystyrene.
2. antistatic antibiotic ABS color master batch according to claim 1, is characterized in that described mineral filler be diatomite and tourmaline powder mass ratio is the mixture of 2:1.
3. antistatic antibiotic ABS color master batch according to claim 1, is characterized in that described toner is one or more mixture in pigment dyestuff, mineral dye or dyestuff.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310251893.2A CN103289298B (en) | 2013-06-24 | 2013-06-24 | A kind of antistatic antibiotic ABS color master batch |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310251893.2A CN103289298B (en) | 2013-06-24 | 2013-06-24 | A kind of antistatic antibiotic ABS color master batch |
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| Publication Number | Publication Date |
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| CN103289298A CN103289298A (en) | 2013-09-11 |
| CN103289298B true CN103289298B (en) | 2015-08-19 |
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| CN201310251893.2A Expired - Fee Related CN103289298B (en) | 2013-06-24 | 2013-06-24 | A kind of antistatic antibiotic ABS color master batch |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104962030A (en) * | 2015-07-12 | 2015-10-07 | 陆思烨 | Natural antibacterial and aging-resistant ABS (acrylonitrile butadiene styrene copolymer) material and preparation method thereof |
| CN105936696A (en) * | 2016-07-19 | 2016-09-14 | 丁飞鹏 | Functional plastic master batch for tea bran making |
| CN106674869A (en) * | 2016-12-23 | 2017-05-17 | 苏州曙帆信电子科技有限公司 | Antistatic and antibacterial ABS (Acrylonitrile Butadiene Styrene) color masterbatches |
| CN107722545A (en) * | 2017-10-16 | 2018-02-23 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of high dispersive antibacterial ABS color master batch |
| CN110079182A (en) * | 2019-04-29 | 2019-08-02 | 深圳市兴盛迪新材料有限公司 | A kind of permanent anti-static exempts to spray ABS material |
| CN112831132B (en) * | 2021-01-29 | 2022-03-01 | 湖南省升阳新材料有限公司 | Flame-retardant color master batch for XPS (extruded polystyrene) foaming insulation board and preparation method thereof |
| CN113186615B (en) * | 2021-05-15 | 2023-08-29 | 浙江世纪晨星纤维科技有限公司 | Environment-friendly antibacterial nylon composite coated yarn and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102344619A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Antistatic PVC plastic floor |
| CN102558680A (en) * | 2011-12-29 | 2012-07-11 | 海尔科化工程塑料国家工程研究中心股份有限公司 | Antibacterial masterbatch |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102131527B (en) * | 2008-07-18 | 2014-11-26 | 奎克-麦德技术公司 | Polyelectrolyte complex for imparting antimicrobial properties to a substrate |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102344619A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Antistatic PVC plastic floor |
| CN102558680A (en) * | 2011-12-29 | 2012-07-11 | 海尔科化工程塑料国家工程研究中心股份有限公司 | Antibacterial masterbatch |
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