CN106751209A - A kind of weatherability polyvinyl chloride Masterbatch - Google Patents
A kind of weatherability polyvinyl chloride Masterbatch Download PDFInfo
- Publication number
- CN106751209A CN106751209A CN201611203216.3A CN201611203216A CN106751209A CN 106751209 A CN106751209 A CN 106751209A CN 201611203216 A CN201611203216 A CN 201611203216A CN 106751209 A CN106751209 A CN 106751209A
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- polyvinyl chloride
- masterbatch
- weatherability
- pvc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
The invention discloses a kind of weatherability polyvinyl chloride Masterbatch, it is made up of the raw material of following weight portion：150 165 parts of polyvinyl chloride, 8 14 parts of ethylene octene block type copolymer, 36 parts of alkyl betaine, 15 28 parts of acetoacetic acid allyl ester, 37 parts of barium titanate, 47 parts of nano magnesia, 48 parts of nano silicon, three 58 parts of (2,4 di-tert-butyl-phenyl) phosphite esters, 45 parts of triethanolamine, 26 parts of potassium peroxydisulfate.The weatherability polyvinyl chloride Masterbatch that the present invention is provided has good weatherability performance, processing cost is low, preparation process is simple, when the coloring of PVC product is applied to, with colour stability raising, the less advantage of aberration, the problems such as color is unstable, aberration is larger when existing PVC Masterbatch is coloured is overcome.
Description
Technical field
The invention belongs to technical field of polymer materials, more particularly to a kind of weatherability polyvinyl chloride Masterbatch.
Background technology
With the improvement of people's living standards, people not only pay close attention to the performance of the product used in various lives, same to time
Its is attractive in appearance for benefit pursuit, and wishes that product of its purchase has good outward appearance.Because there are plastic products raw material sources to enrich, valency
Lattice are cheap, nontoxic, be easy to processing and forming, and rigidity and toughness higher, mechanical strength are good, so being flooded with people's life now
Plastic products miscellaneous, and Masterbatch coloring is the coloring plastic method for most generally using now.Masterbatch is 20th century 60
A kind of plastics, the coloring new product of fiber of age exploitation, it is pigment super quantity to be uniformly attached in resin and is obtained
Polymer compound.With advances in technology, in plastic processes, by adding Masterbatch, so as to play beautification, dress
Adorn, be easy to recognize, improve weatherability, improve mechanical property, improve the effect such as optical property.When being coloured using Masterbatch, pigment
By pre-processing and it is dispersed in vector resin, the dispersive property and coloration efficiency of pigment is substantially increased, with operation
Simply, with low cost, environmentally safe the advantages of.
PVC （Polyvinyl chloride）, rigid PVC is one of most popular plastic material.PVC material have low flammability,
High intensity, resistance to climate variability and excellent geometrical stability.PVC has very strong supporting to oxidant, reducing agent and strong acid
Drag.But it can be corroded by dense the oxidizing acid such as concentrated sulfuric acid, concentrated nitric acid and also do not apply to contacted with aromatic hydrocarbon, chlorinated hydrocabon
Occasion.Corvic is a kind of multi-component plastics, and different additives can be added according to different purposes, therefore with
The difference of composition, its product can be presented different physical and mechanical properties, it can be made to have soft or hard if adding or being added without plasticizer
Product point.Generally speaking PVC product has that chemical-resistant stability, resistance to flame self-extinguishment, wear-resisting, noise elimination shock absorbing, intensity be higher, electric insulation
Property is the advantages of preferable, inexpensive and material source is wide, air-tightness is good.It has the disadvantage that thermal stability is poor, light, heat, the work of oxygen
With easily it is aging.
At present, the variety of raw material such as external PVC Masterbatch technical merit country higher, pigment, dispersant are complete, shape
Into seriation and specialized product structure.But domestic PVC Masterbatch product structure is single, the raw material such as pigment, dispersant
Variety matching is not complete, and there is some difference to cause color and luster, and this is totally unfavorable for the coloring of product.Coloured with Masterbatch
When, because carrier flow performance is poor, the problems such as easily there is flow liner, color and luster uneven, aberration whard to control and unitary function.Cause
How this, solve easily to be produced when PVC Masterbatch is coloured that flow liner, color and luster be uneven, aberration is larger and shock resistance is deteriorated etc. asks
Topic, is the problem that need to be urgently solved when PVC is coloured.Therefore, we set about from the formula of product, new Masterbatch is developed, there is provided
A kind of PVC Masterbatch.
The content of the invention
It is an object of the invention to provide a kind of weatherability polyvinyl chloride Masterbatch.
To achieve these goals, the invention provides a kind of weatherability polyvinyl chloride Masterbatch, by following weight portion
Raw material is obtained：Polyvinyl chloride 150-165 parts, 8-14 parts of ethylene-octene block type copolymer, alkyl betaine 3-6 parts, acetyl second
Allyl propionate 15-28 parts, barium titanate 3-7 parts, nano magnesia 4-7 parts, nano silicon 4-8 parts, three (2,4- di-t-butyls
Phenyl) phosphite ester 5-8 parts, triethanolamine 4-5 parts, potassium peroxydisulfate 2-6 parts.
It also includes nano diatomite 10-20 parts.
It also includes trifluoromethyl sulfonic acid lithium 8-10 parts.
It also includes white oil 13-16 parts.
Beneficial effect：The weatherability polyvinyl chloride Masterbatch that the present invention is provided has good weatherability performance, is processed into
This low, preparation process is simple, when the coloring of PVC product is applied to, with colour stability raising, the less advantage of aberration,
Overcome the problems such as color is unstable, aberration is larger when existing PVC Masterbatch is coloured.
Specific embodiment
Embodiment 1
A kind of weatherability polyvinyl chloride Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：Polyvinyl chloride 150
Part, 8 parts of ethylene-octene block type copolymer, 3 parts of alkyl betaine, 15 parts of acetoacetic acid allyl ester, 3 parts of barium titanate, nano oxygen
Change 4 parts of magnesium, 4 parts of nano silicon, three 5 parts of (2,4- di-tert-butyl-phenyls) phosphite esters, 4 parts of triethanolamine, potassium peroxydisulfate
2 parts.
Embodiment 2
A kind of weatherability polyvinyl chloride Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：Polyvinyl chloride 165
Part, 14 parts of ethylene-octene block type copolymer, 6 parts of alkyl betaine, 28 parts of acetoacetic acid allyl ester, barium titanate 7 part, nanometer
7 parts of magnesia, 8 parts of nano silicon, three 8 parts of (2,4- di-tert-butyl-phenyls) phosphite esters, 5 parts of triethanolamine, persulfuric acid
6 parts of potassium, 20 parts of nano diatomite.
Embodiment 3
A kind of weatherability polyvinyl chloride Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：Polyvinyl chloride 150
Part, 8 parts of ethylene-octene block type copolymer, 3 parts of alkyl betaine, 15 parts of acetoacetic acid allyl ester, 3 parts of barium titanate, nano oxygen
Change 4 parts of magnesium, 4 parts of nano silicon, three 5 parts of (2,4- di-tert-butyl-phenyls) phosphite esters, 4 parts of triethanolamine, potassium peroxydisulfate
2 parts, 10 parts of nano diatomite, 8 parts of trifluoromethyl sulfonic acid lithium.
Embodiment 4
A kind of weatherability polyvinyl chloride Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：Polyvinyl chloride 165
Part, 14 parts of ethylene-octene block type copolymer, 6 parts of alkyl betaine, 28 parts of acetoacetic acid allyl ester, barium titanate 7 part, nanometer
7 parts of magnesia, 8 parts of nano silicon, three 8 parts of (2,4- di-tert-butyl-phenyls) phosphite esters, 5 parts of triethanolamine, persulfuric acid
6 parts of potassium, 20 parts of nano diatomite, 10 parts of trifluoromethyl sulfonic acid lithium, 16 parts of white oil.
The production technology that above-described embodiment 1-4 is used is conventional production process, and its step is：First weighed respectively by said ratio
In raw material input homogenizer, stirring mixing；Then well mixed material is added in double screw extruder and melts, moulds
Change, extrude, granulate, obtain final product.
Claims (4)
1. a kind of weatherability polyvinyl chloride Masterbatch, it is characterised in that be made up of the raw material of following weight portion：Polyvinyl chloride 150-
165 parts, 8-14 parts of ethylene-octene block type copolymer, alkyl betaine 3-6 parts, acetoacetic acid allyl ester 15-28 parts, metatitanic acid
Barium 3-7 parts, nano magnesia 4-7 parts, nano silicon 4-8 parts, three phosphite ester 5-8 parts of (2,4- di-tert-butyl-phenyls),
Triethanolamine 4-5 parts, potassium peroxydisulfate 2-6 parts.
2. a kind of weatherability polyvinyl chloride Masterbatch according to claim 1, it is characterised in that：It also includes nanometer diatom
It is native 10-20 parts.
3. a kind of weatherability polyvinyl chloride Masterbatch according to claim 2, it is characterised in that：It also includes trifluoromethyl
Sulfonic Lithium 8-10 parts.
4. a kind of weatherability polyvinyl chloride Masterbatch according to claim 3, it is characterised in that：It also includes white oil 13-
16 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611203216.3A CN106751209A (en) | 2016-12-23 | 2016-12-23 | A kind of weatherability polyvinyl chloride Masterbatch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611203216.3A CN106751209A (en) | 2016-12-23 | 2016-12-23 | A kind of weatherability polyvinyl chloride Masterbatch |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106751209A true CN106751209A (en) | 2017-05-31 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611203216.3A Pending CN106751209A (en) | 2016-12-23 | 2016-12-23 | A kind of weatherability polyvinyl chloride Masterbatch |
Country Status (1)
| Country | Link |
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| CN (1) | CN106751209A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383708A (en) * | 2017-09-26 | 2017-11-24 | 马鞍山松鹤信息科技有限公司 | A kind of high molecule plastic master batch and its preparation technology |
| CN108102242A (en) * | 2017-11-27 | 2018-06-01 | 广德粤华塑业制品有限公司 | A kind of PVC environmental protection Masterbatch |
| CN108250609A (en) * | 2017-11-29 | 2018-07-06 | 广德粤华塑业制品有限公司 | A kind of environment-friendly PVC color cake |
| CN108250595A (en) * | 2017-11-28 | 2018-07-06 | 广德粤华塑业制品有限公司 | A kind of PVC environmental protection color is husky |
| CN109337246A (en) * | 2018-10-15 | 2019-02-15 | 广东江顺新材料科技股份有限公司 | A kind of the PVC profile particle and its processing technology of environmental protection high durable |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885885A (en) * | 2010-07-20 | 2010-11-17 | 广州市波斯塑胶颜料有限公司 | Color master batch for hard PVC and preparation method thereof |
| CN104356538A (en) * | 2014-10-28 | 2015-02-18 | 宁波一舟塑胶有限公司 | Flame-retardant smoke-eliminating polyvinyl chloride wire and cable material |
| CN105440479A (en) * | 2015-12-08 | 2016-03-30 | 中山市华洋塑胶颜料有限公司 | 102-C yellow weatherproof fluorescent masterbatch granules |
| CN106147082A (en) * | 2016-08-17 | 2016-11-23 | 林炳祥 | A kind of PVC color masterbatch |
-
2016
- 2016-12-23 CN CN201611203216.3A patent/CN106751209A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885885A (en) * | 2010-07-20 | 2010-11-17 | 广州市波斯塑胶颜料有限公司 | Color master batch for hard PVC and preparation method thereof |
| CN104356538A (en) * | 2014-10-28 | 2015-02-18 | 宁波一舟塑胶有限公司 | Flame-retardant smoke-eliminating polyvinyl chloride wire and cable material |
| CN105440479A (en) * | 2015-12-08 | 2016-03-30 | 中山市华洋塑胶颜料有限公司 | 102-C yellow weatherproof fluorescent masterbatch granules |
| CN106147082A (en) * | 2016-08-17 | 2016-11-23 | 林炳祥 | A kind of PVC color masterbatch |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383708A (en) * | 2017-09-26 | 2017-11-24 | 马鞍山松鹤信息科技有限公司 | A kind of high molecule plastic master batch and its preparation technology |
| CN108102242A (en) * | 2017-11-27 | 2018-06-01 | 广德粤华塑业制品有限公司 | A kind of PVC environmental protection Masterbatch |
| CN108250595A (en) * | 2017-11-28 | 2018-07-06 | 广德粤华塑业制品有限公司 | A kind of PVC environmental protection color is husky |
| CN108250609A (en) * | 2017-11-29 | 2018-07-06 | 广德粤华塑业制品有限公司 | A kind of environment-friendly PVC color cake |
| CN109337246A (en) * | 2018-10-15 | 2019-02-15 | 广东江顺新材料科技股份有限公司 | A kind of the PVC profile particle and its processing technology of environmental protection high durable |
| CN109337246B (en) * | 2018-10-15 | 2021-05-18 | 广东江顺新材料科技股份有限公司 | Environment-friendly high-weather-resistance PVC (polyvinyl chloride) profile particle and processing technology thereof |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |
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