CN106496731A - A kind of anti-static polyethylene Masterbatch - Google Patents
A kind of anti-static polyethylene Masterbatch Download PDFInfo
- Publication number
- CN106496731A CN106496731A CN201610909737.4A CN201610909737A CN106496731A CN 106496731 A CN106496731 A CN 106496731A CN 201610909737 A CN201610909737 A CN 201610909737A CN 106496731 A CN106496731 A CN 106496731A
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- parts
- masterbatch
- static polyethylene
- polyethylene masterbatch
- static
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of anti-static polyethylene Masterbatch, which is made up of the raw material of following weight portion：100 130 parts of high density polyethylene (HDPE), 18 24 parts of ethylene ethyl acrylate copolymer, 2 15 parts of calcium stearate, 15 parts of antimony dithiocarbamate, 24 parts of phthalic acid dibutyl ester, 12 18 parts of tetraethylammonium tetrafluoroborate, 15 26 parts of polybutyl methacrylate, 10 15 parts of carboxymethyl cellulose, 8 10 parts of octadecanol, 15 24 parts of white oil.The anti-static polyethylene Masterbatch that the present invention is provided has good antistatic property, processing cost is low, preparation process is simple, when the coloring of PE products is applied to, there is colour stability raising, the less advantage of aberration, overcome the problems such as color is unstable, aberration is larger when existing PE Masterbatch is coloured.
Description
Technical field
A kind of the invention belongs to technical field of polymer materials, more particularly to anti-static polyethylene Masterbatch.
Background technology
With the raising of living standards of the people, people not only pay close attention to the performance of the product used in various lives, same to time
Benefit pursues which is attractive in appearance, and wishes that its product that buys has good outward appearance.As plastic has abundant raw material source, valency
Lattice are cheap, nontoxic, be easy to processing and forming, higher rigidity and toughness, and mechanical strength is good, so being flooded with people's life now
Plastic miscellaneous, and Masterbatch coloring is the coloring plastic method for most generally adopting now.Masterbatch is 20th century 60
A kind of plastics of age exploitation, the coloring new product of fiber, it is pigment super quantity to be uniformly attached in resin and is obtained
Polymer complex.With the progress of technology, in plastic processes, by adding Masterbatch, so as to play beautification, dress
Adorn, be easy to recognize, improve weatherability, improve mechanical property, improve the effect such as optical property.When being coloured using Masterbatch, pigment
Through pretreatment and it is dispersed in vector resin, substantially increases the dispersive property and coloration efficiency of pigment, with operation
Simply, the advantages of with low cost, environmentally safe.
Polyethylene（PE）It is a kind of aggregated obtained thermoplastic resin of ethylene.Industrially, also include ethylene with a small amount of
The copolymer of alpha-olefin.Polyethylene odorless, nontoxic, feel ceraceous, with excellent resistance to low temperature（Minimum use temperature can
Reach -100 ~ -70 °C）, chemical stability is good, is resistant to the erosion of most of soda acids（Intolerant to the acid with oxidizing property）.Under room temperature
Common solvent is not dissolved in, water absorption is little.
At present, the variety of raw material such as the higher country of external PE Masterbatch technical merit, pigment, dispersant are complete, shape
Into seriation and specialized product structure.But domestic PE Masterbatch product structure is single, the former material item such as pigment, dispersant
Plant collocation complete, there is some difference to cause color and luster, and this is totally unfavorable for the coloring of product.When being coloured with Masterbatch,
As carrier flow performance is poor, the problems such as easily there is flow liner, color and luster uneven, wayward aberration and single function.Therefore,
How to solve easily to produce the problems such as flow liner, color and luster be uneven, aberration is larger and shock resistance is deteriorated when PE Masterbatch is coloured, be
The problem that PE urgently need to be solved when colouring.For this purpose, we set about from the formula of product, new Masterbatch is developed, there is provided a kind of PE
Masterbatch.
Content of the invention
It is an object of the invention to provide a kind of anti-static polyethylene Masterbatch.
To achieve these goals, the invention provides a kind of anti-static polyethylene Masterbatch, by the original of following weight portion
Material is obtained：High density polyethylene (HDPE) 100-130 parts, ethylene-ethyl acrylate copolymer 18-24 parts, calcium stearate 2-15 parts, two sulfur
For carbamic acid antimony 1-5 parts, phthalic acid dibutyl ester 2-4 parts, tetraethylammonium tetrafluoroborate 12-18 parts, polymethylacrylic acid fourth
Ester 15-26 parts, carboxymethyl cellulose 10-15 parts, octadecanol 8-10 parts, white oil 15-24 parts.
Which also includes Graphene 3-8 parts.
Which also includes tetraethyl orthosilicate 4-9 parts.
Which also includes dibasic lead phosphite 6-8 parts.
Beneficial effect：The anti-static polyethylene Masterbatch that the present invention is provided has good antistatic property, processing cost
Low, preparation process is simple, when the coloring of PE products is applied to, with colour stability raising, the less advantage of aberration, overcomes
The problems such as when existing PE Masterbatch is coloured color is unstable, aberration is larger.
Specific embodiment
Embodiment 1
A kind of anti-static polyethylene Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：High density polyethylene (HDPE)
100 parts, 18 parts of ethylene-ethyl acrylate copolymer, 2 parts of calcium stearate, 1 part of antimony dithiocarbamate, two fourth of phthalic acid
2 parts of ester, 12 parts of tetraethylammonium tetrafluoroborate, 15 parts of polybutyl methacrylate, 10 parts of carboxymethyl cellulose, 8 parts of octadecanol, white
15 parts of oil.
Embodiment 2
A kind of anti-static polyethylene Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：High density polyethylene (HDPE)
130 parts, 24 parts of ethylene-ethyl acrylate copolymer, 15 parts of calcium stearate, 5 parts of antimony dithiocarbamate, two fourth of phthalic acid
4 parts of ester, 18 parts of tetraethylammonium tetrafluoroborate, 26 parts of polybutyl methacrylate, 15 parts of carboxymethyl cellulose, 10 parts of octadecanol,
24 parts of white oil, 8 parts of Graphene.
Embodiment 3
A kind of anti-static polyethylene Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：High density polyethylene (HDPE)
100 parts, 18 parts of ethylene-ethyl acrylate copolymer, 2 parts of calcium stearate, 1 part of antimony dithiocarbamate, two fourth of phthalic acid
2 parts of ester, 12 parts of tetraethylammonium tetrafluoroborate, 15 parts of polybutyl methacrylate, 10 parts of carboxymethyl cellulose, 8 parts of octadecanol, white
15 parts of oil, 3 parts of Graphene, 4 parts of tetraethyl orthosilicate.
Embodiment 4
A kind of anti-static polyethylene Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：High density polyethylene (HDPE)
130 parts, 24 parts of ethylene-ethyl acrylate copolymer, 15 parts of calcium stearate, 5 parts of antimony dithiocarbamate, two fourth of phthalic acid
4 parts of ester, 18 parts of tetraethylammonium tetrafluoroborate, 26 parts of polybutyl methacrylate, 15 parts of carboxymethyl cellulose, 10 parts of octadecanol,
24 parts of white oil, 8 parts of Graphene, 9 parts of tetraethyl orthosilicate, 8 parts of dibasic lead phosphite.
The production technology that above-described embodiment 1-4 is used is conventional production process, and its step is：First weigh respectively by said ratio
In raw material input homogenizer, stirring mixing；Then the material of mix homogeneously is added to melting in double screw extruder, modeling
Change, extrusion, pelletize, obtain final product.
Claims (4)
1. a kind of anti-static polyethylene Masterbatch, it is characterised in that be made up of the raw material of following weight portion：High density polyethylene (HDPE)
100-130 parts, ethylene-ethyl acrylate copolymer 18-24 parts, calcium stearate 2-15 parts, antimony dithiocarbamate 1-5 parts,
Phthalic acid dibutyl ester 2-4 parts, tetraethylammonium tetrafluoroborate 12-18 parts, polybutyl methacrylate 15-26 parts, carboxymethyl are fine
Dimension element 10-15 parts, octadecanol 8-10 parts, white oil 15-24 parts.
2. a kind of anti-static polyethylene Masterbatch according to claim 1, it is characterised in that：Which also includes Graphene 3-8
Part.
3. a kind of anti-static polyethylene Masterbatch according to claim 2, it is characterised in that：Which also includes tetraethyl orthosilicate
4-9 parts.
4. a kind of anti-static polyethylene Masterbatch according to claim 3, it is characterised in that：Which also includes dibasic phosphorous
Lead plumbate 6-8 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610909737.4A CN106496731A (en) | 2016-10-19 | 2016-10-19 | A kind of anti-static polyethylene Masterbatch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610909737.4A CN106496731A (en) | 2016-10-19 | 2016-10-19 | A kind of anti-static polyethylene Masterbatch |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106496731A true CN106496731A (en) | 2017-03-15 |
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ID=58294456
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610909737.4A Pending CN106496731A (en) | 2016-10-19 | 2016-10-19 | A kind of anti-static polyethylene Masterbatch |
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| CN (1) | CN106496731A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109749206A (en) * | 2019-01-30 | 2019-05-14 | 李丽凤 | A kind of polyethylene color master batch and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103849031A (en) * | 2012-12-04 | 2014-06-11 | 青岛三利中德美水设备有限公司 | Polyethylene antistatic smooth color master batch and preparation method thereof |
-
2016
- 2016-10-19 CN CN201610909737.4A patent/CN106496731A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103849031A (en) * | 2012-12-04 | 2014-06-11 | 青岛三利中德美水设备有限公司 | Polyethylene antistatic smooth color master batch and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张丹枫编著: "《烯烃聚合》", 30 September 2014, 华东理工大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109749206A (en) * | 2019-01-30 | 2019-05-14 | 李丽凤 | A kind of polyethylene color master batch and preparation method thereof |
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Application publication date: 20170315 |
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