CN105440479A - 102-C yellow weatherproof fluorescent masterbatch granules - Google Patents
102-C yellow weatherproof fluorescent masterbatch granules Download PDFInfo
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- CN105440479A CN105440479A CN201510899924.4A CN201510899924A CN105440479A CN 105440479 A CN105440479 A CN 105440479A CN 201510899924 A CN201510899924 A CN 201510899924A CN 105440479 A CN105440479 A CN 105440479A
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Abstract
The invention provides 102-C yellow weatherproof fluorescent masterbatch granules. The 102-C yellow weatherproof fluorescent masterbatch granules are characterized by being prepared from, by mass, 30%-35% of polyvinyl chloride, 2%-5% of an antioxidant, 18%-30% of a pigment, 1%-2% of a dispersing agent and 30%-40% of auxiliaries. Nano calcium carbonate is added to be processed through mixed mixing with the polyvinyl chloride, the pigment, the antioxidant and the dispersing agent, due to the fact that the nano calcium carbonate has the very good compatibility with the polyvinyl chloride and the pigment, the reinforcing, filling and color matching effects are obvious, and the fluorescent masterbatch granules have the excellent dispersity, tensile strength, tearing strength and extensibility; in addition, the advantages of being uniform in color and luster, good in colorability and excellent in heat resistance and weather resistance are achieved.
Description
Technical field
The present invention relates to technical field of polymer materials, being specifically related to a kind of yellow weather-resistant fluorescent look female particle, particularly a kind of color is the female particle of the yellow weather-resistant fluorescent look of 102C.
Background technology
Sheet extrusion is produced and is developed rapidly in China, be mainly used in large-scale recreation ground, the slide plate in the recreation facility fields such as outdoor sliding slide, this slide plate color is general more bright-coloured beautiful, and owing to using out of doors for a long time, therefore need that there is excellent weathering resistance, therefore adopt the female particle of fluorescence color to mix colours.In existing enterprise's production process, the production technique of sheet material is expressing technique, require very high to pigment-dispersing etc., not so the phenomenon that pigment glues roller will be produced in the production process of sheet material, enterprise is caused normally to produce, particularly for the female particle of the yellow weather-resistant fluorescent look of 102C, especially true.
Summary of the invention
In order to solve the problems of the technologies described above; the invention provides the female particle of the yellow weather-resistant fluorescent look of a kind of 102C; solve down-stream enterprise and extrude in production the problem that the roller existed between the yellow sheet material of 102C and roller glues toner; ensure that the normal production of enterprise, the female particle of the yellow weather-resistant fluorescent look of 102C provided by the invention also has excellent weathering resistance simultaneously.
In order to realize technical purpose of the present invention, the present invention adopts following technical scheme.
The female particle of the yellow weather-resistant fluorescent look of a kind of 102C, is characterized in that, by mass percentage, comprise following component: the polyvinyl chloride of 30% ~ 35%, the oxidation inhibitor of 2% ~ 5%, the pigment of 18% ~ 30%, the dispersion agent of 1% ~ 2%, the subsidiary of 30% ~ 40%.
Preferably, described pigment is described pigment is by one or more mixing in your firm pigment of titanium dioxide, isoindolenone pigments, quinophthalone pigments or lithol.
Preferred, described isoindolenone pigments or the firm pigment of lithol that.
Preferably, described oxidation inhibitor is the one in pentanoic, Ursol D, 2,6 di tert butyl 4 methyl phenol.
Preferably, described dispersion agent is one or more mixtures formed with arbitrary proportion in Zinic stearas, calcium stearate, Magnesium Stearate or magnesiumcarbonate.
Preferably, described subsidiary is calcium carbonate.
Preferred, the particle diameter of described calcium carbonate is 10 ~ 100 nanometers.
Compared with prior art, the beneficial effect that the present invention has is:
The female particle of the yellow weather-resistant fluorescent look of a kind of 102C provided by the invention, by adding nano-calcium carbonate, mixing with polyvinyl chloride, pigment, oxidation inhibitor and dispersant, because nano-calcium carbonate and polyvinyl chloride, pigment have good consistency, reinforcement, filling and toning effect are obvious, make the female particle of the fluorescence color in the present invention have excellent dispersiveness, tensile strength, tear strength and extensibility, and have uniform color, tint permanence is good, the feature that thermotolerance, weathering resistance are excellent.
Embodiment
For a better understanding of the present invention, below in conjunction with specific embodiment, invention is described in detail.
Embodiment 1:
By the polyvinyl chloride of 30%, 2% pentanoic, the isoindolenone pigments of 30%, the Zinic stearas of 1% and 37% particle diameter be that the calcium carbonate of 10 ~ 100nm is put in mixer and carried out pre-mixing, then mix in high speed muller, rotating speed is 800rpm, mixing time 30min, afterwards the material mixed being placed on main frame temperature is extrude in the twin screw extruder of 85 DEG C, can obtain required Masterbatch after pelletizing, cooling, drying.
Embodiment 2:
The calcium carbonate being 10 ~ 100nm by the hybrid pigment of the polyvinyl chloride of 35%, the Ursol D of 5%, the isoindolenone pigments of 28% and quinophthalone pigments composition, the calcium stearate of 2% and the particle diameter of 30% is put in mixer and is carried out pre-mixing, then mix in high speed muller, rotating speed is 800rpm, mixing time 30min, afterwards the material mixed being placed on main frame temperature is extrude in the twin screw extruder of 85 DEG C, can obtain required Masterbatch after pelletizing, cooling, drying.
Embodiment 3:
By the polyvinyl chloride of 32%, 4% 2,6-di-tert-butyl-4-methy phenol, 22% your firm pigment, the Magnesium Stearate of 2% and particle diameter of 40% of lithol be that the calcium carbonate of 10 ~ 100nm is put in mixer and carried out pre-mixing, then mix in high speed muller, rotating speed is 800rpm, mixing time 30min, afterwards the material mixed being placed on main frame temperature is extrude in the twin screw extruder of 85 DEG C, can obtain required Masterbatch after pelletizing, cooling, drying.
Embodiment 4:
By the polyvinyl chloride of 35%, 5% 2,6-di-tert-butyl-4-methy phenol, 18% the hybrid pigment, the magnesiumcarbonate of 2% and the particle diameter of 40% that are made up of your firm pigment of titanium dioxide and lithol be that the calcium carbonate of 10 ~ 100nm is put in mixer and carried out pre-mixing, then mix in high speed muller, rotating speed is 800rpm, mixing time 30min, afterwards the material mixed being placed on main frame temperature is extrude in the twin screw extruder of 85 DEG C, can obtain required Masterbatch after pelletizing, cooling, drying.
Test the performance of the female particle of the fluorescence color obtained in embodiment 1-4 below, result is as shown in table 1.
The female particulates' properties detected result of table 1 embodiment 1-4 fluorescence color
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Shore hardness (°) | 55 | 56 | 56 | 56 |
| Tensile strength (MPa) | 2.8 | 2.7 | 2.6 | 3.0 |
| Compression deformation rate (%) | 33 | 35 | 32 | 28 |
| Rebound degree (%) | 35 | 33 | 30 | 37 |
| Color inhibition (level) | 5 | 4 | 5 | 4 |
| Shrinkage rates (%) | 1 | 0.9 | 0.93 | 1 |
| Thermotolerance (DEG C) | 130 | 125 | 125 | 128 |
| Transport property (level) | 5 | 4 | 5 | 4 |
Can obviously find out according to upper table data, the female particle of the yellow weather-resistant fluorescent look of a kind of 102C provided by the invention, there is excellent tensile strength, tear strength and extensibility, and there is uniform color, tint permanence is good, the feature that good dispersity, thermotolerance, weathering resistance are excellent, solves down-stream enterprise and extrudes in production the problem that the roller existed between the yellow sheet material of 102C and roller glues toner, ensure that the normal production of enterprise.
More than show and describe ultimate principle of the present invention, principal character and advantage.The technician of the industry should understand, and above-described embodiment does not limit the present invention in any form, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, and all drops in protection scope of the present invention.
Claims (7)
1. the female particle of the yellow weather-resistant fluorescent look of 102C, is characterized in that, by mass percentage, comprise following component: the polyvinyl chloride of 30% ~ 35%, the oxidation inhibitor of 2% ~ 5%, the pigment of 18% ~ 30%, the dispersion agent of 1% ~ 2%, the subsidiary of 30% ~ 40%.
2. the female particle of the yellow weather-resistant fluorescent look of a kind of 102C according to claim 1, is characterized in that: described pigment is by one or more in your firm pigment of titanium dioxide, isoindolenone pigments, quinophthalone pigments or lithol.
3. the female particle of the yellow weather-resistant fluorescent look of a kind of 102C according to claim 2, is characterized in that: described pigment is isoindolenone pigments or the firm pigment of lithol that.
4. the female particle of the yellow weather-resistant fluorescent look of a kind of 102C according to claim 1, is characterized in that: described oxidation inhibitor is the one in pentanoic, Ursol D, 2,6 di tert butyl 4 methyl phenol.
5. the female particle of the yellow weather-resistant fluorescent look of a kind of 102C according to claim 1, is characterized in that: described dispersion agent is one or more mixtures formed with arbitrary proportion in Zinic stearas, calcium stearate, Magnesium Stearate or magnesiumcarbonate.
6. the female particle of the yellow weather-resistant fluorescent look of a kind of 102C according to claim 1, is characterized in that: described subsidiary is calcium carbonate.
7. the female particle of the yellow weather-resistant fluorescent look of a kind of 102C according to claim 6, is characterized in that: the particle diameter of described calcium carbonate is 10 ~ 100 nanometers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510899924.4A CN105440479A (en) | 2015-12-08 | 2015-12-08 | 102-C yellow weatherproof fluorescent masterbatch granules |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510899924.4A CN105440479A (en) | 2015-12-08 | 2015-12-08 | 102-C yellow weatherproof fluorescent masterbatch granules |
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| Publication Number | Publication Date |
|---|---|
| CN105440479A true CN105440479A (en) | 2016-03-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510899924.4A Pending CN105440479A (en) | 2015-12-08 | 2015-12-08 | 102-C yellow weatherproof fluorescent masterbatch granules |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751209A (en) * | 2016-12-23 | 2017-05-31 | 苏州曙帆信电子科技有限公司 | A kind of weatherability polyvinyl chloride Masterbatch |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083832A (en) * | 1993-08-09 | 1994-03-16 | 广州羊城工程塑料有限公司 | General omnipotent heavy colour mother and production technique thereof |
| CN101885885A (en) * | 2010-07-20 | 2010-11-17 | 广州市波斯塑胶颜料有限公司 | Color master batch for hard PVC and preparation method thereof |
| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
-
2015
- 2015-12-08 CN CN201510899924.4A patent/CN105440479A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083832A (en) * | 1993-08-09 | 1994-03-16 | 广州羊城工程塑料有限公司 | General omnipotent heavy colour mother and production technique thereof |
| CN101885885A (en) * | 2010-07-20 | 2010-11-17 | 广州市波斯塑胶颜料有限公司 | Color master batch for hard PVC and preparation method thereof |
| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751209A (en) * | 2016-12-23 | 2017-05-31 | 苏州曙帆信电子科技有限公司 | A kind of weatherability polyvinyl chloride Masterbatch |
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Application publication date: 20160330 |