CN104292635A - Car bumper composite material with ultrahigh impact strength and preparation method thereof - Google Patents

Car bumper composite material with ultrahigh impact strength and preparation method thereof Download PDF

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Publication number
CN104292635A
CN104292635A CN201410521452.4A CN201410521452A CN104292635A CN 104292635 A CN104292635 A CN 104292635A CN 201410521452 A CN201410521452 A CN 201410521452A CN 104292635 A CN104292635 A CN 104292635A
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parts
district
temperature control
impact strength
matrix material
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翟红波
杨振枢
韦洪屹
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Suzhou Polymer New Materials Technology Co Ltd
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Suzhou Polymer New Materials Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10Homopolymers or copolymers of propene
    • C08J2423/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/16Ethene-propene or ethene-propene-diene copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a car bumper composite material with ultrahigh impact strength and a preparation method thereof. The car bumper composite material comprises the following components in parts by mass: 60-80 parts of polypropylene, 10-20 parts of ethylene-propylene rubber, 15-20 parts of wollastonite, 5-10 parts of glass fibers, 5-10 parts of filler, as well as 20-30 parts of carbon fibers and 3-5 parts of acrylic resin, wherein the filler is calcium carbonate or talc powder. The car bumper composite material with ultrahigh impact strength is simple in formula, and through the selection of the components and the change of content, the prepared car bumper composite material has high impact strength, so that the driving safety is enhanced.

Description

Bumper matrix material of a kind of super high impact strength and preparation method thereof
Technical field
The invention belongs to technical field of composite materials, bumper matrix material being specifically related to a kind of super high impact strength and preparation method thereof.
Background technology
Bumper be arranged on automobile foremost and rearmost end, in vehicle modeling style, play vital effect, it can examine the artistic style of disengaging car load external decoration.Good collision bumper can make user feel pleasing, obtains beautiful enjoyment.Bumper is one of important exterior trimming parts of automobile, and regardless of size, the moulding of automobile, collision bumper always stands in the breach becomes the object that in hairstylist's hand, emphasis is moulded, and handsome in appearance is bright spot and the attraction of car load.At secure context, bumper plays an important role.When automobile collides, it plays absorption energy, alleviates collision, the effect of safety precaution, is the important component part of Hyundai Motor safeguard construction, effectively can alleviate loss of life and personal injury and car breakdown degree.Meanwhile, it is again that in the application component of plastics on automobile, consumption is maximum, volume is maximum, the representational plastic items of most.
In the performance history of collision bumper, answer following several principles: 1. active safety, namely must meet using function to greatest extent, the mounting height of collision bumper should meet regulation (safe and reliable, reasonable in design); 2. passive safety, when namely colliding, collision bumper will have good energy absorption characteristics; 3. harmonious with vehicle modeling in external styling, color and texture, one integrated mass.Correctly selection material, must meet the requirement of 3 aspects: 1. good use properties; 2. excellent processing performance; 3. rational cost.At present, the material of collision bumper selects modified polypropene usually, and it should meet following essential characteristic: 1. thermotolerance 80 1 100 DEG C; 2. shock strength 30 1 80kJ/m2; 3. tensile strength 29 1 39MPa; 4. good moldability, excellent weather resistance and hard is good.
When China's automobile industry regulation speed per hour is 40 kilometers of shocks, collision bumper should be not damaged.This just requires that modified polypropylene material should have feature that is shock-resistant, good toughness.Because China's various places weather difference variation is very large, just require that automobile bumper material will have good weathering resistance.Common injection stage polypropylene simple beam impact strength is generally 2.2 ~ 2.5kJ/mz (23 DEG C).In order to improve its shock strength, normally use EPR, EPDM, sBs or other thermoplastic elastomer and polypropene blended, particularly EPDM is similar to Polypropylene structural, and consistency is better, and the amplitude that modified polypropylene shock strength improves is maximum.Beijing Chemical Research Institute EPDM and polypropylene blending modifiedly successfully develop bumper special material, when its simple beam impact strength reaches 72kJ/, other performance index all reach the level of same kind of products at abroad, and this kind of PP Pipe Compound is applied to the production of collision bumper of charade car, car Santana, favorite Song Hua River car in large quantities.The polypropylene of Jinling Petrochemical Co.'s development gets rid of the modified polypropene bumper special material of P side FE blending toughening, normal temperature Analysis of A Cantilever Beam Under notched Izod impact strength reaches 50OJ/m, through Kunshan, Danyang etc., the experiment of relevant producer injection moulding collision bumper proves, this kind of material producing process is steady, after the collision bumper demoulding, physical dimension is stablized.More domestic scientific researches and production unit have developed high workability, high impact polypropylene PP Pipe Compound, are applicable to very much producing high-grade car collision bumper, performance oneself reach the level of same kind of products at abroad.Such as, Shanghai Communications University's application dynamic vulcanization technology have developed the polypropylene type material of rubber plastic blend, Jiangsu oilfield Jiangdu engineering plastics factory application polyolefin elastomer (POE) carries out toughening modifying to polypropylene, successfully produces collision bumper alloy material.Domestic (comprise and introduce joint vehicle) all kinds of medium and high classes car, economy sedan, light card, minicar bumper special material 80% domesticize.
Summary of the invention
The object of the invention is bumper matrix material that a kind of super high impact strength will be provided and preparation method thereof, improve the impact strength of bumper, thus improve the security of driving.
To achieve these goals, the technical solution used in the present invention is:
A bumper matrix material for super high impact strength, the massfraction of component and each component is as follows: polypropylene 60 ~ 80 parts, 10 ~ 20 parts, ethylene-propylene rubber(EPR), wollastonite 15 ~ 20 parts, 5 ~ 10 parts, glass fibre, filler 5 ~ 10 parts.
Also comprise 20 ~ 30 parts, carbon fiber.
Also comprise acrylic resin 3 ~ 5 parts.
Described filler is calcium carbonate or talcum powder.
Described wollastonite is 800 orders.
The bumper matrix material of super high impact strength, the massfraction of component and each component is preferably as follows: polypropylene 65 ~ 78 parts, 12 ~ 18 parts, ethylene-propylene rubber(EPR), wollastonite 15 ~ 18 parts, 8 ~ 10 parts, glass fibre, filler 6 ~ 8 parts, acrylic resin 3 ~ 5 parts, 25 ~ 30 parts, carbon fiber.
The bumper matrix material of super high impact strength, the massfraction of component and each component is preferably as follows: polypropylene 77 parts, 15 parts, ethylene-propylene rubber(EPR), wollastonite 17 parts, 9 parts, glass fibre, filler 7 parts, 28 parts, carbon fiber, acrylic resin 4 parts.
The preparation method of the bumper matrix material of described super high impact strength, comprises the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 130 ~ 140 DEG C, two district's temperature control 145 ~ 155 DEG C, three district's temperature control 155 ~ 165 DEG C, four district's temperature control 165 ~ 175 DEG C, five district's temperature control 185 ~ 195 DEG C, six district's temperature control 185 ~ 195 DEG C, seven district's temperature control 185 ~ 195 DEG C, eight district's temperature control 185 ~ 195 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 20 ~ 40.
Beneficial effect: bumper matrix material that the invention provides a kind of super high impact strength and preparation method thereof, formula is simple, by the selection of component and the change of content, preparation-obtained bumper matrix material possesses higher impact strength, thus improves the security of driving.
Embodiment
Twin screw extruder SJSH-30 is purchased from Nanjing rubber machinery plant.
Embodiment 1:
A bumper matrix material for super high impact strength, the massfraction of component and each component is as follows: polypropylene 80 parts, 20 parts, ethylene-propylene rubber(EPR), wollastonite 20 parts, 10 parts, glass fibre, filler talcum powder 10 parts.
Preparation method, comprises the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 140 DEG C, two district's temperature control 150 DEG C, three district's temperature control 160 DEG C, four district's temperature control 170 DEG C, five district's temperature control 190 DEG C, six district's temperature control 190 DEG C, seven district's temperature control 190 DEG C, eight district's temperature control 190 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 30.
Embodiment 2:
A bumper matrix material for super high impact strength, the massfraction of component and each component is as follows: polypropylene 60 parts, 10 parts, ethylene-propylene rubber(EPR), wollastonite 15 parts, 5 parts, glass fibre, filler talcum powder 5 parts.
Preparation method, comprises the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 140 DEG C, two district's temperature control 150 DEG C, three district's temperature control 160 DEG C, four district's temperature control 170 DEG C, five district's temperature control 190 DEG C, six district's temperature control 190 DEG C, seven district's temperature control 190 DEG C, eight district's temperature control 190 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 30.
Embodiment 3:
A bumper matrix material for super high impact strength, the massfraction of component and each component is as follows: polypropylene 70 parts, 15 parts, ethylene-propylene rubber(EPR), wollastonite 18 parts, 8 parts, glass fibre, filler talcum powder 8 parts, 20 parts, carbon fiber.
Preparation method, comprises the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 140 DEG C, two district's temperature control 150 DEG C, three district's temperature control 160 DEG C, four district's temperature control 170 DEG C, five district's temperature control 190 DEG C, six district's temperature control 190 DEG C, seven district's temperature control 190 DEG C, eight district's temperature control 190 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 30.
Embodiment 4
A bumper matrix material for super high impact strength, the massfraction of component and each component is as follows: polypropylene 60 parts, 10 parts, ethylene-propylene rubber(EPR), wollastonite 15 parts, 5 parts, glass fibre, filler talcum powder 5 parts, 20 parts, carbon fiber.
Preparation method, comprises the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 140 DEG C, two district's temperature control 150 DEG C, three district's temperature control 160 DEG C, four district's temperature control 170 DEG C, five district's temperature control 190 DEG C, six district's temperature control 190 DEG C, seven district's temperature control 190 DEG C, eight district's temperature control 190 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 30.
Embodiment 5
A bumper matrix material for super high impact strength, the massfraction of component and each component is as follows: polypropylene 80 parts, 20 parts, ethylene-propylene rubber(EPR), wollastonite 20 parts, 10 parts, glass fibre, filler-calcium carbonate 10 parts, acrylic resin 5 parts, 20 parts, carbon fiber.
Preparation method, comprises the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 140 DEG C, two district's temperature control 150 DEG C, three district's temperature control 160 DEG C, four district's temperature control 170 DEG C, five district's temperature control 190 DEG C, six district's temperature control 190 DEG C, seven district's temperature control 190 DEG C, eight district's temperature control 190 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 30.
Embodiment 6
A bumper matrix material for super high impact strength, the massfraction of component and each component is as follows: polypropylene 65 parts, 12 parts, ethylene-propylene rubber(EPR), wollastonite 15 parts, 8 parts, glass fibre, filler-calcium carbonate 6 parts, acrylic resin 5 parts, 25 parts, carbon fiber.
Preparation method, comprises the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 140 DEG C, two district's temperature control 150 DEG C, three district's temperature control 160 DEG C, four district's temperature control 170 DEG C, five district's temperature control 190 DEG C, six district's temperature control 190 DEG C, seven district's temperature control 190 DEG C, eight district's temperature control 190 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 30.
Embodiment 7
A bumper matrix material for super high impact strength, the massfraction of component and each component is preferably as follows: polypropylene 77 parts, 15 parts, ethylene-propylene rubber(EPR), wollastonite 17 parts, 9 parts, glass fibre, filler-calcium carbonate 7 parts, acrylic resin 4 parts, 28 parts, carbon fiber.
Preparation method, comprises the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 140 DEG C, two district's temperature control 150 DEG C, three district's temperature control 160 DEG C, four district's temperature control 170 DEG C, five district's temperature control 190 DEG C, six district's temperature control 190 DEG C, seven district's temperature control 190 DEG C, eight district's temperature control 190 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 30.
The performance test results of the bumper matrix material of super high impact strength prepared by embodiment 1 ~ 7 is in table 1.Testing method is respectively: density GB/T 1033-1986, tensile strength GB/T 1040-1992, elongation GB/T 1040-1992, flexural strength GB/T 9341-2000, notched Izod impact strength GB/T 1843-1996, heat-drawn wire GB/T 1643-1979.
Table 1:
? Density/(g/cm3) Tensile strength/MPa Elongation/% Flexural strength/MPa Notched Izod impact strength/(J/m, 23 DEG C) Heat-drawn wire/DEG C
Embodiment 1 0.98 21.3 440 23.6 590 105
Embodiment 2 0.97 20.8 444 24.1 593 108
Embodiment 3 1.08 24.6 460 27.5 629 114
Embodiment 4 1.09 23.9 462 26.8 632 115
Embodiment 5 1.28 29.8 490 31.7 654 136
Embodiment 6 1.27 30.1 510 31.9 688 158
Embodiment 7 1.58 42.6 580 39.6 720 188
Data as can be seen from table 1, the fill a prescription property indices of bumper matrix material of the super high impact strength prepared of embodiment of the present invention 1-2 all exceedes current national standard, notched Izod impact strength is high, tensile strength and flexural strength are all higher, are a kind of bumper matrix materials of high impact; Carbon fiber is with the addition of in embodiment 3-4, the product indices obtained improves further, acrylic resin and carbon fiber is with the addition of in embodiment 5-7, the product notched Izod impact strength obtained is high, tensile strength and flexural strength significantly improve, and illustrate that acrylic resin and carbon fiber serve enhancement in formula.

Claims (8)

1. a bumper matrix material for super high impact strength, is characterized in that the massfraction of component and each component is as follows: polypropylene 60 ~ 80 parts, 10 ~ 20 parts, ethylene-propylene rubber(EPR), wollastonite 15 ~ 20 parts, 5 ~ 10 parts, glass fibre, filler 5 ~ 10 parts.
2. the bumper matrix material of super high impact strength according to claim 1, is characterized in that: also comprise 20 ~ 30 parts, carbon fiber.
3. the bumper matrix material of super high impact strength according to claim 2, is characterized in that: also comprise acrylic resin 3 ~ 5 parts.
4. the bumper matrix material of super high impact strength according to claim 1, is characterized in that: described filler is calcium carbonate or talcum powder.
5. the bumper matrix material of super high impact strength according to claim 1, is characterized in that: described wollastonite is 800 orders.
6. the bumper matrix material of super high impact strength according to claim 3, it is characterized in that: the massfraction of component and each component is as follows: polypropylene 65 ~ 78 parts, 12 ~ 18 parts, ethylene-propylene rubber(EPR), wollastonite 15 ~ 18 parts, 8 ~ 10 parts, glass fibre, filler 6 ~ 8 parts, acrylic resin 3 ~ 5 parts, 25 ~ 30 parts, carbon fiber.
7. the bumper matrix material of super high impact strength according to claim 1, it is characterized in that: the massfraction of component and each component is as follows: polypropylene 77 parts, 15 parts, ethylene-propylene rubber(EPR), wollastonite 17 parts, 9 parts, glass fibre, filler 7 parts, 28 parts, carbon fiber, acrylic resin 4 parts.
8., according to the preparation method of the bumper matrix material of super high impact strength described in any one in claim 1 ~ 7, it is characterized in that: comprise the steps:
1) polypropylene is mixed with ethylene-propylene rubber(EPR), through twin screw extruder extruding pelletization, obtain toughened master batch;
2) all the other components mixed, the toughened master batch obtained with step 1) is blended, through twin screw extruder extruding pelletization, obtains the bumper matrix material of super high impact strength; Wherein twin screw extruder each section of temperature is respectively: district's temperature control 130 ~ 140 DEG C, two district's temperature control 145 ~ 155 DEG C, three district's temperature control 155 ~ 165 DEG C, four district's temperature control 165 ~ 175 DEG C, five district's temperature control 185 ~ 195 DEG C, six district's temperature control 185 ~ 195 DEG C, seven district's temperature control 185 ~ 195 DEG C, eight district's temperature control 185 ~ 195 DEG C, head temperature 190 DEG C, rotating speed 100rpm, rate of feeding 20 ~ 40.
CN201410521452.4A 2014-09-30 2014-09-30 Car bumper composite material with ultrahigh impact strength and preparation method thereof Withdrawn CN104292635A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
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CN104877240A (en) * 2015-06-12 2015-09-02 刘洋 Polyolefin toughening agent
CN104974420A (en) * 2015-06-23 2015-10-14 苏州博利迈新材料科技有限公司 High impact resistant automobile bumper composite material and preparation method therefor
CN104987651A (en) * 2015-06-30 2015-10-21 苏州博利迈新材料科技有限公司 Method for preparing polyformaldehyde plastic particles for automobile bumpers
CN106184083A (en) * 2015-03-16 2016-12-07 现代自动车株式会社 bumper beam for vehicle
CN107522954A (en) * 2017-08-08 2017-12-29 深圳沃海森科技有限公司 Anti-aging vehicle air conditioning panel and preparation method thereof
CN107868340A (en) * 2017-12-05 2018-04-03 山东柏远复合材料科技有限公司 A kind of co-blend polypropylene is material modified
CN108892865A (en) * 2018-07-06 2018-11-27 杨敏宏 A kind of high rigidity PP composite material and preparation method thereof
CN110194879A (en) * 2019-04-30 2019-09-03 广东安恒塑业有限公司 A kind of MPP material of high intensity and preparation method thereof and cable protection pipe obtained
CN110564071A (en) * 2019-09-30 2019-12-13 安徽国风木塑科技有限公司 flame-retardant expanded polystyrene profile and preparation method thereof
CN111073146A (en) * 2019-12-26 2020-04-28 苏州润佳高分子材料有限公司 Polypropylene-ethylene propylene diene monomer modified composite material for automobile
CN112454708A (en) * 2020-10-22 2021-03-09 上海名辰模塑科技有限公司 Preparation method of automobile bumper composite material
CN113388195A (en) * 2021-05-24 2021-09-14 慈溪市龙山汽配有限公司 Automobile bumper and preparation method thereof

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Application publication date: 20150121