CN105291295A - Lamelliferous color master batch and manufacturing method thereof - Google Patents
Lamelliferous color master batch and manufacturing method thereof Download PDFInfo
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- CN105291295A CN105291295A CN201510788510.4A CN201510788510A CN105291295A CN 105291295 A CN105291295 A CN 105291295A CN 201510788510 A CN201510788510 A CN 201510788510A CN 105291295 A CN105291295 A CN 105291295A
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- laminar
- powder
- look
- coupling agent
- master batch
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- 239000004595 color masterbatch Substances 0.000 title abstract 9
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000007822 coupling agent Substances 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 10
- 238000004040 coloring Methods 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- -1 polyethylene Polymers 0.000 claims description 22
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 21
- 239000000843 powder Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 16
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000010445 mica Substances 0.000 claims description 8
- 229910052618 mica group Inorganic materials 0.000 claims description 8
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 238000005453 pelletization Methods 0.000 claims description 7
- 229910021532 Calcite Inorganic materials 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 6
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 6
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000004645 aluminates Chemical class 0.000 claims description 4
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 4
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 claims description 4
- MYONAGGJKCJOBT-UHFFFAOYSA-N benzimidazol-2-one Chemical compound C1=CC=CC2=NC(=O)N=C21 MYONAGGJKCJOBT-UHFFFAOYSA-N 0.000 claims description 4
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical group [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 claims description 4
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- 150000002910 rare earth metals Chemical class 0.000 claims description 4
- 239000011863 silicon-based powder Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- WYUHTVDGHDRPDW-UHFFFAOYSA-N 3-hydroxy-N-phenyl-4-phenyldiazenylnaphthalene-2-carboxamide Chemical compound C1(=CC=CC=C1)N=NC1=C(C(=CC2=CC=CC=C12)C(=O)NC1=CC=CC=C1)O WYUHTVDGHDRPDW-UHFFFAOYSA-N 0.000 claims description 2
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 239000012425 OXONE® Substances 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 2
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims description 2
- 239000010881 fly ash Substances 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- MPCYPRXRVWZKGF-UHFFFAOYSA-J tetrasodium 5-amino-3-[[4-[4-[(8-amino-1-hydroxy-3,6-disulfonatonaphthalen-2-yl)diazenyl]phenyl]phenyl]diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(N=NC3=CC=C(C=C3)C3=CC=C(C=C3)N=NC3=C(C=C4C=C(C=C(C4=C3O)N)S([O-])(=O)=O)S([O-])(=O)=O)=C(O)C2=C1N MPCYPRXRVWZKGF-UHFFFAOYSA-J 0.000 claims description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 2
- CZIRZNRQHFVCDZ-UHFFFAOYSA-L titan yellow Chemical compound [Na+].[Na+].C1=C(C)C(S([O-])(=O)=O)=C2SC(C3=CC=C(C=C3)/N=N/NC3=CC=C(C=C3)C3=NC4=CC=C(C(=C4S3)S([O-])(=O)=O)C)=NC2=C1 CZIRZNRQHFVCDZ-UHFFFAOYSA-L 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 abstract description 16
- 239000004033 plastic Substances 0.000 abstract description 16
- 238000001816 cooling Methods 0.000 abstract description 2
- 239000000969 carrier Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229920000426 Microplastic Polymers 0.000 description 4
- 230000004075 alteration Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005381 potential energy Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/04—Making granules by dividing preformed material in the form of plates or sheets
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to the field of plastic coloring, in particular to a lamelliferous color master batch for plastic coloring and a manufacturing method of the lamelliferous color master batch. The manufacturing method of the lamelliferous color master batch includes the steps that the lamelliferous color master batch is a cuboid or cube, the side length ranges from 1 mm to 10 mm, the width ranges from 1 mm to 10 mm, and the thickness ranges from 0.2 mm to 1.5 mm; the lamelliferous color master batch comprises components of, by weight percentage, 10%-90% of carriers, 0.01%-70% of a coloring agent, 0%-5% of a coupling agent, 0%-30% of a dispersing agent and 0%-70% of padding; and through a double-screw extruder, the components are molded into a flat material strip through a flat orifice die of an extruder head, cooling and granulating are conducted, and the lamelliferous color master batch is obtained finally. By means of the lamelliferous color master batch, the condensation of the color master batch in a plastic product is kept stable, and the stability of the color of the plastic product is guaranteed.
Description
Technical field
The present invention relates to field of plastic coloring, laminar look mother being specifically related to a kind of coloring plastic and preparation method thereof.
Background technology
The colorize method of plastics is divided into a method of taking out, toner method and Masterbatch method, and wherein Masterbatch method applicability is the strongest, and purposes is the widest.
The profile of Masterbatch common are ellipsoid and cylinder, ellipsoidally typically has a diameter from 2mm ~ 4mm, and thickness is 1mm ~ 3mm; Cylindrical length is 2mm ~ 4mm, and diameter is 1.5mm ~ 3mm.No matter be ellipsoid or cylindrical Masterbatch, its particle surface amass the surface area of volume size and plastic pellet or volume basically identical.Because Masterbatch contains the pigment of high concentration, so the proportion of Masterbatch is general all very large, 1.5g/cm can be reached
3~ 2.5g/cm
3.And the proportion of general-purpose plastics is only 0.8g/cm
3~ 1.05g/cm
3, the proportion of general engineering plastic is 1.14g/cm
3~ 1.38g/cm
3, the proportion of known Masterbatch is much larger than the proportion of plastics.Masterbatch and plastic pellet used in combination time, the Masterbatch that proportion is larger slowly sinks, and make the content of Masterbatch in plastic products that larger change occur, therefore the plastic products color produced is very unstable, and chromatic aberration is large, and percent defective is too high.This problem seriously annoyings Masterbatch practitioner for many years always, and a lot of producer does not find good solution always.
Summary of the invention
In order to solve the problem, the object of the present invention is to provide a kind of can be that the highly stable laminar look of plastic products color is female.
Two of object of the present invention there is provided the preparation method of described laminar look mother.
The present invention is achieved through the following technical solutions:
A kind of laminar look female, and the shape of laminar Masterbatch is cuboid or square, and the length of side is 1mm ~ 10mm, and wide is 1mm ~ 10mm, and thickness is 0.2mm ~ 1.5mm.Further preferably: long is 3mm ~ 6mm × 3mm ~ 6mm, and thickness is 0.5mm ~ 1mm.
Described laminar look female, comprises the following composition counted by weight percentage:
Carrier: 10% ~ 90%
Colouring agent: 0.01% ~ 70%
Coupling agent: 0 ~ 5%
Dispersant: 0 ~ 30%
Filler: 0 ~ 70%.
Preferably, described carrier is one or more the mixture in polyethylene, polypropylene, polystyrene, MPS, propylene cyanogen-BS, polyvinyl chloride, ethylene-vinyl acetate copolymer, ethylene-octene copolymer, thermoplastic polyurethane, polyamide, polybutylene terephthalate (PBT), PETG, Merlon, polymethyl methacrylate.
Preferably, described colouring agent is inorganic colourant, toner, or both mixtures.
Preferably, described inorganic colourant is one or more the mixture in titanium dioxide, carbon black, ultramarine, iron oxide, titan yellow, mica titanium perlatolic powder, copper powder, aluminium powder.
Preferably, described toner is phthalocyanine blue, phthalocyanine green, permanent yellow, forever solid orange, permanent violet, bronze red, sun-proof bright red, quinoline a word used for translation sting one or more mixture in ketone, benzimidazolone, isoindolinone, pyrrolo-pyrrole-dione, transparent red EG, fluorescein BK, transparent orange 3G, transparent blue 2B, transparent violet R.
Preferably, described coupling agent is one or more the mixture in silane coupler, aluminate coupling agent, titanate coupling agent, rare-earth coupling agent or Al-Ti-diffused steel coupling agent.
Preferably, described dispersant is one or more the mixture in stearic acid and its esters, low molecular weight polyethylene wax, low-molecular-weight polypropylene wax, low-molecular-weight ethylenic-vinyl acetate co-polymer wax, oleamide, erucyl amide, ethylene bis stearamide.
Preferably, described filler is one or more the mixture in talcum powder, calcite in powder, mica powder, silicon powder, diatomite, flyash, starch, plant fiber powder.
The preparation method of described laminar look mother, is characterized in that, take raw material by formula, first through mixed at high speed; Again with double screw extruder melting mixing, extrude, the flat aperture mold forming through cross-head is flat material strip; Cooled by tank, then use pelleter pelletizing, be aided with and regulate pelleter hauling speed to regulate the length of side and the thickness of look mother, obtained described laminar Masterbatch.Concrete technology parameter is conventional parameter, regulates a little according to materials.
The present invention is that laminar look female, and the shape of laminar Masterbatch is cuboid or square, and the length of side is 1mm ~ 10mm, and wide is 1mm ~ 10mm, and thickness is 0.2mm ~ 1.5mm.Further preferably: long is 3mm ~ 6mm × 3mm ~ 6mm, and thickness is 0.5mm ~ 1mm; Comprise the carrier counted by weight percentage: 10% ~ 90%, colouring agent 0.01% ~ 70%, coupling agent 0 ~ 5%, dispersant 0 ~ 30% and filler 0 ~ 70%.And by double screw extruder, the flat aperture mold forming through cross-head is flat material strip, last cooling and dicing obtains.
Laminar look of the present invention is female, and the particle diameter of side ratio plastic pellet is large, and the surface area of the surface area ratio plastics single particle of look female single particle is large, and the obstruction power be subject to when making it is comparatively large, thus is not easy to produce sinkage; Weight aspect, the weight of the weight ratio plastics single particle of look female single particle is little or similar, thus the potential energy that look mother is sunk weakens, above two factors, makes look female concentration in plastic products keep stable, ensure that the stability of plastic products color.
concrete embodiment
Below in conjunction with detailed description of the invention, the present invention is described in further detail, understands the present invention to help those skilled in the art.
Embodiment 1
Get polyethylene 10kg, titanium dioxide 60kg, aluminate coupling agent 1kg, low molecular weight polyethylene wax 10kg, calcite in powder 19kg; first through mixed at high speed; again with double screw extruder melting mixing, extrude; the flat aperture mold forming special through cross-head is flat material strip; cooled by tank, then use pelleter pelletizing, be aided with and regulate pelleter hauling speed to regulate the length of side and the thickness of look mother; making the length of side is 2mm × 3mm, and thickness is that the laminar look of 0.5mm is female.
Comparative example 1
Get polyethylene 10kg, titanium dioxide 60kg, aluminate coupling agent 1kg, low molecular weight polyethylene wax 10kg, calcite in powder 19kg, first through mixed at high speed, then with double screw extruder melting mixing, extrude, make cylindric Masterbatch.
Embodiment 2
Get polypropylene 90kg, phthalocyanine blue 0.5kg, titanate coupling agent 0.1kg, ethylene bis stearamide 5kg, talcum powder 4.4kg; first through mixed at high speed; again with double screw extruder melting mixing, extrude; the flat aperture mold forming special through cross-head is flat material strip; cooled by tank, then use pelleter pelletizing, be aided with and regulate pelleter hauling speed to regulate the length of side and the thickness of look mother; making the length of side is 10mm × 5mm, and thickness is that the laminar look of 1mm is female.
Comparative example 2
Get polypropylene 90kg, phthalocyanine blue 0.5kg, titanate coupling agent 0.1kg, ethylene bis stearamide 5kg, talcum powder 4.4kg, first through mixed at high speed, then with double screw extruder melting mixing, extrude, make cylindric Masterbatch.
Embodiment 3
Get polystyrene 40kg, MPS 20kg, mica titanium perlatolic powder 25kg, transparent red EG1kg, low-molecular-weight ethylenic-vinyl acetate co-polymer wax 14kg; coupling agent 0kg; filler 0kg; first through mixed at high speed; again with double screw extruder melting mixing, extrude; the flat aperture mold forming special through cross-head is flat material strip; cooled by tank; then pelleter pelletizing is used; be aided with and regulate pelleter hauling speed to regulate the length of side and the thickness of look mother; making the length of side is 8mm × 6mm, and thickness is that the laminar look of 1.5mm is female.
Comparative example 3
Get polystyrene 40kg, MPS 20kg, mica titanium perlatolic powder 25kg, transparent red EG1kg, low-molecular-weight ethylenic-vinyl acetate co-polymer wax 14kg, coupling agent 0kg, filler 0kg, first through mixed at high speed, again with double screw extruder melting mixing, extrude, make cylindric Masterbatch.
Embodiment 4
Get polyvinyl chloride 25kg, polyamide 25kg, ultramarine 1kg, permanent yellow 1kg, titanate coupling agent 0.8kg, rare-earth coupling agent 0.2kg, oleamide 2kg, erucyl amide 1kg, mica powder 20kg, silicon powder 20kg, diatomite 5kg, first through mixed at high speed, use double screw extruder melting mixing again, extrude, the flat aperture mold forming special through cross-head is flat material strip, cooled by tank, then pelleter pelletizing is used, be aided with and regulate pelleter hauling speed to regulate the length of side and the thickness of look mother, making the length of side is 2mm × 3mm, thickness is that the laminar look of 0.5mm is female.
Comparative example 4
Get polyvinyl chloride 25kg, polyamide 25kg, ultramarine 1kg, permanent yellow 1kg, titanate coupling agent 0.8kg, rare-earth coupling agent 0.2kg, oleamide 2kg, erucyl amide 1kg, mica powder 20kg, silicon powder 20kg, diatomite 5kg, first through mixed at high speed, again with double screw extruder melting mixing, extrude, make cylindric Masterbatch.
Embodiment 5
Get polybutylene terephthalate (PBT) 10kg, PETG 10kg, Merlon 10kg, polymethyl methacrylate 10kg, benzimidazolone 3k, isoindolinone 5k, pyrrolo-pyrrole-dione 2kg, low-molecular-weight ethylenic-vinyl acetate co-polymer wax 10kg, oleamide 5kg, erucyl amide 5kg, calcite in powder 30kg, plant fiber powder 10, first through mixed at high speed, use double screw extruder melting mixing again, extrude, the flat aperture mold forming special through cross-head is flat material strip, cooled by tank, then pelleter pelletizing is used, be aided with and regulate pelleter hauling speed to regulate the length of side and the thickness of look mother, making the length of side is 2mm × 3mm, thickness is that the laminar look of 0.5mm is female.
Comparative example 5
Get polybutylene terephthalate (PBT) 10kg, PETG 10kg, Merlon 10kg, polymethyl methacrylate 10kg, benzimidazolone 3k, isoindolinone 5k, pyrrolo-pyrrole-dione 2kg, low-molecular-weight ethylenic-vinyl acetate co-polymer wax 10kg, oleamide 5kg, erucyl amide 5kg, calcite in powder 30kg, plant fiber powder 10, first through mixed at high speed, again with double screw extruder melting mixing, extrude, make cylindric Masterbatch.
Above-described embodiment, just preferred embodiment of the present invention, is not used for limiting the scope of the present invention, therefore all equivalences done with the feature described in the claims in the present invention and principle change or modify, and all should be included within the claims in the present invention scope.
The look of above embodiment and comparative example is female, add in corresponding plastic pellet by same ratio respectively, make 10 pieces of look boards respectively with injection machine, namely every money look mother makes 10 pieces of look boards, measure the value of chromatism of each look female 10 pieces of look boards again with spectrophotometric color measurement instrument, then calculate corresponding average color difference values.Average color difference sees the following form.
Note: value of chromatism is larger, represents that aberration is larger.
Claims (10)
1. a laminar look female, and it is characterized in that, the shape of laminar Masterbatch is cuboid or square, and the length of side is 1mm ~ 10mm, and wide is 1mm ~ 10mm, and thickness is 0.2mm ~ 1.5mm.
2. laminar look female as described in the appended claim 1, it is characterized in that, comprise the following composition counted by weight percentage:
Carrier: 10% ~ 90%
Colouring agent: 0.01% ~ 70%
Coupling agent: 0 ~ 5%
Dispersant: 0 ~ 30%
Filler: 0 ~ 70%.
3. laminar look female as stated in claim 2, it is characterized in that, described carrier is one or more the mixture in polyethylene, polypropylene, polystyrene, MPS, propylene cyanogen-BS, polyvinyl chloride, ethylene-vinyl acetate copolymer, ethylene-octene copolymer, thermoplastic polyurethane, polyamide, polybutylene terephthalate (PBT), PETG, Merlon, polymethyl methacrylate.
4. laminar look female as stated in claim 2, and it is characterized in that, described colouring agent is inorganic colourant, toner, or both mixtures.
5. laminar look female as claimed in claim 4, and it is characterized in that, described inorganic colourant is one or more the mixture in titanium dioxide, carbon black, ultramarine, iron oxide, titan yellow, mica titanium perlatolic powder, copper powder, aluminium powder.
6. laminar look female as claimed in claim 4, it is characterized in that, described toner is phthalocyanine blue, phthalocyanine green, permanent yellow, forever solid orange, permanent violet, bronze red, sun-proof bright red, quinoline a word used for translation sting one or more mixture in ketone, benzimidazolone, isoindolinone, pyrrolo-pyrrole-dione, transparent red EG, fluorescein BK, transparent orange 3G, transparent blue 2B, transparent violet R.
7. laminar look female as stated in claim 2, and it is characterized in that, described coupling agent is one or more the mixture in silane coupler, aluminate coupling agent, titanate coupling agent, rare-earth coupling agent or Al-Ti-diffused steel coupling agent.
8. laminar look female as stated in claim 2, it is characterized in that, described dispersant is one or more the mixture in stearic acid and its esters, low molecular weight polyethylene wax, low-molecular-weight polypropylene wax, low-molecular-weight ethylenic-vinyl acetate co-polymer wax, oleamide, erucyl amide, ethylene bis stearamide.
9. laminar look female as stated in claim 2, and it is characterized in that, described filler is one or more the mixture in talcum powder, calcite in powder, mica powder, silicon powder, diatomite, flyash, starch, plant fiber powder.
10. as the preparation method of laminar look mother as described in any one in claim 1-9, it is characterized in that, take raw material by formula, first through mixed at high speed; Again with double screw extruder melting mixing, extrude, the flat aperture mold forming through cross-head is flat material strip; Cooled by tank, then use pelleter pelletizing, be aided with and regulate pelleter hauling speed to regulate the length of side and the thickness of look mother, obtained described laminar Masterbatch.
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