CN106758388A - 一种数码印花面料阻燃抗菌涂料 - Google Patents

一种数码印花面料阻燃抗菌涂料 Download PDF

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CN106758388A
CN106758388A CN201611105487.5A CN201611105487A CN106758388A CN 106758388 A CN106758388 A CN 106758388A CN 201611105487 A CN201611105487 A CN 201611105487A CN 106758388 A CN106758388 A CN 106758388A
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parts
powder
diethylene glycol
digit printing
printing fabric
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李霞
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Foshan City Tianshun Technology Co Ltd
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Abstract

本发明涉及一种数码印花面料阻燃抗菌涂料，由以下组分组成：溴化丁基橡胶、氟醚橡胶、苯乙烯‑马来酸酐共聚物、丙酸戊酯、二乙二醇乙醚、二甘醇丁醚、甲基苯胺、二异丁基甲酮、二苯并呋喃、十六烷基溴、咪唑啉、2‑巯基苯并噻唑、轻质碳酸钙粉、氢氧化铝粉末、三氧化二铝粉末、三氧化二锑粉末、石膏粉、石棉纤维、四氧化三铅粉末、炭黑、六氢化邻苯二甲酸酐、锑酸钠粉末、聚丙烯腈纤维、纳米氧化锌、二乙二醇、石油醚、羊毛脂、山梨醇酐单油酸酯、硬脂酸季戊四醇酯、三盐基硫酸铅。本发明产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能，改善了产品性能。

Description

一种数码印花面料阻燃抗菌涂料
技术领域
本发明涉及一种数码印花面料阻燃抗菌涂料，属于数码印花技术领域。
背景技术
数码印花，是用数码技术进行的印花。数码印花技术是随着计算机技术不断发展而逐渐形成的一种集机械、计算机机电子信息技术为一体的高新技术产品。这项技术的出现与不断完善，给纺织印染行业带来了一个全新的概念，其先进的生产原理及手段，给纺织印染带来了一个前所未有的发展机遇。数码印花面料有必要采用合适的方式予以处理，以便获得性能较好的功能，其中采用合适的涂料就是重要的方式之一。
发明内容
本发明的目的在于提供一种数码印花面料阻燃抗菌涂料，以便更好地实现数码印花面料阻燃抗菌涂料的使用功能，使产品具有阻燃、耐酸碱、防霉变抗菌性能，改善产品使用性能。
为了实现上述目的，本发明的技术方案如下。
一种数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：溴化丁基橡胶24～28份、氟醚橡胶22～26份、苯乙烯-马来酸酐共聚物22～26份、丙酸戊酯20～24份、二乙二醇乙醚22～26份、二甘醇丁醚22～26份、甲基苯胺20～24份、二异丁基甲酮22～26份、二苯并呋喃22～26份、十六烷基溴20～24份、咪唑啉20～24份、2-巯基苯并噻唑20～24份、轻质碳酸钙粉22～26份、氢氧化铝粉末20～24份、三氧化二铝粉末18～22份、三氧化二锑粉末22～26份、石膏粉20～24份、石棉纤维18～22份、四氧化三铅粉末20～24份、炭黑18～22份、六氢化邻苯二甲酸酐18～22份、锑酸钠粉末18～22份、聚丙烯腈纤维16～20份、纳米氧化锌12～16份、二乙二醇10～14份、石油醚10～14份、羊毛脂10～14份、山梨醇酐单油酸酯10～14份、硬脂酸季戊四醇酯10～14份、三盐基硫酸铅10～14份。
进一步地，上述数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：溴化丁基橡胶24份、氟醚橡胶22份、苯乙烯-马来酸酐共聚物22份、丙酸戊酯20份、二乙二醇乙醚22份、二甘醇丁醚22份、甲基苯胺20份、二异丁基甲酮22份、二苯并呋喃22份、十六烷基溴20份、咪唑啉20份、2-巯基苯并噻唑20份、轻质碳酸钙粉22份、氢氧化铝粉末20份、三氧化二铝粉末18份、三氧化二锑粉末22份、石膏粉20份、石棉纤维18份、四氧化三铅粉末20份、炭黑18份、六氢化邻苯二甲酸酐18份、锑酸钠粉末18份、聚丙烯腈纤维16份、纳米氧化锌12份、二乙二醇10份、石油醚10份、羊毛脂10份、山梨醇酐单油酸酯10份、硬脂酸季戊四醇酯10份、三盐基硫酸铅10份。
进一步地，上述数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：溴化丁基橡胶26份、氟醚橡胶24份、苯乙烯-马来酸酐共聚物24份、丙酸戊酯22份、二乙二醇乙醚24份、二甘醇丁醚24份、甲基苯胺22份、二异丁基甲酮24份、二苯并呋喃24份、十六烷基溴22份、咪唑啉22份、2-巯基苯并噻唑22份、轻质碳酸钙粉24份、氢氧化铝粉末22份、三氧化二铝粉末20份、三氧化二锑粉末24份、石膏粉22份、石棉纤维20份、四氧化三铅粉末22份、炭黑20份、六氢化邻苯二甲酸酐20份、锑酸钠粉末20份、聚丙烯腈纤维18份、纳米氧化锌14份、二乙二醇12份、石油醚12份、羊毛脂12份、山梨醇酐单油酸酯12份、硬脂酸季戊四醇酯12份、三盐基硫酸铅12份。
进一步地，上述数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：溴化丁基橡胶28份、氟醚橡胶26份、苯乙烯-马来酸酐共聚物26份、丙酸戊酯24份、二乙二醇乙醚26份、二甘醇丁醚26份、甲基苯胺24份、二异丁基甲酮26份、二苯并呋喃26份、十六烷基溴24份、咪唑啉24份、2-巯基苯并噻唑24份、轻质碳酸钙粉26份、氢氧化铝粉末24份、三氧化二铝粉末22份、三氧化二锑粉末26份、石膏粉24份、石棉纤维22份、四氧化三铅粉末24份、炭黑22份、六氢化邻苯二甲酸酐22份、锑酸钠粉末22份、聚丙烯腈纤维20份、纳米氧化锌16份、二乙二醇14份、石油醚14份、羊毛脂14份、山梨醇酐单油酸酯14份、硬脂酸季戊四醇酯14份、三盐基硫酸铅14份。
进一步地，上述数码印花面料阻燃抗菌涂料制备方法步骤如下：
（1）将所述质量份数的溴化丁基橡胶、氟醚橡胶、苯乙烯-马来酸酐共聚物、丙酸戊酯、二乙二醇乙醚、二甘醇丁醚、甲基苯胺、二异丁基甲酮、二苯并呋喃、十六烷基溴、咪唑啉、2-巯基苯并噻唑、轻质碳酸钙粉、氢氧化铝粉末、三氧化二铝粉末、三氧化二锑粉末、石膏粉、石棉纤维、四氧化三铅粉末、炭黑予以混合，超声高速分散，超声波频率为20～40KHz，分散速度5000～5400r/min左右，分散时间为30～60min；
（2）加入所述质量份数的六氢化邻苯二甲酸酐、锑酸钠粉末、聚丙烯腈纤维、纳米氧化锌、二乙二醇，超声高速分散，超声波频率为20～35KHz，分散速度4800～5200r/min左右，分散时间为30～50min；
（3）加入所述质量份数的石油醚、羊毛脂、山梨醇酐单油酸酯、硬脂酸季戊四醇酯、三盐基硫酸铅，超声高速分散，超声波频率为20～30KHz，分散速度4600～4800r/min左右，分散时间为20～40min；混合均匀后制得本品。
该发明的有益效果在于：本发明中的数码印花面料阻燃抗菌涂料，由以下组分组成：溴化丁基橡胶、氟醚橡胶、苯乙烯-马来酸酐共聚物、丙酸戊酯、二乙二醇乙醚、二甘醇丁醚、甲基苯胺、二异丁基甲酮、二苯并呋喃、十六烷基溴、咪唑啉、2-巯基苯并噻唑、轻质碳酸钙粉、氢氧化铝粉末、三氧化二铝粉末、三氧化二锑粉末、石膏粉、石棉纤维、四氧化三铅粉末、炭黑、六氢化邻苯二甲酸酐、锑酸钠粉末、聚丙烯腈纤维、纳米氧化锌、二乙二醇、石油醚、羊毛脂、山梨醇酐单油酸酯、硬脂酸季戊四醇酯、三盐基硫酸铅。本发明产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能，改善了产品性能。
具体实施方式
下面结合实施例对本发明的具体实施方式进行描述，以便更好的理解本发明。
实施例1
本实施例中的数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：溴化丁基橡胶24份、氟醚橡胶22份、苯乙烯-马来酸酐共聚物22份、丙酸戊酯20份、二乙二醇乙醚22份、二甘醇丁醚22份、甲基苯胺20份、二异丁基甲酮22份、二苯并呋喃22份、十六烷基溴20份、咪唑啉20份、2-巯基苯并噻唑20份、轻质碳酸钙粉22份、氢氧化铝粉末20份、三氧化二铝粉末18份、三氧化二锑粉末22份、石膏粉20份、石棉纤维18份、四氧化三铅粉末20份、炭黑18份、六氢化邻苯二甲酸酐18份、锑酸钠粉末18份、聚丙烯腈纤维16份、纳米氧化锌12份、二乙二醇10份、石油醚10份、羊毛脂10份、山梨醇酐单油酸酯10份、硬脂酸季戊四醇酯10份、三盐基硫酸铅10份。
上述数码印花面料阻燃抗菌涂料制备方法步骤如下：
（1）将所述质量份数的溴化丁基橡胶、氟醚橡胶、苯乙烯-马来酸酐共聚物、丙酸戊酯、二乙二醇乙醚、二甘醇丁醚、甲基苯胺、二异丁基甲酮、二苯并呋喃、十六烷基溴、咪唑啉、2-巯基苯并噻唑、轻质碳酸钙粉、氢氧化铝粉末、三氧化二铝粉末、三氧化二锑粉末、石膏粉、石棉纤维、四氧化三铅粉末、炭黑予以混合，超声高速分散，超声波频率为20kHz，分散速度5400r/min左右，分散时间为60min；
（2）加入所述质量份数的六氢化邻苯二甲酸酐、锑酸钠粉末、聚丙烯腈纤维、纳米氧化锌、二乙二醇，超声高速分散，超声波频率为20kHz，分散速度5200r/min左右，分散时间为50min；
（3）加入所述质量份数的石油醚、羊毛脂、山梨醇酐单油酸酯、硬脂酸季戊四醇酯、三盐基硫酸铅，超声高速分散，超声波频率为20kHz，分散速度4800r/min左右，分散时间为40min；混合均匀后制得本品。
实施例2
本实施例中的数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：溴化丁基橡胶26份、氟醚橡胶24份、苯乙烯-马来酸酐共聚物24份、丙酸戊酯22份、二乙二醇乙醚24份、二甘醇丁醚24份、甲基苯胺22份、二异丁基甲酮24份、二苯并呋喃24份、十六烷基溴22份、咪唑啉22份、2-巯基苯并噻唑22份、轻质碳酸钙粉24份、氢氧化铝粉末22份、三氧化二铝粉末20份、三氧化二锑粉末24份、石膏粉22份、石棉纤维20份、四氧化三铅粉末22份、炭黑20份、六氢化邻苯二甲酸酐20份、锑酸钠粉末20份、聚丙烯腈纤维18份、纳米氧化锌14份、二乙二醇12份、石油醚12份、羊毛脂12份、山梨醇酐单油酸酯12份、硬脂酸季戊四醇酯12份、三盐基硫酸铅12份。
上述数码印花面料阻燃抗菌涂料制备方法步骤如下：
（1）将所述质量份数的溴化丁基橡胶、氟醚橡胶、苯乙烯-马来酸酐共聚物、丙酸戊酯、二乙二醇乙醚、二甘醇丁醚、甲基苯胺、二异丁基甲酮、二苯并呋喃、十六烷基溴、咪唑啉、2-巯基苯并噻唑、轻质碳酸钙粉、氢氧化铝粉末、三氧化二铝粉末、三氧化二锑粉末、石膏粉、石棉纤维、四氧化三铅粉末、炭黑予以混合，超声高速分散，超声波频率为30kHz，分散速度5200r/min左右，分散时间为45min；
（2）加入所述质量份数的六氢化邻苯二甲酸酐、锑酸钠粉末、聚丙烯腈纤维、纳米氧化锌、二乙二醇，超声高速分散，超声波频率为27kHz，分散速度5000r/min左右，分散时间为40min；
（3）加入所述质量份数的石油醚、羊毛脂、山梨醇酐单油酸酯、硬脂酸季戊四醇酯、三盐基硫酸铅，超声高速分散，超声波频率为25kHz，分散速度4700r/min左右，分散时间为30min；混合均匀后制得本品。
实施例3
本实施例中的数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：溴化丁基橡胶28份、氟醚橡胶26份、苯乙烯-马来酸酐共聚物26份、丙酸戊酯24份、二乙二醇乙醚26份、二甘醇丁醚26份、甲基苯胺24份、二异丁基甲酮26份、二苯并呋喃26份、十六烷基溴24份、咪唑啉24份、2-巯基苯并噻唑24份、轻质碳酸钙粉26份、氢氧化铝粉末24份、三氧化二铝粉末22份、三氧化二锑粉末26份、石膏粉24份、石棉纤维22份、四氧化三铅粉末24份、炭黑22份、六氢化邻苯二甲酸酐22份、锑酸钠粉末22份、聚丙烯腈纤维20份、纳米氧化锌16份、二乙二醇14份、石油醚14份、羊毛脂14份、山梨醇酐单油酸酯14份、硬脂酸季戊四醇酯14份、三盐基硫酸铅14份。
上述数码印花面料阻燃抗菌涂料制备方法步骤如下：
（1）将所述质量份数的溴化丁基橡胶、氟醚橡胶、苯乙烯-马来酸酐共聚物、丙酸戊酯、二乙二醇乙醚、二甘醇丁醚、甲基苯胺、二异丁基甲酮、二苯并呋喃、十六烷基溴、咪唑啉、2-巯基苯并噻唑、轻质碳酸钙粉、氢氧化铝粉末、三氧化二铝粉末、三氧化二锑粉末、石膏粉、石棉纤维、四氧化三铅粉末、炭黑予以混合，超声高速分散，超声波频率为40kHz，分散速度5000r/min，分散时间为30min；
（2）加入所述质量份数的六氢化邻苯二甲酸酐、锑酸钠粉末、聚丙烯腈纤维、纳米氧化锌、二乙二醇，超声高速分散，超声波频率为35kHz，分散速度4800r/min，分散时间为30min；
（3）加入所述质量份数的石油醚、羊毛脂、山梨醇酐单油酸酯、硬脂酸季戊四醇酯、三盐基硫酸铅，超声高速分散，超声波频率为30kHz，分散速度4600r/min左右，分散时间为20min；混合均匀后制得本品。
针对实施例1、实施例2和实施例3中的产品和某市售产品进行性能测量，所测得的数据如表1所示。防火阻燃等级测试采用UL94标准。
表1性能测试结果
可见，本发明产品具有较好的耐腐蚀、防火阻燃、防霉变、抗菌性能。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (5)

1.一种数码印花面料阻燃抗菌涂料，其特征在于：由以下质量份数的组分组成：溴化丁基橡胶24～28份、氟醚橡胶22～26份、苯乙烯-马来酸酐共聚物22～26份、丙酸戊酯20～24份、二乙二醇乙醚22～26份、二甘醇丁醚22～26份、甲基苯胺20～24份、二异丁基甲酮22～26份、二苯并呋喃22～26份、十六烷基溴20～24份、咪唑啉20～24份、2-巯基苯并噻唑20～24份、轻质碳酸钙粉22～26份、氢氧化铝粉末20～24份、三氧化二铝粉末18～22份、三氧化二锑粉末22～26份、石膏粉20～24份、石棉纤维18～22份、四氧化三铅粉末20～24份、炭黑18～22份、六氢化邻苯二甲酸酐18～22份、锑酸钠粉末18～22份、聚丙烯腈纤维16～20份、纳米氧化锌12～16份、二乙二醇10～14份、石油醚10～14份、羊毛脂10～14份、山梨醇酐单油酸酯10～14份、硬脂酸季戊四醇酯10～14份、三盐基硫酸铅10～14份。
2.根据权利要求1所述的数码印花面料阻燃抗菌涂料，其特征在于：所述数码印花面料阻燃抗菌涂料由以下质量份数的组分组成：溴化丁基橡胶24份、氟醚橡胶22份、苯乙烯-马来酸酐共聚物22份、丙酸戊酯20份、二乙二醇乙醚22份、二甘醇丁醚22份、甲基苯胺20份、二异丁基甲酮22份、二苯并呋喃22份、十六烷基溴20份、咪唑啉20份、2-巯基苯并噻唑20份、轻质碳酸钙粉22份、氢氧化铝粉末20份、三氧化二铝粉末18份、三氧化二锑粉末22份、石膏粉20份、石棉纤维18份、四氧化三铅粉末20份、炭黑18份、六氢化邻苯二甲酸酐18份、锑酸钠粉末18份、聚丙烯腈纤维16份、纳米氧化锌12份、二乙二醇10份、石油醚10份、羊毛脂10份、山梨醇酐单油酸酯10份、硬脂酸季戊四醇酯10份、三盐基硫酸铅10份。
3.根据权利要求1至2所述的数码印花面料阻燃抗菌涂料，其特征在于：所述数码印花面料阻燃抗菌涂料由以下质量份数的组分组成：溴化丁基橡胶26份、氟醚橡胶24份、苯乙烯-马来酸酐共聚物24份、丙酸戊酯22份、二乙二醇乙醚24份、二甘醇丁醚24份、甲基苯胺22份、二异丁基甲酮24份、二苯并呋喃24份、十六烷基溴22份、咪唑啉22份、2-巯基苯并噻唑22份、轻质碳酸钙粉24份、氢氧化铝粉末22份、三氧化二铝粉末20份、三氧化二锑粉末24份、石膏粉22份、石棉纤维20份、四氧化三铅粉末22份、炭黑20份、六氢化邻苯二甲酸酐20份、锑酸钠粉末20份、聚丙烯腈纤维18份、纳米氧化锌14份、二乙二醇12份、石油醚12份、羊毛脂12份、山梨醇酐单油酸酯12份、硬脂酸季戊四醇酯12份、三盐基硫酸铅12份。
4.根据权利要求1至3所述的数码印花面料阻燃抗菌涂料，其特征在于：所述数码印花面料阻燃抗菌涂料由以下质量份数的组分组成：溴化丁基橡胶28份、氟醚橡胶26份、苯乙烯-马来酸酐共聚物26份、丙酸戊酯24份、二乙二醇乙醚26份、二甘醇丁醚26份、甲基苯胺24份、二异丁基甲酮26份、二苯并呋喃26份、十六烷基溴24份、咪唑啉24份、2-巯基苯并噻唑24份、轻质碳酸钙粉26份、氢氧化铝粉末24份、三氧化二铝粉末22份、三氧化二锑粉末26份、石膏粉24份、石棉纤维22份、四氧化三铅粉末24份、炭黑22份、六氢化邻苯二甲酸酐22份、锑酸钠粉末22份、聚丙烯腈纤维20份、纳米氧化锌16份、二乙二醇14份、石油醚14份、羊毛脂14份、山梨醇酐单油酸酯14份、硬脂酸季戊四醇酯14份、三盐基硫酸铅14份。
5.根据权利要求1所述的数码印花面料阻燃抗菌涂料，其特征在于：所述数码印花面料阻燃抗菌涂料制备方法步骤如下：
（1）将所述质量份数的溴化丁基橡胶、氟醚橡胶、苯乙烯-马来酸酐共聚物、丙酸戊酯、二乙二醇乙醚、二甘醇丁醚、甲基苯胺、二异丁基甲酮、二苯并呋喃、十六烷基溴、咪唑啉、2-巯基苯并噻唑、轻质碳酸钙粉、氢氧化铝粉末、三氧化二铝粉末、三氧化二锑粉末、石膏粉、石棉纤维、四氧化三铅粉末、炭黑予以混合，超声高速分散，超声波频率为20～40KHz，分散速度约5000～5400r/min，分散时间为30～60min左右；
（2）加入所述质量份数的六氢化邻苯二甲酸酐、锑酸钠粉末、聚丙烯腈纤维、纳米氧化锌、二乙二醇，超声高速分散，超声波频率为20～35KHz，分散速度为约4800～5200r/min，分散时间为30～50min左右；
（3）加入所述质量份数的石油醚、羊毛脂、山梨醇酐单油酸酯、硬脂酸季戊四醇酯、三盐基硫酸铅，超声高速分散，超声波频率为20～30KHz，分散速度为约4600～4800r/min，分散时间为20～40min左右；混合均匀后制得本品。
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