CN106049103A - 一种数码印花面料阻燃抗菌涂料 - Google Patents

一种数码印花面料阻燃抗菌涂料 Download PDF

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CN106049103A
CN106049103A CN201610523875.9A CN201610523875A CN106049103A CN 106049103 A CN106049103 A CN 106049103A CN 201610523875 A CN201610523875 A CN 201610523875A CN 106049103 A CN106049103 A CN 106049103A
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ethylenedioxybis
ethanol
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王苏芳
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ZHEJIANG YI MENGYUAN TECHNOLOGY Co Ltd
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Abstract

本发明涉及一种数码印花面料阻燃抗菌涂料，由以下组分组成：三甘醇二异辛酸酯、酚醛环氧树脂、石墨粉、磷酸三辛酯、硬脂酸酯、氧化锆粉末、三盐基硫酸铅、三聚氰胺氰尿酸盐、偏苯三酸三辛酯、甲基乙烯基硅橡胶、三甘醇二异辛酸酯、邻苯二甲酸二辛酯、硬脂酸甘油酯、八甲基环四硅氧烷、异佛尔酮、聚乙烯醇缩丁醛、高氯酸铵、对羟基苯甲酸乙酯、杀毒矾、聚磷酸铵、辛酸甘油酯、苯乙烯化苯酚、尼泊金丙酯、香兰素。本发明产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能，改善了产品性能。

Description

一种数码印花面料阻燃抗菌涂料
技术领域
本发明涉及一种数码印花面料阻燃抗菌涂料，属于数码印花技术领域。
背景技术
数码印花，是用数码技术进行的印花。数码印花技术是随着计算机技术不断发展而逐渐形成的一种集机械、计算机机电子信息技术为一体的高新技术产品。这项技术的出现与不断完善，给纺织印染行业带来了一个全新的概念，其先进的生产原理及手段，给纺织印染带来了一个前所未有的发展机遇。数码印花面料有必要采用合适的方式予以处理，以便获得性能较好的功能，其中采用合适的涂料就是重要的方式之一。
发明内容
本发明的目的在于提供一种数码印花面料阻燃抗菌涂料，以便更好地实现数码印花面料阻燃抗菌涂料的使用功能。
为了实现上述目的，本发明的技术方案如下。
一种数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：三甘醇二异辛酸酯18～22份、酚醛环氧树脂20～24份、石墨粉16～20份、磷酸三辛酯14～18份、硬脂酸酯20～24份、氧化锆粉末16～20份、三盐基硫酸铅14～18份、三聚氰胺氰尿酸盐20～24份、偏苯三酸三辛酯16～20份、甲基乙烯基硅橡胶14～18份、三甘醇二异辛酸酯20～24份、邻苯二甲酸二辛酯16～20份、硬脂酸甘油酯16～20份、八甲基环四硅氧烷14～18份、异佛尔酮20～24份、聚乙烯醇缩丁醛16～20份、高氯酸铵14～18份、对羟基苯甲酸乙酯20～24份、杀毒矾16～20份、聚磷酸铵14～18份、辛酸甘油酯20～24份、苯乙烯化苯酚16～20份、尼泊金丙酯14～18份、香兰素20～24份。
进一步地，上述数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：三甘醇二异辛酸酯18份、酚醛环氧树脂20份、石墨粉16份、磷酸三辛酯14份、硬脂酸酯20份、氧化锆粉末16份、三盐基硫酸铅14份、三聚氰胺氰尿酸盐20份、偏苯三酸三辛酯16份、甲基乙烯基硅橡胶14份、三甘醇二异辛酸酯20份、邻苯二甲酸二辛酯16份、硬脂酸甘油酯16份、八甲基环四硅氧烷14份、异佛尔酮20份、聚乙烯醇缩丁醛16份、高氯酸铵14份、对羟基苯甲酸乙酯20份、杀毒矾16份、聚磷酸铵14份、辛酸甘油酯20份、苯乙烯化苯酚16份、尼泊金丙酯14份、香兰素20份。
进一步地，上述数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：三甘醇二异辛酸酯20份、酚醛环氧树脂22份、石墨粉18份、磷酸三辛酯16份、硬脂酸酯22份、氧化锆粉末18份、三盐基硫酸铅16份、三聚氰胺氰尿酸盐22份、偏苯三酸三辛酯18份、甲基乙烯基硅橡胶16份、三甘醇二异辛酸酯22份、邻苯二甲酸二辛酯18份、硬脂酸甘油酯18份、八甲基环四硅氧烷16份、异佛尔酮22份、聚乙烯醇缩丁醛18份、高氯酸铵16份、对羟基苯甲酸乙酯22份、杀毒矾18份、聚磷酸铵16份、辛酸甘油酯22份、苯乙烯化苯酚18份、尼泊金丙酯16份、香兰素22份。
进一步地，上述数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：三甘醇二异辛酸酯22份、酚醛环氧树脂24份、石墨粉20份、磷酸三辛酯18份、硬脂酸酯24份、氧化锆粉末20份、三盐基硫酸铅18份、三聚氰胺氰尿酸盐24份、偏苯三酸三辛酯20份、甲基乙烯基硅橡胶18份、三甘醇二异辛酸酯24份、邻苯二甲酸二辛酯20份、硬脂酸甘油酯20份、八甲基环四硅氧烷18份、异佛尔酮24份、聚乙烯醇缩丁醛20份、高氯酸铵18份、对羟基苯甲酸乙酯24份、杀毒矾20份、聚磷酸铵18份、辛酸甘油酯24份、苯乙烯化苯酚20份、尼泊金丙酯18份、香兰素24份。
进一步地，上述数码印花面料阻燃抗菌涂料制备方法步骤如下：
(1)将所述质量份数的三甘醇二异辛酸酯、酚醛环氧树脂、石墨粉、磷酸三辛酯、硬脂酸酯、氧化锆粉末、硬脂酸甘油酯、八甲基环四硅氧烷、异佛尔酮、聚乙烯醇缩丁醛、高氯酸铵、对羟基苯甲酸乙酯、杀毒矾、聚磷酸铵、辛酸甘油酯、苯乙烯化苯酚、尼泊金丙酯、香兰素予以混合，超声高速分散，超声波频率为20～40KHz，分散速度5000～5400r/min左右，分散时间为30～60min；
(2)加入所述质量份数的盐基硫酸铅、三聚氰胺氰尿酸盐、偏苯三酸三辛酯，超声高速分散，超声波频率为20～35KHz，分散速度4800～5200r/min左右，分散时间为30～50min；
(3)加入所述质量份数的三甲基乙烯基硅橡胶、三甘醇二异辛酸酯、邻苯二甲酸二辛酯，超声高速分散，超声波频率为20～30KHz，分散速度4600～4800r/min左右，分散时间为20～40min；混合均匀后制得本品。
该发明的有益效果在于：本发明涉及一种数码印花面料阻燃抗菌涂料，由以下组分组成：三甘醇二异辛酸酯、酚醛环氧树脂、石墨粉、磷酸三辛酯、硬脂酸酯、氧化锆粉末、三盐基硫酸铅、三聚氰胺氰尿酸盐、偏苯三酸三辛酯、甲基乙烯基硅橡胶、三甘醇二异辛酸酯、邻苯二甲酸二辛酯、硬脂酸甘油酯、八甲基环四硅氧烷、异佛尔酮、聚乙烯醇缩丁醛、高氯酸铵、对羟基苯甲酸乙酯、杀毒矾、聚磷酸铵、辛酸甘油酯、苯乙烯化苯酚、尼泊金丙酯、香兰素。本数码印花面料阻燃抗菌涂料制备工艺方法简单，所制备的产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能，改善了产品性能。
具体实施方式
下面结合实施例对本发明的具体实施方式进行描述，以便更好的理解本发明。
实施例1
本实施例中的数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：三甘醇二异辛酸酯18份、酚醛环氧树脂20份、石墨粉16份、磷酸三辛酯14份、硬脂酸酯20份、氧化锆粉末16份、三盐基硫酸铅14份、三聚氰胺氰尿酸盐20份、偏苯三酸三辛酯16份、甲基乙烯基硅橡胶14份、三甘醇二异辛酸酯20份、邻苯二甲酸二辛酯16份、硬脂酸甘油酯16份、八甲基环四硅氧烷14份、异佛尔酮20份、聚乙烯醇缩丁醛16份、高氯酸铵14份、对羟基苯甲酸乙酯20份、杀毒矾16份、聚磷酸铵14份、辛酸甘油酯20份、苯乙烯化苯酚16份、尼泊金丙酯14份、香兰素20份。
上述数码印花面料阻燃抗菌涂料制备方法步骤如下：
(1)将所述质量份数的三甘醇二异辛酸酯、酚醛环氧树脂、石墨粉、磷酸三辛酯、硬脂酸酯、氧化锆粉末、硬脂酸甘油酯、八甲基环四硅氧烷、异佛尔酮、聚乙烯醇缩丁醛、高氯酸铵、对羟基苯甲酸乙酯、杀毒矾、聚磷酸铵、辛酸甘油酯、苯乙烯化苯酚、尼泊金丙酯、香兰素予以混合，超声高速分散，超声波频率为20kHz，分散速度5400r/min左右，分散时间为60min；
(2)加入所述质量份数的盐基硫酸铅、三聚氰胺氰尿酸盐、偏苯三酸三辛酯，超声高速分散，超声波频率为20kHz，分散速度5200r/min左右，分散时间为50min；
(3)加入所述质量份数的三甲基乙烯基硅橡胶、三甘醇二异辛酸酯、邻苯二甲酸二辛酯，超声高速分散，超声波频率为20kHz，分散速度4800r/min左右，分散时间为40min；混合均匀后制得本品。
实施例2
本实施例中的数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：三甘醇二异辛酸酯20份、酚醛环氧树脂22份、石墨粉18份、磷酸三辛酯16份、硬脂酸酯22份、氧化锆粉末18份、三盐基硫酸铅16份、三聚氰胺氰尿酸盐22份、偏苯三酸三辛酯18份、甲基乙烯基硅橡胶16份、三甘醇二异辛酸酯22份、邻苯二甲酸二辛酯18份、硬脂酸甘油酯18份、八甲基环四硅氧烷16份、异佛尔酮22份、聚乙烯醇缩丁醛18份、高氯酸铵16份、对羟基苯甲酸乙酯22份、杀毒矾18份、聚磷酸铵16份、辛酸甘油酯22份、苯乙烯化苯酚18份、尼泊金丙酯16份、香兰素22份。
上述数码印花面料阻燃抗菌涂料制备方法步骤如下：
(1)将所述质量份数的三甘醇二异辛酸酯、酚醛环氧树脂、石墨粉、磷酸三辛酯、硬脂酸酯、氧化锆粉末、硬脂酸甘油酯、八甲基环四硅氧烷、异佛尔酮、聚乙烯醇缩丁醛、高氯酸铵、对羟基苯甲酸乙酯、杀毒矾、聚磷酸铵、辛酸甘油酯、苯乙烯化苯酚、尼泊金丙酯、香兰素予以混合，超声高速分散，超声波频率为30kHz，分散速度5200r/min左右，分散时间为45min；
(2)加入所述质量份数的盐基硫酸铅、三聚氰胺氰尿酸盐、偏苯三酸三辛酯，超声高速分散，超声波频率为27kHz，分散速度5000r/min左右，分散时间为40min；
(3)加入所述质量份数的三甲基乙烯基硅橡胶、三甘醇二异辛酸酯、邻苯二甲酸二辛酯，超声高速分散，超声波频率为25kHz，分散速度4700r/min左右，分散时间为30min；混合均匀后制得本品。
实施例3
本实施例中的数码印花面料阻燃抗菌涂料，由以下质量份数的组分组成：三甘醇二异辛酸酯22份、酚醛环氧树脂24份、石墨粉20份、磷酸三辛酯18份、硬脂酸酯24份、氧化锆粉末20份、三盐基硫酸铅18份、三聚氰胺氰尿酸盐24份、偏苯三酸三辛酯20份、甲基乙烯基硅橡胶18份、三甘醇二异辛酸酯24份、邻苯二甲酸二辛酯20份、硬脂酸甘油酯20份、八甲基环四硅氧烷18份、异佛尔酮24份、聚乙烯醇缩丁醛20份、高氯酸铵18份、对羟基苯甲酸乙酯24份、杀毒矾20份、聚磷酸铵18份、辛酸甘油酯24份、苯乙烯化苯酚20份、尼泊金丙酯18份、香兰素24份。
上述数码印花面料阻燃抗菌涂料制备方法步骤如下：
(1)将所述质量份数的三甘醇二异辛酸酯、酚醛环氧树脂、石墨粉、磷酸三辛酯、硬脂酸酯、氧化锆粉末、硬脂酸甘油酯、八甲基环四硅氧烷、异佛尔酮、聚乙烯醇缩丁醛、高氯酸铵、对羟基苯甲酸乙酯、杀毒矾、聚磷酸铵、辛酸甘油酯、苯乙烯化苯酚、尼泊金丙酯、香兰素予以混合，超声高速分散，超声波频率为40kHz，分散速度5000r/min，分散时间为30min；
(2)加入所述质量份数的盐基硫酸铅、三聚氰胺氰尿酸盐、偏苯三酸三辛酯，超声高速分散，超声波频率为35kHz，分散速度4800r/min，分散时间为30min；
(3)加入所述质量份数的三甲基乙烯基硅橡胶、三甘醇二异辛酸酯、邻苯二甲酸二辛酯，超声高速分散，超声波频率为30kHz，分散速度4600r/min左右，分散时间为20min；混合均匀后制得本品。
针对实施例1、实施例2和实施例3中的产品和某市售产品进行性能测量，所测得的数据如表1所示。防火阻燃等级测试采用UL94标准。
表1性能测试结果
可见，本发明产品具有较好的耐腐蚀、防火阻燃、防霉变、抗菌性能。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (5)

1.一种数码印花面料阻燃抗菌涂料，其特征在于：由以下质量份数的组分组成：三甘醇二异辛酸酯18～22份、酚醛环氧树脂20～24份、石墨粉16～20份、磷酸三辛酯14～18份、硬脂酸酯20～24份、氧化锆粉末16～20份、三盐基硫酸铅14～18份、三聚氰胺氰尿酸盐20～24份、偏苯三酸三辛酯16～20份、甲基乙烯基硅橡胶14～18份、三甘醇二异辛酸酯20～24份、邻苯二甲酸二辛酯16～20份、硬脂酸甘油酯16～20份、八甲基环四硅氧烷14～18份、异佛尔酮20～24份、聚乙烯醇缩丁醛16～20份、高氯酸铵14～18份、对羟基苯甲酸乙酯20～24份、杀毒矾16～20份、聚磷酸铵14～18份、辛酸甘油酯20～24份、苯乙烯化苯酚16～20份、尼泊金丙酯14～18份、香兰素20～24份。
2.根据权利要求1所述的数码印花面料阻燃抗菌涂料，其特征在于：所述数码印花面料阻燃抗菌涂料由以下质量份数的组分组成：三甘醇二异辛酸酯18份、酚醛环氧树脂20份、石墨粉16份、磷酸三辛酯14份、硬脂酸酯20份、氧化锆粉末16份、三盐基硫酸铅14份、三聚氰胺氰尿酸盐20份、偏苯三酸三辛酯16份、甲基乙烯基硅橡胶14份、三甘醇二异辛酸酯20份、邻苯二甲酸二辛酯16份、硬脂酸甘油酯16份、八甲基环四硅氧烷14份、异佛尔酮20份、聚乙烯醇缩丁醛16份、高氯酸铵14份、对羟基苯甲酸乙酯20份、杀毒矾16份、聚磷酸铵14份、辛酸甘油酯20份、苯乙烯化苯酚16份、尼泊金丙酯14份、香兰素20份。
3.根据权利要求1至2所述的数码印花面料阻燃抗菌涂料，其特征在于：所述数码印花面料阻燃抗菌涂料由以下质量份数的组分组成：三甘醇二异辛酸酯20份、酚醛环氧树脂22份、石墨粉18份、磷酸三辛酯16份、硬脂酸酯22份、氧化锆粉末18份、三盐基硫酸铅16份、三聚氰胺氰尿酸盐22份、偏苯三酸三辛酯18份、甲基乙烯基硅橡胶16份、三甘醇二异辛酸酯22份、邻苯二甲酸二辛酯18份、硬脂酸甘油酯18份、八甲基环四硅氧烷16份、异佛尔酮22份、聚乙烯醇缩丁醛18份、高氯酸铵16份、对羟基苯甲酸乙酯22份、杀毒矾18份、聚磷酸铵16份、辛酸甘油酯22份、苯乙烯化苯酚18份、尼泊金丙酯16份、香兰素22份。
4.根据权利要求1至3所述的数码印花面料阻燃抗菌涂料，其特征在于：所述数码印花面料阻燃抗菌涂料由以下质量份数的组分组成：三甘醇二异辛酸酯22份、酚醛环氧树脂24份、石墨粉20份、磷酸三辛酯18份、硬脂酸酯24份、氧化锆粉末20份、三盐基硫酸铅18份、三聚氰胺氰尿酸盐24份、偏苯三酸三辛酯20份、甲基乙烯基硅橡胶18份、三甘醇二异辛酸酯24份、邻苯二甲酸二辛酯20份、硬脂酸甘油酯20份、八甲基环四硅氧烷18份、异佛尔酮24份、聚乙烯醇缩丁醛20份、高氯酸铵18份、对羟基苯甲酸乙酯24份、杀毒矾20份、聚磷酸铵18份、辛酸甘油酯24份、苯乙烯化苯酚20份、尼泊金丙酯18份、香兰素24份。
5.根据权利要求1所述的数码印花面料阻燃抗菌涂料，其特征在于：所述数码印花面料阻燃抗菌涂料制备方法步骤如下：
（1）将所述质量份数的三甘醇二异辛酸酯、酚醛环氧树脂、石墨粉、磷酸三辛酯、硬脂酸酯、氧化锆粉末、硬脂酸甘油酯、八甲基环四硅氧烷、异佛尔酮、聚乙烯醇缩丁醛、高氯酸铵、对羟基苯甲酸乙酯、杀毒矾、聚磷酸铵、辛酸甘油酯、苯乙烯化苯酚、尼泊金丙酯、香兰素予以混合，超声高速分散，超声波频率为20～40KHz，分散速度约5000～5400r/min，分散时间为30～60min左右；
（2）加入所述质量份数的盐基硫酸铅、三聚氰胺氰尿酸盐、偏苯三酸三辛酯，超声高速分散，超声波频率为20～35KHz，分散速度为约4800～5200r/min，分散时间为30～50min左右；
（3）加入所述质量份数的三甲基乙烯基硅橡胶、三甘醇二异辛酸酯、邻苯二甲酸二辛酯，超声高速分散，超声波频率为20～30KHz，分散速度为约4600～4800r/min，分散时间为20～40min左右；混合均匀后制得本品。
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