CN106758140A - 一种运动护膝中防护外筒用制作布料 - Google Patents

一种运动护膝中防护外筒用制作布料 Download PDF

Info

Publication number
CN106758140A
CN106758140A CN201710040972.7A CN201710040972A CN106758140A CN 106758140 A CN106758140 A CN 106758140A CN 201710040972 A CN201710040972 A CN 201710040972A CN 106758140 A CN106758140 A CN 106758140A
Authority
CN
China
Prior art keywords
parts
outer barrel
sports
making cloth
cloth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710040972.7A
Other languages
English (en)
Inventor
江崇礼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Ruicheng Machinery Design Co Ltd
Original Assignee
Qingdao Ruicheng Machinery Design Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Ruicheng Machinery Design Co Ltd filed Critical Qingdao Ruicheng Machinery Design Co Ltd
Priority to CN201710040972.7A priority Critical patent/CN106758140A/zh
Publication of CN106758140A publication Critical patent/CN106758140A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
    • A41D13/06—Knee or foot
    • A41D13/065—Knee protectors
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/20—Halides of elements of Groups 4 or 14 of the Periodic Table, e.g. zirconyl chloride
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/503—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms without bond between a carbon atom and a metal or a boron, silicon, selenium or tellurium atom
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D06M13/517—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond containing silicon-halogen bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

一种运动护膝中防护外筒用制作布料，所述制作布料为经强化涂料进行加工处理过的弹性织物。本发明提供的运动护膝中防护外筒用制作布料具有优良的耐磨、防撕裂、防撞击、防水、环保无气味等性能，针对室内/室外篮球、羽毛球(尤其是普通的户外水泥场地)等较差运动场所的运动项目，甚至是针对目前社会上兴起的户外运动项目，都可以起到非常好的防护作用，适于推广应用。

Description

一种运动护膝中防护外筒用制作布料
技术领域
本发明属于运动护具制作材料技术领域，涉及一种运动护膝中防护外筒用制作布料。
背景技术
膝盖为位于大小腿之间的连接部位。膝的主要内部组成结构为半月板以及四条韧带。半月板为膝内部股骨下端和胫骨上端之间的接连处所垫的一块新月形的纤维软骨组织，作用是缓冲膝关节的震动，以及避免两块骨头的直接摩擦。另外，它由四条主要的韧带支撑着。其中有两条在膝的两侧，称为中侧突韧带和外侧突韧带，主要功能是防止膝部轴离位；另外两条韧带则分别分布在膝前后方，称为前十字韧带和后十字韧带，作用是防止膝部前后移位。目前，年轻人多热爱运动，篮球、旱冰、羽毛球等都是比较受欢迎的运动项目，在这些运动中膝盖属于特别容易受伤的部位，传统的运动用护膝只有薄薄的一层织物和海绵，不能起到很好的保护作用。授权公告号为CN201303604Y的中国专利公开了一种运动专用护膝，包括圆筒状的护膝本体，在所述的护膝本体对应膝盖的部位置入一层气垫，所述的气垫封闭固定在护膝本体的内部。该护膝中由于气垫的使用，对使用者膝盖的运动造成一定程度的干扰，而且其防滑、耐磨、防撕裂性能较差。授权公告号为CN204426775U的中国专利公开了一种运动护膝，其包括护膝本体、缓冲块，所述护膝本体为弹性材料制成，所述护膝本体对应膝部侧面设有与护膝本体固定连接缓冲块，所述缓冲块为三角形模块，所述运动护膝还包括防滑贴片，所述护膝本体内侧壁具有与护膝本体贴合的防滑贴片，所述防滑贴片为直径2mm－4mm的圆片，防滑贴片在护膝本体内侧壁均匀分布。该护膝耐磨性差，结构复杂，制作成本高。此外，实际应用发现，上述运动护膝以及类似产品在耐磨性、防撞击、防撕裂性等性能方面表现较差，无法适应一些剧烈的运动，如室内/室外篮球、羽毛球(尤其是普通的户外水泥场地)等场所的运动项目，甚至是目前兴起的户外运动，对使用者的膝盖防护性能较差。
发明内容
为了解决现有技术的上述缺陷，本发明提供了一种运动护膝中防护外筒用制作布料。
本发明的上述目的是通过下述技术方案来实现的：
一种运动护膝中防护外筒用制作布料，所述制作布料为经强化涂料进行加工处理过的弹性织物。
进一步地，所述加工处理的具体步骤为：将制作布料通过强化涂料，经过一浸一扎，之后通过烘箱在110-120℃下烘干，随后将烘干后的制作布料制成防护外筒。
进一步地，所述强化涂料由以下重量份数的原料构成：双十八烷基二甲基氯化铵37～44份；四正丙基锆酸酯28-31份；N，N’－间苯撑双马来酰亚胺23-25份；聚乙烯醇缩丁醛17-20份；辛基异噻唑啉酮13-15份；硅酸镁11-13份；十八烷基三氯硅烷8-12份；2-咪唑烷酮10-11份；醋酸乙烯－乙烯共聚乳液11-13份；苯二甲酸二丁酯10-16份；纳米二氧化钛5-7份；二正丁基二硫代氨基甲酸锌13-18份；羟乙基纤维素3-6份；马来酸酐接枝聚丙烯2-3份；瓜尔胶3-5份；二醇苯基醚1-2份；2-苯基咪唑啉1-2份；聚乙烯醇2-3份；氟化碳1-2份；去离子水1100-1300份。
进一步地，所述强化涂料的制备方法包括如下步骤：
(1)将双十八烷基二甲基氯化铵、四正丙基锆酸酯、N，N’－间苯撑双马来酰亚胺、聚乙烯醇缩丁醛、辛基异噻唑啉酮、苯二甲酸二丁酯、2-咪唑烷酮、十八烷基三氯硅烷、二正丁基二硫代氨基甲酸锌、马来酸酐接枝聚丙烯、瓜尔胶、聚乙烯醇、氟化碳加入去离子水中，加热搅拌均匀，保持温度为100-110℃，搅拌速度控制为150-200rad/min，静置3-3.5h后冷却至室温，过滤，滤液备用；
(2)按照所述重量份数将硅酸镁、纳米二氧化钛送至球磨机，磨至粒径为20-40nm，然后混合搅拌，100-120r/min的速度搅拌30-40分钟，搅拌均匀得到混合物；
(3)将步骤(2)制得的混合物加入步骤(1)制得的滤液中，超声高速分散，超声波频率为20kHz，分散速度6200r/min，分散时间为40min；
(4)加入剩余的醋酸乙烯－乙烯共聚乳液、羟乙基纤维素、二醇苯基醚、2-苯基咪唑啉，超声高速分散，超声波频率为20kHz，分散速度5500r/min，分散时间为50min，得强化涂料。
本发明提供的运动护膝中防护外筒用制作布料具有优良的耐磨、防撕裂、防撞击、防水、环保无气味等性能，针对室内/室外篮球、羽毛球(尤其是普通的户外水泥场地)等较差运动场所的运动项目，甚至是针对目前社会上兴起的户外运动项目，都可以起到非常好的防护作用，适于推广应用。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚，下面将结合实施例对本发明的技术方案进行清楚、完整地描述。显然，所描述的实施例是本发明的一部分，而不是全部的实施例。基于所描述的本发明的实施例，本领域普通技术人员在无需创造性劳动的前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明涉及一种新型耐磨运动护膝，包括护膝本体，护膝本体包括分别由弹性织物制成的防护内筒、防护外筒，在防护内筒、防护外筒之间设置有多层织物纤维层，优选地，所述织物纤维层为2-3层，每层厚度不超过1毫米。进一步地，所述织物纤维层为芳纶等复合材料制成。
在本发明的一种实施方式中，防护外筒的制作布料经强化涂料进行加工处理。具体步骤为：将制作布料通过强化涂料，经过一浸一扎(先浸入强化涂料，再扎干)，之后通过烘箱在110-120℃下烘干，随后将烘干后的制作布料制成防护外筒。
所述强化涂料的具体成分为：
双十八烷基二甲基氯化铵37～44份；四正丙基锆酸酯28-31份；N，N’－间苯撑双马来酰亚胺23-25份；聚乙烯醇缩丁醛17-20份；辛基异噻唑啉酮13-15份；硅酸镁11-13份；十八烷基三氯硅烷8-12份；2-咪唑烷酮10-11份；醋酸乙烯－乙烯共聚乳液11-13份；苯二甲酸二丁酯10-16份；纳米二氧化钛5-7份；二正丁基二硫代氨基甲酸锌13-18份；羟乙基纤维素3-6份；马来酸酐接枝聚丙烯2-3份；瓜尔胶3-5份；二醇苯基醚1-2份；2-苯基咪唑啉1-2份；聚乙烯醇2-3份；氟化碳1-2份；去离子水1100-1300份。
优选地，所述纳米二氧化钛的粒径为20-30nm。
所述十八烷基三氯硅烷采用天然带电矿物质材料，加入十八烷基三氯硅烷可以显著提高对大肠杆菌和金黄色葡萄球菌等的抗菌性能。
本发明中N，N’－间苯撑双马来酰亚胺、醋酸乙烯－乙烯共聚乳液、纳米二氧化钛等的组合能够很好地提高涂膜致密性、防腐蚀性、耐水性、耐热、耐候性等性能。采用醋酸乙烯－乙烯共聚乳液，还可以极大地提高涂料抗沾粘性能，同时具有良好的弹性和韧性，其涂膜具有了良好内磨性、抗开裂性能和耐沾污性性能。
所述强化涂料的制备方法包括如下步骤：
(1)将双十八烷基二甲基氯化铵、四正丙基锆酸酯、N，N’－间苯撑双马来酰亚胺、聚乙烯醇缩丁醛、辛基异噻唑啉酮、苯二甲酸二丁酯、2-咪唑烷酮、十八烷基三氯硅烷、二正丁基二硫代氨基甲酸锌、马来酸酐接枝聚丙烯、瓜尔胶、聚乙烯醇、氟化碳加入去离子水中，加热搅拌均匀，保持温度为100-110℃，搅拌速度控制为150-200rad/min，静置3-3.5h后冷却至室温，过滤，滤液备用；
(2)按照所述重量份数将硅酸镁、纳米二氧化钛送至球磨机，磨至粒径为20-40nm，然后混合搅拌，100-120r/min的速度搅拌30-40分钟，搅拌均匀得到混合物；
(3)将步骤(2)制得的混合物加入步骤(1)制得的滤液中，超声高速分散，超声波频率为20kHz，分散速度6200r/min，分散时间为40min；
(4)加入剩余的醋酸乙烯－乙烯共聚乳液、羟乙基纤维素、二醇苯基醚、2-苯基咪唑啉，超声高速分散，超声波频率为20kHz，分散速度5500r/min，分散时间为50min，得强化涂料。
在一种实施方式中，所述强化涂料包括以下重量份数的原料：双十八烷基二甲基氯化铵37份；四正丙基锆酸酯30份；N，N’－间苯撑双马来酰亚胺23份；聚乙烯醇缩丁醛20份；辛基异噻唑啉酮13份；硅酸镁11份；十八烷基三氯硅烷12份；2-咪唑烷酮10份；醋酸乙烯－乙烯共聚乳液13份；苯二甲酸二丁酯16份；纳米二氧化钛5份；二正丁基二硫代氨基甲酸锌15份；羟乙基纤维素6份；马来酸酐接枝聚丙烯2份；瓜尔胶5份；二醇苯基醚1份；2-苯基咪唑啉2份；聚乙烯醇2份；氟化碳1份；去离子水1200份。
在一种实施方式中，所述强化涂料包括以下重量份数的原料：双十八烷基二甲基氯化铵44份；四正丙基锆酸酯28份；N，N’－间苯撑双马来酰亚胺24份；聚乙烯醇缩丁醛17份；辛基异噻唑啉酮15份；硅酸镁13份；十八烷基三氯硅烷8份；2-咪唑烷酮11份；醋酸乙烯－乙烯共聚乳液11份；苯二甲酸二丁酯10份；纳米二氧化钛5份；二正丁基二硫代氨基甲酸锌18份；羟乙基纤维素4份；马来酸酐接枝聚丙烯3份；瓜尔胶4份；二醇苯基醚1-2份；2-苯基咪唑啉1份；聚乙烯醇2份；氟化碳1份；去离子水1100份。
在一种实施方式中，所述强化涂料包括以下重量份数的原料：双十八烷基二甲基氯化铵40份；四正丙基锆酸酯31份；N，N’－间苯撑双马来酰亚胺25份；聚乙烯醇缩丁醛18份；辛基异噻唑啉酮13份；硅酸镁11份；十八烷基三氯硅烷10份；2-咪唑烷酮10份；醋酸乙烯－乙烯共聚乳液12份；苯二甲酸二丁酯13份；纳米二氧化钛5份；二正丁基二硫代氨基甲酸锌19份；羟乙基纤维素5份；马来酸酐接枝聚丙烯2.5份；瓜尔胶4份；二醇苯基醚1份；2-苯基咪唑啉1份；聚乙烯醇3份；氟化碳1份；去离子水1300份。
在一种实施方式中，所述强化涂料包括以下重量份数的原料：双十八烷基二甲基氯化铵39份；四正丙基锆酸酯31份；N，N’－间苯撑双马来酰亚胺25份；聚乙烯醇缩丁醛19份；辛基异噻唑啉酮13份；硅酸镁12份；十八烷基三氯硅烷11份；2-咪唑烷酮11份；醋酸乙烯－乙烯共聚乳液13份；苯二甲酸二丁酯14份；纳米二氧化钛7份；二正丁基二硫代氨基甲酸锌16份；羟乙基纤维素3份；马来酸酐接枝聚丙烯2份；瓜尔胶3份；二醇苯基醚1份；2-苯基咪唑啉1.5份；聚乙烯醇3份；氟化碳2份；去离子水1300份。
在一种实施方式中，所述强化涂料包括以下重量份数的原料：双十八烷基二甲基氯化铵42份；四正丙基锆酸酯30份；N，N’－间苯撑双马来酰亚胺23份；聚乙烯醇缩丁醛17份；辛基异噻唑啉酮14份；硅酸镁12份；十八烷基三氯硅烷11份；2-咪唑烷酮11份；醋酸乙烯－乙烯共聚乳液12份；苯二甲酸二丁酯14份；纳米二氧化钛6份；二正丁基二硫代氨基甲酸锌15份；羟乙基纤维素3份；马来酸酐接枝聚丙烯2份；瓜尔胶4份；二醇苯基醚1.5份；2-苯基咪唑啉1份；聚乙烯醇2.5份；氟化碳2份；去离子水1200份。
实际制作过程中，首先按照上述步骤制作强化涂料，然后将弹性织物经过一浸一扎(先浸入强化涂料，再扎干)，之后通过烘箱在110-120℃下烘干，随后将烘干后的制作布料制成防护外筒。随后利用弹性织物制作防护内筒，以及将2-3层织物纤维层裁剪至合适规格。最后将织物纤维层放入防护内筒、防护外筒之间，缝合边沿，形成本发明的新型耐磨运动护膝。
经测试，本发明的新型耐磨运动护膝的防护外筒拉伸强度数值范围为21.15-24.22MPa，断裂伸长率571-596％，耐切割指数达到3，耐磨量(mg/1000次)0.35-0.38，防火阻燃级别V-0，湿度大于60％腐蚀率(25℃)2.9％-3.7％，pH＝3.5酸环境腐蚀率4.2％-4.6％，pH＝8.5碱环境腐蚀率4.1％-4.6％，大肠杆菌霉菌存活率2.1％-3.0％，耐冲击性/(kg·cm)141-145，耐高温(500℃)22-25小时无变化，苯类物质检测：未检测到来源SGS测试。可见本发明的新型耐磨运动护膝通过对防护外筒进行强化涂料处理，从而具有优良的耐磨性能、抗冲击性能、抗撕裂、防撞击、耐水性、耐热、抗菌性、环保等综合性能，优于现有同类产品，可以对处于复杂运动条件下的使用者进行最合适和最安全的保护，适于推广应用。
最后应说明的是：以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。

Claims (4)

1.一种运动护膝中防护外筒用制作布料，其特征在于：所述制作布料为经强化涂料进行加工处理过的弹性织物。
2.根据权利要求1所述的运动护膝中防护外筒用制作布料，其特征在于：所述加工处理的具体步骤为：将制作布料通过强化涂料，经过一浸一扎，之后通过烘箱在110-120℃下烘干，随后将烘干后的制作布料制成防护外筒。
3.根据权利要求2所述的运动护膝中防护外筒用制作布料，其特征在于：所述强化涂料由以下重量份数的原料构成：双十八烷基二甲基氯化铵37～44份；四正丙基锆酸酯28-31份；N，N’－间苯撑双马来酰亚胺23-25份；聚乙烯醇缩丁醛17-20份；辛基异噻唑啉酮13-15份；硅酸镁11-13份；十八烷基三氯硅烷8-12份；2-咪唑烷酮10-11份；醋酸乙烯－乙烯共聚乳液11-13份；苯二甲酸二丁酯10-16份；纳米二氧化钛5-7份；二正丁基二硫代氨基甲酸锌13-18份；羟乙基纤维素3-6份；马来酸酐接枝聚丙烯2-3份；瓜尔胶3-5份；二醇苯基醚1-2份；2-苯基咪唑啉1-2份；聚乙烯醇2-3份；氟化碳1-2份；去离子水1100-1300份。
4.根据权利要求3所述的运动护膝中防护外筒用制作布料，其特征在于：所述强化涂料的制备方法包括如下步骤：
(1)将双十八烷基二甲基氯化铵、四正丙基锆酸酯、N，N’－间苯撑双马来酰亚胺、聚乙烯醇缩丁醛、辛基异噻唑啉酮、苯二甲酸二丁酯、2-咪唑烷酮、十八烷基三氯硅烷、二正丁基二硫代氨基甲酸锌、马来酸酐接枝聚丙烯、瓜尔胶、聚乙烯醇、氟化碳加入去离子水中，加热搅拌均匀，保持温度为100-110℃，搅拌速度控制为150-200rad/min，静置3-3.5h后冷却至室温，过滤，滤液备用；
(2)按照所述重量份数将硅酸镁、纳米二氧化钛送至球磨机，磨至粒径为20-40nm，然后混合搅拌，100-120r/min的速度搅拌30-40分钟，搅拌均匀得到混合物；
(3)将步骤(2)制得的混合物加入步骤(1)制得的滤液中，超声高速分散，超声波频率为20kHz，分散速度6200r/min，分散时间为40min；
(4)加入剩余的醋酸乙烯－乙烯共聚乳液、羟乙基纤维素、二醇苯基醚、2-苯基咪唑啉，超声高速分散，超声波频率为20kHz，分散速度5500r/min，分散时间为50min，得强化涂料。
CN201710040972.7A 2017-01-20 2017-01-20 一种运动护膝中防护外筒用制作布料 Pending CN106758140A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710040972.7A CN106758140A (zh) 2017-01-20 2017-01-20 一种运动护膝中防护外筒用制作布料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710040972.7A CN106758140A (zh) 2017-01-20 2017-01-20 一种运动护膝中防护外筒用制作布料

Publications (1)

Publication Number Publication Date
CN106758140A true CN106758140A (zh) 2017-05-31

Family

ID=58944773

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710040972.7A Pending CN106758140A (zh) 2017-01-20 2017-01-20 一种运动护膝中防护外筒用制作布料

Country Status (1)

Country Link
CN (1) CN106758140A (zh)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10325081A (ja) * 1997-05-21 1998-12-08 Unitika Ltd 透湿防水性コーティング布帛及びその製造方法
CN101805995A (zh) * 2010-03-23 2010-08-18 嘉兴学院 织物整理剂及织物整理方法
CN104195834A (zh) * 2014-09-02 2014-12-10 威尔克工业纺织（嘉兴）有限公司 一种具有抗菌功能的防水透湿面料
CN105239382A (zh) * 2015-11-17 2016-01-13 安徽柏拉图涂层织物有限公司 一种复合型耐磨防水涂层布
CN105696346A (zh) * 2016-03-08 2016-06-22 杨超 一种服装面料用抗菌阻燃涂料
CN105780491A (zh) * 2016-03-08 2016-07-20 杨超 一种服装面料用抗菌阻燃涂料的制备方法
CN106192372A (zh) * 2016-07-11 2016-12-07 青岛银世达塑胶有限公司 一种新型防护手套

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10325081A (ja) * 1997-05-21 1998-12-08 Unitika Ltd 透湿防水性コーティング布帛及びその製造方法
CN101805995A (zh) * 2010-03-23 2010-08-18 嘉兴学院 织物整理剂及织物整理方法
CN104195834A (zh) * 2014-09-02 2014-12-10 威尔克工业纺织（嘉兴）有限公司 一种具有抗菌功能的防水透湿面料
CN105239382A (zh) * 2015-11-17 2016-01-13 安徽柏拉图涂层织物有限公司 一种复合型耐磨防水涂层布
CN105696346A (zh) * 2016-03-08 2016-06-22 杨超 一种服装面料用抗菌阻燃涂料
CN105780491A (zh) * 2016-03-08 2016-07-20 杨超 一种服装面料用抗菌阻燃涂料的制备方法
CN106192372A (zh) * 2016-07-11 2016-12-07 青岛银世达塑胶有限公司 一种新型防护手套

Similar Documents

Publication Publication Date Title
US5317037A (en) Moldable composition of matter
CN106723481A (zh) 一种新型耐磨运动护膝
CN101622020A (zh) 亲水性涂层
CN106192372A (zh) 一种新型防护手套
CN107383283A (zh) 一种结构型抗菌丙烯酸乳液及其制备方法和应用
CN112812261A (zh) 一种水性聚氨酯乳液、丁腈橡胶-聚氨酯复合手套及其制备方法
CN106758140A (zh) 一种运动护膝中防护外筒用制作布料
CN106752465A (zh) 一种运动护膝中防护外筒用制作布料的制备方法
BR0110786A (pt) Composição aperfeiçoada de borracha
CN106758210A (zh) 一种新型耐磨运动护膝的制备方法
BRPI0413903B8 (pt) processo para preparação de uma fibra elástica, fibra elástica e tecido de veludo
CN107880577A (zh) 一种抗菌防霉复合板及其制备方法
CN104947222A (zh) 一种质轻蓬松型生态抑菌羽绒纤维及其制作方法
CN107502973A (zh) 一种用于保健护肩的远红外线复合纤维及其制备方法
MA28017A1 (fr) Compositions ophtalmiques traitant l'hypertention oculaire
CN108530743A (zh) 一种塑料配方
CN113429493B (zh) 一种非释放型高分子抗菌防螨剂的制备方法
CN107502981A (zh) 一种羽绒服用抗菌防潮羽绒的加工工艺
CN107227000A (zh) 一种防火吸声驱虫环保发泡材料及其制备方法
CN104559671A (zh) 一种多种设备壳体用水性阻燃防锈降噪涂料及其制备方法
CN107057411A (zh) 一种使用熟贝壳的杀菌消毒液涂料
CN106519606B (zh) 一种用于3d打印的阻燃型可降解复合材料及其制备方法
CS38191A2 (en) Eye-drops
CN108586785A (zh) 一种新型橡胶地板及其制备方法
FI970092A (fi) Pyrido(3,2,1-i,j)(3,1)bentsoksatsiinijohdannaiset

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531

RJ01 Rejection of invention patent application after publication