CN105696346A - 一种服装面料用抗菌阻燃涂料 - Google Patents

一种服装面料用抗菌阻燃涂料 Download PDF

Info

Publication number
CN105696346A
CN105696346A CN201610128260.6A CN201610128260A CN105696346A CN 105696346 A CN105696346 A CN 105696346A CN 201610128260 A CN201610128260 A CN 201610128260A CN 105696346 A CN105696346 A CN 105696346A
Authority
CN
China
Prior art keywords
parts
nano
vinyl acetate
acrylate
retardant coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610128260.6A
Other languages
English (en)
Inventor
杨超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610128260.6A priority Critical patent/CN105696346A/zh
Publication of CN105696346A publication Critical patent/CN105696346A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55—Epoxy resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2243—Mono-, di-, or triglycerides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/252—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing bromine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3566—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing sulfur
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

一种服装面料用抗菌阻燃涂料，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32～36份；双酚A环氧树脂25-28份；有机硅改性苯丙乳液23-25份；氰酸酯环氧树脂共聚物18-22份；聚乙烯醇缩丁醛27-30份；聚丙烯22-25份；单硬脂酸甘油单酯10-13份；云母粉16-20份；负离子添加剂13-15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物11-15份；醋酸乙烯－乙烯共聚乳液11-13份；苯二甲酸二丁酯10-16份；纳米氢氧化镁7-9份；纳米氢氧化铝5-7份；二正丁基二硫代氨基甲酸锌15-19份；脂肪酸甘油酯5-8份；羟乙基纤维素3-6份；聚溴化苯乙烯2-3份；瓜尔胶3-5份；纤维素醚1-2份；2-苯基咪唑啉1-2份；聚乙烯醇2-3份；月桂酸1-2份；去离子水1200-1500份。

Description

一种服装面料用抗菌阻燃涂料
技术领域
本发明涉及涂料技术领域，具体涉及一种服装面料用抗菌阻燃涂料。
背景技术
在服装大世界里，服装的面料五花八门，日新月异。但是从总体上来讲，优质、高档的面料，大都具有穿著舒适、吸汗透气、悬垂挺括、视觉高贵、触觉柔软等几个方面的特点。由于户外环境复杂多变，为抵御恶劣环境对人体的伤害，保护身体热量不被散失以及快速排出运动时所产生的汗水，在登山、攀岩及其他户外运动时穿着，以适应野外各种天气变化对人体所带来的影响的服装叫做户外服。因此，需要改进现有面料的材料，使面料具有抗菌、阻燃等优异的性能。
公开号为CN105256574A的中国专利公开了一种服装面料用抗菌阻燃涂料，由以下质量份数的组分组成：聚丙烯酸22～26份、海藻酸钠糊24～28份、聚乙二醇酯20～24份、过硼酸钠24～28份、聚异戊二烯20～24份、聚对苯二甲酸乙二醇酯24～28份、硫酸基甜菜碱20～24份、四正丙基锆酸酯26～30份、聚磷酸铵20～24份、辛酸甘油酯24～28份、双十八烷基二甲基氯化铵20～24份、聚四氟乙烯微粉24～28份、二正丁基二硫代氨基甲酸锌20～24份、巴西棕榈蜡24～28份、对羟基苯甲酸丁酯20～24份、脱氢醋酸钠24～28份、氢氧化镁20～24份、百菌清24～28份、椰子油脂肪酸24～28份、纳米磷酸锆载银抗菌剂20～24份、水1000～2000份。该涂料在耐腐蚀性、抗菌性等综合性能仍然不够理想，仍需进一步改进。
发明内容
本发明的目的是提供一种服装面料用抗菌阻燃涂料，该涂料具有更高的耐腐蚀性和抗菌性能，提高了防火性能，较现有技术具有较大改进。
本发明的上述目的是通过下述技术方案来实现的：
一种服装面料用抗菌阻燃涂料，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32～36份；双酚A环氧树脂25-28份；有机硅改性苯丙乳液23-25份；氰酸酯环氧树脂共聚物18-22份；聚乙烯醇缩丁醛27-30份；聚丙烯22-25份；单硬脂酸甘油单酯10-13份；云母粉16-20份；负离子添加剂13-15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物11-15份；醋酸乙烯－乙烯共聚乳液11-13份；苯二甲酸二丁酯10-16份；纳米氢氧化镁7-9份；纳米氢氧化铝5-7份；二正丁基二硫代氨基甲酸锌15-19份；脂肪酸甘油酯5-8份；羟乙基纤维素3-6份；聚溴化苯乙烯2-3份；瓜尔胶3-5份；纤维素醚1-2份；2-苯基咪唑啉1-2份；聚乙烯醇2-3份；月桂酸1-2份；去离子水1200-1500份。
进一步地，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32份；双酚A环氧树脂25份；有机硅改性苯丙乳液23份；氰酸酯环氧树脂共聚物22份；聚乙烯醇缩丁醛30份；聚丙烯22份；单硬脂酸甘油单酯12份；云母粉18份；负离子添加剂14份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物15份；醋酸乙烯－乙烯共聚乳液13份；苯二甲酸二丁酯16份；纳米氢氧化镁8份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌15份；脂肪酸甘油酯5份；羟乙基纤维素6份；聚溴化苯乙烯2份；瓜尔胶5份；纤维素醚1份；2-苯基咪唑啉2份；聚乙烯醇2份；月桂酸1份；去离子水1200份。
进一步地，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32～36份；双酚A环氧树脂27份；有机硅改性苯丙乳液24份；氰酸酯环氧树脂共聚物20份；聚乙烯醇缩丁醛27份；聚丙烯23份；单硬脂酸甘油单酯11份；云母粉17份；负离子添加剂13份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物11份；醋酸乙烯－乙烯共聚乳液11份；苯二甲酸二丁酯10份；纳米氢氧化镁8份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌18份；脂肪酸甘油酯8份；羟乙基纤维素4份；聚溴化苯乙烯3份；瓜尔胶4份；纤维素醚1-2份；2-苯基咪唑啉1份；聚乙烯醇2份；月桂酸1份；去离子水1500份。
进一步地，包括以下重量份数的原料：聚羟丙基二甲基氯化铵36份；双酚A环氧树脂28份；有机硅改性苯丙乳液25份；氰酸酯环氧树脂共聚物19份；聚乙烯醇缩丁醛28份；聚丙烯25份；单硬脂酸甘油单酯10份；云母粉16份；负离子添加剂15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物14份；醋酸乙烯－乙烯共聚乳液12份；苯二甲酸二丁酯13份；纳米氢氧化镁7份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌19份；脂肪酸甘油酯6份；羟乙基纤维素5份；聚溴化苯乙烯2.5份；瓜尔胶4份；纤维素醚1份；2-苯基咪唑啉1份；聚乙烯醇3份；月桂酸1份；去离子水1500份。
进一步地，包括以下重量份数的原料：聚羟丙基二甲基氯化铵33份；双酚A环氧树脂26份；有机硅改性苯丙乳液25份；氰酸酯环氧树脂共聚物21份；聚乙烯醇缩丁醛29份；聚丙烯23份；单硬脂酸甘油单酯13份；云母粉20份；负离子添加剂15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物14份；醋酸乙烯－乙烯共聚乳液13份；苯二甲酸二丁酯14份；纳米氢氧化镁9份；纳米氢氧化铝7份；二正丁基二硫代氨基甲酸锌16份；脂肪酸甘油酯7份；羟乙基纤维素3份；聚溴化苯乙烯2份；瓜尔胶3份；纤维素醚1份；2-苯基咪唑啉1.5份；聚乙烯醇3份；月桂酸2份；去离子水1300份。
进一步地，包括以下重量份数的原料：聚羟丙基二甲基氯化铵35份；双酚A环氧树脂28份；有机硅改性苯丙乳液23份；氰酸酯环氧树脂共聚物18份；聚乙烯醇缩丁醛27份；聚丙烯24份；单硬脂酸甘油单酯11份；云母粉18份；负离子添加剂13份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物12份；醋酸乙烯－乙烯共聚乳液12份；苯二甲酸二丁酯14份；纳米氢氧化镁9份；纳米氢氧化铝6份；二正丁基二硫代氨基甲酸锌15份；脂肪酸甘油酯5份；羟乙基纤维素3份；聚溴化苯乙烯2份；瓜尔胶4份；纤维素醚1.5份；2-苯基咪唑啉1份；聚乙烯醇2.5份；月桂酸2份；去离子水1400-1500份。
进一步地，所述纳米氢氧化镁的粒径为20-50nm。
进一步地，所述纳米氢氧化铝的粒径为30-40nm。
进一步地，所述负离子添加剂采用天然带电矿物质材料。
进一步地，所述丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物中，按重量百分比计，丙烯酸酯占45％，苯乙烯占33％，醋酸乙烯占22％，共聚物的重均分子量为80000-100000，并且具有5mgKOH/g的羟基值，平均粒径为0.7-1μm。
本发明的一种服装面料用抗菌阻燃涂料与现有技术相比，本发明的服装面料用抗菌阻燃涂料在耐腐蚀性、抗菌性能、耐候性、耐冲击性的性能方面取得显著改进，适于推广应用。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚，下面将结合实施例对本发明的技术方案进行清楚、完整地描述。显然，所描述的实施例是本发明的一部分，而不是全部的实施例。基于所描述的本发明的实施例，本领域普通技术人员在无需创造性劳动的前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1：
一种服装面料用抗菌阻燃涂料，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32份；双酚A环氧树脂25份；有机硅改性苯丙乳液23份；氰酸酯环氧树脂共聚物22份；聚乙烯醇缩丁醛30份；聚丙烯22份；单硬脂酸甘油单酯12份；云母粉18份；负离子添加剂14份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物15份；醋酸乙烯－乙烯共聚乳液13份；苯二甲酸二丁酯16份；纳米氢氧化镁8份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌15份；脂肪酸甘油酯5份；羟乙基纤维素6份；聚溴化苯乙烯2份；瓜尔胶5份；纤维素醚1份；2-苯基咪唑啉2份；聚乙烯醇2份；月桂酸1份；去离子水1200份。
优选地，所述纳米氢氧化镁的粒径为20-50nm。
优选地，所述纳米氢氧化铝的粒径为30-40nm。
其中，所述丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物中，按重量百分比计，丙烯酸酯占45％，苯乙烯占33％，醋酸乙烯占22％，共聚物的重均分子量为80000-100000，并且具有5mgKOH/g的羟基值，平均粒径为0.7-1μm。
所述负离子添加剂采用天然带电矿物质材料，加入负离子添加剂可以显著提高对大肠杆菌和金黄色葡萄球菌等的抗菌性能。
本发明中丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物具有优异的阻燃性，而其与有机硅改性苯丙乳液、醋酸乙烯－乙烯共聚乳液、以及氰酸酯环氧树脂共聚物的组合能够很好地提高涂膜致密性、防腐蚀性、耐水性、耐热、耐候性等性能。采用醋酸乙烯－乙烯共聚乳液，还可以极大地提高涂料抗沾粘性能，同时具有良好的弹性和韧性，其涂膜具有了良好抗开裂性能和耐沾污性和耐擦洗性能。
所述服装面料用抗菌阻燃涂料的制备方法包括如下步骤：
(1)将聚羟丙基二甲基氯化铵、双酚A环氧树脂、有机硅改性苯丙乳液、氰酸酯环氧树脂共聚物、聚乙烯醇缩丁醛、聚丙烯、单硬脂酸甘油单酯、苯二甲酸二丁酯、二正丁基二硫代氨基甲酸锌、聚溴化苯乙烯、瓜尔胶、聚乙烯醇、月桂酸加入去离子水中，加热搅拌均匀，保持温度为90-105℃，搅拌速度控制为300-400rad/min，静置2-2.5h后冷却至室温，过滤，滤液备用；
(2)按照所述重量份数将丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物、云母粉、负离子添加剂、纳米氢氧化镁、纳米氢氧化铝送至球磨机，磨至粒径为30-50nm，然后混合搅拌，100-120r/min的速度搅拌40-50分钟，搅拌均匀得到混合物；
(3)将步骤(2)制得的混合物加入步骤(1)制得的滤液中，超声高速分散，超声波频率为20kHz，分散速度5500r/min，分散时间为55min；
(4)加入剩余的醋酸乙烯－乙烯共聚乳液、脂肪酸甘油酯、羟乙基纤维素、纤维素醚、2-苯基咪唑啉，超声高速分散，超声波频率为20kHz，分散速度4800r/min，分散时间为40min，得服装面料用抗菌阻燃涂料。
实施例2：
一种服装面料用抗菌阻燃涂料，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32～36份；双酚A环氧树脂27份；有机硅改性苯丙乳液24份；氰酸酯环氧树脂共聚物20份；聚乙烯醇缩丁醛27份；聚丙烯23份；单硬脂酸甘油单酯11份；云母粉17份；负离子添加剂13份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物11份；醋酸乙烯－乙烯共聚乳液11份；苯二甲酸二丁酯10份；纳米氢氧化镁8份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌18份；脂肪酸甘油酯8份；羟乙基纤维素4份；聚溴化苯乙烯3份；瓜尔胶4份；纤维素醚1-2份；2-苯基咪唑啉1份；聚乙烯醇2份；月桂酸1份；去离子水1500份。
制备方法同实施例1。
实施例3：
一种服装面料用抗菌阻燃涂料，包括以下重量份数的原料：聚羟丙基二甲基氯化铵36份；双酚A环氧树脂28份；有机硅改性苯丙乳液25份；氰酸酯环氧树脂共聚物19份；聚乙烯醇缩丁醛28份；聚丙烯25份；单硬脂酸甘油单酯10份；云母粉16份；负离子添加剂15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物14份；醋酸乙烯－乙烯共聚乳液12份；苯二甲酸二丁酯13份；纳米氢氧化镁7份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌19份；脂肪酸甘油酯6份；羟乙基纤维素5份；聚溴化苯乙烯2.5份；瓜尔胶4份；纤维素醚1份；2-苯基咪唑啉1份；聚乙烯醇3份；月桂酸1份；去离子水1500份。
制备方法同实施例1。
实施例4：
一种服装面料用抗菌阻燃涂料，包括以下重量份数的原料：聚羟丙基二甲基氯化铵33份；双酚A环氧树脂26份；有机硅改性苯丙乳液25份；氰酸酯环氧树脂共聚物21份；聚乙烯醇缩丁醛29份；聚丙烯23份；单硬脂酸甘油单酯13份；云母粉20份；负离子添加剂15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物14份；醋酸乙烯－乙烯共聚乳液13份；苯二甲酸二丁酯14份；纳米氢氧化镁9份；纳米氢氧化铝7份；二正丁基二硫代氨基甲酸锌16份；脂肪酸甘油酯7份；羟乙基纤维素3份；聚溴化苯乙烯2份；瓜尔胶3份；纤维素醚1份；2-苯基咪唑啉1.5份；聚乙烯醇3份；月桂酸2份；去离子水1300份。
制备方法同实施例1。
实施例5：
一种服装面料用抗菌阻燃涂料，包括以下重量份数的原料：聚羟丙基二甲基氯化铵35份；双酚A环氧树脂28份；有机硅改性苯丙乳液23份；氰酸酯环氧树脂共聚物18份；聚乙烯醇缩丁醛27份；聚丙烯24份；单硬脂酸甘油单酯11份；云母粉18份；负离子添加剂13份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物12份；醋酸乙烯－乙烯共聚乳液12份；苯二甲酸二丁酯14份；纳米氢氧化镁9份；纳米氢氧化铝6份；二正丁基二硫代氨基甲酸锌15份；脂肪酸甘油酯5份；羟乙基纤维素3份；聚溴化苯乙烯2份；瓜尔胶4份；纤维素醚1.5份；2-苯基咪唑啉1份；聚乙烯醇2.5份；月桂酸2份；去离子水1400-1500份。
制备方法同实施例1。
对比例1：
浙江某公司制作的服装面料用抗菌阻燃涂料，由以下质量份数的组分组成：聚丙烯酸22份、海藻酸钠糊24份、聚乙二醇酯20份、过硼酸钠24份、聚异戊二烯20份、聚对苯二甲酸乙二醇酯24份、硫酸基甜菜碱20份、四正丙基锆酸酯26份、聚磷酸铵20份、辛酸甘油酯24份、双十八烷基二甲基氯化铵20份、聚四氟乙烯微粉24份、二正丁基二硫代氨基甲酸锌20份、巴西棕榈蜡24份、对羟基苯甲酸丁酯20份、脱氢醋酸钠24份、氢氧化镁20份、百菌清24份、脂肪酸酰胺20份、椰子油脂肪酸24份、纳米磷酸锆载银抗菌剂20份、吡啶硫酮铜24份、三聚氰胺氰尿酸盐20份、水1000份。
针对实施例1-5的产品和对比例1中产品进行性能测量，所测得的数据如表1所示。
检测项目 实施例1 实施例2 实施例3 实施例4 实施例5 对比例1
防火阻燃级别 V-0 V-0 V-0 V-0 V-0 V-1
湿度大于60％腐蚀率，25℃ 4.10％ 4.50％ 4.20％ 4.20％ 4.30％ 7.10％
pH＝3.5酸环境腐蚀率 5.50％ 6.10％ 5.90％ 5.80％ 5.70％ 9.30％
pH＝8.5碱环境腐蚀率 4.50％ 4.10％ 4.60％ 4.40％ 4.30％ 8.30％
大肠杆菌霉菌存活率 2.50％ 2.90％ 3.10％ 2.40％ 2.70％ 9.10％
黑曲霉存活率 3.10％ 3.30％ 3.40％ 3.20％ 3.10％ 9.70％
耐冲击性/(kg·cm) 53 51 51 53 52 39
附着力 1 1 1 1 1 2
铅笔硬度测试 3H 3H 3H 3H 3H 2H
最后应说明的是：以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。

Claims (10)

1.一种服装面料用抗菌阻燃涂料，其特征在于，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32～36份；双酚A环氧树脂25-28份；有机硅改性苯丙乳液23-25份；氰酸酯环氧树脂共聚物18-22份；聚乙烯醇缩丁醛27-30份；聚丙烯22-25份；单硬脂酸甘油单酯10-13份；云母粉16-20份；负离子添加剂13-15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物11-15份；醋酸乙烯－乙烯共聚乳液11-13份；苯二甲酸二丁酯10-16份；纳米氢氧化镁7-9份；纳米氢氧化铝5-7份；二正丁基二硫代氨基甲酸锌15-19份；脂肪酸甘油酯5-8份；羟乙基纤维素3-6份；聚溴化苯乙烯2-3份；瓜尔胶3-5份；纤维素醚1-2份；2-苯基咪唑啉1-2份；聚乙烯醇2-3份；月桂酸1-2份；去离子水1200-1500份。
2.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32份；双酚A环氧树脂25份；有机硅改性苯丙乳液23份；氰酸酯环氧树脂共聚物22份；聚乙烯醇缩丁醛30份；聚丙烯22份；单硬脂酸甘油单酯12份；云母粉18份；负离子添加剂14份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物15份；醋酸乙烯－乙烯共聚乳液13份；苯二甲酸二丁酯16份；纳米氢氧化镁8份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌15份；脂肪酸甘油酯5份；羟乙基纤维素6份；聚溴化苯乙烯2份；瓜尔胶5份；纤维素醚1份；2-苯基咪唑啉2份；聚乙烯醇2份；月桂酸1份；去离子水1200份。
3.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于，包括以下重量份数的原料：聚羟丙基二甲基氯化铵32～36份；双酚A环氧树脂27份；有机硅改性苯丙乳液24份；氰酸酯环氧树脂共聚物20份；聚乙烯醇缩丁醛27份；聚丙烯23份；单硬脂酸甘油单酯11份；云母粉17份；负离子添加剂13份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物11份；醋酸乙烯－乙烯共聚乳液11份；苯二甲酸二丁酯10份；纳米氢氧化镁8份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌18份；脂肪酸甘油酯8份；羟乙基纤维素4份；聚溴化苯乙烯3份；瓜尔胶4份；纤维素醚1-2份；2-苯基咪唑啉1份；聚乙烯醇2份；月桂酸1份；去离子水1500份。
4.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于，包括以下重量份数的原料：聚羟丙基二甲基氯化铵36份；双酚A环氧树脂28份；有机硅改性苯丙乳液25份；氰酸酯环氧树脂共聚物19份；聚乙烯醇缩丁醛28份；聚丙烯25份；单硬脂酸甘油单酯10份；云母粉16份；负离子添加剂15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物14份；醋酸乙烯－乙烯共聚乳液12份；苯二甲酸二丁酯13份；纳米氢氧化镁7份；纳米氢氧化铝5份；二正丁基二硫代氨基甲酸锌19份；脂肪酸甘油酯6份；羟乙基纤维素5份；聚溴化苯乙烯2.5份；瓜尔胶4份；纤维素醚1份；2-苯基咪唑啉1份；聚乙烯醇3份；月桂酸1份；去离子水1500份。
5.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于，包括以下重量份数的原料：聚羟丙基二甲基氯化铵33份；双酚A环氧树脂26份；有机硅改性苯丙乳液25份；氰酸酯环氧树脂共聚物21份；聚乙烯醇缩丁醛29份；聚丙烯23份；单硬脂酸甘油单酯13份；云母粉20份；负离子添加剂15份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物14份；醋酸乙烯－乙烯共聚乳液13份；苯二甲酸二丁酯14份；纳米氢氧化镁9份；纳米氢氧化铝7份；二正丁基二硫代氨基甲酸锌16份；脂肪酸甘油酯7份；羟乙基纤维素3份；聚溴化苯乙烯2份；瓜尔胶3份；纤维素醚1份；2-苯基咪唑啉1.5份；聚乙烯醇3份；月桂酸2份；去离子水1300份。
6.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于，包括以下重量份数的原料：聚羟丙基二甲基氯化铵35份；双酚A环氧树脂28份；有机硅改性苯丙乳液23份；氰酸酯环氧树脂共聚物18份；聚乙烯醇缩丁醛27份；聚丙烯24份；单硬脂酸甘油单酯11份；云母粉18份；负离子添加剂13份；丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物12份；醋酸乙烯－乙烯共聚乳液12份；苯二甲酸二丁酯14份；纳米氢氧化镁9份；纳米氢氧化铝6份；二正丁基二硫代氨基甲酸锌15份；脂肪酸甘油酯5份；羟乙基纤维素3份；聚溴化苯乙烯2份；瓜尔胶4份；纤维素醚1.5份；2-苯基咪唑啉1份；聚乙烯醇2.5份；月桂酸2份；去离子水1400-1500份。
7.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于：所述纳米氢氧化镁的粒径为20-50nm。
8.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于：所述纳米氢氧化铝的粒径为30-40nm。
9.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于：所述负离子添加剂采用天然带电矿物质材料。
10.根据权利要求1所述的服装面料用抗菌阻燃涂料，其特征在于：所述丙烯酸酯-苯乙烯-醋酸乙烯三元共聚物中，按重量百分比计，丙烯酸酯占45％，苯乙烯占33％，醋酸乙烯占22％，共聚物的重均分子量为80000-100000，并且具有5mgKOH/g的羟基值，平均粒径为0.7-1μm。
CN201610128260.6A 2016-03-08 2016-03-08 一种服装面料用抗菌阻燃涂料 Pending CN105696346A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610128260.6A CN105696346A (zh) 2016-03-08 2016-03-08 一种服装面料用抗菌阻燃涂料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610128260.6A CN105696346A (zh) 2016-03-08 2016-03-08 一种服装面料用抗菌阻燃涂料

Publications (1)

Publication Number Publication Date
CN105696346A true CN105696346A (zh) 2016-06-22

Family

ID=56220948

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610128260.6A Pending CN105696346A (zh) 2016-03-08 2016-03-08 一种服装面料用抗菌阻燃涂料

Country Status (1)

Country Link
CN (1) CN105696346A (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106192372A (zh) * 2016-07-11 2016-12-07 青岛银世达塑胶有限公司 一种新型防护手套
CN106758140A (zh) * 2017-01-20 2017-05-31 青岛瑞诚铭机械设计有限公司 一种运动护膝中防护外筒用制作布料
CN109554923A (zh) * 2018-11-23 2019-04-02 山东如意科技集团有限公司 一种数码印花面料阻燃抗菌涂料

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104695245A (zh) * 2013-12-09 2015-06-10 黄慧娟 一种提花涂料
CN104774514A (zh) * 2015-04-29 2015-07-15 富思特新材料科技发展股份有限公司 能吸附和分解空气中甲醛的低挥发性有机化合物净味涂料及其制备方法
CN105220846A (zh) * 2015-08-14 2016-01-06 刘仕帝 一种建筑物防火涂料的涂布工艺
CN105256574A (zh) * 2015-11-25 2016-01-20 绍兴市柯桥区原色纺织科技有限公司 一种服装面料用抗菌阻燃涂料
CN105297444A (zh) * 2015-11-17 2016-02-03 温州职业技术学院 一种抗菌阻燃服装涂料

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104695245A (zh) * 2013-12-09 2015-06-10 黄慧娟 一种提花涂料
CN104774514A (zh) * 2015-04-29 2015-07-15 富思特新材料科技发展股份有限公司 能吸附和分解空气中甲醛的低挥发性有机化合物净味涂料及其制备方法
CN105220846A (zh) * 2015-08-14 2016-01-06 刘仕帝 一种建筑物防火涂料的涂布工艺
CN105297444A (zh) * 2015-11-17 2016-02-03 温州职业技术学院 一种抗菌阻燃服装涂料
CN105256574A (zh) * 2015-11-25 2016-01-20 绍兴市柯桥区原色纺织科技有限公司 一种服装面料用抗菌阻燃涂料

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106192372A (zh) * 2016-07-11 2016-12-07 青岛银世达塑胶有限公司 一种新型防护手套
CN106758140A (zh) * 2017-01-20 2017-05-31 青岛瑞诚铭机械设计有限公司 一种运动护膝中防护外筒用制作布料
CN109554923A (zh) * 2018-11-23 2019-04-02 山东如意科技集团有限公司 一种数码印花面料阻燃抗菌涂料

Similar Documents

Publication Publication Date Title
CN105696346A (zh) 一种服装面料用抗菌阻燃涂料
CN104194572B (zh) 一种耐腐蚀阻燃涂料
CN103897571A (zh) 一种水性双组份木器清漆及其用途
CN104371382B (zh) 一种水性油漆用发光铝颜料及其制备方法
CN105256572A (zh) 一种无卤阻燃涂层胶及其制备方法
CN105421064A (zh) 一种纺织面料用阻燃抗菌涂层
CN104877251A (zh) 一种环保低烟无铅聚氯乙烯电工管及其制备方法
CN104005236B (zh) 窗帘用遮光涂层及其使用方法
CN108441090A (zh) 卷材涂料及其制备方法
CN101263166B (zh) 制备基于氯乙烯的共聚物的方法以及包含使用该方法制备的基于氯乙烯的共聚物的氯乙烯增塑溶胶组合物
CN104892821A (zh) 醋酸乙烯酯与叔碳酸乙烯酯共聚乳液的研制方法
CN110467836A (zh) 一种绘画颜料的配方及其制备方法
CN106118284A (zh) 水性纳米复合涂料及其制备方法
CN104449221A (zh) 一种高附着阻燃耐腐涂料
CN105780491A (zh) 一种服装面料用抗菌阻燃涂料的制备方法
CN104403451A (zh) 一种环保型防火地板涂料及其制备方法
CN103834329B (zh) 一种无卤环保胶黏剂及其制备方法
CN105482166A (zh) 无毒环保稳定剂助剂及其制备方法
CN109423101A (zh) 一种聚酰胺蜡防沉剂
CN104046148A (zh) 一种木制家具用防火涂料及其制备方法
CN104559113A (zh) 消光pc/abs复合材料
CN104263130A (zh) 一种弹性防水涂料
CN102443310A (zh) 一种用于内墙消除刷痕增加细腻度的涂料
CN101864235A (zh) 一种外墙涂料的制备方法
CN104877494A (zh) 一种添加聚四氟乙烯超细粉的阻燃型外墙乳胶涂料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160622

RJ01 Rejection of invention patent application after publication