CN105421064A - 一种纺织面料用阻燃抗菌涂层 - Google Patents

一种纺织面料用阻燃抗菌涂层 Download PDF

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CN105421064A
CN105421064A CN201510966463.8A CN201510966463A CN105421064A CN 105421064 A CN105421064 A CN 105421064A CN 201510966463 A CN201510966463 A CN 201510966463A CN 105421064 A CN105421064 A CN 105421064A
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parts
flame
mass fraction
face fabric
weaving face
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马建锋
陈丽丽
周苗
言丽清
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Shaoxing Inkjet Digital Printing Co Ltd
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Abstract

本发明涉及一种纺织面料用阻燃抗菌涂层，由以下质量份数的组分组成：羟乙基纤维素22～26份、氯磺化聚乙烯24～28份、纳米氧化锌20～24份、丙烯酸甲酯24～28份、羟基环己基苯基甲酮20～24份、三聚磷酸钠24～28份、钛白粉20～24份、二异氰酸甲苯酯26～30份、聚乙烯醇缩丁醛20～24份、苯代氨基树脂24～28份、硬脂酸甘油酯20～24份、聚二甲基硅氧烷24～28份、丙烯酸乳液20～24份、巴西棕榈蜡24～28份、钼酸铵20～24份、柠檬酸钠24～28份、碳酸钙粉末20～24份、百菌清24～28份、椰子油脂肪酸24～28份、纳米磷酸锆载银抗菌剂20～24份、水1000～2000份。本品具有较为优越的阻燃、耐酸碱、抗菌性能，适合在面料领域使用。

Description

一种纺织面料用阻燃抗菌涂层
技术领域
本发明涉及一种纺织面料用阻燃抗菌涂层，属于面料技术领域。
背景技术
在纺织面料大世界里，纺织面料的面料五花八门，日新月异。但是从总体上来讲，优质、高档的面料，大都具有穿著舒适、吸汗透气、悬垂挺括、视觉高贵、触觉柔软等几个方面的特点。由于户外环境复杂多变，为抵御恶劣环境对人体的伤害，保护身体热量不被散失以及快速排出运动时所产生的汗水，在登山、攀岩及其他户外运动时穿着，以适应野外各种天气变化对人体所带来的影响的纺织面料叫做户外服。因此，需要改进现有面料的材料，使面料具有抗菌、阻燃等优异的性能。
发明内容
本发明的目的在于提供一种纺织面料用阻燃抗菌涂层，以便更好地实现纺织面料用阻燃抗菌涂层的功能。
为了实现上述目的，本发明的技术方案如下。
一种纺织面料用阻燃抗菌涂层，由以下质量份数的组分组成：羟乙基纤维素22～26份、氯磺化聚乙烯24～28份、纳米氧化锌20～24份、丙烯酸甲酯24～28份、羟基环己基苯基甲酮20～24份、三聚磷酸钠24～28份、钛白粉20～24份、二异氰酸甲苯酯26～30份、聚乙烯醇缩丁醛20～24份、苯代氨基树脂24～28份、硬脂酸甘油酯20～24份、聚二甲基硅氧烷24～28份、丙烯酸乳液20～24份、巴西棕榈蜡24～28份、钼酸铵20～24份、柠檬酸钠24～28份、碳酸钙粉末20～24份、百菌清24～28份、正硅酸乙酯20～24份、椰子油脂肪酸24～28份、纳米磷酸锆载银抗菌剂20～24份、蓖麻油24～28份、铬酸锌20～24份、水1000～2000份。
进一步地，上述纺织面料用阻燃抗菌涂层，由以下质量份数的组分组成：羟乙基纤维素22份、氯磺化聚乙烯24份、纳米氧化锌20份、丙烯酸甲酯24份、羟基环己基苯基甲酮20份、三聚磷酸钠24份、钛白粉20份、二异氰酸甲苯酯26份、聚乙烯醇缩丁醛20份、苯代氨基树脂24份、硬脂酸甘油酯20份、聚二甲基硅氧烷24份、丙烯酸乳液20份、巴西棕榈蜡24份、钼酸铵20份、柠檬酸钠24份、碳酸钙粉末20份、百菌清24份、正硅酸乙酯20份、椰子油脂肪酸24份、纳米磷酸锆载银抗菌剂20份、蓖麻油24份、铬酸锌20份、水1000份。
进一步地，上述纺织面料用阻燃抗菌涂层，由以下质量份数的组分组成：羟乙基纤维素24份、氯磺化聚乙烯26份、纳米氧化锌22份、丙烯酸甲酯26份、羟基环己基苯基甲酮22份、三聚磷酸钠26份、钛白粉22份、二异氰酸甲苯酯28份、聚乙烯醇缩丁醛22份、苯代氨基树脂26份、硬脂酸甘油酯22份、聚二甲基硅氧烷26份、丙烯酸乳液22份、巴西棕榈蜡26份、钼酸铵22份、柠檬酸钠26份、碳酸钙粉末22份、百菌清26份、正硅酸乙酯22份、椰子油脂肪酸26份、纳米磷酸锆载银抗菌剂22份、蓖麻油26份、铬酸锌22份、水1500份。
进一步地，上述纺织面料用阻燃抗菌涂层，由以下质量份数的组分组成：羟乙基纤维素26份、氯磺化聚乙烯28份、纳米氧化锌24份、丙烯酸甲酯28份、羟基环己基苯基甲酮24份、三聚磷酸钠28份、钛白粉24份、二异氰酸甲苯酯30份、聚乙烯醇缩丁醛24份、苯代氨基树脂28份、硬脂酸甘油酯24份、聚二甲基硅氧烷28份、丙烯酸乳液24份、巴西棕榈蜡28份、钼酸铵24份、柠檬酸钠28份、碳酸钙粉末24份、百菌清28份、正硅酸乙酯24份、椰子油脂肪酸28份、纳米磷酸锆载银抗菌剂24份、蓖麻油28份、铬酸锌24份、水2000份。
进一步地，上述纺织面料用阻燃抗菌涂层制备方法步骤如下：
（1）将所述质量份数的羟乙基纤维素、氯磺化聚乙烯、纳米氧化锌、丙烯酸甲酯、羟基环己基苯基甲酮、三聚磷酸钠、钛白粉、二异氰酸甲苯酯、聚乙烯醇缩丁醛、苯代氨基树脂、硬脂酸甘油酯、聚二甲基硅氧烷、巴西棕榈蜡、钼酸铵、柠檬酸钠、碳酸钙粉末、百菌清、正硅酸乙酯、椰子油脂肪酸、蓖麻油、铬酸锌加入上述质量份数的水中，超声高速分散，超声波频率为20～40KHz，分散速度5000～5400r/min左右，分散时间为30～60min；
（2）加入所述质量份数的丙烯酸乳液，超声高速分散，超声波频率为20～35KHz，分散速度4800～5200r/min左右，分散时间为30～50min；
（3）加入所述质量份数的纳米磷酸锆载银抗菌剂，超声高速分散，超声波频率为20～30KHz，分散速度4600～4800r/min左右，分散时间为20～40min；混合均匀后制得本品。
该发明的有益效果在于：本纺织面料用阻燃抗菌涂层制备工艺方法简单，所制备的产品具有较为优越的阻燃、耐酸碱、抗菌性能，适合在面料领域使用，改善了产品性能，加工使用方便。
具体实施方式
下面结合实施例对本发明的具体实施方式进行描述，以便更好的理解本发明。
实施例1
本实施例中的纺织面料用阻燃抗菌涂层，由以下质量份数的组分组成：羟乙基纤维素22份、氯磺化聚乙烯24份、纳米氧化锌20份、丙烯酸甲酯24份、羟基环己基苯基甲酮20份、三聚磷酸钠24份、钛白粉20份、二异氰酸甲苯酯26份、聚乙烯醇缩丁醛20份、苯代氨基树脂24份、硬脂酸甘油酯20份、聚二甲基硅氧烷24份、丙烯酸乳液20份、巴西棕榈蜡24份、钼酸铵20份、柠檬酸钠24份、碳酸钙粉末20份、百菌清24份、正硅酸乙酯20份、椰子油脂肪酸24份、纳米磷酸锆载银抗菌剂20份、蓖麻油24份、铬酸锌20份、水1000份。
上述纺织面料用阻燃抗菌涂层制备方法步骤如下：
（1）将所述质量份数的羟乙基纤维素、氯磺化聚乙烯、纳米氧化锌、丙烯酸甲酯、羟基环己基苯基甲酮、三聚磷酸钠、钛白粉、二异氰酸甲苯酯、聚乙烯醇缩丁醛、苯代氨基树脂、硬脂酸甘油酯、聚二甲基硅氧烷、巴西棕榈蜡、钼酸铵、柠檬酸钠、碳酸钙粉末、百菌清、正硅酸乙酯、椰子油脂肪酸、蓖麻油、铬酸锌加入上述质量份数的水中，超声高速分散，超声波频率为20kHz，分散速度5400r/min左右，分散时间为60min；
（2）加入所述质量份数的丙烯酸乳液，超声高速分散，超声波频率为20kHz，分散速度5200r/min左右，分散时间为50min；
（3）加入所述质量份数的纳米磷酸锆载银抗菌剂，超声高速分散，超声波频率为20kHz，分散速度4800r/min左右，分散时间为40min；混合均匀后制得本品。
实施例2
本实施例中的纺织面料用阻燃抗菌涂层，由以下质量份数的组分组成：羟乙基纤维素24份、氯磺化聚乙烯26份、纳米氧化锌22份、丙烯酸甲酯26份、羟基环己基苯基甲酮22份、三聚磷酸钠26份、钛白粉22份、二异氰酸甲苯酯28份、聚乙烯醇缩丁醛22份、苯代氨基树脂26份、硬脂酸甘油酯22份、聚二甲基硅氧烷26份、丙烯酸乳液22份、巴西棕榈蜡26份、钼酸铵22份、柠檬酸钠26份、碳酸钙粉末22份、百菌清26份、正硅酸乙酯22份、椰子油脂肪酸26份、纳米磷酸锆载银抗菌剂22份、蓖麻油26份、铬酸锌22份、水1500份。
上述纺织面料用阻燃抗菌涂层制备方法步骤如下：
（1）将所述质量份数的羟乙基纤维素、氯磺化聚乙烯、纳米氧化锌、丙烯酸甲酯、羟基环己基苯基甲酮、三聚磷酸钠、钛白粉、二异氰酸甲苯酯、聚乙烯醇缩丁醛、苯代氨基树脂、硬脂酸甘油酯、聚二甲基硅氧烷、巴西棕榈蜡、钼酸铵、柠檬酸钠、碳酸钙粉末、百菌清、正硅酸乙酯、椰子油脂肪酸、蓖麻油、铬酸锌加入上述质量份数的水中，超声高速分散，超声波频率为30kHz，分散速度5200r/min左右，分散时间为45min；
（2）加入所述质量份数的丙烯酸乳液，超声高速分散，超声波频率为27kHz，分散速度5000r/min左右，分散时间为40min；
（3）加入所述质量份数的纳米磷酸锆载银抗菌剂，超声高速分散，超声波频率为25kHz，分散速度4700r/min左右，分散时间为30min；混合均匀后制得本品。
实施例3
本实施例中的纺织面料用阻燃抗菌涂层，由以下质量份数的组分组成：羟乙基纤维素26份、氯磺化聚乙烯28份、纳米氧化锌24份、丙烯酸甲酯28份、羟基环己基苯基甲酮24份、三聚磷酸钠28份、钛白粉24份、二异氰酸甲苯酯30份、聚乙烯醇缩丁醛24份、苯代氨基树脂28份、硬脂酸甘油酯24份、聚二甲基硅氧烷28份、丙烯酸乳液24份、巴西棕榈蜡28份、钼酸铵24份、柠檬酸钠28份、碳酸钙粉末24份、百菌清28份、正硅酸乙酯24份、椰子油脂肪酸28份、纳米磷酸锆载银抗菌剂24份、蓖麻油28份、铬酸锌24份、水2000份。
上述纺织面料用阻燃抗菌涂层制备方法步骤如下：
（1）将所述质量份数的羟乙基纤维素、氯磺化聚乙烯、纳米氧化锌、丙烯酸甲酯、羟基环己基苯基甲酮、三聚磷酸钠、钛白粉、二异氰酸甲苯酯、聚乙烯醇缩丁醛、苯代氨基树脂、硬脂酸甘油酯、聚二甲基硅氧烷、巴西棕榈蜡、钼酸铵、柠檬酸钠、碳酸钙粉末、百菌清、正硅酸乙酯、椰子油脂肪酸、蓖麻油、铬酸锌加入上述质量份数的水中，超声高速分散，超声波频率为40kHz，分散速度5000r/min，分散时间为30min；
（2）加入所述质量份数的丙烯酸乳液，超声高速分散，超声波频率为35kHz，分散速度4800r/min，分散时间为30min；
（3）加入所述质量份数的纳米磷酸锆载银抗菌剂，超声高速分散，超声波频率为30kHz，分散速度4600r/min左右，分散时间为20min；混合均匀后制得本品。
针对实施例1、实施例2和实施例3中的产品和某市售产品进行性能测量，所测得的数据如表1所示。防火阻燃等级测试采用UL94标准。
表1性能测试结果
可见，本发明材料具有较好的耐腐蚀、防火阻燃、抗菌性能。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (5)

1.一种纺织面料用阻燃抗菌涂层，其特征在于：由以下质量份数的组分组成：羟乙基纤维素22～26份、氯磺化聚乙烯24～28份、纳米氧化锌20～24份、丙烯酸甲酯24～28份、羟基环己基苯基甲酮20～24份、三聚磷酸钠24～28份、钛白粉20～24份、二异氰酸甲苯酯26～30份、聚乙烯醇缩丁醛20～24份、苯代氨基树脂24～28份、硬脂酸甘油酯20～24份、聚二甲基硅氧烷24～28份、丙烯酸乳液20～24份、巴西棕榈蜡24～28份、钼酸铵20～24份、柠檬酸钠24～28份、碳酸钙粉末20～24份、百菌清24～28份、正硅酸乙酯20～24份、椰子油脂肪酸24～28份、纳米磷酸锆载银抗菌剂20～24份、蓖麻油24～28份、铬酸锌20～24份、水1000～2000份。
2.根据权利要求1所述的纺织面料用阻燃抗菌涂层，其特征在于：所述纺织面料用阻燃抗菌涂层由以下质量份数的组分组成：羟乙基纤维素22份、氯磺化聚乙烯24份、纳米氧化锌20份、丙烯酸甲酯24份、羟基环己基苯基甲酮20份、三聚磷酸钠24份、钛白粉20份、二异氰酸甲苯酯26份、聚乙烯醇缩丁醛20份、苯代氨基树脂24份、硬脂酸甘油酯20份、聚二甲基硅氧烷24份、丙烯酸乳液20份、巴西棕榈蜡24份、钼酸铵20份、柠檬酸钠24份、碳酸钙粉末20份、百菌清24份、正硅酸乙酯20份、椰子油脂肪酸24份、纳米磷酸锆载银抗菌剂20份、蓖麻油24份、铬酸锌20份、水1000份。
3.根据权利要求1所述的纺织面料用阻燃抗菌涂层，其特征在于：所述纺织面料用阻燃抗菌涂层由以下质量份数的组分组成：羟乙基纤维素24份、氯磺化聚乙烯26份、纳米氧化锌22份、丙烯酸甲酯26份、羟基环己基苯基甲酮22份、三聚磷酸钠26份、钛白粉22份、二异氰酸甲苯酯28份、聚乙烯醇缩丁醛22份、苯代氨基树脂26份、硬脂酸甘油酯22份、聚二甲基硅氧烷26份、丙烯酸乳液22份、巴西棕榈蜡26份、钼酸铵22份、柠檬酸钠26份、碳酸钙粉末22份、百菌清26份、正硅酸乙酯22份、椰子油脂肪酸26份、纳米磷酸锆载银抗菌剂22份、蓖麻油26份、铬酸锌22份、水1500份。
4.根据权利要求1所述的纺织面料用阻燃抗菌涂层，其特征在于：所述纺织面料用阻燃抗菌涂层由以下质量份数的组分组成：羟乙基纤维素26份、氯磺化聚乙烯28份、纳米氧化锌24份、丙烯酸甲酯28份、羟基环己基苯基甲酮24份、三聚磷酸钠28份、钛白粉24份、二异氰酸甲苯酯30份、聚乙烯醇缩丁醛24份、苯代氨基树脂28份、硬脂酸甘油酯24份、聚二甲基硅氧烷28份、丙烯酸乳液24份、巴西棕榈蜡28份、钼酸铵24份、柠檬酸钠28份、碳酸钙粉末24份、百菌清28份、正硅酸乙酯24份、椰子油脂肪酸28份、纳米磷酸锆载银抗菌剂24份、蓖麻油28份、铬酸锌24份、水2000份。
5.根据权利要求1或4所述的纺织面料用阻燃抗菌涂层，其特征在于：所述纺织面料用阻燃抗菌涂层制备方法步骤如下：
（1）将所述质量份数的羟乙基纤维素、氯磺化聚乙烯、纳米氧化锌、丙烯酸甲酯、羟基环己基苯基甲酮、三聚磷酸钠、钛白粉、二异氰酸甲苯酯、聚乙烯醇缩丁醛、苯代氨基树脂、硬脂酸甘油酯、聚二甲基硅氧烷、巴西棕榈蜡、钼酸铵、柠檬酸钠、碳酸钙粉末、百菌清、正硅酸乙酯、椰子油脂肪酸、蓖麻油、铬酸锌加入上述质量份数的水中，超声高速分散，超声波频率为20～40KHz，分散速度5000～5400r/min左右，分散时间为30～60min；
（2）加入所述质量份数的丙烯酸乳液，超声高速分散，超声波频率为20～35KHz，分散速度4800～5200r/min左右，分散时间为30～50min；
（3）加入所述质量份数的纳米磷酸锆载银抗菌剂，超声高速分散，超声波频率为20～30KHz，分散速度4600～4800r/min左右，分散时间为20～40min；混合均匀后制得本品。
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