CN106753076A - A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof - Google Patents
A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN106753076A CN106753076A CN201510829820.6A CN201510829820A CN106753076A CN 106753076 A CN106753076 A CN 106753076A CN 201510829820 A CN201510829820 A CN 201510829820A CN 106753076 A CN106753076 A CN 106753076A
- Authority
- CN
- China
- Prior art keywords
- environment
- glue material
- parts
- friendlywallpaper
- wallpaper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paper (AREA)
Abstract
The present invention relates to a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof, described Environment-friendlywallpaper wallpaper glue material includes the component of following parts by weight：35~50 parts of mixed with resin emulsion, 0.8~1.5 part of powder, 3~5 parts of auxiliary agent, 45~60 parts of water, Environment-friendlywallpaper wallpaper glue material keeps stirring at low speed by first adding water in stirred tank, it is subsequently adding part of auxiliary to be well mixed, adds powder, and improving stirred tank rotating speed disperses it, after reducing stirred tank rotating speed again, mixed with resin emulsion and another part auxiliary agent are sequentially added, addition thickener is adjusted to required viscosity, that is, Environment-friendlywallpaper wallpaper glue material is obtained.Compared with prior art, Environment-friendlywallpaper wallpaper glue material of the invention has excellent water resistance, stain resistant, adhesive property and environmental-protecting performance, additionally, preparation process is simple, cost of material be low, equipment is easy to get.
Description
Technical field
The present invention relates to adhesive field, more particularly, to a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and
Its preparation method.
Background technology
With the improvement of people ' s living standards, the finishing of house decoration and public place is also more and more, for
The stickup of wallpaper and hobby are also and kind is also more and more.But the overwhelming majority is still using glue and glue at present
Powder carrys out adhesive material, and containing substantial amounts of formaldehyde and benzene etc. in conventional glue, its volatility is stronger, causes finishing
The chemical substance in air is increased after completion, especially formaldehyde etc. is even more exceeded does not know how many times.Thus develop
Go out turns into current adhesive field without the environment-friendly adhesive of payment of duty, the chemical substance without high volatilities such as formaldehyde
Study hotspot.
Chinese patent 201310003337.3 discloses a kind of bi-component acrylic ester structure adhesive, by component A
Constituted with B component, according to mass fraction 1:1 is matched, and described component A presses mass fraction by following original
Material composition：45 parts~75 parts of acrylic ester monomer, 15 parts~45 parts of toughened resin, 0.5 part of initiator
~10 parts, 0.01 part~1 part of stabilizer, 0.1~5 part of coupling agent, 0.5~10 part of thixotropic agent；Described B groups
Divide and be made up of following raw material by mass fraction：45 parts~75 parts of acrylic ester monomer, toughened resin 15 parts~45
Part, 0.5 part~10 parts of accelerator, 0.01 part~1 part of stabilizer, 0.1~5 part of coupling agent, thixotropic agent 0.5~10
Part.Although the adhesive of the patent has preferable adhesive property and storage stability, the cost of its each raw material
Higher, preparation technology is relatively cumbersome, while its acrylic ester monomer for using is in terms of water resistance and stain resistant
Shortcomings, are not suitable for being bonded wallpaper.
The content of the invention
The purpose of the present invention is exactly to provide a kind of for pasting wall for the defect for overcoming above-mentioned prior art to exist
Environment-friendlywallpaper wallpaper glue material of paper and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, including following parts by weight component：
Described mixed with resin emulsion is by pure-acrylic emulsion and the modified silicone acrylic emulsion (3~4) in mass ratio of being modified:1 mixing
Form.
Described modified pure-acrylic emulsion is made up of following steps：At 30~60 DEG C, based on 100g pure-acrylic emulsions,
1.0~1.8g silane couplers are added toward pure-acrylic emulsion, 0.2~0.4g initiators, stirring mixing is added
After 30~60min；
Described modified silicone acrylic emulsion is made up of following steps：At 40~60 DEG C, based on 100g pure-acrylic emulsions,
1~2g plasticizer, 20~40min of stirring mixing are added toward pure-acrylic emulsion.
The solid content of described pure-acrylic emulsion is 35%, and emulsion particle diameter is 0.1~0.2 μm, and emulsion viscosity is
200~2000, testing conditions are：3#.12rpm, 25 DEG C (i.e. at 25 DEG C, the 3# using resin viscosity instrument turns
The registration that son is measured with the rotating speed of 12rpm)；
Described initiator is ammonium persulfate, and described silane coupler is silane coupler KH-560；
The solid content of described silicone acrylic emulsion is 47%, and emulsion particle diameter is 0.1~0.2 μm, and silicone content is 5%, breast
Fluid viscosity is 1000~4000, and testing conditions are：3#.30rpm, 25 DEG C (i.e. at 25 DEG C, using resin viscosity
The registration that the 3# rotors of instrument are measured with the rotating speed of 30rpm).
Described powder is hydroxyethyl cellulose.
Described auxiliary agent includes the component of following parts by weight：2~4 parts of coalescents, 0.1~0.3 part of nertralizer,
0.1~0.4 part of bactericide, 0.2~0.5 part of defoamer, 0.5~1.5 part of thickener.
Described coalescents are alcohol ester 12, and described nertralizer is AMP-95 neutralizing amines, described defoamer
It is dimethyl silicone polymer, described alkali swollen thickener is association type alkali swollen thickener DR-72.
A kind of preparation method of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, comprises the following steps：
(1) 45~60 parts of water are weighed by weight to be placed in stirred tank, keep stirring at low speed, and film forming is helped
The defoamer of 2~4 parts of agent, 0.1~0.3 part of nertralizer and 1/2 dosage puts into stirred tank successively, stirs,
(2) weigh again during 0.8~1.5 part of powder adds stirred tank, and improve stirred tank rotating speed, high-speed stirred makes powder
Body is uniformly dispersed；
(3) reduce stirred tank rotating speed and add 35~50 parts of mixed with resin emulsions, uniform rear addition to be mixed is remaining
0.1~0.4 part of the defoamer and bactericide of 1/2 dosage, are slow added into 0.5~1.5 part of regulation viscosity of thickener, i.e.,
Obtain Environment-friendlywallpaper wallpaper glue material；
Above-mentioned steps are carried out at normal temperatures and pressures.
The rotating speed of the stirring at low speed described in step (1) is 300~600 revs/min；
The rotating speed of the high-speed stirred described in step (2) is 1200~1600 revs/min, and mixing time is 15~60min；
The rotating speed of stirred tank is down to 500~600 revs/min in step (3).
The mixed with resin emulsion that the present invention is used is the mixture of be modified pure-acrylic emulsion and modified silicone acrylic emulsion, is being applied
In material forming process, the silicone acrylic emulsion composition that is modified can form one layer of organic silicon structural membrane, the knot in coating layer surface
The hydrophobic angle of structure film is very big, and moisture is difficult in paint film surface dispersion, remains so as to permeate so that coating Rotating fields
It is difficult to be destroyed and lost adhesive property by hydrone, water resistance is greatly increased, additionally, modified silicone acrylic emulsion is by adding
Plus plasticizer reduces its glass transition temperature and film-forming temperature so that the film-forming temperature of silicone acrylic emulsion and pure-acrylic emulsion
Close, at 25 DEG C or so, the temperature in use requirement of coating is substantially reduced prepared by enter.Meanwhile, it is modified pure
Acrylic emulsion introduces polar group by adding silane coupler, increased dope layer to the viscous of wall and wallpaper etc.
Knot performance.
Compared with prior art, the present invention has advantages below：
1) excellent combination property：The knot of pure-acrylic emulsion and silicone acrylic emulsion in major ingredient mixed with resin emulsion of the invention
Structure is more similar, and compatibility is very well, uniform without agglomerate glue in last obtained coating, and combines both excellent
Point, with excellent adhesive property, water resistance and stain resistant etc., the even structure after paint solidification, stability
It is high；Additionally, the pH value in coating is moderate, the acid and alkali corrosion to metope and wallpaper is effectively avoided；
2) the with low cost, feature of environmental protection is good：The present invention is prepared using the raw material without toxic volatile substances such as formaldehyde
Form, for being bonded during wallpaper etc., the toxic volatile substance such as formaldehyde, Environmental Safety, additionally, main will not be produced
Raw emulsion is wanted to be easy to get, the consumption of expensive auxiliary agent is few, and whole preparation technology is prepared from normal temperatures and pressures,
Process is simple, required equipment, low production cost.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.
Auxiliary agent employed in following examples is：Coalescents use alcohol ester 12, propane diols BS-12, in
With agent AMP-95 neutralizing amines, bactericide FA-34, defoamer dimethyl silicone polymer, thickener is with forming
Mould assembly alkali swollen thickener DR-72, plasticizer tributyl phthalate, silane coupler silane coupler
KH550, initiator ammonium persulfate；Powder is hydroxyethyl cellulose HLB-55C.
Embodiment 1
A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, including following parts by weight component：Mixed with resin breast
35 parts of liquid, 0.8 part of powder, 2 parts of coalescents, 0.1 part of nertralizer, 0.2 part of bactericide, defoamer 0.4
Part, 0.5 part of thickener, 45 parts of water.Mixed with resin emulsion presses matter by modified pure-acrylic emulsion and modified silicone acrylic emulsion
Amount compares 3:1 mixes, and modified pure-acrylic emulsion is made up of following steps：At 30 DEG C, by pure third breasts of 100g
Liquid meter, 1.0g silane couplers are added toward pure-acrylic emulsion, add 0.2g initiators, stirring mixing 60min
Afterwards；Modified silicone acrylic emulsion is made up of following steps：It is past pure based on 100g pure-acrylic emulsions at 40 DEG C
1g plasticizer are added in acrylic emulsion, stirring mixes 20min, and the solid content of pure-acrylic emulsion is 35%, emulsion
Particle diameter is 0.1~0.2 μm, and emulsion viscosity is 200, and testing conditions are：3#.12rpm, 25 DEG C (i.e. at 25 DEG C,
The registration for using the 3# rotors of resin viscosity instrument to be measured with the rotating speed of 12rpm)；The solid content of silicone acrylic emulsion is 47%,
Emulsion particle diameter is 0.1~0.2 μm, and silicone content is 5%, and emulsion viscosity is 1000, and testing conditions are：3#.30rpm,
25 DEG C (i.e. at 25 DEG C, the registration for using the 3# rotors of resin viscosity instrument to be measured with the rotating speed of 30rpm).
A kind of preparation method of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, comprises the following steps：
(1) 45 parts of water are weighed by weight to be placed in stirred tank, keep 300 revs/min of stirring at low speed, and will
2 parts of coalescents, 0.1 part and 0.2 part defoamer of nertralizer put into stirred tank successively, stir,
(2) weigh again during 0.8 part of powder adds stirred tank, and improve stirred tank rotating speed to 1200 revs/min, at a high speed
Stirring 60min makes powder be uniformly dispersed；
(3) reduce stirred tank rotating speed to 500 revs/min and add 35 parts of mixed with resin emulsions, it is to be mixed it is uniform after
0.2 part remaining 0.2 part of defoamer and bactericide is added, 0.5 part of regulation viscosity of thickener is slow added into, i.e.,
Obtain Environment-friendlywallpaper wallpaper glue material；
Above-mentioned steps are carried out at normal temperatures and pressures.
Embodiment 2
A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, including following parts by weight component：Mixed with resin breast
50 parts of liquid, 1.5 parts of powder, 4 parts of coalescents, 0.2 part of nertralizer, 0.1 part of bactericide, defoamer 0.2
Part, 0.5 part of thickener, 60 parts of water.Mixed with resin emulsion presses matter by modified pure-acrylic emulsion and modified silicone acrylic emulsion
Amount compares 4:1 mixes, and modified pure-acrylic emulsion is made up of following steps：At 60 DEG C, by pure third breasts of 100g
Liquid meter, 1.8g silane couplers are added toward pure-acrylic emulsion, add 0.4g initiators, stirring mixing 30min
Afterwards；Modified silicone acrylic emulsion is made up of following steps：It is past pure based on 100g pure-acrylic emulsions at 60 DEG C
2g plasticizer are added in acrylic emulsion, stirring mixes 40min, and the solid content of pure-acrylic emulsion is 35%, emulsion
Particle diameter is 0.1~0.2 μm, and emulsion viscosity is 2000, and testing conditions are：3#.12rpm, 25 DEG C (i.e. at 25 DEG C,
The registration for using the 3# rotors of resin viscosity instrument to be measured with the rotating speed of 12rpm)；The solid content of silicone acrylic emulsion is 47%,
Emulsion particle diameter is 0.1~0.2 μm, and silicone content is 5%, and emulsion viscosity is 4000, and testing conditions are：3#.30rpm,
25 DEG C (i.e. at 25 DEG C, the registration for using the 3# rotors of resin viscosity instrument to be measured with the rotating speed of 30rpm).
A kind of preparation method of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, comprises the following steps：
(1) 60 parts of water are weighed by weight to be placed in stirred tank, keep 600 revs/min of stirring at low speed, and will
4 parts of coalescents, 0.2 part and 0.1 part defoamer of nertralizer put into stirred tank successively, stir,
(2) weigh again during 1.5 parts of powders add stirred tanks, and improve stirred tank rotating speed to 1600 revs/min, at a high speed
Stirring 15min makes powder be uniformly dispersed；
(3) reduce stirred tank rotating speed to 600 revs/min and add 50 parts of mixed with resin emulsions, it is to be mixed it is uniform after
0.1 part remaining 0.1 part of defoamer and bactericide is added, 0.5 part of regulation viscosity of thickener is slow added into, i.e.,
Obtain Environment-friendlywallpaper wallpaper glue material；
Above-mentioned steps are carried out at normal temperatures and pressures.
Embodiment 3
A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, including following parts by weight component：Mixed with resin breast
40 parts of liquid, 1.2 parts of powder, 2.5 parts of coalescents, 0.3 part of nertralizer, 0.4 part of bactericide, defoamer 0.3
Part, 1.5 parts of thickener, 50 parts of water.Mixed with resin emulsion presses matter by modified pure-acrylic emulsion and modified silicone acrylic emulsion
Amount compares 3.5:1 mixes, and modified pure-acrylic emulsion is made up of following steps：At 45 DEG C, by 100g pure third
Emulsion meter, 1.4g silane couplers are added toward pure-acrylic emulsion, add 0.3g initiators, stirring mixing 45min
Afterwards；Modified silicone acrylic emulsion is made up of following steps：It is past pure based on 100g pure-acrylic emulsions at 45 DEG C
1.5g plasticizer are added in acrylic emulsion, stirring mixes 30min, and the solid content of pure-acrylic emulsion is 35%, breast
Liquid particle diameter is 0.1~0.2 μm, and emulsion viscosity is 1100, and testing conditions are：3#.12rpm, 25 DEG C (i.e. at 25 DEG C
Under, the registration for using the 3# rotors of resin viscosity instrument to be measured with the rotating speed of 12rpm)；The solid content of silicone acrylic emulsion is
47%, emulsion particle diameter is 0.1~0.2 μm, and silicone content is 5%, and emulsion viscosity is 2500, and testing conditions are：
3#.30rpm, 25 DEG C (i.e. at 25 DEG C, use what the 3# rotors of resin viscosity instrument were measured with the rotating speed of 30rpm
Registration).
A kind of preparation method of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, comprises the following steps：
(1) 50 parts of water are weighed by weight to be placed in stirred tank, keep 450 revs/min of stirring at low speed, and will
2.5 parts of coalescents, 0.3 part and 0.15 part defoamer of nertralizer put into stirred tank successively, stir,
(2) weigh again during 1.2 parts of powders add stirred tanks, and improve stirred tank rotating speed to 1400 revs/min, at a high speed
Stirring 45min makes powder be uniformly dispersed；
(3) reduce stirred tank rotating speed to 550 revs/min and add 40 parts of mixed with resin emulsions, it is to be mixed it is uniform after
0.4 part remaining 0.15 part of defoamer and bactericide is added, 1.5 parts of regulation viscosity of thickener is slow added into, i.e.,
Obtain Environment-friendlywallpaper wallpaper glue material；
Above-mentioned steps are carried out at normal temperatures and pressures.
Embodiment 4
A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, including following parts by weight component：Mixed with resin breast
45 parts of liquid, 1.0 parts of powder, 2.8 parts of coalescents, 0.25 part of nertralizer, 0.3 part of bactericide, defoamer
0.5 part, 1 part of thickener, 50 parts of water.Mixed with resin emulsion presses matter by modified pure-acrylic emulsion and modified silicone acrylic emulsion
Amount compares 3.5:1 mixes, and modified pure-acrylic emulsion is made up of following steps：At 45 DEG C, by 100g pure third
Emulsion meter, 1.2g silane couplers are added toward pure-acrylic emulsion, add 0.25g initiators, stirring mixing 40min
Afterwards；Modified silicone acrylic emulsion is made up of following steps：It is past pure based on 100g pure-acrylic emulsions at 50 DEG C
1.6g plasticizer are added in acrylic emulsion, stirring mixes 30min, and the solid content of pure-acrylic emulsion is 35%, breast
Liquid particle diameter is 0.1~0.2 μm, and emulsion viscosity is 1500, and testing conditions are：3#.12rpm, 25 DEG C (i.e. at 25 DEG C
Under, the registration for using the 3# rotors of resin viscosity instrument to be measured with the rotating speed of 12rpm)；The solid content of silicone acrylic emulsion is
47%, emulsion particle diameter is 0.1~0.2 μm, and silicone content is 5%, and emulsion viscosity is 2000, and testing conditions are：
3#.30rpm, 25 DEG C (i.e. at 25 DEG C, use what the 3# rotors of resin viscosity instrument were measured with the rotating speed of 30rpm
Registration).
A kind of preparation method of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, comprises the following steps：
(1) 50 parts of water are weighed by weight to be placed in stirred tank, keep 450 revs/min of stirring at low speed, and will
2.8 parts of coalescents, 0.25 part and 0.25 part defoamer of nertralizer put into stirred tank successively, stir,
(2) weigh again during 1.0 parts of powders add stirred tanks, and improve stirred tank rotating speed to 1500 revs/min, at a high speed
Stirring 30min makes powder be uniformly dispersed；
(3) reduce stirred tank rotating speed to 550 revs/min and add 45 parts of mixed with resin emulsions, it is to be mixed it is uniform after
0.3 part remaining 0.25 part of defoamer and bactericide is added, 1 part of regulation viscosity of thickener is slow added into, obtained final product
To Environment-friendlywallpaper wallpaper glue material；
Above-mentioned steps are carried out at normal temperatures and pressures.
Performance test is carried out to Environment-friendlywallpaper wallpaper glue material obtained in embodiment 1~4, wherein viscosity performance test is used
JC/T548-1994 standards, organic matter Volatility Levels use GB18583-2008 standards, water resistance and stain resistant
Property is respectively that, according to GB/T 1733-1993 and GB/T 9780-2013, acquired results are specifically as shown in table 1.
The Environment-friendlywallpaper wallpaper glue material performance of table 1
The above-mentioned description to embodiment is to be understood that and use hair for ease of those skilled in the art
It is bright.Person skilled in the art obviously easily can make various modifications to these embodiments, and herein
The General Principle of explanation is applied in other embodiment without by performing creative labour.Therefore, the present invention is not limited
In above-described embodiment, those skilled in the art's announcement of the invention, do not depart from that scope made changes
Entering and change all should be within protection scope of the present invention.
Claims (9)
1. a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper, it is characterised in that including following parts by weight
Component：
2. a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper according to claim 1, it is characterised in that
Described mixed with resin emulsion is by pure-acrylic emulsion and the modified silicone acrylic emulsion (3~4) in mass ratio of being modified:1 mixes.
3. a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper according to claim 2, it is characterised in that
Described modified pure-acrylic emulsion is made up of following steps：It is past based on 100g pure-acrylic emulsions at 30~60 DEG C
1.0~1.8g silane couplers are added in pure-acrylic emulsion, 0.2~0.4g initiators, 30~60min of stirring mixing is added
Afterwards；
Described modified silicone acrylic emulsion is made up of following steps：At 40~60 DEG C, based on 100g pure-acrylic emulsions,
1~2g plasticizer, 20~40min of stirring mixing are added toward pure-acrylic emulsion.
4. a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper according to claim 3, it is characterised in that
The solid content of described pure-acrylic emulsion is 35%, and emulsion particle diameter is 0.1~0.2 μm, and emulsion viscosity is 200~2000,
Testing conditions are：3#.12rpm, 25 DEG C；
Described initiator is ammonium persulfate, and described silane coupler is silane coupler KH-560；
The solid content of described silicone acrylic emulsion is 47%, and emulsion particle diameter is 0.1~0.2 μm, and silicone content is 5%, breast
Fluid viscosity is 1000~4000, and testing conditions are：3#.30rpm, 25 DEG C.
5. a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper according to claim 1, it is characterised in that
Described powder is hydroxyethyl cellulose.
6. a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper according to claim 1, it is characterised in that
Described auxiliary agent includes the component of following parts by weight：2~4 parts of coalescents, 0.1~0.3 part of nertralizer is sterilized
0.1~0.4 part of agent, 0.2~0.5 part of defoamer, 0.5~1.5 part of thickener.
7. a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper according to claim 6, it is characterised in that
Described coalescents are alcohol ester 12, and described nertralizer is AMP-95 neutralizing amines, and described defoamer is poly-
Dimethyl siloxane, described alkali swollen thickener is association type alkali swollen thickener DR-72.
8. a kind of preparation method of the as claimed in claim 6 Environment-friendlywallpaper wallpaper glue material for being used for sticking wallpaper, its
It is characterised by, comprises the following steps：
(1) 45~60 parts of water are weighed by weight to be placed in stirred tank, keep stirring at low speed, and film forming is helped
The defoamer of 2~4 parts of agent, 0.1~0.3 part of nertralizer and 1/2 dosage puts into stirred tank successively, stirs,
(2) weigh again during 0.8~1.5 part of powder adds stirred tank, and improve stirred tank rotating speed, high-speed stirred makes powder
Body is uniformly dispersed；
(3) reduce stirred tank rotating speed and add 35~50 parts of mixed with resin emulsions, uniform rear addition to be mixed is remaining
0.1~0.4 part of the defoamer and bactericide of 1/2 dosage, are slow added into 0.5~1.5 part of regulation viscosity of thickener, i.e.,
Obtain Environment-friendlywallpaper wallpaper glue material；
Above-mentioned steps are carried out at normal temperatures and pressures.
9. the preparation method of a kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper according to claim 8,
Characterized in that, the rotating speed of the stirring at low speed described in step (1) is 300~600 revs/min；
The rotating speed of the high-speed stirred described in step (2) is 1200~1600 revs/min, and mixing time is 15~60min；
The rotating speed of stirred tank is down to 500~600 revs/min in step (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510829820.6A CN106753076A (en) | 2015-11-25 | 2015-11-25 | A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510829820.6A CN106753076A (en) | 2015-11-25 | 2015-11-25 | A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106753076A true CN106753076A (en) | 2017-05-31 |
Family
ID=58964722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510829820.6A Pending CN106753076A (en) | 2015-11-25 | 2015-11-25 | A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106753076A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107686711A (en) * | 2017-09-29 | 2018-02-13 | 佛山市涂无忧建材有限公司 | A kind of transparent watertight glue with hydrophobicity and weatherability and preparation method thereof |
| CN109517540A (en) * | 2018-11-16 | 2019-03-26 | 上海瀚氏科技集团有限公司 | Environmentally friendly vehicle article shading curtain and its production technology |
| CN112011294A (en) * | 2020-08-27 | 2020-12-01 | 浙江理工大学 | Environment-friendly antibacterial organic-inorganic composite adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701138A (en) * | 2009-11-19 | 2010-05-05 | 夏良强 | Cohesive glue for flexible decorative tile and manufacturing method thereof |
| CN101962521A (en) * | 2010-04-02 | 2011-02-02 | 上海东方雨虹防水技术有限责任公司 | Opening time adjustable wallpaper adhesive and preparation method thereof |
| CN102605679A (en) * | 2012-03-15 | 2012-07-25 | 广东银洋树脂有限公司 | Wallpaper |
| CN102977823A (en) * | 2012-11-19 | 2013-03-20 | 浦江宇翔胶水有限公司 | Environmentally-friendly glue for wallpaper and preparation method thereof |
-
2015
- 2015-11-25 CN CN201510829820.6A patent/CN106753076A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701138A (en) * | 2009-11-19 | 2010-05-05 | 夏良强 | Cohesive glue for flexible decorative tile and manufacturing method thereof |
| CN101962521A (en) * | 2010-04-02 | 2011-02-02 | 上海东方雨虹防水技术有限责任公司 | Opening time adjustable wallpaper adhesive and preparation method thereof |
| CN102605679A (en) * | 2012-03-15 | 2012-07-25 | 广东银洋树脂有限公司 | Wallpaper |
| CN102977823A (en) * | 2012-11-19 | 2013-03-20 | 浦江宇翔胶水有限公司 | Environmentally-friendly glue for wallpaper and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107686711A (en) * | 2017-09-29 | 2018-02-13 | 佛山市涂无忧建材有限公司 | A kind of transparent watertight glue with hydrophobicity and weatherability and preparation method thereof |
| CN109517540A (en) * | 2018-11-16 | 2019-03-26 | 上海瀚氏科技集团有限公司 | Environmentally friendly vehicle article shading curtain and its production technology |
| CN112011294A (en) * | 2020-08-27 | 2020-12-01 | 浙江理工大学 | Environment-friendly antibacterial organic-inorganic composite adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102745943B (en) | Manufacture and construction method of powdery outer wall natural stone paint | |
| CN106632816B (en) | A kind of colorful continuous phase silicone acrylic emulsion and preparation method thereof reacted with protective glue | |
| CN106189640B (en) | A kind of preparation method of modified aqueous acrylic acid cold coating | |
| CN102372885A (en) | High viscosity polyvinyl acetate emulsion and preparation method thereof | |
| CN104559336A (en) | Modified silica sol and preparation method thereof | |
| CN106753076A (en) | A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof | |
| CN106243961A (en) | Display screen processing aqueous peelable glue and preparation method thereof | |
| CN103319716A (en) | Silicone resin and preparation method thereof | |
| CN109679427A (en) | Low-volatile water-soluble pearlescent effect art coatings and preparation method thereof | |
| CN109504281A (en) | A kind of emulsion-type mould release and preparation method thereof | |
| CN107163761A (en) | A kind of colorful base paint emulsion of excellent performance and preparation method thereof | |
| CN106830749B (en) | A kind of color liquid sliver and its application | |
| CN109439110A (en) | A kind of high-performance water-based glass wine bottle coating and preparation method thereof | |
| CN102675986A (en) | Water-based coloring base material and preparation method thereof | |
| CN116285632B (en) | Tensile and ultraviolet-resistant resin coating and preparation method and application thereof | |
| CN107573830A (en) | A kind of nanometer water UV ultraviolet light cured varnish and preparation method and application | |
| CN108300047A (en) | A kind of indoor anti-pollution water-water coating and preparation method thereof | |
| CN107129629A (en) | A kind of redispersible latex powder and preparation method thereof | |
| CN109054639A (en) | A kind of green paulownia oil-based paint and preparation method thereof | |
| CN107118645A (en) | A kind of waterproof artificial granite speckle multicolor finish and preparation method thereof | |
| CN105820781B (en) | A kind of bi-component waterborne Laminating adhesive and preparation method thereof | |
| CN105669915A (en) | Water-soluble epoxy silicone acrylic resin and preparation method thereof | |
| CN115124898A (en) | Granite coating and preparation method thereof | |
| CN105348958B (en) | A kind of water-based dumb light coating varnish of two-component organic inorganic hybridization and preparation method thereof and construction method | |
| CN107674528A (en) | A kind of high-performance multicolor finish and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
|
| RJ01 | Rejection of invention patent application after publication |