CN102675986A - Water-based coloring base material and preparation method thereof - Google Patents
Water-based coloring base material and preparation method thereof Download PDFInfo
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- CN102675986A CN102675986A CN2012101616505A CN201210161650A CN102675986A CN 102675986 A CN102675986 A CN 102675986A CN 2012101616505 A CN2012101616505 A CN 2012101616505A CN 201210161650 A CN201210161650 A CN 201210161650A CN 102675986 A CN102675986 A CN 102675986A
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Abstract
The invention discloses a water-based coloring base material and a preparation method thereof. The water-based coloring base material comprises the following raw materials in percentage by weight: 30-40% of water-base resin 1, 20-30% of water-base resin 2, 20-30% of water, 1-1.5% of sensitiser, 1-2% of thickener, 5-8% of alcohol ether solvent, 0.1-0.5% of defoamer, and 0.5-1% of PH value regulator. The water-based coloring base material has the advantages of high permeability, high coloring effect, environmental protection and no odor, good adhesion, convenience in construction and the like, besides the basic properties of both of a UV (Ultraviolet) water-based coloring base material and a purely water-based coloring base material. In addition, the water-based coloring base material can be directly matched with a water-based pigment and a water-based dye, and diluted by water to obtain appropriate color concentration, thereby achieving perfect ornamental effect and meeting the requirements of customers.
Description
Technical field
The present invention relates to painted base-material of a kind of water-based and preparation method.
Background technology
At present, to be roughly water-based UV painted painted with water-based for the traditional painted base-material of woodenware.But the painted base-material staple of water-based UV is a UV exsiccant waterborne polyurethane resin; Because its specific molecule structure; Disadvantages such as being easy to generate in the film process is clamminess does, painted easy accumulation, construction process thickening influence the coloring effect of woodenware finished product, do not reach requirement of client.And the painted base-material of traditional water-based, the drying and forming-film process is very fast relatively, cause painted stiff, permeability is not good, gradation sense is not strong; Simultaneously upper strata UV system there is not the crosslinking reaction group; Whole paint film is prone to come off, and sticking power is not good, does not equally also reach customer requirement.
Summary of the invention
To above two kinds of problem and shortage that painted base-material produces; The purpose of this invention is to provide painted base-material of a kind of water-based and preparation method, this base-material has hypertonicity, strong coloring effect when taking into account sticking power; More can highlight the texture of timber, can better satisfy client's demand.
The objective of the invention is to realize through following technical scheme:
The painted base-material of a kind of water-based is characterized in that: this base-material is made up of following components in weight percentage: water-base resin A 30-40%, water-base resin B 20-30%, water 20-30%, sensitizer 1-1.5%, thickening material 1-2%, pure ether solvent 5-8%, skimmer 0.1-0.5%, pH value regulator 0.5-1%; More than each percentages of ingredients sum be 100%; Said water-base resin A is a UV watersoluble polyurethane acrylic acid emulsion; Said water-base resin B is the water-based ACRYLIC EMULSION; Said pH value regulator is 10% ammoniacal liquor or AMP-95, the article 2-amino-2-methyl-1-propanol by name or the mixture of two kinds of products.
Said water-base resin A elects the UV aqueous acrylic emulsion as; Article are called ionic aliphatic urethane acrylate emulsion (Aliphatic urethane acrylate emulsion; Ionic stabilized), can be the ionic aliphatic urethane acrylate emulsion of special company of cyanogen or Beyer Co., Ltd.The key technical indexes: moisture 60%, viscosity＜25 ℃ of 200cps at, density are that 1.05 g/cm3, pH value are 7.02, and the normal temperature state is a milky white liquid,
Said water-base resin B elects the pure acrylic acid emulsion as, and article are called water base property ACRYLIC EMULSION (COLLODIAL DISPERSION), can be the ionic aliphatic urethane acrylate emulsion of special company of cyanogen or Beyer Co., Ltd.The key technical indexes: solid content is 30%, viscosity is that 100cps, density are that 1.04 g/cm3, second-order transition temperature are that 43 ℃, film-forming temperature are that 20 ℃, pH value are 8.0, and the normal temperature state is a transparence liquid.
Said water is deionized water.Said sensitizer is that Changzhou China titanizing RUNTECURE 1103 (2-hydroxy-2-methyls-1-phenyl-1-acetone) are commonly called as 1173; RUNTECURE 1020 (UVNUL MS-40) is commonly called as BP; RUNTECURE 1104 (1-hydroxyl-cyclohexyl-phenyl ketone) is commonly called as 184, BASF Lucirin TPO (2,4; 6 trimethylbenzoyls-diphenyl phosphate oxidation), Changxing chemistry 6420 (response type tertiary amine aided initiatings; Elongation: 30.2%; Viscosity: 25 ℃ of 15-25cps at) or more than the mixture of several kinds of sensitizer.
Said thickening material is the TAFIGELPUR42 of bright icepro chemical industry; The special polyurethane thickener of article non-ionic type by name, technical indicator: active part be about 32%, density is that 1.06 g/cm3, pH value are 6.0, solubleness is that turbid shape solution, normal temperature state are turbid shape white liquid in the water.Or the BYK425 of Bi Ke company, article water-borne coatings by name and pigment concentrate slurry are used the liquid auxiliary rheological agents, and chemical constitution is the modified urea polyurethane soln, and active substance accounts for about 50%, and solvent is that W 166 600, normal temperature state are milky white liquid.
The 2-Butoxy ethanol (BCS) that said pure ether solvent is a DOW Chemical; Article are called butyl glycol ether, the key technical indexes: molecular formula is that C6H14O2, molecular weight are 118.17, density is 0.901 g/cm3, fusing point is that 171 ℃, flash-point are 61 ℃ for-70 ℃, boiling point.Or the butyl alcohol (NBA) of DOW Chemical, article are called propyl carbinol.The key technical indexes: molecular formula is that CH3 (CH2) 3OH, molecular weight are 74.12, density is 0.809 g/cm3, fusing point is that 117.25 ℃, flash-point are 35 ℃ for-88.9 ℃, boiling point, and is water-soluble slightly.
Said skimmer is the TEGO AIREX 901W that high (TEGO) company of enlightening produces, and is a kind of efficient deaerating agent liquid concentrator, and is effective especially to eliminating microvesicle.Or the Dehydran 1293 of the Ninghua worker of section production, be a kind of skimmer and air release agent, can be used for pure water-borne coatings and polymer emulsion and be the basis, contain the coating of cosolvent.Or the mixed solution of two kinds of skimmers.
Said pH value regulator is 10% ammoniacal liquor or AMP-95, and article are called 2-amino-2-methyl-1-propanol, the key technical indexes: viscosity is that 225cps, pH value are 6.7, neutralization equivalent is 93-97, and the normal temperature state is a clarified liq.
The present invention because to consider between two kinds of resins, resin and pH value regulate between and slight chemical reaction can take place between resin and the solvent, concrete interpolation order also has the requirement of strictness.
The preparation method of the painted base-material of a kind of water-based is characterized in that: this method comprises the steps:
1) slowly stir water-base resin A, stirring velocity is 500rpm;
2) with water and the pre-mixing of pH value regulator, slowly join in the water-base resin A solution, improve stirring velocity simultaneously to 600rpm, churning time is 20 minutes;
3) slowly add water-base resin B, churning time is 20 minutes;
4) with water and pure ether solvent pre-mixing, slowly add, improve stirring velocity to 800rpm, churning time is 10 minutes;
5) slowly add skimmer, improve stirring velocity to 1000rpm, churning time is 10 minutes;
6) slowly add thickening material, keep stirring velocity, churning time is 10 minutes;
7) slowly add sensitizer, improve stirring velocity to 1200rpm, churning time is 10 minutes, obtains the painted base-material of water-based.
The raw-material weight that uses among the present invention must be through the accurate weighing of electronic scales, and to avoid loss and error, each raw-material add-on meets the components in weight percentage composition requirement in this base-material.
The present invention has advantages such as hypertonicity, strong coloring effect, environment-friendly tasteless, sticking power are good, convenient construction when taking into account the painted base-material fundamental property of painted base-material of UV water-based and water-based.Can directly arrange in pairs or groups water-based paint and dyestuff, dilute with water modulates suitable color density, to reach perfect decorative effect, satisfies requirement of client.This painted base-material additive color process need not be ground and high speed dispersion, only needs suitably manually to stir, and uses painted roller coating machine to woodenware painted (coloring process also can manual wiping accomplish) then, and site operation is extremely convenient.Through the selection collocation of water-based paint and dyestuff, the painted base-material of this water-based shows fabulous gradation sense, embodies natural, graceful, the agile characteristics of woodenware product, plays decorative effect preferably.
Advantage of the present invention is: in the painted process of woodenware product, can solve the painted easy accumulation of the painted base-material of traditional water-based, problems such as permeability is not good, gradation sense is strong, construction process thickening.
Embodiment
Embodiment 1
The painted base-material of a kind of water-based, this base-material is made up of following components in weight percentage: water-base resin A 40 kg, water-base resin B 30 kg, water 21 kg, sensitizer 1kg, thickening material 1kg, pure ether solvent 6 kg, skimmer 0.5 kg, pH value regulator 0.5 kg; Water-base resin A elects the UV aqueous acrylic emulsion as; Article are called ionic aliphatic urethane acrylate emulsion (Aliphatic urethane acrylate emulsion; Ionic stabilized), can be the ionic aliphatic urethane acrylate emulsion of special company of cyanogen or Beyer Co., Ltd.The key technical indexes: moisture 60%, viscosity＜25 ℃ of 200cps at, density are that 1.05 g/cm3, pH value are 7.02, and the normal temperature state is a milky white liquid,
Water-base resin B elects the pure acrylic acid emulsion as, and article are called water base property ACRYLIC EMULSION (COLLODIAL DISPERSION), can be the ionic aliphatic urethane acrylate emulsion of special company of cyanogen or Beyer Co., Ltd.The key technical indexes: solid content is 30%, viscosity is that 100cps, density are that 1.04 g/cm3, second-order transition temperature are that 43 ℃, film-forming temperature are that 20 ℃, pH value are 8.0, and the normal temperature state is a transparence liquid.Said pH value regulator is 10% ammoniacal liquor or AMP-95, the article 2-amino-2-methyl-1-propanol by name or the mixture of two kinds of products.
Water is deionized water.Sensitizer is that Changzhou China titanizing RUNTECURE 1103 (2-hydroxy-2-methyls-1-phenyl-1-acetone) are commonly called as 1173; RUNTECURE 1020 (UVNUL MS-40) is commonly called as BP; RUNTECURE 1104 (1-hydroxyl-cyclohexyl-phenyl ketone) is commonly called as 184, BASF Lucirin TPO (2,4; 6 trimethylbenzoyls-diphenyl phosphate oxidation), Changxing chemistry 6420 (response type tertiary amine aided initiatings; Elongation: 30.2%; Viscosity: 25 ℃ of 15-25cps at) or more than the mixture of several kinds of sensitizer.
Thickening material is the TAFIGELPUR42 of bright icepro chemical industry; The special polyurethane thickener of article non-ionic type by name, technical indicator: active part be about 32%, density is that 1.06 g/cm3, pH value are 6.0, solubleness is that turbid shape solution, normal temperature state are turbid shape white liquid in the water.Or the BYK425 of Bi Ke company, article water-borne coatings by name and pigment concentrate slurry are used the liquid auxiliary rheological agents, and chemical constitution is the modified urea polyurethane soln, and active substance accounts for about 50%, and solvent is that W 166 600, normal temperature state are milky white liquid.
The alcohol ether solvent is the 2-Butoxy ethanol (BCS) of DOW Chemical; Article are called butyl glycol ether, the key technical indexes: molecular formula is that C6H14O2, molecular weight are 118.17, density is 0.901 g/cm3, fusing point is that 171 ℃, flash-point are 61 ℃ for-70 ℃, boiling point.Or the butyl alcohol (NBA) of DOW Chemical, article are called propyl carbinol.The key technical indexes: molecular formula is that CH3 (CH2) 3OH, molecular weight are 74.12, density is 0.809 g/cm3, fusing point is that 117.25 ℃, flash-point are 35 ℃ for-88.9 ℃, boiling point, and is water-soluble slightly.
Skimmer is the TEGO AIREX 901W that high (TEGO) company of enlightening produces, and is a kind of efficient deaerating agent liquid concentrator, and is effective especially to eliminating microvesicle.Or the Dehydran 1293 of the Ninghua worker of section production, be a kind of skimmer and air release agent, can be used for pure water-borne coatings and polymer emulsion and be the basis, contain the coating of cosolvent.Or the mixed solution of two kinds of skimmers.
The pH value regulator is 10% ammoniacal liquor or AMP-95, and article are called 2-amino-2-methyl-1-propanol, the key technical indexes: viscosity is that 225cps, pH value are 6.7, neutralization equivalent is 93-97, and the normal temperature state is a clarified liq.
The present invention because to consider between two kinds of resins, resin and pH value regulate between and slight chemical reaction can take place between resin and the solvent, concrete interpolation order also has the requirement of strictness.The preparation method of the painted base-material of a kind of water-based, this method comprises the steps:
1) slowly stir water-base resin A 40 kg, stirring velocity is 500rpm;
2) with water 15 kg and the 0.5 kg pre-mixing of pH value regulator, slowly join in the water-base resin A solution, improve stirring velocity simultaneously to 600rpm, churning time is 20 minutes;
3) slowly add water-base resin B 30 kg, churning time is 20 minutes;
4) with water 6 kg and the 6 kg pre-mixings of pure ether solvent, slowly add, improve stirring velocity to 800rpm, churning time is 10 minutes;
5) slowly add skimmer 0.5 kg, improve stirring velocity to 1000rpm, churning time is 10 minutes;
6) slowly add thickening material 1kg, keep stirring velocity, churning time is 10 minutes;
7) slowly add sensitizer 1kg, improve stirring velocity to 1200rpm, churning time is 10 minutes, obtains the painted base-material of water-based.
The raw-material weight that uses among the present invention must be through the accurate weighing of electronic scales, and to avoid loss and error, each raw-material add-on meets the components in weight percentage composition requirement in this base-material.
End of processing to be prepared, quality examination basic technical indicator such as table 1:
Table 1
| Standard | Instrument | Experimental data |
| Viscosity (25 ℃) | Be coated with 6 glasss | 20-25 second |
| PH value (25 ℃) | The PH meter | 8.0-8.5 |
| Solids content | The solid content measuring appearance | 28-30% |
Coating process of the present invention can adopt painted special-purpose roller coating machine or manual wiping.Behind painted dry the end,, accomplish the making of woodenware finished product according to conventional UV coating process.
Concrete coating process such as following table 2:
Table 2
| Product description | Glue spread (g/ ㎡) | Work machine | Remarks |
| The color of the painted base-material ﹢ of water-based 10-20% | 15-20 | Painted special-purpose roller coating machine | 50-70 ℃ of infrared rays baking |
| UV fills putty | 30-35 | The special-purpose roller coating machine of putty | 120-130mj 240# sanding |
| The UV wear-resistant primer | 15-18 | Common roller coating machine | 70-80mj |
| UV sanding priming paint | 15-20 | Common roller coating machine | 70-80mj |
| UV sanding priming paint | 15-20 | Common roller coating machine | 1-2 minute levelling 120-130mj 400# sanding |
| The UV finish paint | 5-6 | The special-purpose roller coating machine of finish paint | 70-80mj |
| The UV finish paint | 5-6 | The special-purpose roller coating machine of finish paint | 25-280mj |
The present invention contrasts painted base-material of traditional water-based UV and the painted base-material of water-based, according to EN ISO2409 standard, and test sticking power, concrete outcome such as following table 3:
Table 3
Comparing result shows that the present invention has better coloring effect when taking into account sticking power, more can highlight the texture of timber, can better satisfy client's demand.
Embodiment 2
It only is that weight proportion is different that embodiment 2 compares with embodiment 1; The painted base-material of another water-based, this base-material is made up of following components in weight percentage: water-base resin A 30 kg, water-base resin B 20 kg, water 20 kg, sensitizer 1kg, thickening material 1kg, pure ether solvent 5 kg, skimmer 0.1 kg, pH value regulator 0.5 kg.
Embodiment 3
It only is that weight proportion is different that embodiment 3 compares with embodiment 1; The painted base-material of another water-based, this base-material is made up of following components in weight percentage: water-base resin A 35 kg, water-base resin B 25 kg, water 28 kg, sensitizer 1.5kg, thickening material 1kg, pure ether solvent 6 kg, skimmer 0.5 kg, pH value regulator 0.8 kg.
Embodiment 2 shows fabulous gradation sense with the painted base-material of water-based of embodiment 3, embodies natural, graceful, the agile characteristics of woodenware product, plays decorative effect preferably, satisfies request for utilization.
Claims (8)
1. painted base-material of water-based, it is characterized in that: this base-material is made up of following components in weight percentage: water-base resin A 30-40%, water-base resin B 20-30%, water 20-30%, sensitizer 1-1.5%, thickening material 1-2%, pure ether solvent 5-8%, skimmer 0.1-0.5%, pH value regulator 0.5-1%; More than each percentages of ingredients sum be 100%; Said water-base resin A is a UV watersoluble polyurethane acrylic acid emulsion; Said water-base resin B is the water-based ACRYLIC EMULSION; Said pH value regulator is 10% ammoniacal liquor or AMP-95, the article 2-amino-2-methyl-1-propanol by name or the mixture of two kinds of products.
2. the painted base-material of water-based according to claim 1 is characterized in that: said water-base resin A is the ionic aliphatic urethane acrylate emulsion of special company of cyanogen or Beyer Co., Ltd.
3. the painted base-material of water-based according to claim 1 is characterized in that: said water-base resin B is the water base property ACRYLIC EMULSION of BASF or Aberdeen.
4. the painted base-material of water-based according to claim 1; It is characterized in that: said sensitizer is 2-hydroxy-2-methyl-1-phenyl-1-acetone or 1-hydroxyl-cyclohexyl-phenyl ketone or 2; 4,6 trimethylbenzoyls-diphenyl phosphate oxidation or more than several kinds mixture.
5. the painted base-material of water-based according to claim 1 is characterized in that: said thickening material be non-ionic type special polyurethane thickener or for water-borne coatings and pigment concentrate slurry with the liquid auxiliary rheological agents or the mixture of two kinds of products.
6. the painted base-material of water-based according to claim 1 is characterized in that: said pure ether solvent is a butyl glycol ether, or the propyl carbinol or the mixture of two kinds of products.
7. the painted base-material of water-based according to claim 1 is characterized in that: TEGO AIREX 901W or the Dehydran 1293 of the Ninghua worker of section production or the mixed solution of two kind of skimmer that said skimmer is produced for Di Gao company.
8. the preparation method of the painted base-material of the described water-based of claim 1, it is characterized in that: this method comprises the steps:
1) slowly stir water-base resin A, stirring velocity is 500rpm;
2) with water and the pre-mixing of pH value regulator, slowly join in the water-base resin A solution, improve stirring velocity simultaneously to 600rpm, churning time is 20 minutes;
3) slowly add water-base resin B, churning time is 20 minutes;
4) with water and pure ether solvent pre-mixing, slowly add, improve stirring velocity to 800rpm, churning time is 10 minutes;
5) slowly add skimmer, improve stirring velocity to 1000rpm, churning time is 10 minutes;
6) slowly add thickening material, keep stirring velocity, churning time is 10 minutes;
7) slowly add sensitizer, improve stirring velocity to 1200rpm, churning time is 10 minutes, obtains the painted base-material of water-based.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104046240A (en) * | 2014-07-02 | 2014-09-17 | 江苏海田技术有限公司 | Aqueous color-wrapping glaze base material and preparation method thereof |
| CN104725988A (en) * | 2013-12-23 | 2015-06-24 | 惠州市绿孔雀科技有限公司 | Water-based paint with high adhesive force |
| CN104927470A (en) * | 2015-07-17 | 2015-09-23 | 广东华兹卜化学工业有限公司 | Water-based thick-coated carpentry transparent base paint and preparation method thereof |
| CN105176268A (en) * | 2015-10-19 | 2015-12-23 | 佛山市高明阳光逸采涂料有限公司 | Waterborne UV coloring agent and preparation method thereof |
| CN106807610A (en) * | 2017-02-21 | 2017-06-09 | 江苏海田技术有限公司 | A kind of timber floor log color effect coating process |
| CN108841303A (en) * | 2018-06-28 | 2018-11-20 | 湖南冠艺家居股份有限公司 | The aqueous base-material of log color and preparation method for European furniture |
| CN110669390A (en) * | 2019-09-10 | 2020-01-10 | 嘉宝莉化工集团股份有限公司 | Water-based multifunctional self-drying coloring base material and preparation method thereof |
| CN111117371A (en) * | 2020-01-20 | 2020-05-08 | 浙江纳美新材料股份有限公司 | Special color paste for bamboo and wood dyeing and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104725988A (en) * | 2013-12-23 | 2015-06-24 | 惠州市绿孔雀科技有限公司 | Water-based paint with high adhesive force |
| CN104046240A (en) * | 2014-07-02 | 2014-09-17 | 江苏海田技术有限公司 | Aqueous color-wrapping glaze base material and preparation method thereof |
| CN104927470A (en) * | 2015-07-17 | 2015-09-23 | 广东华兹卜化学工业有限公司 | Water-based thick-coated carpentry transparent base paint and preparation method thereof |
| CN105176268A (en) * | 2015-10-19 | 2015-12-23 | 佛山市高明阳光逸采涂料有限公司 | Waterborne UV coloring agent and preparation method thereof |
| CN106807610A (en) * | 2017-02-21 | 2017-06-09 | 江苏海田技术有限公司 | A kind of timber floor log color effect coating process |
| CN108841303A (en) * | 2018-06-28 | 2018-11-20 | 湖南冠艺家居股份有限公司 | The aqueous base-material of log color and preparation method for European furniture |
| CN110669390A (en) * | 2019-09-10 | 2020-01-10 | 嘉宝莉化工集团股份有限公司 | Water-based multifunctional self-drying coloring base material and preparation method thereof |
| CN111117371A (en) * | 2020-01-20 | 2020-05-08 | 浙江纳美新材料股份有限公司 | Special color paste for bamboo and wood dyeing and preparation method thereof |
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Application publication date: 20120919 |