CN101962521A - Opening time adjustable wallpaper adhesive and preparation method thereof - Google Patents

Opening time adjustable wallpaper adhesive and preparation method thereof Download PDF

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Publication number
CN101962521A
CN101962521A CN 201010138319 CN201010138319A CN101962521A CN 101962521 A CN101962521 A CN 101962521A CN 201010138319 CN201010138319 CN 201010138319 CN 201010138319 A CN201010138319 A CN 201010138319A CN 101962521 A CN101962521 A CN 101962521A
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Prior art keywords
ether
mechanical stirring
cellulose
emulsion
water
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CN 201010138319
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CN101962521B (en
Inventor
王雪莉
刘操
吁磊
许渊
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SHANGHAI ORIENTAL YUHONG WATERPROOF TECHNOLOGY Co Ltd
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SHANGHAI ORIENTAL YUHONG WATERPROOF TECHNOLOGY Co Ltd
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Publication of CN101962521A publication Critical patent/CN101962521A/en
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Abstract

The invention relates to an opening time adjustable wallpaper adhesive and a preparation method thereof. The wallpaper adhesive consists of the following raw materials in percentage by weight: 5 to 95 percent of emulsion, 0.5 to 25 percent of cellulose ether, 0.5 to 35 percent of starch ether and the balance of water. The preparation method comprises the following steps of: mixing the following raw materials: 5 to 95 percent of emulsion, 0.5 to 25 percent of cellulose ether, 0.5 to 35 percent of starch ether and the balance of water; adding the cellulose ether into water for dissolution, and fully stirring uniformly; adding the starch ether into aqueous solution of cellulose ether, and fully stirring uniformly; and mixing the cellulose ether and starch ether mixed solution and the emulsion according to a ratio, and fully stirring uniformly. The invention has the advantages that: the starch ether and the cellulose ether are compounded into the emulsion through mechanical blending, and the two materials are coordinated to fulfill the aims of thickening, retaining water and improving construction performance.

Description

Adjustable wallpaper tackiness agent of open hour and manufacture method thereof
Technical field
The present invention relates to a kind of wallpaper tackiness agent, relate in particular to the component and the manufacture method thereof of this wallpaper tackiness agent.
Background technology
The wallpaper tackiness agent adopts modified-cellulose as main component usually, cooperates the metope treatment agent all to have bond effect preferably to the wallpaper of differing texture.Yet because the cold water-soluble of ether of cellulose is relatively poor, construction has brought a lot of inconvenience to house ornamentation.
The report of at present relevant wallpaper tackiness agent is all less both at home and abroad, mainly concentrates on the research to the polyvinyl alcohol tackiness agent, and adjustable wallpaper tackiness agent of open hour is not still had report.
So-called adjustable wallpaper tackiness agent of open hour is meant: a kind ofly regulate this wallpaper tackiness agent film forming surface drying time to satisfy the wallpaper tackiness agent of different construction requirements by changing in the prescription each component concentration.
Summary of the invention
The technical issues that need to address of the present invention have provided adjustable wallpaper tackiness agent of a kind of open hour, are intended to solve the above problems;
The present invention also provides the method for making the said products.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical solutions:
The present invention is that water is formed by emulsion, ether of cellulose, starch ethers, surplus; Each raw material accounts for weight percent: emulsion 5-95%, ether of cellulose 0.5-25%, and starch ethers 0.5-35%, surplus is a water; Described ether of cellulose is a molecular weight 1,000~200, the hydroxyethylmethyl-cellulose ether of 000 hydroxypropyl methyl cellulose ether or molecular weight 1,000~200,000; Starch ethers is yam starch ether or W-Gum ether or wheat starch ether or tapioca (flour) ether; Emulsion adopts VAE emulsion or benzene emulsion or pure-acrylic emulsion.
Preparation method of the present invention realizes by following steps:
Batching: take by weighing ether of cellulose, starch ethers, emulsion and water by above-mentioned prescription;
With the ether of cellulose dissolving that is added to the water, stir;
Again starch ethers is joined in the cellulose ether aqueous solution, stir;
The mixing solutions and the emulsion of ether of cellulose and starch ethers are mixed in proportion, stir promptly.
Compared with prior art, the invention has the beneficial effects as follows: advance in the emulsion starch ethers, ether of cellulose are compound by mechanical blending, reach two kinds of material thickenings, water conservation, improve the coordinative role of workability.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail:
The present invention is achieved by the following technical solutions:
The present invention is that water is formed by emulsion, ether of cellulose, starch ethers, surplus; Each raw material accounts for weight percent: emulsion 5-95%, ether of cellulose 0.5-25%, and starch ethers 0.5-35%, surplus is a water; Described ether of cellulose is a molecular weight 1,000~200, the hydroxyethylmethyl-cellulose ether of 000 hydroxypropyl methyl cellulose ether or molecular weight 1,000~200,000; Starch ethers is yam starch ether or W-Gum ether or wheat starch ether or tapioca (flour) ether; Emulsion adopts VAE emulsion or benzene emulsion or pure-acrylic emulsion.
Preparation method of the present invention realizes by following steps:
Batching: take by weighing ether of cellulose, starch ethers, emulsion and water by above-mentioned prescription;
With the ether of cellulose dissolving that is added to the water, stir;
Again starch ethers is joined in the cellulose ether aqueous solution, stir;
The mixing solutions and the emulsion of ether of cellulose and starch ethers are mixed in proportion, stir promptly.
In view of starch ethers has very strong thixotropy, can improve workability, ether of cellulose has good water-retentivity and thickening effectiveness, with the aqueous solution of starch ethers and ether of cellulose and emulsion in proportion blend prepare adjustable wallpaper tackiness agent of open hour, starch ethers is dissolved in the water with colloidal form, and its aqueous solution contains the hydration macromole, the flowability performance non-Newtonian fluid of solution, thixotropy is stronger, can improve workability; The ether of cellulose water retention capacity is strong, has significant thickening power, advances in the emulsion starch ethers, ether of cellulose are compound by mechanical blending, reaches two kinds of material thickenings, water conservation, improves the coordinative role of workability.
Open hour provided by the invention adjustable wallpaper tackiness agent stable preparation process is easy to realize suitability for industrialized production, and cost is low, technology is simple.And prepared wallpaper adhesives excellent property can not pollute wallpaper, and is environmentally friendly to the human body toxicological harmless, and the open hour can be regulated by the change of prescription according to actual needs, have the potentiality of applying, and market outlook are wide.
Embodiment 1
By weight,, after abundant mechanical stirring, in solution, add starch ethers 3%, be uniformly dispersed by mechanical stirring with ether of cellulose 4%, water 42%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 51%.
Embodiment 2
By weight,, after abundant mechanical stirring, in solution, add starch ethers 2.5%, be uniformly dispersed by mechanical stirring with ether of cellulose 0.5%, water 26%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 71%.
Embodiment 3
By weight,, after abundant mechanical stirring, in solution, add starch ethers 8%, be uniformly dispersed by mechanical stirring with ether of cellulose 11%, water 62%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 19%.
Embodiment 4
By weight,, after abundant mechanical stirring, in solution, add starch ethers 0.5%, be uniformly dispersed by mechanical stirring with ether of cellulose 25%, water 69.5%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 5%.
Embodiment 5
By weight,, after abundant mechanical stirring, in solution, add starch ethers 35%, be uniformly dispersed by mechanical stirring with ether of cellulose 6%, water 53%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 6%.
Embodiment 6
By weight,, after abundant mechanical stirring, in solution, add starch ethers 12%, be uniformly dispersed by mechanical stirring with ether of cellulose 18%, water 52%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 18%.
Embodiment 7
By weight,, after abundant mechanical stirring, in solution, add starch ethers 5.5%, be uniformly dispersed by mechanical stirring with ether of cellulose 3.5%, water 43%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 48%.
Embodiment 8
By weight,, after abundant mechanical stirring, in solution, add starch ethers 3%, be uniformly dispersed by mechanical stirring with ether of cellulose 22%, water 64%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 11%.
Embodiment 9
By weight,, after abundant mechanical stirring, in solution, add starch ethers 31%, be uniformly dispersed by mechanical stirring with ether of cellulose 4%, water 44%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 21%.
Embodiment 10
By weight,, after abundant mechanical stirring, in solution, add starch ethers 12%, be uniformly dispersed by mechanical stirring with ether of cellulose 17%, water 58%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 13%.
Embodiment 11
By weight,, after abundant mechanical stirring, in solution, add starch ethers 8%, be uniformly dispersed by mechanical stirring with ether of cellulose 9.5%, water 47.5%.Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 35%.
All on sale on the raw materials market that the present invention adopts.

Claims (10)

1. an adjustable wallpaper tackiness agent of open hour is that water is formed by emulsion, ether of cellulose, starch ethers, surplus; Each raw material accounts for weight percent: emulsion 5-95%, ether of cellulose 0.5-25%, and starch ethers 0.5-35%, surplus is a water.
2. adjustable wallpaper tackiness agent of open hour according to claim 1, wherein: described ether of cellulose is a molecular weight 1,000~200, the hydroxyethylmethyl-cellulose ether of 000 hydroxypropyl methyl cellulose ether or molecular weight 1,000~200,000; Starch ethers is yam starch ether or W-Gum ether or wheat starch ether or tapioca (flour) ether; Emulsion adopts VAE emulsion or benzene emulsion or pure-acrylic emulsion.
3. the preparation method of an adjustable wallpaper tackiness agent of open hour, realize by following steps:
Batching: each raw material accounts for weight percent and is: emulsion 5-95%, ether of cellulose 0.5-25%, and starch ethers 0.5-35%, surplus is a water;
With the ether of cellulose dissolving that is added to the water, stir;
Again starch ethers is joined in the cellulose ether aqueous solution, stir;
The mixing solutions and the emulsion of ether of cellulose and starch ethers are mixed in proportion, stir promptly.
4. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 3, wherein: by weight,, after abundant mechanical stirring, in solution, add starch ethers 3%, be uniformly dispersed by mechanical stirring with ether of cellulose 4%, water 42%; Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 51%.
5. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 3, wherein: by weight, with ether of cellulose 0.5%, water 26%, after abundant mechanical stirring, in solution, add starch ethers 2.5%, be uniformly dispersed by mechanical stirring; Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 71%.
6. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 3, wherein: by weight,, after abundant mechanical stirring, in solution, add starch ethers 8%, be uniformly dispersed by mechanical stirring with ether of cellulose 11%, water 62%; Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 19%.
7. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 3, wherein: by weight, with ether of cellulose 25%, water 69.5%, after abundant mechanical stirring, in solution, add starch ethers 0.5%, be uniformly dispersed by mechanical stirring; Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 5%.
8. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 3, wherein: by weight,, after abundant mechanical stirring, in solution, add starch ethers 35%, be uniformly dispersed by mechanical stirring with ether of cellulose 6%, water 53%; Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 6%.
9. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 3, wherein: by weight,, after abundant mechanical stirring, in solution, add starch ethers 12%, be uniformly dispersed by mechanical stirring with ether of cellulose 18%, water 52%; Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 18%.
10. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 3, wherein: by weight, with ether of cellulose 3.5%, water 43%, after abundant mechanical stirring, in solution, add starch ethers 5.5%, be uniformly dispersed by mechanical stirring; Again through the abundant mixing of mechanical stirring promptly with mixture solution and emulsion 48%.
CN2010101383192A 2010-04-02 2010-04-02 Opening time adjustable wallpaper adhesive and preparation method thereof Active CN101962521B (en)

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CN101962521B CN101962521B (en) 2012-06-06

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102732184A (en) * 2012-07-18 2012-10-17 郭曲玲 Elastic waterproof binder additive and preparation method thereof
CN105542678A (en) * 2016-02-14 2016-05-04 佛山市恒学科技服务有限公司 Long-acting antimicrobial mildewproof wallpaper adhesive
CN106634685A (en) * 2017-01-03 2017-05-10 黄淇浩 Environment-friendly antistatic wallpaper glue and preparation method thereof
CN106753076A (en) * 2015-11-25 2017-05-31 铂恩塞尔新材料(上海)股份有限公司 A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof
CN108658495A (en) * 2017-08-08 2018-10-16 苏州金螳螂建筑装饰股份有限公司 Bond reinforcing agent and preparation method thereof and binding material and its construction method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1958702A (en) * 2006-09-06 2007-05-09 江都中远装饰工程设计研究所 Hydrosol powder of glue for building

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1958702A (en) * 2006-09-06 2007-05-09 江都中远装饰工程设计研究所 Hydrosol powder of glue for building

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102732184A (en) * 2012-07-18 2012-10-17 郭曲玲 Elastic waterproof binder additive and preparation method thereof
CN106753076A (en) * 2015-11-25 2017-05-31 铂恩塞尔新材料(上海)股份有限公司 A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof
CN105542678A (en) * 2016-02-14 2016-05-04 佛山市恒学科技服务有限公司 Long-acting antimicrobial mildewproof wallpaper adhesive
CN106634685A (en) * 2017-01-03 2017-05-10 黄淇浩 Environment-friendly antistatic wallpaper glue and preparation method thereof
CN108658495A (en) * 2017-08-08 2018-10-16 苏州金螳螂建筑装饰股份有限公司 Bond reinforcing agent and preparation method thereof and binding material and its construction method

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