CN102605679A - Wallpaper - Google Patents
Wallpaper Download PDFInfo
- Publication number
- CN102605679A CN102605679A CN2012100682251A CN201210068225A CN102605679A CN 102605679 A CN102605679 A CN 102605679A CN 2012100682251 A CN2012100682251 A CN 2012100682251A CN 201210068225 A CN201210068225 A CN 201210068225A CN 102605679 A CN102605679 A CN 102605679A
- Authority
- CN
- China
- Prior art keywords
- monomer
- deionized water
- wallpaper
- stage
- initator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 claims abstract description 37
- 230000001070 adhesive effect Effects 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 239000000178 monomer Substances 0.000 claims description 141
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 99
- 239000000839 emulsion Substances 0.000 claims description 95
- 239000008367 deionised water Substances 0.000 claims description 78
- 229910021641 deionized water Inorganic materials 0.000 claims description 78
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 36
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical group [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 36
- 238000006243 chemical reaction Methods 0.000 claims description 34
- 230000000977 initiatory effect Effects 0.000 claims description 32
- 239000004094 surface-active agent Substances 0.000 claims description 29
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 27
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 18
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 238000012546 transfer Methods 0.000 claims description 17
- 239000011248 coating agent Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 15
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 238000004945 emulsification Methods 0.000 claims description 14
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 13
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- 238000009413 insulation Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000004132 cross linking Methods 0.000 claims description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 9
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 9
- -1 (methyl) hydroxy-ethyl Chemical group 0.000 claims description 8
- 208000031639 Chromosome Deletion Diseases 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000006378 damage Effects 0.000 abstract description 6
- 238000005034 decoration Methods 0.000 abstract description 5
- 239000002518 antifoaming agent Substances 0.000 description 13
- 239000012467 final product Substances 0.000 description 12
- 239000002562 thickening agent Substances 0.000 description 12
- 239000000080 wetting agent Substances 0.000 description 12
- 230000007613 environmental effect Effects 0.000 description 11
- 239000002585 base Substances 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 230000032050 esterification Effects 0.000 description 6
- 238000005886 esterification reaction Methods 0.000 description 6
- 238000006068 polycondensation reaction Methods 0.000 description 6
- 238000010790 dilution Methods 0.000 description 5
- 239000012895 dilution Substances 0.000 description 5
- 230000002159 abnormal effect Effects 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000004026 adhesive bonding Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 3
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 3
- 230000002457 bidirectional effect Effects 0.000 description 3
- 238000003851 corona treatment Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention discloses wallpaper, which comprises adhesive, a base and wall treatment agent. The adhesive is coated onto the base. The wall treatment agent is coated to a wall before the wallpaper is adhered. The wallpaper is environment-friendly and re-stickable. Even replacing new wallpaper causes no harm to the wall and leaves no adhesive residue on the wall. Both the adhesive and the wall treatment agent are waterborne, environment-friendly and harmless to human bodies. The wallpaper is widely applicable to indoor decoration for houses, hotels, entertainment places and the like.
Description
Technical field
The present invention relates to chemical technology field, relate in particular to a kind of reusable wallpaper.
Background technology
The raising of Along with people's living standard and quality of life, increasing consumer is also increasingly high to quality, style, the grade of interior decoration, and wallpaper is widely used in interior decoration by people and decorates, and wallpaper miscellaneous can satisfy consumer's demands of different.
But existing wallpaper can only use in disposable stickup, when changing wallpaper, can not peel off with metope well; Leave cull or incomplete wallpaper easily on the wall; Wallpaper can not be recycled, but also cause the untidy of metope, need carry out the secondary cleaning metope.Also some wallpaper is when peeling off metope, and adhesive is together torn together with the part material of metope, and metope is caused damage.In addition, wallpaper generally is made up of base material and adhesive, and adhesive coated is on base material, and base material passes through adhesive bond on metope.Existing adhesive is generally solvent-based adhesive, and the organic solvent that contains in the solvent-based adhesive not only pollutes the environment, and human body is had harm.On the other hand, the price of organic solvent is also relatively more expensive, can increase the cost of wallpaper manufacturer.
Therefore, prior art awaits to improve and development.
Summary of the invention
Deficiency in view of above-mentioned prior art the object of the present invention is to provide a kind of wallpaper, and said wallpaper is a kind of environment protection type wallpaper that can repeatedly paste, and being intended to solve existing wallpaper can not the repeated problem of using and containing.
Technical scheme of the present invention is following:
A kind of wallpaper, wherein, said wallpaper is made up of adhesive, base material and metope finishing agent; Said adhesive is attached on the base material through coating; Said metope finishing agent is before pasting wallpaper, coats on the metope.
Described wallpaper, wherein, said adhesive comprises monomer, deionized water, sodium acid carbonate, initator and surfactant;
Said deionized water is divided into the deionized water of participating in emulsion reaction and the deionized water two parts of participating in polymerisation, and the deionized water of said participation emulsion reaction is 20 ~ 30% of a total monomer weight; The deionized water of said participation polymerisation is 43 ~ 47% of a total monomer weight;
Said sodium acid carbonate account for said participation polymerisation deionized water weight 0.2 ~ 0.4%.
Said initator is a sodium peroxydisulfate, is 7 ~ 12% of total monomer weight;
Said monomer is by weight percentage, and is composed of the following components:
A, 93 ~ 97% acrylic acid ester soft monomer, its general structure is CH
2=CHCOOR, R are the alkyl of carbon containing 2 ~ 12;
B, 1 ~ 4% acrylic compounds polar monomer, its general structure is CH
2=C (R
1) COOR
2, R
1Be H or CH
3, R
2Hydroxyalkyl for H or carbon containing 2 ~ 4;
C, 0 ~ 3% can self-crosslinking monomer.
Described wallpaper, wherein, said acrylic acid ester soft monomer is one or both the mixture in butyl acrylate, the Isooctyl acrylate monomer; Said acrylic compounds polar monomer is (methyl) acrylic acid or (methyl) hydroxy-ethyl acrylate; The monomer of said ability self-crosslinking is N hydroxymethyl acrylamide or DAAM.
Described wallpaper, wherein, said sodium peroxydisulfate is divided into just initiating stage and dropping stage two parts, and the said mass concentration of the sodium peroxydisulfate of initiating stage just is 15 ~ 20%, is 1 ~ 2% of total monomer weight; The mass concentration of the sodium peroxydisulfate in said dropping stage is 1 ~ 3%, is 6 ~ 10% of total monomer weight.
Described wallpaper, wherein, the preparation process of said adhesive is following:
S1, with monomer, the deionized water of participating in emulsion reaction and surfactant emulsification 30min at least, monomer emulsions;
S2, with deionized water heat temperature raising to 65 ~ 75 of participating in polymerisation in the agitated reactor ℃, add the partial monosomy emulsion again, stir;
S3, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 75 ~ 85 ℃, 3 ~ 4h adds, and dropwises the back 84-86 ℃ of insulation 1 ~ 3 hour; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of auxiliary agent.
Described wallpaper, wherein, said metope finishing agent comprises monomer, deionized water, sodium acid carbonate, initator and surfactant;
Said deionized water is divided into the deionized water of participating in emulsion reaction and the deionized water two parts of participating in polymerisation, and the deionized water of said participation emulsion reaction is 20 ~ 30% of a total monomer weight; The deionized water of said participation polymerisation is 200 ~ 300% of a total monomer weight;
Said sodium acid carbonate account for said participation polymerisation deionized water weight 0.1 ~ 0.3%;
Said initator is an ammonium persulfate, accounts for 3 ~ 12% of total monomer weight;
Said monomer is by weight percentage, and is composed of the following components:
A, 40 ~ 50% acrylic acid ester soft monomer, its general structure is CH
2=CHCOOR, R are the alkyl of carbon containing 2 ~ 12;
B, 50 ~ 60% hard monomer, its general structure is CH
2=C (R
1) COOR
2, R
1Be CH
3, R
2Alkyl for carbon containing 1 ~ 12;
C, 0 ~ 5% acrylic compounds polar monomer, its general structure is CH
2=C (R
1) COOR
2, R
1Be H or CH
3, R
2Hydroxyalkyl for H or carbon containing 2 ~ 4.
Described wallpaper, wherein, said acrylic acid soft monomer is one or both in butyl acrylate, the Isooctyl acrylate monomer; Said hard monomer is a methyl methacrylate; Said acrylic compounds polar monomer is an acrylic acid.
Described wallpaper, wherein, said ammonium persulfate is divided into just initiating stage and dropping stage two parts, and the said mass concentration of the ammonium persulfate of initiating stage just is 13 ~ 17%, is 2 ~ 8% of total monomer weight; The mass concentration of the ammonium persulfate in said dropping stage is 13 ~ 17%, is 1 ~ 4% of total monomer weight.
Described wallpaper, wherein, the preparation process of said metope finishing agent is following:
S100, with the deionized water emulsification of monomer, surfactant and participation emulsion reaction 30min at least, monomer emulsions;
S200, will participate in polymerisation the deionized water heat temperature raising to 80-90 ℃, add the partial monosomy emulsion again, stir;
S300, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 84-86 ℃, 2 ~ 4h adds, and dropwises the back at 84-86 ℃ of insulation 0.5 ~ 1.5h; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of auxiliary agent.
Described wallpaper, wherein, said base material is film, cloth or the metal sheet of plastics class.
Beneficial effect: wallpaper provided by the present invention is made up of adhesive, base material and metope finishing agent, is a kind of environment protection type wallpaper that can repeatedly paste, even when the wallpaper that more renews, also can not cause damage to metope, also can on metope, not leave cull.Said adhesive and metope finishing agent all are water-based, environmental protection, harmless, can be widely used in interior decorations such as household, hotel and public place of entertainment and use.
The specific embodiment
The present invention provides a kind of wallpaper, and is clearer, clear and definite for making the object of the invention, technical scheme and effect, below to further explain of the present invention.Should be appreciated that specific embodiment described herein only in order to explanation the present invention, and be not used in qualification the present invention.
A kind of wallpaper is provided among the present invention, is a kind of environment protection type wallpaper that can repeatedly paste, when the wallpaper that more renews, also can not cause damage to metope, also can on metope, not leave cull.Said wallpaper is made up of adhesive, base material and metope finishing agent, and said adhesive is attached on the base material through coating, and the mode of coating can be scraper type or transfer type etc.; Said metope finishing agent is before pasting wallpaper, coats on the metope, and metope is play a part to repair and protection.Said base material can the plastics class film or cloth, also can be the sheet material of various metal species, can print various patterns or decorative pattern on the said base material, also can cut into different shape, to form decorative effect.Said adhesive and metope finishing agent all are water-based, environmental protection, harmless, can be widely used in interior decorations such as household, hotel and public place of entertainment and use.Said wallpaper can repeatedly be pasted, and when changing, also can not damage metope, also can on metope, not leave cull.
Said adhesive is a kind of aqueous adhesive of environmental protection; Prepare by the mode of various acrylic ester monomers through emulsion polymerisation, the structure of tool self-crosslinking, and polymer molecular chain is soft; In the coating dry run, take place crosslinked; Form network structure, increased cohesive force, thereby had peelable subsides property again.Said adhesive mainly is made up of monomer, deionized water, sodium acid carbonate and initator etc.
Said monomer is by weight percentage, and is composed of the following components:
(1) 93 ~ 97% acrylic acid ester soft monomer, its general structure is: CH
2=CHCOOR, R are the alkyl of carbon containing 2 ~ 12.Said acrylic acid ester soft monomer can be one or both the mixture in butyl acrylate, the Isooctyl acrylate monomer;
(2) 1 ~ 4% acrylic compounds polar monomer, its general structure is: CH
2=C (R
1) COOR
2, R
1Be H or CH
3, R
2Hydroxyalkyl for H or carbon containing 2 ~ 4.Said acrylic compounds polar monomer can be (methyl) acrylic acid or (methyl) hydroxy-ethyl acrylate;
The monomer of (3) 0 ~ 3% ability self-crosslinking can be self-cross linking monomers such as N hydroxymethyl acrylamide, or DAAM.
Said deionized water is divided into the deionized water of participating in emulsion reaction and the deionized water two parts of participating in polymerisation, and the deionized water of said participation emulsion reaction is 20 ~ 30% of a total monomer weight; The deionized water of said participation polymerisation is 43 ~ 47% of a total monomer weight.Said sodium acid carbonate account for said participation polymerisation deionized water weight 0.2 ~ 0.4%.
Said initator is a sodium peroxydisulfate, is 7 ~ 12% of total monomer weight.Said sodium peroxydisulfate is divided into just initiating stage and dropping stage two parts, and the said mass concentration of the sodium peroxydisulfate of initiating stage just is 15 ~ 20%, is 1 ~ 2% of total monomer weight; The mass concentration of the sodium peroxydisulfate in said dropping stage is 1 ~ 3%, is 6 ~ 10% of total monomer weight.
Said adhesive is accomplished by emulsion polymerisation, and solids content >=50%, the Tg of resulting polymers must use 0.5 ~ 2% surfactant (to the monomer total amount) at-60 ~-20 ℃ during polymerization.Said surfactant can be that anion and nonionic are compound, also can be independent anion, like lauryl sodium sulfate or dodecyl sodium sulfate etc.For increasing WATER RESISTANCE, alkali resistance and animal migration can be used double bond containing reactive surfactant, like AMPS, and COPS-1 etc.The initiation of said polymerisation can be that the thermal decomposition type also can be redox, and reaction temperature is at 60 ~ 85 ℃.
The preparation method of said adhesive also is provided among the present invention:
S1, with monomer, the deionized water of participating in emulsion reaction and surfactant emulsify at a high speed 30min at least, monomer emulsions that must be stable;
S2, with deionized water heat temperature raising to 65 ~ 75 of participating in polymerisation in the agitated reactor ℃, add the partial monosomy emulsion again, stir;
S3, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 75 ~ 85 ℃, 3 ~ 4h adds, and dropwises the back 84-86 ℃ of insulation 1 ~ 3 hour; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of various auxiliary agents and gets final product.
The emulsion of partial monosomy described in the step S2 accounts for 10% of monomer emulsions gross weight.In the dropping process of the remaining monomer emulsion described in the step S3 and the initator in the stage of dropping, initator dropwises than the late 15min of monomer emulsions.Among the step S3, said auxiliary agent is wetting agent, thickener or antifoaming agent etc.
The said adhesive that obtains is being added an amount of thickener (like ammoniacal liquor; Or alkali swelling or association type) and wetting agent be transferred to suitable viscosity (> 500cps) after; Coat on release liners or the mould release membrance; Through 105 ℃ of dry 5min, transfer to again on PVC (plastics) or the various metal decorative material, get final product to such an extent that wallpaper is adorned in the environmental protection that can repeatedly fit of the present invention.
Said metope finishing agent is to be formed through emulsion polymerisation by various acrylic ester monomers, is water-based, and the low VOC discharging of safety has ultra-fine grain diameter, narrow distribution.Said metope finishing agent has strong permeability, and water-alkali resistance has good adhesive force to various metopes (cement, wooden, aluminium alloy, plastic-steel etc.), metope is risen repair and protective effect.Said metope finishing agent mainly is made up of monomer, deionized water, sodium acid carbonate and initator etc.
Said monomer is by weight percentage, and is composed of the following components:
(1) 40 ~ 50% acrylic acid ester soft monomer, its general structure is: CH
2=CHCOOR, R are the alkyl of carbon containing 2 ~ 12.Described acrylic acid soft monomer can be in butyl acrylate, the Isooctyl acrylate monomer etc. one or both;
(2) 50 ~ 60% hard monomer, its general structure are CH
2=C (R
1) COOR
2, R
1Be CH
3, R
2Be the alkyl of carbon containing 1 ~ 12, described hard monomer can be methyl methacrylate;
(3) 0 ~ 5% acrylic compounds polar monomer, its general structure is: CH
2=C (R
1) COOR
2, R
1Be H or CH
3, R
2Hydroxyalkyl for H or carbon containing 2 ~ 4.Described acrylic compounds polar monomer can be acrylic acid.
Said deionized water is divided into the deionized water of participating in emulsion reaction and the deionized water two parts of participating in polymerisation, and the deionized water of said participation emulsion reaction is 20 ~ 30% of a total monomer weight; The deionized water of said participation polymerisation is 200 ~ 300% of a total monomer weight.Said sodium acid carbonate account for said participation polymerisation deionized water weight 0.1 ~ 0.3%.
Said initator is an ammonium persulfate, is to account for 3 ~ 12% of total monomer weight.Said ammonium persulfate is divided into just initiating stage and dropping stage two parts, and the said mass concentration of the ammonium persulfate of initiating stage just is 13 ~ 17%, is 2 ~ 8% of total monomer weight; The mass concentration of the ammonium persulfate in said dropping stage is 13 ~ 17%, is 1 ~ 4% of total monomer weight.
Said metope finishing agent is accomplished by emulsion polymerisation, solids content 30%, and the Tg of resulting polymers must use 10% surfactant (this means effective surfactant, and surfactant can be 100% solid, also can be solution) at 25 ℃ during polymerization.Said surfactant can be that anion and nonionic are compound, can be independent anion also, like lauryl sodium sulfate.The initiation of said polymerisation can be that the thermal decomposition type also can be redox, and reaction temperature is at 70-86 ℃.
The preparation method of said metope finishing agent also is provided among the present invention:
S100, with the deionized water emulsification of monomer, surfactant and participation emulsion reaction 30min at least, monomer emulsions that must be stable;
S200, with the deionized water heat temperature raising of participating in polymerisation in the agitated reactor to 80-90 ℃, add the partial monosomy emulsion again, stir;
S300, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 84-86 ℃, 2 ~ 4h adds, and dropwises the back at 84-86 ℃ of insulation 0.5 ~ 1.5h; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of various auxiliary agents and gets final product.
The emulsion of partial monosomy described in the step S200 is to account for 10 ~ 20% of monomer emulsions gross weight.In the dropping process of the remaining monomer emulsion described in the step S300 and the initator in the stage of dropping, initator dropwises than the late 15min of monomer emulsions.Among the step S300, said auxiliary agent is wetting agent, thickener or antifoaming agent etc.
With the emulsion that obtains and water dilution proportion by 1:1, add antifoaming agent again after, roller coat or brush on blade coating putty and the metope that polishes flat.Behind the dry 6h, can paste the environmental protection dress wallpaper that repeatedly to fit.
Embodiment 1
1, the preparation of adhesive
(1) Polycondensation Reactor and Esterification Reactor (quality, kg)
Participate in the deionized water of polymerisation: 260
Sodium acid carbonate: 1
(2) emulsification
Participate in the deionized water of emulsion reaction: 140
Surfactant: 7.5
Butyl acrylate: 500
Isooctyl acrylate monomer: 50
Acrylic acid: 12
Self-cross linking monomer: 5.5
(3) initator
First initiating stage: sodium peroxydisulfate/water: 1.54/7
The dropping stage: sodium peroxydisulfate/water: 0.7/45
Technology: S1, with monomer and deionized water and the surfactant emulsify at a high speed of participating in emulsion reaction 30min at least, monomer emulsions that must be stable;
S2, with the deionized water heat temperature raising to 65 of participating in polymerisation in the agitated reactor ℃, add the monomer emulsions that accounts for monomer emulsions gross weight 10% again, stir;
S3, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 75 ~ 85 ℃, 3 ~ 4h adds (initator than monomer emulsion after 15 ~ 30min drip off), dropwises the back 84 ℃ of insulations 3 hours; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of various auxiliary agents (wetting agent, thickener or antifoaming agent etc.) and gets final product.
With the emulsion that obtains with line rod blade coating on the BOPP of sided corona treatment (bidirectional stretching polypropylene film), 20 microns of gluings, 105 ℃ of dry 5min, survey peeling force and be: 1 ~ 3.0N/25mm, can fit glass and stainless steel for a long time and not have glue residual.
2, the preparation of metope finishing agent
(1) Polycondensation Reactor and Esterification Reactor (quality, kg)
Participate in the deionized water of polymerisation: 1000
Sodium acid carbonate: 2
(2) emulsification
Participate in the deionized water of emulsion reaction: 125
Surfactant: 60
Butyl acrylate: 150
Methyl methacrylate: 250
Isooctyl acrylate monomer: 69
Acrylic acid: 17
(3) initator
First initiating stage: ammonium persulfate/water: 3/18
The dropping stage: ammonium persulfate/water: 1.4/8
Technology: S100, with the deionized water emulsification of monomer, surfactant and participation emulsion reaction 30min at least, monomer emulsions that must be stable;
S200, with the deionized water heat temperature raising to 80 of participating in polymerisation in the agitated reactor ℃, add the monomer emulsions that accounts for monomer emulsions gross weight 10% again, stir;
S300, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 84-86 ℃, 3h adds, and dropwises the back 84-86 ℃ of insulation 0.5 hour; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of auxiliary agent (wetting agent, thickener or antifoaming agent) and gets final product.
With the emulsion that obtains and water dilution proportion by 1:1, add antifoaming agent again after, roller coat or brush on blade coating putty and the metope that polishes flat dry 6h.The anti-accumulation of salt in the surface soil property (48h) that records described metope finishing agent is no abnormal.
3, the preparation of wallpaper
The said adhesive that obtains adding after an amount of thickener is transferred to suitable viscosity with wetting agent, is coated on release liners or the mould release membrance, and 105 ℃ of dry 5min of warp transfer to PVC film and last again, get final product the environmental protection wall paper that can repeatedly fit.
4, the use of wallpaper
On metope, need to paste the place of wallpaper, coating one deck metope finishing agent earlier, treat the metope drying after, the environmental protection wall paper that can repeatedly fit again sticks on the metope.Said wallpaper can be bonded on the metope, optionally tears and paste more than 20 times, and on metope, can not leave a trace.
Embodiment 2
1, the preparation of adhesive
(1) Polycondensation Reactor and Esterification Reactor (quality, kg)
Participate in the deionized water of polymerisation: 255
Sodium acid carbonate: 1.2
(2) emulsification
Participate in the deionized water of emulsion reaction: 120
Surfactant: 3
Butyl acrylate: 500
Isooctyl acrylate monomer: 50
Acrylic acid: 23
Self-cross linking monomer: 17.5
(3) initator
First initiating stage: sodium peroxydisulfate/water: 0.9/5.1
The dropping stage: sodium peroxydisulfate/water: 0.3/39.7
Technology: S1, with monomer and deionized water and the surfactant emulsify at a high speed of participating in emulsion reaction 30min at least, monomer emulsions that must be stable;
S2, with the deionized water heat temperature raising to 70 of participating in polymerisation in the agitated reactor ℃, add the monomer emulsions that accounts for monomer emulsions gross weight 10% again, stir;
S3, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 75 ~ 85 ℃, 3 ~ 4h adds (initator than monomer emulsion after 15 ~ 30min drip off), dropwises the back 86 ℃ of insulations 1 hour; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of various auxiliary agents (wetting agent, thickener or antifoaming agent etc.) and gets final product.
With the emulsion that obtains with line rod blade coating on the BOPP of sided corona treatment (bidirectional stretching polypropylene film), 20 microns of gluings, 105 ℃ of dry 5min, survey peeling force and be: 1 ~ 3.0N/25mm, can fit glass and stainless steel for a long time and not have glue residual.
2, the preparation of metope finishing agent
(1) Polycondensation Reactor and Esterification Reactor (quality, kg)
Participate in the deionized water of polymerisation: 1000
Sodium acid carbonate: 2
(2) emulsification
Participate in the deionized water of emulsion reaction: 125
Surfactant: 60
Butyl acrylate: 150
Isooctyl acrylate monomer: 69
Methyl methacrylate: 250
Acrylic acid: 17
(3) initator
First initiating stage: ammonium persulfate/water: 3/18
The dropping stage: ammonium persulfate/water: 1.4/8
Technology: S100, with the deionized water emulsification of monomer, surfactant and participation emulsion reaction 30min at least, monomer emulsions that must be stable;
S200, with the deionized water heat temperature raising to 85 of participating in polymerisation in the agitated reactor ℃, add the monomer emulsions that accounts for monomer emulsions gross weight 15% again, stir;
S300, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 84-86 ℃, 4h adds, and dropwises the back 84-86 ℃ of insulation 1.5 hours; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of auxiliary agent (wetting agent, thickener or antifoaming agent) and gets final product.
With the emulsion that obtains and water dilution proportion by 1:1, add antifoaming agent again after, roller coat or brush on blade coating putty and the metope that polishes flat dry 6h.The anti-accumulation of salt in the surface soil property (48h) that records described metope finishing agent is no abnormal.
With the emulsion that obtains and water dilution proportion by 1:1, add antifoaming agent again after, roller coat or brush on blade coating putty and the metope that polishes flat dry 6h.The anti-accumulation of salt in the surface soil property (48h) that records described metope finishing agent is no abnormal.
3, the preparation of wallpaper
The said adhesive that obtains adding after an amount of thickener is transferred to suitable viscosity with wetting agent, is coated on release liners or the mould release membrance, and 105 ℃ of dry 5min of warp transfer to PVC film and last again, get final product the environmental protection wall paper that can repeatedly fit.
4, the use of wallpaper
On metope, need to paste the place of wallpaper, coating one deck metope finishing agent earlier, treat the metope drying after, the environmental protection wall paper that can repeatedly fit again sticks on the metope.Said wallpaper can be bonded on the metope, optionally tears and paste more than 20 times, and on metope, can not leave a trace.
Embodiment 3
1, the preparation of adhesive
(1) Polycondensation Reactor and Esterification Reactor (quality, kg)
Participate in the deionized water of polymerisation: 270
Sodium acid carbonate: 2.3
(2) emulsification
Participate in the deionized water of emulsion reaction: 172.5
Surfactant: 17.25
Butyl acrylate: 500
Isooctyl acrylate monomer: 52
Acrylic acid: 11.5
Self-cross linking monomer: 11.5
(3) initator
First initiating stage: sodium peroxydisulfate/water: 2.3/9.2
The dropping stage: sodium peroxydisulfate/water: 1.7/55.8
Technology: S1, with monomer and deionized water and the surfactant emulsify at a high speed of participating in emulsion reaction 30min at least, monomer emulsions that must be stable;
S2, with the deionized water heat temperature raising to 75 of participating in polymerisation in the agitated reactor ℃, add the monomer emulsions that accounts for monomer emulsions gross weight 10% again, stir;
S3, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 75 ~ 85 ℃, 3 ~ 4h adds (initator than monomer emulsion after 15 ~ 30min drip off), dropwises the back 85 ℃ of insulations 2 hours; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of various auxiliary agents (wetting agent, thickener or antifoaming agent etc.) and gets final product.
With the emulsion that obtains with line rod blade coating on the BOPP of sided corona treatment (bidirectional stretching polypropylene film), 20 microns of gluings, 105 ℃ of dry 5min, survey peeling force and be: 1 ~ 3.0N/25mm, can fit glass and stainless steel for a long time and not have glue residual.
2, the preparation of metope finishing agent
(1) Polycondensation Reactor and Esterification Reactor (quality, kg)
Participate in the deionized water of polymerisation: 1300
Sodium acid carbonate: 1.3
(2) emulsification
Participate in the deionized water of emulsion reaction: 128
Surfactant: 65
Butyl acrylate: 200
Isooctyl acrylate monomer: 65
Methyl methacrylate: 268
Acrylic acid: 10
(3) initator
First initiating stage: ammonium persulfate/water: 4.8/25.2
The dropping stage: ammonium persulfate/water: 3/15
Technology: S100, with the deionized water emulsification of monomer, surfactant and participation emulsion reaction 30min at least, monomer emulsions that must be stable;
S200, with the deionized water heat temperature raising to 90 of participating in polymerisation in the agitated reactor ℃, add the monomer emulsions that accounts for monomer emulsions gross weight 10% again, stir;
S300, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 84-86 ℃, 3h adds, and dropwises the back 84-86 ℃ of insulation 0.5 hour; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of auxiliary agent (wetting agent, thickener or antifoaming agent) and gets final product.
With the emulsion that obtains and water dilution proportion by 1:1, add antifoaming agent again after, roller coat or brush on blade coating putty and the metope that polishes flat dry 6h.The anti-accumulation of salt in the surface soil property (48h) that records described metope finishing agent is no abnormal.
3, the preparation of wallpaper
The said adhesive that obtains adding after an amount of thickener is transferred to suitable viscosity with wetting agent, is coated on release liners or the mould release membrance, and 105 ℃ of dry 5min of warp transfer to PVC film and last again, get final product the environmental protection wall paper that can repeatedly fit.
4, the use of wallpaper
On metope, need to paste the place of wallpaper, coating one deck metope finishing agent earlier, treat the metope drying after, the environmental protection wall paper that can repeatedly fit again sticks on the metope.Said wallpaper can be bonded on the metope, optionally tears and paste more than 20 times, and on metope, can not leave a trace.
Should be understood that application of the present invention is not limited to above-mentioned giving an example, concerning those of ordinary skills, can improve or conversion that all these improvement and conversion all should belong to the protection domain of accompanying claims of the present invention according to above-mentioned explanation.
Claims (10)
1. a wallpaper is characterized in that, said wallpaper is made up of adhesive, base material and metope finishing agent; Said adhesive is attached on the base material through coating; Said metope finishing agent is before pasting wallpaper, coats on the metope.
2. wallpaper according to claim 1 is characterized in that said adhesive comprises monomer, deionized water, sodium acid carbonate, initator and surfactant;
Said deionized water is divided into the deionized water of participating in emulsion reaction and the deionized water two parts of participating in polymerisation, and the deionized water of said participation emulsion reaction is 20 ~ 30% of a total monomer weight; The deionized water of said participation polymerisation is 43 ~ 47% of a total monomer weight;
Said sodium acid carbonate account for said participation polymerisation deionized water weight 0.2 ~ 0.4%.
Said initator is a sodium peroxydisulfate, is 7 ~ 12% of total monomer weight;
Said monomer is by weight percentage, and is composed of the following components:
A, 93 ~ 97% acrylic acid ester soft monomer, its general structure is CH
2=CHCOOR, R are the alkyl of carbon containing 2 ~ 12;
B, 1 ~ 4% acrylic compounds polar monomer, its general structure is CH
2=C (R
1) COOR
2, R
1Be H or CH
3, R
2Hydroxyalkyl for H or carbon containing 2 ~ 4;
C, 0 ~ 3% can self-crosslinking monomer.
3. wallpaper according to claim 2 is characterized in that, said acrylic acid ester soft monomer is one or both the mixture in butyl acrylate, the Isooctyl acrylate monomer; Said acrylic compounds polar monomer is (methyl) acrylic acid or (methyl) hydroxy-ethyl acrylate; The monomer of said ability self-crosslinking is N hydroxymethyl acrylamide or DAAM.
4. wallpaper according to claim 2 is characterized in that, said sodium peroxydisulfate is divided into just initiating stage and dropping stage two parts, and the said mass concentration of the sodium peroxydisulfate of initiating stage just is 15 ~ 20%, is 1 ~ 2% of total monomer weight; The mass concentration of the sodium peroxydisulfate in said dropping stage is 1 ~ 3%, is 6 ~ 10% of total monomer weight.
5. wallpaper according to claim 2 is characterized in that, the preparation process of said adhesive is following:
S1, with monomer, the deionized water of participating in emulsion reaction and surfactant emulsification 30min at least, monomer emulsions;
S2, with deionized water heat temperature raising to 65 ~ 75 of participating in polymerisation in the agitated reactor ℃, add the partial monosomy emulsion again, stir;
S3, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 75 ~ 85 ℃, 3 ~ 4h adds, and dropwises the back 84-86 ℃ of insulation 1 ~ 3 hour; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of auxiliary agent.
6. wallpaper according to claim 1 is characterized in that, said metope finishing agent comprises monomer, deionized water, sodium acid carbonate, initator and surfactant;
Said deionized water is divided into the deionized water of participating in emulsion reaction and the deionized water two parts of participating in polymerisation, and the deionized water of said participation emulsion reaction is 20 ~ 30% of a total monomer weight; The deionized water of said participation polymerisation is 200 ~ 300% of a total monomer weight;
Said sodium acid carbonate account for said participation polymerisation deionized water weight 0.1 ~ 0.3%;
Said initator is an ammonium persulfate, accounts for 3 ~ 12% of total monomer weight;
Said monomer is by weight percentage, and is composed of the following components:
A, 40 ~ 50% acrylic acid ester soft monomer, its general structure is CH
2=CHCOOR, R are the alkyl of carbon containing 2 ~ 12;
B, 50 ~ 60% hard monomer, its general structure is CH
2=C (R
1) COOR
2, R
1Be CH
3, R
2Alkyl for carbon containing 1 ~ 12;
C, 0 ~ 5% acrylic compounds polar monomer, its general structure is CH
2=C (R
1) COOR
2, R
1Be H or CH
3, R
2Hydroxyalkyl for H or carbon containing 2 ~ 4.
7. wallpaper according to claim 6 is characterized in that, said acrylic acid soft monomer is one or both in butyl acrylate, the Isooctyl acrylate monomer; Said hard monomer is a methyl methacrylate; Said acrylic compounds polar monomer is an acrylic acid.
8. wallpaper according to claim 6 is characterized in that, said ammonium persulfate is divided into just initiating stage and dropping stage two parts, and the said mass concentration of the ammonium persulfate of initiating stage just is 13 ~ 17%, is 2 ~ 8% of total monomer weight; The mass concentration of the ammonium persulfate in said dropping stage is 13 ~ 17%, is 1 ~ 4% of total monomer weight.
9. wallpaper according to claim 6 is characterized in that, the preparation process of said metope finishing agent is following:
S100, with the deionized water emulsification of monomer, surfactant and participation emulsion reaction 30min at least, monomer emulsions;
S200, will participate in polymerisation the deionized water heat temperature raising to 80-90 ℃, add the partial monosomy emulsion again, stir;
S300, the adding just initator of initiating stage react; Equitemperature begins to drip the remaining monomer emulsion and the initator in the stage of dropping when no longer raising; Maintain the temperature at 84-86 ℃, 2 ~ 4h adds, and dropwises the back at 84-86 ℃ of insulation 0.5 ~ 1.5h; Cooling adds ammoniacal liquor and transfers pH to 7.5 ~ 8.5, adds an amount of auxiliary agent.
10. wallpaper according to claim 1 is characterized in that, said base material is film, cloth or the metal sheet of plastics class.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210068225.1A CN102605679B (en) | 2012-03-15 | 2012-03-15 | Wallpaper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210068225.1A CN102605679B (en) | 2012-03-15 | 2012-03-15 | Wallpaper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102605679A true CN102605679A (en) | 2012-07-25 |
| CN102605679B CN102605679B (en) | 2014-03-26 |
Family
ID=46523414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210068225.1A Active CN102605679B (en) | 2012-03-15 | 2012-03-15 | Wallpaper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102605679B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102979007A (en) * | 2012-11-28 | 2013-03-20 | 上海艺亨实业有限公司 | Multifunctional ecological anion wallpaper |
| CN105482596A (en) * | 2015-11-25 | 2016-04-13 | 安徽索亚装饰材料有限公司 | Pumice-polylactic acid porous fiber modified acrylic resin emulsion coating-containing wallpaper |
| CN105505091A (en) * | 2015-11-25 | 2016-04-20 | 安徽索亚装饰材料有限公司 | Wallpaper containing a porous silicon carbide-polylactic acid porous fiber modified acrylic resin emulsion coating |
| CN105505079A (en) * | 2015-11-25 | 2016-04-20 | 安徽索亚装饰材料有限公司 | Wallpaper containing a zeolite powder-polylactic acid porous fiber modified acrylic resin emulsion coating |
| CN106753076A (en) * | 2015-11-25 | 2017-05-31 | 铂恩塞尔新材料（上海）股份有限公司 | A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof |
| CN108049179A (en) * | 2017-12-04 | 2018-05-18 | 杨帮燕 | A kind of preparation method of sound insulation curtain cloth |
| CN108546532A (en) * | 2018-05-10 | 2018-09-18 | 叶陈瑶 | A kind of waterproof air previous polyurethane acrylate wallpaper special glue and its preparation method and application |
| CN110028620A (en) * | 2019-03-20 | 2019-07-19 | 广东银洋环保新材料有限公司 | Pressure sensitive adhesive and preparation method thereof can be removed in a kind of one pack system |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2086272U (en) * | 1991-03-12 | 1991-10-09 | 上海真空喷铝包装材料厂 | Metallized wall paper |
| CN2106737U (en) * | 1990-10-15 | 1992-06-10 | 梁文德 | Self-bonding wall paper and wall-veneered cloth |
| CN1140780A (en) * | 1995-07-18 | 1997-01-22 | 马奔 | Moonlight wall paper |
| JP2007270413A (en) * | 2006-03-31 | 2007-10-18 | Dainippon Printing Co Ltd | Foamed wallpaper |
| CN201835184U (en) * | 2010-09-06 | 2011-05-18 | 崔江 | Wall paper made of stone paper |
-
2012
- 2012-03-15 CN CN201210068225.1A patent/CN102605679B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2106737U (en) * | 1990-10-15 | 1992-06-10 | 梁文德 | Self-bonding wall paper and wall-veneered cloth |
| CN2086272U (en) * | 1991-03-12 | 1991-10-09 | 上海真空喷铝包装材料厂 | Metallized wall paper |
| CN1140780A (en) * | 1995-07-18 | 1997-01-22 | 马奔 | Moonlight wall paper |
| JP2007270413A (en) * | 2006-03-31 | 2007-10-18 | Dainippon Printing Co Ltd | Foamed wallpaper |
| CN201835184U (en) * | 2010-09-06 | 2011-05-18 | 崔江 | Wall paper made of stone paper |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102979007A (en) * | 2012-11-28 | 2013-03-20 | 上海艺亨实业有限公司 | Multifunctional ecological anion wallpaper |
| CN102979007B (en) * | 2012-11-28 | 2017-02-08 | 上海艺亨实业有限公司 | Multifunctional ecological anion wallpaper |
| CN105482596A (en) * | 2015-11-25 | 2016-04-13 | 安徽索亚装饰材料有限公司 | Pumice-polylactic acid porous fiber modified acrylic resin emulsion coating-containing wallpaper |
| CN105505091A (en) * | 2015-11-25 | 2016-04-20 | 安徽索亚装饰材料有限公司 | Wallpaper containing a porous silicon carbide-polylactic acid porous fiber modified acrylic resin emulsion coating |
| CN105505079A (en) * | 2015-11-25 | 2016-04-20 | 安徽索亚装饰材料有限公司 | Wallpaper containing a zeolite powder-polylactic acid porous fiber modified acrylic resin emulsion coating |
| CN106753076A (en) * | 2015-11-25 | 2017-05-31 | 铂恩塞尔新材料（上海）股份有限公司 | A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof |
| CN108049179A (en) * | 2017-12-04 | 2018-05-18 | 杨帮燕 | A kind of preparation method of sound insulation curtain cloth |
| CN108546532A (en) * | 2018-05-10 | 2018-09-18 | 叶陈瑶 | A kind of waterproof air previous polyurethane acrylate wallpaper special glue and its preparation method and application |
| CN108546532B (en) * | 2018-05-10 | 2020-09-22 | 常州都铂高分子有限公司 | Waterproof breathable polyurethane acrylate wallpaper special glue and preparation method and application thereof |
| CN110028620A (en) * | 2019-03-20 | 2019-07-19 | 广东银洋环保新材料有限公司 | Pressure sensitive adhesive and preparation method thereof can be removed in a kind of one pack system |
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|---|---|
| CN102605679B (en) | 2014-03-26 |
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