CN106750947A - 一种新型环保抗静电阻燃电缆用材料 - Google Patents

一种新型环保抗静电阻燃电缆用材料 Download PDF

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CN106750947A
CN106750947A CN201611205556.XA CN201611205556A CN106750947A CN 106750947 A CN106750947 A CN 106750947A CN 201611205556 A CN201611205556 A CN 201611205556A CN 106750947 A CN106750947 A CN 106750947A
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杨玉双
徐华芳
王江海
蒋艳
金德胜
朱李红
黄显武
王焰芳
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ANHUI TIANYUAN CABLE Co Ltd
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    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
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    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
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Abstract

本发明公开了一种新型环保抗静电阻燃电缆用材料,其是由如下重量份数的原料组成:聚丙烯树脂60‑90份、EPDM树脂15‑25份、高密度聚乙烯20‑40份、三元乙丙橡胶40‑48份、聚苯硫醚30‑34份、硫化锌10‑20份、聚酰亚胺5‑8份、气相法白炭黑10‑12份、陶瓷化硼酸锌4‑10份、偶联剂6‑8份、发泡助剂4‑8份、阻燃剂4‑8份、热稳定剂3‑5份。与现有技术相比,本发明的电缆材料添加氢氧化镁作为阻燃剂,达到阻燃效果;添加聚苯硫醚和硫化锌可以有效的防止静电的产生;还添加了偶联剂、发泡助剂等组分,提高了阻燃材料的各项性能、使用寿命。

Description

一种新型环保抗静电阻燃电缆用材料
技术领域
本发明涉及电缆生产技术领域,具体涉及一种新型环保抗静电阻燃电缆用材料。
背景技术
电线电缆绝缘及护套用塑料俗称电缆料,其中包括了橡胶、塑料、尼龙等多种品种。电缆料生产企业是以电缆生产企业为用户,只要有电线电缆需求就有电缆料的市场。电线电缆产品中除钢芯铝绞线、电磁线等裸线产品外几乎都需要绝缘层口。目前我国有电线电缆生产企业近5000家,又有城乡电网改造、西部大开发及通信设施大面积升级改造对电线电缆产品的巨大需求,因而从一段时间来看,电缆料在我国具有广泛的市场发展前景。
然而,随着电气火灾事故的频繁发生,电线电缆的阻燃问题逐渐引起世界各国的重视。电缆燃烧时释放出大量有毒烟雾和腐蚀性气体,妨碍了人们的安全撤离和灭火工作,使生命财产遭到严重损失。目前使用的聚乙烯抗静电性和阻燃性较差,在制作电线电缆时容易引起火灾。
发明内容
本发明旨在提供了一种新型环保抗静电阻燃电缆用材料。
本发明提供如下技术方案:
一种新型环保抗静电阻燃电缆用材料,其是由如下重量份数的原料组成:聚丙烯树脂60-90份、EPDM树脂15-25份、高密度聚乙烯20-40份、三元乙丙橡胶40-48份、聚苯硫醚30-34份、硫化锌10-20份、聚酰亚胺5-8份、气相法白炭黑10-12份、陶瓷化硼酸锌4-10份、偶联剂6-8份、发泡助剂4-8份、阻燃剂4-8份、热稳定剂3-5份。
所述偶联剂由如下重量份数的原料制成:丁二烯基三乙氧基硅烷4-6份、乙烯基三乙酰基硅烷3-5份、乙烯基硅油1-2份、活性剂2-3份。
所述阻燃剂为氢氧化铝和氢氧化镁,氢氧化铝与氢氧化镁的用量比为2:5。
所述热稳定剂为为氧化硒、氢氧化硒或辛酸硒。
与现有技术相比,本发明的有益效果是:本发明的电缆材料添加氢氧化镁作为阻燃剂,达到阻燃效果;添加聚苯硫醚和硫化锌可以有效的防止静电的产生;还添加了偶联剂、发泡助剂等组分,提高了阻燃材料的各项性能、使用寿命。
具体实施方式
下面将结合本发明实施例,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例1一种新型环保抗静电阻燃电缆用材料,其是由如下重量份数的原料组成:聚丙烯树脂60份、EPDM树脂15份、高密度聚乙烯20份、三元乙丙橡胶40份、聚苯硫醚30份、硫化锌10份、聚酰亚胺5份、气相法白炭黑10份、陶瓷化硼酸锌4份、偶联剂6份、发泡助剂4份、阻燃剂4份、热稳定剂3份。
所述偶联剂由如下重量份数的原料制成:丁二烯基三乙氧基硅烷4-6份、乙烯基三乙酰基硅烷3-5份、乙烯基硅油1-2份、活性剂2-3份。
所述阻燃剂为氢氧化铝和氢氧化镁,氢氧化铝与氢氧化镁的用量比为2:5。
所述热稳定剂为为氧化硒、氢氧化硒或辛酸硒。
实施例2一种新型环保抗静电阻燃电缆用材料,其是由如下重量份数的原料组成:聚丙烯树脂90份、EPDM树脂25份、高密度聚乙烯40份、三元乙丙橡胶48份、聚苯硫醚34份、硫化锌20份、聚酰亚胺8份、气相法白炭黑12份、陶瓷化硼酸锌10份、偶联剂8份、发泡助剂8份、阻燃剂8份、热稳定剂5份。
所述偶联剂由如下重量份数的原料制成:丁二烯基三乙氧基硅烷4-6份、乙烯基三乙酰基硅烷3-5份、乙烯基硅油1-2份、活性剂2-3份。
所述阻燃剂为氢氧化铝和氢氧化镁,氢氧化铝与氢氧化镁的用量比为2:5。
所述热稳定剂为为氧化硒、氢氧化硒或辛酸硒。
实施例3一种新型环保抗静电阻燃电缆用材料,其是由如下重量份数的原料组成:聚丙烯树脂75份、EPDM树脂18份、高密度聚乙烯30份、三元乙丙橡胶44份、聚苯硫醚32份、硫化锌15份、聚酰亚胺7份、气相法白炭黑11份、陶瓷化硼酸锌8份、偶联剂7份、发泡助剂6份、阻燃剂6份、热稳定剂4份。
所述偶联剂由如下重量份数的原料制成:丁二烯基三乙氧基硅烷4-6份、乙烯基三乙酰基硅烷3-5份、乙烯基硅油1-2份、活性剂2-3份。
所述阻燃剂为氢氧化铝和氢氧化镁,氢氧化铝与氢氧化镁的用量比为2:5。
所述热稳定剂为为氧化硒、氢氧化硒或辛酸硒。
对于本领域技术人员而言,显然本发明不限于所述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是所述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。

Claims (4)

1.一种新型环保抗静电阻燃电缆用材料,其特征在于,其是由如下重量份数的原料组成:聚丙烯树脂60-90份、EPDM树脂15-25份、高密度聚乙烯20-40份、三元乙丙橡胶40-48份、聚苯硫醚30-34份、硫化锌10-20份、聚酰亚胺5-8份、气相法白炭黑10-12份、陶瓷化硼酸锌4-10份、偶联剂6-8份、发泡助剂4-8份、阻燃剂4-8份、热稳定剂3-5份。
2.根据权利要求1所述的一种新型环保抗静电阻燃电缆用材料,其特征在于:所述偶联剂由如下重量份数的原料制成:丁二烯基三乙氧基硅烷4-6份、乙烯基三乙酰基硅烷3-5份、乙烯基硅油1-2份、活性剂2-3份。
3.根据权利要求1所述的一种新型环保抗静电阻燃电缆用材料,其特征在于:所述阻燃剂为氢氧化铝和氢氧化镁,氢氧化铝与氢氧化镁的用量比为2:5。
4.根据权利要求1所述的一种新型环保抗静电阻燃电缆用材料,其特征在于:所述热稳定剂为为氧化硒、氢氧化硒或辛酸硒。
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Citations (6)

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JPH03227337A (ja) * 1990-01-31 1991-10-08 Fujikura Ltd 難燃性組成物および難燃性ケーブル
JPH07145308A (ja) * 1993-11-25 1995-06-06 Mitsubishi Gas Chem Co Inc 帯電防止性ポリマー組成物
CN103724810A (zh) * 2013-12-31 2014-04-16 广东三凌塑料管材有限公司 一种聚丙烯电缆护套管
CN105860247A (zh) * 2016-06-20 2016-08-17 江苏达胜高聚物股份有限公司 一种低烟无卤建筑电缆绝缘材料及其制备方法
CN105885424A (zh) * 2016-06-12 2016-08-24 安徽天元电缆有限公司 一种电力电缆用耐火材料
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JPH07145308A (ja) * 1993-11-25 1995-06-06 Mitsubishi Gas Chem Co Inc 帯電防止性ポリマー組成物
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CN105885424A (zh) * 2016-06-12 2016-08-24 安徽天元电缆有限公司 一种电力电缆用耐火材料
CN106024167A (zh) * 2016-06-12 2016-10-12 安徽天元电缆有限公司 一种阻燃、耐火电缆材料
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