CN106715330A - 结晶性硅钛酸盐的制造方法 - Google Patents
结晶性硅钛酸盐的制造方法 Download PDFInfo
- Publication number
- CN106715330A CN106715330A CN201580052702.7A CN201580052702A CN106715330A CN 106715330 A CN106715330 A CN 106715330A CN 201580052702 A CN201580052702 A CN 201580052702A CN 106715330 A CN106715330 A CN 106715330A
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- CN
- China
- Prior art keywords
- mixed gel
- silicic acid
- titanium tetrachloride
- sodium
- sio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- 239000010936 titanium Substances 0.000 claims abstract description 61
- 239000011734 sodium Substances 0.000 claims abstract description 58
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 45
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 40
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 31
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 26
- 150000003388 sodium compounds Chemical class 0.000 claims abstract description 26
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 21
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 14
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 29
- 229910052700 potassium Inorganic materials 0.000 claims description 22
- 150000003112 potassium compounds Chemical class 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
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- 229910052906 cristobalite Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 229910052682 stishovite Inorganic materials 0.000 claims description 9
- 229910052905 tridymite Inorganic materials 0.000 claims description 9
- 150000001340 alkali metals Chemical class 0.000 claims description 8
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 8
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 238000001179 sorption measurement Methods 0.000 abstract description 25
- 229910004298 SiO 2 Inorganic materials 0.000 abstract description 13
- 239000013535 sea water Substances 0.000 abstract description 13
- 239000000499 gel Substances 0.000 description 49
- 229960004029 silicic acid Drugs 0.000 description 35
- 239000007864 aqueous solution Substances 0.000 description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 18
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 17
- 239000003463 adsorbent Substances 0.000 description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 14
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 13
- 239000011591 potassium Substances 0.000 description 13
- 239000004115 Sodium Silicate Substances 0.000 description 12
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- 239000004111 Potassium silicate Substances 0.000 description 7
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- 229910052913 potassium silicate Inorganic materials 0.000 description 7
- 235000011121 sodium hydroxide Nutrition 0.000 description 7
- 235000011118 potassium hydroxide Nutrition 0.000 description 6
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
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- GNKTZDSRQHMHLZ-UHFFFAOYSA-N [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] Chemical compound [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] GNKTZDSRQHMHLZ-UHFFFAOYSA-N 0.000 description 2
- -1 alkali metal salt Chemical class 0.000 description 2
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- 238000000975 co-precipitation Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0211—Compounds of Ti, Zr, Hf
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/12—Processing by absorption; by adsorption; by ion-exchange
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- High Energy & Nuclear Physics (AREA)
- General Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-204045 | 2014-10-02 | ||
| JP2014204045A JP6025795B2 (ja) | 2014-10-02 | 2014-10-02 | 結晶性シリコチタネートの製造方法 |
| PCT/JP2015/077715 WO2016052611A1 (ja) | 2014-10-02 | 2015-09-30 | 結晶性シリコチタネートの製造方法 |
Publications (1)
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| CN106715330A true CN106715330A (zh) | 2017-05-24 |
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| CN201580052702.7A Pending CN106715330A (zh) | 2014-10-02 | 2015-09-30 | 结晶性硅钛酸盐的制造方法 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110193349A (zh) * | 2019-06-27 | 2019-09-03 | 中国科学院青海盐湖研究所 | 负载钛硅酸盐的生物质碳气凝胶吸附剂及其制法与应用 |
| CN117222597A (zh) * | 2021-04-22 | 2023-12-12 | 三井化学株式会社 | 改性铝硅酸盐的制造方法、改性铝硅酸盐及使用了改性铝硅酸盐的芳香族多羟基化合物的制造方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6808443B2 (ja) * | 2016-10-26 | 2021-01-06 | 日本化学工業株式会社 | 結晶性シリコチタネートの製造方法 |
| KR102035801B1 (ko) * | 2017-10-19 | 2019-10-24 | 한국과학기술원 | 세슘과 스트론튬의 동시 흡착을 위한 나트륨과 칼륨을 포함하는 티타늄실리케이트 흡착제 및 그 제조방법 |
| WO2019151748A1 (ko) * | 2018-01-31 | 2019-08-08 | 서강대학교산학협력단 | 판형 티타노실리케이트 분자체, 상기 분자체의 제조 방법, 및 상기 분자체를 포함하는 이산화탄소 흡착제 |
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| WO1994019277A1 (en) * | 1993-02-25 | 1994-09-01 | Sandia National Laboratories | Novel silico-titanates and their methods of making and using |
| CN1131126A (zh) * | 1995-12-22 | 1996-09-18 | 吉林大学 | 钛硅酸盐沸石分子筛晶体及其制备方法 |
| CN103831090A (zh) * | 2014-03-07 | 2014-06-04 | 中国人民解放军海军工程大学 | 一种铯选择性吸附剂及其制备方法 |
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| US6436294B2 (en) * | 1998-11-24 | 2002-08-20 | 3M Innovative Properties Company | Process for modifying the metal ion sorption capacity of a medium |
| US6974563B2 (en) * | 2002-06-18 | 2005-12-13 | Lynntech, Inc. | Ion exchange materials for the separation of 90Y from 90SR |
| JP5696244B1 (ja) * | 2014-03-27 | 2015-04-08 | 日本化学工業株式会社 | 吸着材 |
| JP2016003151A (ja) * | 2014-06-16 | 2016-01-12 | 日本化学工業株式会社 | 結晶性シリコチタネートの製造方法 |
| JP6356567B2 (ja) * | 2014-10-02 | 2018-07-11 | 日本化学工業株式会社 | 結晶性シリコチタネートの製造方法 |
| JP5758057B1 (ja) * | 2015-02-09 | 2015-08-05 | 日本化学工業株式会社 | 結晶性シリコチタネートの製造方法 |
-
2014
- 2014-10-02 JP JP2014204045A patent/JP6025795B2/ja active Active
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2015
- 2015-09-30 EP EP15847637.4A patent/EP3190087A4/en not_active Withdrawn
- 2015-09-30 CN CN201580052702.7A patent/CN106715330A/zh active Pending
- 2015-09-30 US US15/515,231 patent/US20170216813A1/en not_active Abandoned
- 2015-09-30 WO PCT/JP2015/077715 patent/WO2016052611A1/ja active Application Filing
- 2015-09-30 CA CA2962911A patent/CA2962911A1/en not_active Abandoned
- 2015-10-01 TW TW104132297A patent/TW201615552A/zh unknown
Patent Citations (3)
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| WO1994019277A1 (en) * | 1993-02-25 | 1994-09-01 | Sandia National Laboratories | Novel silico-titanates and their methods of making and using |
| CN1131126A (zh) * | 1995-12-22 | 1996-09-18 | 吉林大学 | 钛硅酸盐沸石分子筛晶体及其制备方法 |
| CN103831090A (zh) * | 2014-03-07 | 2014-06-04 | 中国人民解放军海军工程大学 | 一种铯选择性吸附剂及其制备方法 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110193349A (zh) * | 2019-06-27 | 2019-09-03 | 中国科学院青海盐湖研究所 | 负载钛硅酸盐的生物质碳气凝胶吸附剂及其制法与应用 |
| CN117222597A (zh) * | 2021-04-22 | 2023-12-12 | 三井化学株式会社 | 改性铝硅酸盐的制造方法、改性铝硅酸盐及使用了改性铝硅酸盐的芳香族多羟基化合物的制造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3190087A4 (en) | 2018-05-23 |
| US20170216813A1 (en) | 2017-08-03 |
| JP6025795B2 (ja) | 2016-11-16 |
| TW201615552A (zh) | 2016-05-01 |
| CA2962911A1 (en) | 2016-04-07 |
| JP2016074548A (ja) | 2016-05-12 |
| EP3190087A1 (en) | 2017-07-12 |
| WO2016052611A1 (ja) | 2016-04-07 |
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