CN106714852A - Perfume composition - Google Patents

Perfume composition Download PDF

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Publication number
CN106714852A
CN106714852A CN201580046823.0A CN201580046823A CN106714852A CN 106714852 A CN106714852 A CN 106714852A CN 201580046823 A CN201580046823 A CN 201580046823A CN 106714852 A CN106714852 A CN 106714852A
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weight
content
flavor compositions
plum
composition
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CN106714852B (en
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朴胤玉
姜成辉
尹保任
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LG H&H Co Ltd
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LG Household and Health Care Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00Formulations or additives for perfume preparations

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Botany (AREA)
  • Zoology (AREA)
  • Emergency Medicine (AREA)
  • Fats And Perfumes (AREA)
  • Cosmetics (AREA)
  • Seasonings (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The specification relates to a perfume composition reproducing Prunus salicina blossom fragrance, containing a Prunus salicina blossom fragrance component and an artificial fragrance component.

Description

Flavor compositions
Technical field
The present invention relates to a kind of flavor compositions of reproducible plum flowery odour.
Background technology
Japanese plum (Prunus salicina) is the rosaceous deciduous tree of Rosales of dicotyledon, and it highly reaches 10m, bark is dark brown and the irregular rosaceous deciduous tree split.It grows in Hanbando middle part, also referred to as Purple peach, Japanese plum.Japanese plum diseases and insect pests resistance is strong, soil suitability is excellent, therefore, can be cultivated in the whole area of Hanbando.
Plum flower is bloomed in April, is first opened than leaf, usually spends fasciation in vain for 3.Calyx piece has slightly sawtooth, floral leaf Length is 1cm.Plum flower was once to determine the precious flower that is used as the royal badge for representing great Han empires by ancestor emperor high, Because it gives off a strong fragrance and beautiful, in national maximum plum milpa Jin Quan, plum flower section can be all held every year.
Though plum flower has distinctive fragrance, popular very few to its cognition degree compared to plum fruit, accordingly, it would be desirable to Develop can reproduction of reality plum flowery odour so that with distinguished, new feature flavor compositions.
The content of the invention
Invent problem to be solved
It is an object of the present invention to provide a kind of flavor compositions, the peculiar fragrance of a flower that it reproduces plum flower, with excellent Palatability.
The technical scheme of solve problem
The present invention provides a kind of flavor compositions, and it includes plum flowery odour composition and artificial flavors composition, above-mentioned artificial Fragrance component is selected from the one kind in the group being made up of linalool, MDJ, bergamio and benzyl acetate Or it is two or more.
In addition, the present invention provides a kind of skin preparations for extenal use, comprising above-mentioned flavor compositions.
In addition, the present invention provides a kind of personal care product, comprising above-mentioned flavor compositions.
In addition, the present invention provides a kind of household care products, comprising above-mentioned flavor compositions.
Invention effect
The flavor compositions of one embodiment of the present invention can reproduce plum flowery odour.
In addition, flavor compositions according to an embodiment of the present invention, with the similarity with plum flowery odour height And/or the fragrance satisfaction of height.
Specific embodiment
Hereinafter, the present invention will be explained in more detail.
When mentioning which inscape of which part "comprising" in this manual, such as without especially opposite record, then Refer to be not excluded for other inscapes, can also include other inscapes.
In the full text of this specification, the term " combinations thereof " in the performance of Markush form is included in, refers to be selected from The mixing or combination of one or more of the group constituted in the inscape described in the performance by Markush form, i.e., be Refer to comprising one or more of group being made up of above-mentioned inscape.
The present invention provides a kind of flavor compositions, and it includes plum flowery odour composition and artificial flavors composition, above-mentioned artificial Fragrance component is selected from by linalool (Linalool), MDJ (Hedione), bergamio (Linalyl Acetate one or more) and in the group that is constituted of benzyl acetate (Benzyl Acetate).
Plum flowery odour composition of the invention is the natural component of plum flower.
An implementation method according to this specification, above-mentioned plum flowery odour composition includes anethole (Anethole), lemon Alkene (Limonene), 2- aminobenzaldehydes (2-Aminobenzaldehyde), carvol (Carvone), gaultherolin (Methyl salicylate), benzaldehyde (Benzaldehyde), methyl nonyl ketone (Methyl nonyl ketone) and Phenmethylol (Benzyl alcohol).
According to another implementation method, above-mentioned plum flowery odour composition also comprising be selected from by anisaldehyde (Anisaldehyde), One or two in the group that hexyl acetate (Hexyl acetate) and methyl cinnamate (Methyl cinnamate) are constituted Above composition.
Above-mentioned anethole (Anethole), limonene (Limonene), 2- aminobenzaldehydes (2- Aminobenzaldehyde), carvol (Carvone), gaultherolin (Methyl salicylate), benzaldehyde (Benzaldehyde), methyl nonyl ketone (Methyl nonyl ketone), phenmethylol (Benzyl alcohol), fennel Aldehyde (Anisaldehyde), hexyl acetate (Hexyl acetate) and methyl cinnamate (Methyl cinnamate) etc. are Lee The main component of sub- flowery odour.But, in the case where only above-mentioned plum flowery odour composition is included, it is impossible to reproduce plum and spend peculiar Fragrance.
Flavor compositions according to an embodiment of the present invention, in addition to comprising above-mentioned plum flowery odour composition, also wrap Containing one or more in the group being made up of linalool, MDJ, bergamio and benzyl acetate Artificial flavors composition such that it is able to reproduce plum flowery odour and can have excellent palatability.
Above-mentioned plum flowery odour composition is using the effective headspace analysis of fragrance matter for analyzing natural goods (Headspace analysis) method and obtain.
Method usually as fragrance is extracted, often uses extraction (extraction), the steaming using vapor of solvent During evaporating method (distillation) etc., but utilization above method extraction flavor component, perfume (or spice) is caused because of heating, pressurization etc. Disappearance, change of taste composition etc., the fragrance characteristic having with original matter have very big difference.As the side for improving disadvantages mentioned above Method, develops head space (Headspace) method and SPME (SPME, Solid-Phase Micro Extraction) method Deng.Both approaches are different from conventional method, do not use solvent, without pretreatment, therefore do not need substantial amounts of sample, can Flavor component can be analyzed by sample itself, therefore the above method is can reproduce that sample has former dulcet good Method.
In one implementation method of this specification, above-mentioned plum flowery odour composition can be analyzed and/or be carried using Head space Take, but be not limited to the above method.
In one implementation method of this specification, the content of above-mentioned plum flower natural component is counted on the basis of total flavor compositions 75 weight of weight % to 98 % are accounted for, the content of above-mentioned artificial flavors is counted on the basis of total flavor compositions and accounts for 2 weights of weight % to 25 Amount %.
The content of above-mentioned artificial flavors counts accounting less than in the case of 2 weight % on the basis of total flavor compositions, fragrance Similitude can reduce;In the case of more than 25 weight %, influence can be produced on preference.Therefore, the spices in above range Composition can have the degree of reproducibility of plum flowery odour and/or with preference high.It is however not limited to above range contains Amount, purpose, formulation also dependent on composition and change.
In one implementation method of this specification, above-mentioned artificial flavors are selected from by linalool, MDJ, acetic acid Fragrant camphor tree ester and benzyl acetate composition group in one or more.
In one implementation method of this specification, above-mentioned artificial flavors include MDJ.Specifically, it is above-mentioned Artificial flavors include MDJ, and selected from the group being made up of linalool, bergamio and benzyl acetate One or more.
In another embodiment of the present invention, above-mentioned artificial flavors include linalool, MDJ, acetic acid virtue Camphor tree ester and benzyl acetate.
In one implementation method of this specification, above-mentioned plum flowery odour composition includes anethole (Anethole), limonene (Limonene), 2- aminobenzaldehydes (2-Aminobenzaldehyde), carvol (Carvone), gaultherolin (Methyl salicylate), benzaldehyde (Benzaldehyde), methyl nonyl ketone (Methyl nonyl ketone) and Phenmethylol (Benzyl alcohol), above-mentioned artificial flavors composition includes linalool, MDJ, bergamio And benzyl acetate.
Also, counted on the basis of the gross mass of above-mentioned flavor compositions, the content of anethole is 15 weights of weight % to 35 Amount %;The content of limonene is 12.5 weight of weight % to 25 %;The content of 2- aminobenzaldehydes is 7 weights of weight % to 17 Amount %;The content of carvol is 2.5 weight of weight % to 8.5 %;The content of gaultherolin is 1.8 weight of weight % to 7 %; The content of benzaldehyde is 4 weight of weight % to 8 %;The content of methyl nonyl ketone is 0.8 weight of weight % to 3 %;Phenmethylol Content be 0.8 weight of weight % to 1.8 %;The content of linalool is 8 weight of weight % to 18 %;MDJ Content be 9 weight of weight % to 20 %;The content of bergamio is 3 weight of weight % to 9.5 %;The content of benzyl acetate It is 2 weight of weight % to 8 %.
In another implementation method, above-mentioned plum flowery odour composition also includes anisaldehyde (Anisaldehyde), hexyl acetate (Hexyl acetate) and methyl cinnamate (Methyl cinnamate), on the basis of the gross mass of above-mentioned flavor compositions Meter, the content of anisaldehyde is 0.3 weight of weight % to 1.5 %;The content of hexyl acetate is 0.2 weight of weight % to 0.6 %;Meat The content of acid methylester is 0.1 weight of weight % to 0.3 %.
In this specification, above-mentioned plum flowery odour composition and artificial flavors composition can be used city's pin product, it is possible to use from plant The composition that thing separates or synthesizes and prepare, but not limited to this.
In addition, providing the skin preparations for extenal use comprising above-mentioned flavor compositions in this specification.
In this specification, there are basic cosmetics, makeup cosmetic or body skin care item, ointment as above-mentioned skin preparations for extenal use Deng, its formulation is not particularly limited, can be selected from by gel, skin lotion, concentration elite, emulsion, gel, ointment, paste, spray A kind of formulation in the group of mist agent and creme composition.
In this specification, the formulation of above-mentioned basic cosmetics or body skin care item has lotion, creme, Essence, gel, change Adornment water, facial mask, nourishing cream, massage cream, emulsion, balneation agent, suncream, sunblock lotion etc., but not limited to this.
In addition, in this specification, the formulation of above-mentioned makeup cosmetic have foundation emulsion, sun screen, lipstick, eye shadow, eye-liner, Mascara, eyebrow pencil etc., but not limited to this.
Personal care product comprising above-mentioned flavor compositions is provided in this specification.
Above-mentioned personal care product has the Hair Stying Products such as hair cream, hair moistening liquid, hair conditioner, pomade, gel, mousse;Toothpaste, The dental products such as gargle;The skin cleaners such as perfumed soap, washing cream, mildy wash, makeup remover and makeup remover;Perfume etc., but do not limit In this.
Household care products comprising above-mentioned flavor compositions are provided in this specification.
Above-mentioned household care products have aromatic;And liquid ceanser, kitchen lotion, laundry lotion, bathroom lotion etc. Lotion, but not limited to this.
In addition, in an implementation method of this specification, above-mentioned composition can also include spices, pigment, sterilization according to formulation The additives generally in the art such as agent, antioxidant, preservative, NMF, thickener, inorganic salts, synthetic high polymer matter.
Above-mentioned skin preparations for extenal use, personal care product and household care products can be in the models of the purpose for not influenceing this specification Enclose it is interior respectively comprising the flavor compositions, its content and formulation are not limited, by selecting aforementioned additive, can be as needed Required formulation is selected to be prepared.
Embodiment
Hereinafter, in order to illustrate this specification, enumerate embodiment and be described in detail.But, the implementation of this specification Example can be deformed into various different embodiments, and the scope of this specification is not limited to embodiments discussed below.This specification Embodiment provided to more completely illustrate this specification to those skilled in the art.
The flavor component that experimental example 1. is spent using head space (Headspace) method analysis plum
Headspace analysis method is the method for the sample flavor component of extractable nature script, present invention uses head space Analytic approach, following constituent analysis has been carried out using the method described in document.The denseer plum branch of fragrance is selected, in Japanese plum Colored part puts sealable plastics, using power set forced circulation extraneous air, and flows through the air of circulation Teenax posts trap flavor component.Be located at the plum peasant household in North Kyongsang Jin Quan cities where trapping field, and trapped 7 it is small When.The teenax posts that fragrance will have been trapped are connected on gas chromatographic analysis (Gas chromatography) device, analyze institute The species and content of the flavor component of trapping, the results are shown in table 1 below.
< analysis conditions >
Analytical instrument:Agilent 7890A
Detector:FID/MSD 1:1
Post:TC-WAX 30m×250μm×0.25μm
Injection unit temperature:100℃
Test section temperature:250℃
Furnace temperature:40 DEG C (5 minutes)~230 DEG C (100 minutes), 3.0 DEG C/min
Mobile phase gas:He
Injection rate:1μl
Table 1
Spices title Weight %
Anethole 28.8
Limonene 20.8
2- aminobenzaldehydes 14.7
Carvol 8.0
Gaultherolin 5.9
Benzaldehyde 5.1
Methyl nonyl ketone 1.4
Phenmethylol 1.3
Anisaldehyde 0.85
Hexyl acetate 0.39
Methyl cinnamate 0.26
Other 12.5
Total content 100.00
It is analyzing as described above as a result, it is possible to confirm that natural plum flowery odour composition is:Anethole (Anethole) 28.8 weight %, the weight of 20.8 weight %, 2- aminobenzaldehyde (2-Aminobenzaldehyde) of limonene (Limonene) 14.7 Amount %, the weight % of carvol (Carvone) 8.0, the weight % of gaultherolin (Methyl salicylate) 5.9, benzaldehyde (Benzaldehyde) 5.1 weight %, methyl nonyl ketone (Methyl nonyl ketone) 1.4 weight %, phenmethylol (Benzyl alcohol) 1.3 weight %, the weight % of anisaldehyde (Anisaldehyde) 0.85, hexyl acetate (Hexyl Acetate) the 0.39 weight % and weight % of methyl cinnamate (Methyl cinnamate) 0.26.And, it is thus identified that it is relative In overall natural plum flowery odour composition, the total amount of mentioned component accounts for 87.5 weight %.
The plum flowery odour of experimental example 2. reproduces the preparation of spices and compares with former aromatic fragrance
11 experts for being engaged in fragrance industry original fragrance is spent to plum and combined by table 2 below constitute reproduction spices (ginseng According to table 2) carry out sensory evaluation.
Table 2
Evaluation result, the plum flower combined according to above-mentioned table 2 reproduces spices and is be evaluated as spending former aromatic phase with plum Low like property, the satisfaction to fragrance is be evaluated as unsatisfied level.
Therefore, it is inappropriate that the fragrance of plum flower is only reproduced by head space (Headspace) analysis result.Can be upper New flavor component is added on the basis of head space (Headspace) result for stating table 1 to confirm necessity that plum flowery odour reproduces Property.
The preparation of the flavor compositions of experimental example 3.
The plum fragrance of a flower has the distinctive fragrance of fragrant and fruity the characteristic of the sweet honey that adulterated in the soft fragrance of a flower. Therefore, in addition to plum flowery odour composition, the linalool with above-mentioned plum flowery odour feature, dihydro jasmone acid be also added The artificial flavors composition of methyl esters, bergamio and benzyl acetate is prepared into flavor compositions.
Spices is prepared into by the composition for combining table 3 below.
Table 3
(unit:Weight %)
The fragrance repeatability of the flavor compositions of experimental example 4. is evaluated
27 to 46 years old healthy 18 common womans are carried out into sensory evaluation as sensory evaluation object.Plum is spent The evaluation of original fragrance repeatability is evaluated by the questionnaire of table 4 below, to being prepared in embodiment 1 to 5 and comparative example 1 to 3 Flavor compositions evaluated with 5 points of point systems.Evaluate room and sample preparation room to separate, make estimator to sample without prior It is cognitive.
The plum flowery odour repeatability evaluation result of above-mentioned comparative example 1 to 3 and embodiment 1 to 5 such as table 5 below is recorded.
Table 4
Fraction Similarity
1 It is very different
2 It is slightly different
3 Typically
4 It is somewhat similar
5 It is closely similar
Table 5
Evaluation object is 18 women that average age is 37.1 years old.
It is able to confirm that by the result of upper table 5, the only ratio comprising plum flowery odour composition of the analysis based on above-mentioned experimental example 1 Low-down similarity is shown compared with example 1.In addition, being able to confirm that by adjusting containing for the main component in plum flowery odour composition The flavor compositions and plum of flavor compositions, i.e. comparative example 2 and the comparative example 3 measuring and prepare spend former aromatic similarity Increase is small.
In contrast to this, it is able to confirm that comprising in linalool, MDJ, bergamio and benzyl acetate The embodiment 1 to 5 of one or more artificial flavors composition spends former dulcet similarity increased with plum.
Enable in particular to confirm that the similarity of the embodiment 2 to 5 comprising MDJ is high, by embodiment 2 Result is able to confirm that, comprising plum flowery odour composition and contains linalool, MDJ, bergamio and second In the case of the artificial flavors composition of acid benzyl ester, similarity increases most.
The fragrance satisfaction evaluation of the flavor compositions of experimental example 5.
27 to 46 years old healthy 18 common womans are carried out into sensory evaluation as sensory evaluation object.It is inclined to fragrance The evaluation of good degree is evaluated by the questionnaire of table 6, and the flavor compositions to being prepared in embodiment 1 to 5 and comparative example 1 to 3 use 5 Point point system is evaluated.Evaluate room and sample preparation room to separate, make estimator to sample without cognitive in advance.
The satisfaction evaluation result of the plum flowery odour of above-mentioned comparative example 1 to 3 and embodiment 1 to 5 such as table 7 is recorded.
Table 6
Fraction Similarity
1 It is very bad
2 It is somewhat bad
3 Typically
4 It is slightly good
5 It is very good
Table 7
Evaluation object is 18 women that average age is 37.1 years old.
Be able to confirm that by the result of above-mentioned table 7, based on the analysis of above-mentioned experimental example 1 only comprising plum flowery odour into The comparative example 1 for dividing shows low-down satisfaction.In addition, be able to confirm that, to main in plum flowery odour composition by adjusting Comparative example 2 and the satisfaction of comparative example 3 prepared by the content of composition do not reach the average level of satisfaction evaluation yet.
In contrast to this, it is able to confirm that comprising in linalool, MDJ, bergamio and benzyl acetate The satisfaction of the embodiment 1 to 5 of one or more artificial flavors composition increases.
Enable in particular to confirm, the satisfaction of the embodiment 2 to 5 comprising MDJ is high, by the knot of embodiment 2 Fruit is able to confirm that, comprising plum flowery odour composition and contains linalool, MDJ, bergamio and acetic acid In the case of the artificial flavors composition of benzyl ester, satisfaction increases most.
From upper table 5 and the result of table 7, in above-mentioned plum flowery odour composition comprising selected from by linalool, dihydro jasmine The situation of one or more the artificial flavors composition in the group of ketone acid methyl esters, bergamio and benzyl acetate composition Under, it is able to confirm that the lifting that special dulcet similarity high and satisfaction are spent with plum.

Claims (10)

1. a kind of flavor compositions, wherein, comprising plum flowery odour composition and artificial flavors composition, the artificial flavors composition is Selected from one or more in the group being made up of linalool, MDJ, bergamio and benzyl acetate.
2. flavor compositions according to claim 1, wherein, the plum flowery odour composition comprising anethole, limonene, 2- aminobenzaldehydes, carvol, gaultherolin, benzaldehyde, methyl nonyl ketone and phenmethylol.
3. flavor compositions according to claim 2, wherein, the plum flowery odour composition is also comprising being selected from by fennel Aldehyde, hexyl acetate and methyl cinnamate composition group in one or more.
4. flavor compositions according to claim 1, wherein, the artificial flavors include MDJ.
5. flavor compositions according to claim 1, wherein, the content of the plum flower natural component is with total combinations of perfumes Meter accounts for 75 weight of weight % to 98 % on the basis of thing, and the content of the artificial flavors is counted on the basis of total flavor compositions and accounts for 2 weights The amount weight of % to 25 %.
6. flavor compositions according to claim 2, wherein, the artificial flavors composition includes linalool, dihydro jasmine Ketone acid methyl esters, bergamio and benzyl acetate, are counted on the basis of the gross mass of the flavor compositions, and the content of anethole is 15 weight of weight % to 35 %;The content of limonene is 12.5 weight of weight % to 25 %;The content of 2- aminobenzaldehydes is 7 weights The amount weight of % to 17 %;The content of carvol is 2.5 weight of weight % to 8.5 %;The content of gaultherolin is 1.8 weight % To 7 weight %;The content of benzaldehyde is 4 weight of weight % to 8 %;The content of methyl nonyl ketone is 0.8 weights of weight % to 3 Amount %;The content of phenmethylol is 0.8 weight of weight % to 1.8 %;The content of linalool is 8 weight of weight % to 18 %;Dihydro The content of methyl jasmonate is 9 weight of weight % to 20 %;The content of bergamio is 3 weight of weight % to 9.5 %;Second The content of acid benzyl ester is 2 weight of weight % to 8 %.
7. flavor compositions according to claim 6, wherein, the plum flowery odour composition also includes anisaldehyde, acetic acid Own ester and methyl cinnamate, are counted on the basis of the gross mass of the flavor compositions, the content of anisaldehyde for 0.3 weight % extremely 1.5 weight %;The content of hexyl acetate is 0.2 weight of weight % to 0.6 %;The content of methyl cinnamate be 0.1 weight % extremely 0.3 weight %.
8. a kind of skin preparations for extenal use, wherein, comprising the flavor compositions any one of claim 1~7.
9. a kind of personal care product, wherein, comprising the flavor compositions any one of claim 1~7.
10. a kind of household care products, wherein, comprising the flavor compositions any one of claim 1~7.
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