CN106702749A - 一种纺织面料表面改性处理剂及其制备方法 - Google Patents

一种纺织面料表面改性处理剂及其制备方法 Download PDF

Info

Publication number
CN106702749A
CN106702749A CN201611150232.0A CN201611150232A CN106702749A CN 106702749 A CN106702749 A CN 106702749A CN 201611150232 A CN201611150232 A CN 201611150232A CN 106702749 A CN106702749 A CN 106702749A
Authority
CN
China
Prior art keywords
parts
powder
mesh
fabric surface
surface modification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611150232.0A
Other languages
English (en)
Inventor
梁荣强
谢小坚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongshan Degaoxing Intellectual Property Center LP
Original Assignee
Zhongshan Degaoxing Intellectual Property Center LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongshan Degaoxing Intellectual Property Center LP filed Critical Zhongshan Degaoxing Intellectual Property Center LP
Priority to CN201611150232.0A priority Critical patent/CN106702749A/zh
Publication of CN106702749A publication Critical patent/CN106702749A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D06M13/03—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons with unsaturated hydrocarbons, e.g. alkenes, or alkynes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D06M13/156—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246—Esters of unsaturated carboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D06M13/298—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/572—Reaction products of isocyanates with polyesters or polyesteramides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

本发明涉及一种纺织面料表面改性处理剂，由以下组分组成：甲基乙烯基苯基硅橡胶、SEBS热塑性弹性体、聚酯氨基甲酸酯树脂、亚麻油、樟脑油、丙酸异戊酯、4‑羟基‑4‑甲基‑2‑戊酮、纯丙乳液、氧化苦参碱、8‑羟基喹啉铜、氯化三乙基锡、丁香酚、纳米硫酸钡、聚六亚甲基胍、柠檬烯、磺胺嘧啶银、氯氧化锆粉末、苯基含氢硅树脂、硼镁石粉末、铬酸锶粉末、十溴联苯醚、纳米氢氧化镁、三氯乙基磷酸酯、磷酸三氯乙酯、邻苯二甲酸二异壬酯、聚丙烯酸乙酯、对氯间二甲苯酚、三异丙醇胺、对叔丁基苯甲酸、马来酸酐接枝聚乙烯。本发明产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能，改善了产品性能。

Description

一种纺织面料表面改性处理剂及其制备方法
技术领域
本发明涉及一种纺织面料表面改性处理剂及其制备方法，属于纺织技术领域。
背景技术
纺织助剂是纺织品生产加工过程中必须的化学品。纺织助剂对提高纺织品的产品质量和附加价值具有不可或缺的重要作用，它不仅能赋予纺织品各种特殊功能和风格，如柔软、防皱、防缩、防水、抗菌、抗静电、阻燃等，还可以改进染整工艺，起到节约能源和降低加工成本的作用。纺织助剂对提升纺织工业的整体水平以及在纺织产业链中的作用是至关重要的。
发明内容
本发明的目的在于提供一种纺织面料表面改性处理剂，以便更好地实现纺织面料表面改性处理剂的使用功能，使产品具有阻燃、耐酸碱、防霉变抗菌性能，改善产品使用性能。
为了实现上述目的，本发明的技术方案如下。
一种纺织面料表面改性处理剂，由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶28～32份、SEBS热塑性弹性体26～30份、聚酯氨基甲酸酯树脂26～30份、亚麻油24～28份、樟脑油26～30份、丙酸异戊酯26～30份、4-羟基-4-甲基-2-戊酮24～28份、纯丙乳液26～30份、氧化苦参碱26～30份、8-羟基喹啉铜24～28份、氯化三乙基锡24～28份、丁香酚24～28份、纳米硫酸钡26～30份、聚六亚甲基胍24～28份、柠檬烯22～26份、磺胺嘧啶银26～30份、氯氧化锆粉末24～28份、苯基含氢硅树脂22～26份、硼镁石粉末24～28份、铬酸锶粉末22～26份、十溴联苯醚22～26份、纳米氢氧化镁22～26份、三氯乙基磷酸酯20～24份、磷酸三氯乙酯16～20份、邻苯二甲酸二异壬酯14～18份、聚丙烯酸乙酯14～18份、对氯间二甲苯酚14～18份、三异丙醇胺14～18份、对叔丁基苯甲酸14～18份、马来酸酐接枝聚乙烯14～18份。
进一步地，上述纺织面料表面改性处理剂，由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶28份、SEBS热塑性弹性体26份、聚酯氨基甲酸酯树脂26份、亚麻油24份、樟脑油26份、丙酸异戊酯26份、4-羟基-4-甲基-2-戊酮24份、纯丙乳液26份、氧化苦参碱26份、8-羟基喹啉铜24份、氯化三乙基锡24份、丁香酚24份、纳米硫酸钡26份、聚六亚甲基胍24份、柠檬烯22份、磺胺嘧啶银26份、氯氧化锆粉末24份、苯基含氢硅树脂22份、硼镁石粉末24份、铬酸锶粉末22份、十溴联苯醚22份、纳米氢氧化镁22份、三氯乙基磷酸酯20份、磷酸三氯乙酯16份、邻苯二甲酸二异壬酯14份、聚丙烯酸乙酯14份、对氯间二甲苯酚14份、三异丙醇胺14份、对叔丁基苯甲酸14份、马来酸酐接枝聚乙烯14份。
进一步地，上述纺织面料表面改性处理剂，由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶30份、SEBS热塑性弹性体28份、聚酯氨基甲酸酯树脂28份、亚麻油26份、樟脑油28份、丙酸异戊酯28份、4-羟基-4-甲基-2-戊酮26份、纯丙乳液28份、氧化苦参碱28份、8-羟基喹啉铜26份、氯化三乙基锡26份、丁香酚26份、纳米硫酸钡28份、聚六亚甲基胍26份、柠檬烯24份、磺胺嘧啶银28份、氯氧化锆粉末26份、苯基含氢硅树脂24份、硼镁石粉末26份、铬酸锶粉末24份、十溴联苯醚24份、纳米氢氧化镁24份、三氯乙基磷酸酯22份、磷酸三氯乙酯18份、邻苯二甲酸二异壬酯16份、聚丙烯酸乙酯16份、对氯间二甲苯酚16份、三异丙醇胺16份、对叔丁基苯甲酸16份、马来酸酐接枝聚乙烯16份。
进一步地，上述纺织面料表面改性处理剂，由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶32份、SEBS热塑性弹性体30份、聚酯氨基甲酸酯树脂30份、亚麻油28份、樟脑油30份、丙酸异戊酯30份、4-羟基-4-甲基-2-戊酮28份、纯丙乳液30份、氧化苦参碱30份、8-羟基喹啉铜28份、氯化三乙基锡28份、丁香酚28份、纳米硫酸钡30份、聚六亚甲基胍28份、柠檬烯26份、磺胺嘧啶银30份、氯氧化锆粉末28份、苯基含氢硅树脂26份、硼镁石粉末28份、铬酸锶粉末26份、十溴联苯醚26份、纳米氢氧化镁26份、三氯乙基磷酸酯24份、磷酸三氯乙酯20份、邻苯二甲酸二异壬酯18份、聚丙烯酸乙酯18份、对氯间二甲苯酚18份、三异丙醇胺18份、对叔丁基苯甲酸18份、马来酸酐接枝聚乙烯18份。
进一步地，所述铬酸锶粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为3～9∶4～8∶1。
进一步地，所述氯氧化锆粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为3～7∶2～8∶1。
进一步地，所述聚丙烯酸乙酯的粘度在25℃为120～140mpa.s。
进一步地，所述硼镁石粉末由三种粒径目数的粉体组成，其粒径目数分别为20～50目、50～70目、70～90目，上述三种粉体的混合质量比例为2～4∶3～5∶1。
进一步地，所述亚麻油的粘度在25℃为80～100mpa.s。
进一步地，上述纺织面料表面改性处理剂制备方法步骤如下：
(1)将所述质量份数的甲基乙烯基苯基硅橡胶、SEBS热塑性弹性体、聚酯氨基甲酸酯树脂、亚麻油、樟脑油、丙酸异戊酯、4-羟基-4-甲基-2-戊酮、纯丙乳液、氧化苦参碱、8-羟基喹啉铜、氯化三乙基锡、丁香酚、纳米硫酸钡、聚六亚甲基胍、柠檬烯、磺胺嘧啶银、氯氧化锆粉末、苯基含氢硅树脂、硼镁石粉末、铬酸锶粉末予以混合，超声高速分散，超声波频率为20～40KHz，分散速度5000～5400r/min左右，分散时间为30～60min；
(2)加入所述质量份数的十溴联苯醚、纳米氢氧化镁、三氯乙基磷酸酯、磷酸三氯乙酯、邻苯二甲酸二异壬酯，超声高速分散，超声波频率为20～35KHz，分散速度4800～5200r/min左右，分散时间为30～50min；
(3)加入所述质量份数的聚丙烯酸乙酯、对氯间二甲苯酚、三异丙醇胺、对叔丁基苯甲酸、马来酸酐接枝聚乙烯，超声高速分散，超声波频率为20～30KHz，分散速度4600～4800r/min左右，分散时间为20～40min；混合均匀后制得本品。
该发明的有益效果在于：本发明中的纺织面料表面改性处理剂，由以下组分组成：甲基乙烯基苯基硅橡胶、SEBS热塑性弹性体、聚酯氨基甲酸酯树脂、亚麻油、樟脑油、丙酸异戊酯、4-羟基-4-甲基-2-戊酮、纯丙乳液、氧化苦参碱、8-羟基喹啉铜、氯化三乙基锡、丁香酚、纳米硫酸钡、聚六亚甲基胍、柠檬烯、磺胺嘧啶银、氯氧化锆粉末、苯基含氢硅树脂、硼镁石粉末、铬酸锶粉末、十溴联苯醚、纳米氢氧化镁、三氯乙基磷酸酯、磷酸三氯乙酯、邻苯二甲酸二异壬酯、聚丙烯酸乙酯、对氯间二甲苯酚、三异丙醇胺、对叔丁基苯甲酸、马来酸酐接枝聚乙烯。本发明产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能，改善了产品性能。
具体实施方式
下面结合实施例对本发明的具体实施方式进行描述，以便更好的理解本发明。
本发明中的纺织面料表面改性处理剂，由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶28～32份、SEBS热塑性弹性体26～30份、聚酯氨基甲酸酯树脂26～30份、亚麻油24～28份、樟脑油26～30份、丙酸异戊酯26～30份、4-羟基-4-甲基-2-戊酮24～28份、纯丙乳液26～30份、氧化苦参碱26～30份、8-羟基喹啉铜24～28份、氯化三乙基锡24～28份、丁香酚24～28份、纳米硫酸钡26～30份、聚六亚甲基胍24～28份、柠檬烯22～26份、磺胺嘧啶银26～30份、氯氧化锆粉末24～28份、苯基含氢硅树脂22～26份、硼镁石粉末24～28份、铬酸锶粉末22～26份、十溴联苯醚22～26份、纳米氢氧化镁22～26份、三氯乙基磷酸酯20～24份、磷酸三氯乙酯16～20份、邻苯二甲酸二异壬酯14～18份、聚丙烯酸乙酯14～18份、对氯间二甲苯酚14～18份、三异丙醇胺14～18份、对叔丁基苯甲酸14～18份、马来酸酐接枝聚乙烯14～18份。
所述铬酸锶粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为3～9∶4～8∶1。
所述氯氧化锆粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为3～7∶2～8∶1。
所述聚丙烯酸乙酯的粘度在25℃为120～140mpa.s。
所述硼镁石粉末由三种粒径目数的粉体组成，其粒径目数分别为20～50目、50～70目、70～90目，上述三种粉体的混合质量比例为2～4∶3～5∶1。
所述亚麻油的粘度在25℃为80～100mpa.s。
实施例1
本实施例中的纺织面料表面改性处理剂，由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶28份、SEBS热塑性弹性体26份、聚酯氨基甲酸酯树脂26份、亚麻油24份、樟脑油26份、丙酸异戊酯26份、4-羟基-4-甲基-2-戊酮24份、纯丙乳液26份、氧化苦参碱26份、8-羟基喹啉铜24份、氯化三乙基锡24份、丁香酚24份、纳米硫酸钡26份、聚六亚甲基胍24份、柠檬烯22份、磺胺嘧啶银26份、氯氧化锆粉末24份、苯基含氢硅树脂22份、硼镁石粉末24份、铬酸锶粉末22份、十溴联苯醚22份、纳米氢氧化镁22份、三氯乙基磷酸酯20份、磷酸三氯乙酯16份、邻苯二甲酸二异壬酯14份、聚丙烯酸乙酯14份、对氯间二甲苯酚14份、三异丙醇胺14份、对叔丁基苯甲酸14份、马来酸酐接枝聚乙烯14份。
所述铬酸锶粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为3∶4∶1。
所述氯氧化锆粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为3∶2∶1。
所述聚丙烯酸乙酯的粘度在25℃为120mpa.s。
所述硼镁石粉末由三种粒径目数的粉体组成，其粒径目数分别为20～50目、50～70目、70～90目，上述三种粉体的混合质量比例为2∶3∶1。
所述亚麻油的粘度在25℃为80mpa.s。
上述纺织面料表面改性处理剂制备方法步骤如下：
(1)将所述质量份数的甲基乙烯基苯基硅橡胶、SEBS热塑性弹性体、聚酯氨基甲酸酯树脂、亚麻油、樟脑油、丙酸异戊酯、4-羟基-4-甲基-2-戊酮、纯丙乳液、氧化苦参碱、8-羟基喹啉铜、氯化三乙基锡、丁香酚、纳米硫酸钡、聚六亚甲基胍、柠檬烯、磺胺嘧啶银、氯氧化锆粉末、苯基含氢硅树脂、硼镁石粉末、铬酸锶粉末予以混合，超声高速分散，超声波频率为20kHz，分散速度5400r/min左右，分散时间为60min；
(2)加入所述质量份数的十溴联苯醚、纳米氢氧化镁、三氯乙基磷酸酯、磷酸三氯乙酯、邻苯二甲酸二异壬酯，超声高速分散，超声波频率为20kHz，分散速度5200r/min左右，分散时间为50min；
(3)加入所述质量份数的聚丙烯酸乙酯、对氯间二甲苯酚、三异丙醇胺、对叔丁基苯甲酸、马来酸酐接枝聚乙烯，超声高速分散，超声波频率为20kHz，分散速度4800r/min左右，分散时间为40min；混合均匀后制得本品。
实施例2
本实施例中的纺织面料表面改性处理剂，由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶30份、SEBS热塑性弹性体28份、聚酯氨基甲酸酯树脂28份、亚麻油26份、樟脑油28份、丙酸异戊酯28份、4-羟基-4-甲基-2-戊酮26份、纯丙乳液28份、氧化苦参碱28份、8-羟基喹啉铜26份、氯化三乙基锡26份、丁香酚26份、纳米硫酸钡28份、聚六亚甲基胍26份、柠檬烯24份、磺胺嘧啶银28份、氯氧化锆粉末26份、苯基含氢硅树脂24份、硼镁石粉末26份、铬酸锶粉末24份、十溴联苯醚24份、纳米氢氧化镁24份、三氯乙基磷酸酯22份、磷酸三氯乙酯18份、邻苯二甲酸二异壬酯16份、聚丙烯酸乙酯16份、对氯间二甲苯酚16份、三异丙醇胺16份、对叔丁基苯甲酸16份、马来酸酐接枝聚乙烯16份。
所述铬酸锶粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为6∶6∶1。
所述氯氧化锆粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为5∶4∶1。
所述聚丙烯酸乙酯的粘度在25℃为130mpa.s。
所述硼镁石粉末由三种粒径目数的粉体组成，其粒径目数分别为20～50目、50～70目、70～90目，上述三种粉体的混合质量比例为3∶4∶1。
所述亚麻油的粘度在25℃为90mpa.s。
上述纺织面料表面改性处理剂制备方法步骤如下：
(1)将所述质量份数的甲基乙烯基苯基硅橡胶、SEBS热塑性弹性体、聚酯氨基甲酸酯树脂、亚麻油、樟脑油、丙酸异戊酯、4-羟基-4-甲基-2-戊酮、纯丙乳液、氧化苦参碱、8-羟基喹啉铜、氯化三乙基锡、丁香酚、纳米硫酸钡、聚六亚甲基胍、柠檬烯、磺胺嘧啶银、氯氧化锆粉末、苯基含氢硅树脂、硼镁石粉末、铬酸锶粉末予以混合，超声高速分散，超声波频率为30kHz，分散速度5200r/min左右，分散时间为45min；
(2)加入所述质量份数的十溴联苯醚、纳米氢氧化镁、三氯乙基磷酸酯、磷酸三氯乙酯、邻苯二甲酸二异壬酯，超声高速分散，超声波频率为27kHz，分散速度5000r/min左右，分散时间为40min；
(3)加入所述质量份数的聚丙烯酸乙酯、对氯间二甲苯酚、三异丙醇胺、对叔丁基苯甲酸、马来酸酐接枝聚乙烯，超声高速分散，超声波频率为25kHz，分散速度4700r/min左右，分散时间为30min；混合均匀后制得本品。
实施例3
本实施例中的纺织面料表面改性处理剂，由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶32份、SEBS热塑性弹性体30份、聚酯氨基甲酸酯树脂30份、亚麻油28份、樟脑油30份、丙酸异戊酯30份、4-羟基-4-甲基-2-戊酮28份、纯丙乳液30份、氧化苦参碱30份、8-羟基喹啉铜28份、氯化三乙基锡28份、丁香酚28份、纳米硫酸钡30份、聚六亚甲基胍28份、柠檬烯26份、磺胺嘧啶银30份、氯氧化锆粉末28份、苯基含氢硅树脂26份、硼镁石粉末28份、铬酸锶粉末26份、十溴联苯醚26份、纳米氢氧化镁26份、三氯乙基磷酸酯24份、磷酸三氯乙酯20份、邻苯二甲酸二异壬酯18份、聚丙烯酸乙酯18份、对氯间二甲苯酚18份、三异丙醇胺18份、对叔丁基苯甲酸18份、马来酸酐接枝聚乙烯18份。
所述铬酸锶粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为9∶8∶1。
所述氯氧化锆粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为7∶8∶1。
所述聚丙烯酸乙酯的粘度在25℃为140mpa.s。
所述硼镁石粉末由三种粒径目数的粉体组成，其粒径目数分别为20～50目、50～70目、70～90目，上述三种粉体的混合质量比例为4∶5∶1。
所述亚麻油的粘度在25℃为100mpa.s。
上述纺织面料表面改性处理剂制备方法步骤如下：
(1)将所述质量份数的甲基乙烯基苯基硅橡胶、SEBS热塑性弹性体、聚酯氨基甲酸酯树脂、亚麻油、樟脑油、丙酸异戊酯、4-羟基-4-甲基-2-戊酮、纯丙乳液、氧化苦参碱、8-羟基喹啉铜、氯化三乙基锡、丁香酚、纳米硫酸钡、聚六亚甲基胍、柠檬烯、磺胺嘧啶银、氯氧化锆粉末、苯基含氢硅树脂、硼镁石粉末、铬酸锶粉末予以混合，超声高速分散，超声波频率为40kHz，分散速度5000r/min，分散时间为30min；
(2)加入所述质量份数的十溴联苯醚、纳米氢氧化镁、三氯乙基磷酸酯、磷酸三氯乙酯、邻苯二甲酸二异壬酯，超声高速分散，超声波频率为35kHz，分散速度4800r/min，分散时间为30min；
(3)加入所述质量份数的聚丙烯酸乙酯、对氯间二甲苯酚、三异丙醇胺、对叔丁基苯甲酸、马来酸酐接枝聚乙烯，超声高速分散，超声波频率为30kHz，分散速度4600r/min左右，分散时间为20min；混合均匀后制得本品。
针对实施例1、实施例2和实施例3中的产品和某市售产品进行性能测量，所测得的数据如表1所示。防火阻燃等级测试采用UL94标准。
表1 性能测试结果
可见，本发明产品具有较好的耐腐蚀、防火阻燃、防霉变、抗菌性能。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (10)

1.一种纺织面料表面改性处理剂，其特征在于：由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶28～32份、SEBS热塑性弹性体26～30份、聚酯氨基甲酸酯树脂26～30份、亚麻油24～28份、樟脑油26～30份、丙酸异戊酯26～30份、4-羟基-4-甲基-2-戊酮24～28份、纯丙乳液26～30份、氧化苦参碱26～30份、8-羟基喹啉铜24～28份、氯化三乙基锡24～28份、丁香酚24～28份、纳米硫酸钡26～30份、聚六亚甲基胍24～28份、柠檬烯22～26份、磺胺嘧啶银26～30份、氯氧化锆粉末24～28份、苯基含氢硅树脂22～26份、硼镁石粉末24～28份、铬酸锶粉末22～26份、十溴联苯醚22～26份、纳米氢氧化镁22～26份、三氯乙基磷酸酯20～24份、磷酸三氯乙酯16～20份、邻苯二甲酸二异壬酯14～18份、聚丙烯酸乙酯14～18份、对氯间二甲苯酚14～18份、三异丙醇胺14～18份、对叔丁基苯甲酸14～18份、马来酸酐接枝聚乙烯14～18份。
2.根据权利要求1所述的纺织面料表面改性处理剂，其特征在于：所述纺织面料表面改性处理剂由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶28份、SEBS热塑性弹性体26份、聚酯氨基甲酸酯树脂26份、亚麻油24份、樟脑油26份、丙酸异戊酯26份、4-羟基-4-甲基-2-戊酮24份、纯丙乳液26份、氧化苦参碱26份、8-羟基喹啉铜24份、氯化三乙基锡24份、丁香酚24份、纳米硫酸钡26份、聚六亚甲基胍24份、柠檬烯22份、磺胺嘧啶银26份、氯氧化锆粉末24份、苯基含氢硅树脂22份、硼镁石粉末24份、铬酸锶粉末22份、十溴联苯醚22份、纳米氢氧化镁22份、三氯乙基磷酸酯20份、磷酸三氯乙酯16份、邻苯二甲酸二异壬酯14份、聚丙烯酸乙酯14份、对氯间二甲苯酚14份、三异丙醇胺14份、对叔丁基苯甲酸14份、马来酸酐接枝聚乙烯14份。
3.根据权利要求1至2所述的纺织面料表面改性处理剂，其特征在于：所述纺织面料表面改性处理剂由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶30份、SEBS热塑性弹性体28份、聚酯氨基甲酸酯树脂28份、亚麻油26份、樟脑油28份、丙酸异戊酯28份、4-羟基-4-甲基-2-戊酮26份、纯丙乳液28份、氧化苦参碱28份、8-羟基喹啉铜26份、氯化三乙基锡26份、丁香酚26份、纳米硫酸钡28份、聚六亚甲基胍26份、柠檬烯24份、磺胺嘧啶银28份、氯氧化锆粉末26份、苯基含氢硅树脂24份、硼镁石粉末26份、铬酸锶粉末24份、十溴联苯醚24份、纳米氢氧化镁24份、三氯乙基磷酸酯22份、磷酸三氯乙酯18份、邻苯二甲酸二异壬酯16份、聚丙烯酸乙酯16份、对氯间二甲苯酚16份、三异丙醇胺16份、对叔丁基苯甲酸16份、马来酸酐接枝聚乙烯16份。
4.根据权利要求1至3所述的纺织面料表面改性处理剂，其特征在于：所述纺织面料表面改性处理剂由以下质量份数的组分组成：甲基乙烯基苯基硅橡胶32份、SEBS热塑性弹性体30份、聚酯氨基甲酸酯树脂30份、亚麻油28份、樟脑油30份、丙酸异戊酯30份、4-羟基-4-甲基-2-戊酮28份、纯丙乳液30份、氧化苦参碱30份、8-羟基喹啉铜28份、氯化三乙基锡28份、丁香酚28份、纳米硫酸钡30份、聚六亚甲基胍28份、柠檬烯26份、磺胺嘧啶银30份、氯氧化锆粉末28份、苯基含氢硅树脂26份、硼镁石粉末28份、铬酸锶粉末26份、十溴联苯醚26份、纳米氢氧化镁26份、三氯乙基磷酸酯24份、磷酸三氯乙酯20份、邻苯二甲酸二异壬酯18份、聚丙烯酸乙酯18份、对氯间二甲苯酚18份、三异丙醇胺18份、对叔丁基苯甲酸18份、马来酸酐接枝聚乙烯18份。
5.根据权利要求1至4所述的纺织面料表面改性处理剂，其特征在于：所述铬酸锶粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为3～9∶4～8∶1。
6.根据权利要求1至4所述的纺织面料表面改性处理剂，其特征在于：所述氯氧化锆粉末由三种粒径目数的粉体组成，其粒径目数分别为30～50目、50～80目、80～100目，上述三种粉体的混合质量比例为3～7∶2～8∶1。
7.根据权利要求1至5所述的纺织面料表面改性处理剂，其特征在于：所述聚丙烯酸乙酯的粘度在25℃为120～140mpa.s。
8.根据权利要求1所述的纺织面料表面改性处理剂，其特征在于：所述硼镁石粉末由三种粒径目数的粉体组成，其粒径目数分别为20～50目、50～70目、70～90目，上述三种粉体的混合质量比例为2～4∶3～5∶1。
9.根据权利要求1所述的纺织面料表面改性处理剂，其特征在于：所述亚麻油的粘度在25℃为80～100mpa.s。
10.根据权利要求1所述的纺织面料表面改性处理剂，其特征在于：所述纺织面料表面改性处理剂制备方法步骤如下：
(1)将所述质量份数的甲基乙烯基苯基硅橡胶、SEBS热塑性弹性体、聚酯氨基甲酸酯树脂、亚麻油、樟脑油、丙酸异戊酯、4-羟基-4-甲基-2-戊酮、纯丙乳液、氧化苦参碱、8-羟基喹啉铜、氯化三乙基锡、丁香酚、纳米硫酸钡、聚六亚甲基胍、柠檬烯、磺胺嘧啶银、氯氧化锆粉末、苯基含氢硅树脂、硼镁石粉末、铬酸锶粉末予以混合，超声高速分散，超声波频率为20～40KHz，分散速度约5000～5400r/min，分散时间为30～60min左右；
(2)加入所述质量份数的十溴联苯醚、纳米氢氧化镁、三氯乙基磷酸酯、磷酸三氯乙酯、邻苯二甲酸二异壬酯，超声高速分散，超声波频率为20～35KHz，分散速度为约4800～5200r/min，分散时间为30～50min左右；
(3)加入所述质量份数的聚丙烯酸乙酯、对氯间二甲苯酚、三异丙醇胺、对叔丁基苯甲酸、马来酸酐接枝聚乙烯，超声高速分散，超声波频率为20～30KHz，分散速度为约4600～4800r/min，分散时间为20～40min左右；混合均匀后制得本品。
CN201611150232.0A 2016-12-13 2016-12-13 一种纺织面料表面改性处理剂及其制备方法 Pending CN106702749A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611150232.0A CN106702749A (zh) 2016-12-13 2016-12-13 一种纺织面料表面改性处理剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611150232.0A CN106702749A (zh) 2016-12-13 2016-12-13 一种纺织面料表面改性处理剂及其制备方法

Publications (1)

Publication Number Publication Date
CN106702749A true CN106702749A (zh) 2017-05-24

Family

ID=58935815

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611150232.0A Pending CN106702749A (zh) 2016-12-13 2016-12-13 一种纺织面料表面改性处理剂及其制备方法

Country Status (1)

Country Link
CN (1) CN106702749A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112920312A (zh) * 2021-03-01 2021-06-08 吴江市天利聚合物有限公司 一种高粘附性纺织浆料及其制备方法
CN113818243A (zh) * 2021-10-18 2021-12-21 厦门勤嘉诚工贸有限公司 一种环保再生仿真丝涤纶面料
WO2023171353A1 (ja) * 2022-03-08 2023-09-14 信越化学工業株式会社 ２液型熱伝導性付加硬化型シリコーン組成物及びそのシリコーン硬化物
WO2023171352A1 (ja) * 2022-03-08 2023-09-14 信越化学工業株式会社 熱伝導性付加硬化型シリコーン組成物及びそのシリコーン硬化物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106087393A (zh) * 2016-07-29 2016-11-09 李云海 一种纺织服装面料阻燃抗菌涂层
CN106118405A (zh) * 2016-07-29 2016-11-16 王志英 一种数码印花面料阻燃抗菌涂料
CN106189828A (zh) * 2016-08-29 2016-12-07 袁华 一种室内装修用抗菌防霉变阻燃底漆
CN106189636A (zh) * 2016-08-01 2016-12-07 龚灿锋 一种纺织面料阻燃抗菌涂层

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106087393A (zh) * 2016-07-29 2016-11-09 李云海 一种纺织服装面料阻燃抗菌涂层
CN106118405A (zh) * 2016-07-29 2016-11-16 王志英 一种数码印花面料阻燃抗菌涂料
CN106189636A (zh) * 2016-08-01 2016-12-07 龚灿锋 一种纺织面料阻燃抗菌涂层
CN106189828A (zh) * 2016-08-29 2016-12-07 袁华 一种室内装修用抗菌防霉变阻燃底漆

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112920312A (zh) * 2021-03-01 2021-06-08 吴江市天利聚合物有限公司 一种高粘附性纺织浆料及其制备方法
CN112920312B (zh) * 2021-03-01 2022-04-22 吴江市天利聚合物有限公司 一种高粘附性纺织浆料及其制备方法
CN113818243A (zh) * 2021-10-18 2021-12-21 厦门勤嘉诚工贸有限公司 一种环保再生仿真丝涤纶面料
WO2023171353A1 (ja) * 2022-03-08 2023-09-14 信越化学工業株式会社 ２液型熱伝導性付加硬化型シリコーン組成物及びそのシリコーン硬化物
WO2023171352A1 (ja) * 2022-03-08 2023-09-14 信越化学工業株式会社 熱伝導性付加硬化型シリコーン組成物及びそのシリコーン硬化物

Similar Documents

Publication Publication Date Title
CN106702749A (zh) 一种纺织面料表面改性处理剂及其制备方法
CN105462006B (zh) 一种防静电丁腈手套及其制作方法
CN102619127B (zh) 一种环保高适印性无纺壁纸原纸
CN104805680A (zh) 一种功能性织物的制备方法
CN1285795C (zh) 一种高效抗菌、防臭织物的制备方法
CN107401051B (zh) 氧化锌-季铵盐聚合物复合抗菌剂及其制备方法
CN107287899A (zh) 棉织物的抗菌整理方法
JP2013177711A (ja) 手袋及びその製造方法
CN109400798B (zh) 环保型超疏水/疏油纺织品整理剂、其制备方法及应用
CN104532584B (zh) 一种抗菌棉织物的制备方法
CN108866668A (zh) 一种纳米阻燃纤维及其制备方法
TW201522388A (zh) 含氟聚合物及處理劑
CN108384078A (zh) 一种导电防护胶质手套的制备方法
CN106009857A (zh) 一种阻燃抗菌面料
CN105155269A (zh) 一种季铵盐抗菌剂单体改性织物整理剂及其制备方法
CN105088373A (zh) 一种抗菌面料及其制备方法
CN110382651A (zh) 拒油剂组合物
CN102937841B (zh) 吸汗防污喷膜鼠标及其制备方法
CN106590476A (zh) 一种静电植绒胶粘剂及其制备方法
CN105297444A (zh) 一种抗菌阻燃服装涂料
CN104727147A (zh) 拒水防油整理剂及其应用
KR102022466B1 (ko) 항균 분말을 원단에 부착시키기 위한 코팅액
CN1710187B (zh) 纳米复合金属涂层纺织品及制备工艺
CN111607977B (zh) 一种抗菌抗病毒皮革及其制备方法和应用
CN106634113A (zh) 一种电力设施用表面处理涂层

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170524