CN106700748A - Preparation method of scrub-resistant calcium carbonate powder interior wall coating - Google Patents
Preparation method of scrub-resistant calcium carbonate powder interior wall coating Download PDFInfo
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- CN106700748A CN106700748A CN201611260770.5A CN201611260770A CN106700748A CN 106700748 A CN106700748 A CN 106700748A CN 201611260770 A CN201611260770 A CN 201611260770A CN 106700748 A CN106700748 A CN 106700748A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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Abstract
The invention discloses a preparation method of a scrub-resistant calcium carbonate powder interior wall coating. The preparation method comprises the following steps: 1) weighing calcium carbonate, hydrochloric acid, formaldehyde, pure water, sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, calcium hydroxide, magnesium hydride, phosphoric acid, sodium hydroxide, paraffin and calcium oxide; 2) putting hydrochloric acid, formaldehyde, pure water, sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, phosphoric acid and sodium hydroxide into a reaction still provided with a stirrer and a thermometer, warming to 60 to 80 DEG C, stirring for 30 to 50 min, adding paraffin, cooling to 30 to 50 DEG C, and continuously stirring for 20 to 40 min; 3) warming to 90 to 100 DEG C, adding the remaining raw materials, stirring for 100 to 120 min, grinding through a three-roller grinder, cooling, filtering and examining to be qualified so as to obtain the coating. The coating is bright, clean and smooth and free of power removal or brush mark, the fineness is 25 to 45 microns, the surface dry lasts for 20 to 40 min, and the solid dry lasts for 18 to 22 h; the coating is free of caked paste or precipitate and and is uniform in color and luster, easy for brush application and free of sagging, the heat resistance at 100 DEG C is unchanged for 1 to 5 h, and the adhesive force is 100%.
Description
Technical field
The present invention relates to paint field, more particularly to a kind of preparation method of scrubbing resistance calcium carbonate powder interior wall coating.
Background technology
Calcium carbonate is that the extremely wide precious resources lime stone of purposes is trade name of the limestone as raw mineral materials.Limestone
On history of human civilization, be distributed in nature with it is wide, be widely used the characteristics of be easily obtained.As important building
Material has long production history, and in modern industry, lime stone is manufacture cement, lime, the primary raw material of calcium carbide, is smelting
Indispensable flux limestone in metal working industry, after fat lime stone is through superfine grinding, be widely used in papermaking, rubber, paint,
In the manufacture of the products such as coating, medicine, cosmetics, feed, sealing, bonding, polishing.According to incompletely statistics, manufacture of cement consumption
Lime stone and building stone, lime production, flux for metallurgy, the ratio between summation of calcium carbonate superfine powder consumption lime stone is 1: 3.Lime
Rock is non-renewable resources, and with the development of the continuous progressive and nanometer technology of science and technology, the application field of lime stone will also
Further widen.
Calcium carbonate can play a kind of skeleton function as Chinese white in coating, and calcium carbonate can conduct in coatings industry
Extender pigment.Because calcium carbonate color is white, the relative latex in coating, solvent price is all cheap, and particle is thin, can be
It is dispersed in coating, so being a large amount of extender pigments for using.Due to the raising of environmental consciousness, coating is big in terms of building
Amount water paint, because calcium carbonate is white and hydrophilic, price is again cheap, so obtaining application.Inserting for calcium carbonate can increase
Deposition and permeability of the strong priming paint to substrate surface.It, for filling and leading up basal plane, is the centre of overall coating that putty is in coating
Layer, no matter what putty is required for plus mass filler, the filler body in putty is powdered whiting, then adds some zinc barium on a small quantity
It is white to prevent enamelled coating loose to increase viscosity, while being properly joined into winnofil to be polished after doing.
Liquid reason stone texture product makes product fully achieve Water-borne modification with unique technique for packing, and VOC content is extremely low,
Substantially increase the service life of exterior wall paint；Simulation quality high, coating surface is concavo-convex submissive, and color is interpenetrated, the energy on color
Imitate natural granite stone；Environmental protection and energy saving, the increasingly rare valuable stone material of substitutable resources coordinates external wall outer insulation to carry out specialty
Artificial granite decoration, comply fully with country with the energy-conserving and environment-protective requirement of building coating；Decorative effect is excellent, the color depth with
Meaning, decorative pattern size is random.Exterior wall paint liquid reason stone texture product improves the service life of exterior wall paint；Coating is wear-resistant, washable
Brush, high temperature resistant, acid rain resistant, adhesive force is strong, and ductility is good, waterproof, mould proof, and self-cleaning is good；Application property is excellent, one-shot forming, construction
Phase is short；Cost performance is high, is suitable for any irregular metope, can decorate the parts such as any bending, thin side, can fully demonstrate building
Lines and stereovision.Wall load-bearing is reduced, cost only has the 30~40% of natural granite cost.
Therefore, present invention exploitation devises the good scrubbing resistance of a kind of fast drying, nontoxic, water-tolerant, non-ignitable and erasibility
Calcium carbonate powder interior wall coating, to meet the market demand.
The content of the invention
The technical problem of solution：
The application dries slow, poor erasibility, poor water resistance, the technical problem that Storage period is short and adhesive force is low for existing coating,
A kind of preparation method of scrubbing resistance calcium carbonate powder interior wall coating is provided.
Technical scheme：
A kind of preparation method of scrubbing resistance calcium carbonate powder interior wall coating, it comprises the following steps：
The first step：Weigh calcium carbonate, hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, hydrogen
Calcium oxide, magnesium hydride, phosphoric acid, NaOH, paraffin and calcium oxide；
Second step：By hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, phosphoric acid and hydrogen-oxygen
Change sodium input to be provided with the reactor of agitator and thermometer, be warming up to 60-80 DEG C, stir 30-50min, mixing speed is
400-600 revs/min, paraffin is added, be cooled to 30-50 DEG C, continue to stir 20-40min；
3rd step：90-100 DEG C is warming up to, surplus stock is added, 100-120min is stirred, mixing speed is 800-1000 revs/min
Clock, grinds, cooled and filtered, after the assay was approved through three-roll grinder.
As one embodiment of the present invention, step 1）Described in each raw material, by weight match it is as follows：Calcium carbonate
100 parts, hydrochloric acid 1-5 parts, formaldehyde 1.5-5.5 parts, pure water 80-100 parts, penta sodium pentachlorophenate 10-30 parts, styrene 30-50 parts, propylene
Acid butyl ester 20-40 parts, methacrylic acid 15-35 parts, calcium hydroxide 30-50 parts, magnesium hydride 1-5 parts, phosphoric acid 0.3-0.7 parts, hydrogen
Sodium oxide molybdena 0.5-2.5 parts, paraffin 1-5 parts, calcium oxide 25-45 parts.
As one embodiment of the present invention, step 1）Described in each raw material, by weight match it is as follows：Calcium carbonate
100 parts, hydrochloric acid 2-4 parts, formaldehyde 2.5-4.5 parts, pure water 85-95 parts, penta sodium pentachlorophenate 15-25 parts, styrene 35-45 parts, propylene
Acid butyl ester 25-35 parts, methacrylic acid 20-30 parts, calcium hydroxide 35-45 parts, magnesium hydride 2-4 parts, phosphoric acid 0.4-0.6 parts, hydrogen
Sodium oxide molybdena 1-2 parts, paraffin 2-4 parts, calcium oxide 30-40 parts.
As one embodiment of the present invention, step 1）Described in each raw material, 100 parts of calcium carbonate, 2 parts of hydrochloric acid, formaldehyde
2.5 parts, 85 parts of pure water, 15 parts of penta sodium pentachlorophenate, 35 parts of styrene, 25 parts of butyl acrylate, 20 parts of methacrylic acid, calcium hydroxide
35 parts, 2 parts of magnesium hydride, 0.4 part of phosphoric acid, 1 part of NaOH, 2 parts of paraffin, 30 parts of calcium oxide.
As one embodiment of the present invention, step 1）Described in each raw material, 100 parts of calcium carbonate, 4 parts of hydrochloric acid, formaldehyde
4.5 parts, 95 parts of pure water, 25 parts of penta sodium pentachlorophenate, 45 parts of styrene, 35 parts of butyl acrylate, 30 parts of methacrylic acid, calcium hydroxide
45 parts, 4 parts of magnesium hydride, 0.6 part of phosphoric acid, 2 parts of NaOH, 4 parts of paraffin, 40 parts of calcium oxide.
As one embodiment of the present invention, step 1）Described in each raw material, 100 parts of calcium carbonate, 3 parts of hydrochloric acid, formaldehyde
3.5 parts, 90 parts of pure water, 20 parts of penta sodium pentachlorophenate, 40 parts of styrene, 30 parts of butyl acrylate, 25 parts of methacrylic acid, calcium hydroxide
40 parts, 3 parts of magnesium hydride, 0.5 part of phosphoric acid, 1.5 parts of NaOH, 3 parts of paraffin, 35 parts of calcium oxide.
Beneficial effect：
A kind of preparation method of scrubbing resistance calcium carbonate powder interior wall coating of the present invention, obtained coating has following technology
Effect：1st, film is bright and clean smooth, not shedding, and without brush mark, 25-45 μm of fineness, surface drying 20-40min does solid work 18-22h；2nd, coating
Without caking paste and precipitation, easily uniform color, brushing, no sag, 1-5h is unchanged at 100 DEG C of heat resistance, adhesive force 100%；
3rd, water resistance 5-10d is non-foaming, do not fall off, not shedding, and alkali resistance 4-8d is without elephant skin；4th, it is non-ignitable, nontoxic, tasteless, scrub resistance
1200-1800 times not show-through, and wearability is good, bin stability 6-10 month, can extensively produce and constantly replace current material.
Specific embodiment
Embodiment 1:
Proportioning weighs 100 parts of calcium carbonate, 1 part of hydrochloric acid, 1.5 parts of formaldehyde, 80 parts of pure water, 10 parts of penta sodium pentachlorophenate, benzene by weight
30 parts of ethene, 20 parts of butyl acrylate, 15 parts of methacrylic acid, 30 parts of calcium hydroxide, 1 part of magnesium hydride, 0.3 part of phosphoric acid, hydrogen-oxygen
Change 0.5 part of sodium, 1 part of paraffin, 25 parts of calcium oxide.
By hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, phosphoric acid and NaOH
Input is provided with the reactor of agitator and thermometer, is warming up to 60 DEG C, stirs 30min, and mixing speed is 400 revs/min, plus
Enter paraffin, be cooled to 30 DEG C, continue to stir 20min.
90 DEG C are warming up to, surplus stock is added, 100min is stirred, mixing speed is 800 revs/min, through three-roll grinder
Grinding, cooled and filtered, after the assay was approved.
Film is bright and clean smooth, not shedding, and without brush mark, 45 μm of fineness, surface drying 40min does solid work 22h；Coating is without caking paste
Thing and precipitation, uniform color, easily brushing, no sag, 1h is unchanged at 100 DEG C of heat resistance, adhesive force 100%；Water resistance 5d does not rise
Steep, do not fall off, not shedding, alkali resistance 4-8d is without elephant skin；It is non-ignitable, nontoxic, tasteless, 1200 not show-through, wearabilities of scrub resistance
It is good, bin stability 6-10 month, can extensively produce and constantly replace current material.
Embodiment 2:
Proportioning weighs 100 parts of calcium carbonate, 5 parts of hydrochloric acid, 5.5 parts of formaldehyde, 100 parts of pure water, 30 parts of penta sodium pentachlorophenate, benzene by weight
50 parts of ethene, 40 parts of butyl acrylate, 35 parts of methacrylic acid, 50 parts of calcium hydroxide, 5 parts of magnesium hydride, 0.7 part of phosphoric acid, hydrogen-oxygen
Change 2.5 parts of sodium, 5 parts of paraffin, 45 parts of calcium oxide.
By hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, phosphoric acid and NaOH
Input is provided with the reactor of agitator and thermometer, is warming up to 80 DEG C, stirs 50min, and mixing speed is 600 revs/min, plus
Enter paraffin, be cooled to 50 DEG C, continue to stir 40min.
100 DEG C are warming up to, surplus stock is added, 120min is stirred, mixing speed is 1000 revs/min, is ground through three rollers
Machine grinds, cooled and filtered, after the assay was approved.
Film is bright and clean smooth, not shedding, and without brush mark, 40 μm of fineness, surface drying 35min does solid work 21h；Coating is without caking paste
Thing and precipitation, uniform color, easily brushing, no sag, 2h is unchanged at 100 DEG C of heat resistance, adhesive force 100%；Water resistance 6d does not rise
Steep, do not fall off, not shedding, alkali resistance 4-8d is without elephant skin；It is non-ignitable, nontoxic, tasteless, 1400 not show-through, wearabilities of scrub resistance
Good, bin stability 7 months can extensively be produced and constantly replace current material.
Embodiment 3:
Proportioning weighs 100 parts of calcium carbonate, 2 parts of hydrochloric acid, 2.5 parts of formaldehyde, 85 parts of pure water, 15 parts of penta sodium pentachlorophenate, benzene by weight
35 parts of ethene, 25 parts of butyl acrylate, 20 parts of methacrylic acid, 35 parts of calcium hydroxide, 2 parts of magnesium hydride, 0.4 part of phosphoric acid, hydrogen-oxygen
Change 1 part of sodium, 2 parts of paraffin, 30 parts of calcium oxide.
By hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, phosphoric acid and NaOH
Input is provided with the reactor of agitator and thermometer, is warming up to 60 DEG C, stirs 30min, and mixing speed is 400 revs/min, plus
Enter paraffin, be cooled to 30 DEG C, continue to stir 20min.
90 DEG C are warming up to, surplus stock is added, 100min is stirred, mixing speed is 800 revs/min, through three-roll grinder
Grinding, cooled and filtered, after the assay was approved.
Film is bright and clean smooth, not shedding, and without brush mark, 35 μm of fineness, surface drying 30min does solid work 20h；Coating is without caking paste
Thing and precipitation, uniform color, easily brushing, no sag, 3h is unchanged at 100 DEG C of heat resistance, adhesive force 100%；Water resistance 8d does not rise
Steep, do not fall off, not shedding, alkali resistance 6d is without elephant skin；Non-ignitable, nontoxic, tasteless, scrub resistance 1500 times is not show-through, and wearability is good,
Bin stability 8 months, can extensively produce and constantly replace current material.
Embodiment 4:
Proportioning weighs 100 parts of calcium carbonate, 4 parts of hydrochloric acid, 4.5 parts of formaldehyde, 95 parts of pure water, 25 parts of penta sodium pentachlorophenate, benzene by weight
45 parts of ethene, 35 parts of butyl acrylate, 30 parts of methacrylic acid, hydroxide Ca45 part, 4 parts of magnesium hydride, 0.6 part of phosphoric acid, hydrogen-oxygen
Change 2 parts of sodium, 4 parts of paraffin, 40 parts of calcium oxide.
By hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, phosphoric acid and NaOH
Input is provided with the reactor of agitator and thermometer, is warming up to 80 DEG C, stirs 50min, and mixing speed is 600 revs/min, plus
Enter paraffin, be cooled to 50 DEG C, continue to stir 40min.
100 DEG C are warming up to, surplus stock is added, 120min is stirred, mixing speed is 1000 revs/min, is ground through three rollers
Machine grinds, cooled and filtered, after the assay was approved.
Film is bright and clean smooth, not shedding, and without brush mark, 30 μm of fineness, surface drying 25min does solid work 19h；Coating is without caking paste
Thing and precipitation, uniform color, easily brushing, no sag, 4h is unchanged at 100 DEG C of heat resistance, adhesive force 100%；Water resistance 9d does not rise
Steep, do not fall off, not shedding, alkali resistance 7d is without elephant skin；Non-ignitable, nontoxic, tasteless, scrub resistance 1600 times is not show-through, and wearability is good,
Bin stability 9 months, can extensively produce and constantly replace current material.
Embodiment 5:
Proportioning weighs 100 parts of calcium carbonate, 3 parts of hydrochloric acid, 3.5 parts of formaldehyde, 90 parts of pure water, 20 parts of penta sodium pentachlorophenate, benzene by weight
40 parts of ethene, 30 parts of butyl acrylate, 25 parts of methacrylic acid, 40 parts of calcium hydroxide, 3 parts of magnesium hydride, 0.5 part of phosphoric acid, hydrogen-oxygen
Change 1.5 parts of sodium, 3 parts of paraffin, 35 parts of calcium oxide.
By hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, phosphoric acid and NaOH
Input is provided with the reactor of agitator and thermometer, is warming up to 70 DEG C, stirs 40min, and mixing speed is 500 revs/min, plus
Enter paraffin, be cooled to 40 DEG C, continue to stir 30min.
95 DEG C are warming up to, surplus stock is added, 110min is stirred, mixing speed is 900 revs/min, through three-roll grinder
Grinding, cooled and filtered, after the assay was approved.
Film is bright and clean smooth, not shedding, and without brush mark, 25 μm of fineness, surface drying 20min does solid work 18h；Coating is without caking paste
Thing and precipitation, uniform color, easily brushing, no sag, 5h is unchanged at 100 DEG C of heat resistance, adhesive force 100%；Water resistance 10d is not
Bubble, do not fall off, not shedding, alkali resistance 4-8d is without elephant skin；Non-ignitable, nontoxic, tasteless, scrub resistance 1800 times is not show-through, wear-resisting
Property good, bin stability 10 months, can produce extensively and constantly replace current material.
All components in above example can be with commercially available.
The above embodiments are intended to illustrate the present invention, rather than limitation, therefore with it is of the invention
Any change in claims suitable implication and scope, is all considered as being included within the scope of the claims.
Claims (6)
1. a kind of preparation method of scrubbing resistance calcium carbonate powder interior wall coating, it is characterised in that：Comprise the following steps：
The first step：Weigh calcium carbonate, hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, hydrogen
Calcium oxide, magnesium hydride, phosphoric acid, NaOH, paraffin and calcium oxide；
Second step：By hydrochloric acid, formaldehyde, pure water, penta sodium pentachlorophenate, styrene, butyl acrylate, methacrylic acid, phosphoric acid and hydrogen-oxygen
Change sodium input to be provided with the reactor of agitator and thermometer, be warming up to 60-80 DEG C, stir 30-50min, mixing speed is
400-600 revs/min, paraffin is added, be cooled to 30-50 DEG C, continue to stir 20-40min；
3rd step：90-100 DEG C is warming up to, surplus stock is added, 100-120min is stirred, mixing speed is 800-1000 revs/min
Clock, grinds, cooled and filtered, after the assay was approved through three-roll grinder.
2. the preparation method of a kind of scrubbing resistance calcium carbonate powder interior wall coating according to claim 1, it is characterised in that：Step
Rapid 1）Described in each raw material, by weight match it is as follows：100 parts of calcium carbonate is hydrochloric acid 1-5 parts, formaldehyde 1.5-5.5 parts, pure
Water 80-100 parts, penta sodium pentachlorophenate 10-30 parts, styrene 30-50 parts, butyl acrylate 20-40 parts, methacrylic acid 15-35 parts,
Calcium hydroxide 30-50 parts, magnesium hydride 1-5 parts, phosphoric acid 0.3-0.7 parts, NaOH 0.5-2.5 parts, paraffin 1-5 parts, calcium oxide
25-45 parts.
3. the preparation method of a kind of scrubbing resistance calcium carbonate powder interior wall coating according to claim 1, it is characterised in that：Step
Rapid 1）Described in each raw material, by weight match it is as follows：100 parts of calcium carbonate is hydrochloric acid 2-4 parts, formaldehyde 2.5-4.5 parts, pure
Water 85-95 parts, penta sodium pentachlorophenate 15-25 parts, styrene 35-45 parts, butyl acrylate 25-35 parts, methacrylic acid 20-30 parts,
Calcium hydroxide 35-45 parts, magnesium hydride 2-4 parts, phosphoric acid 0.4-0.6 parts, NaOH 1-2 parts, paraffin 2-4 parts, calcium oxide 30-40
Part.
4. the preparation method of a kind of scrubbing resistance calcium carbonate powder interior wall coating according to claim 1, it is characterised in that：Step
Rapid 1）Described in each raw material, 100 parts of calcium carbonate, 2 parts of hydrochloric acid, 2.5 parts of formaldehyde, 85 parts of pure water, 15 parts of penta sodium pentachlorophenate, styrene
35 parts, 25 parts of butyl acrylate, 20 parts of methacrylic acid, 35 parts of calcium hydroxide, 2 parts of magnesium hydride, 0.4 part of phosphoric acid, NaOH 1
Part, 2 parts of paraffin, 30 parts of calcium oxide.
5. the preparation method of a kind of scrubbing resistance calcium carbonate powder interior wall coating according to claim 1, it is characterised in that：Step
Rapid 1）Described in each raw material, 100 parts of calcium carbonate, 4 parts of hydrochloric acid, 4.5 parts of formaldehyde, 95 parts of pure water, 25 parts of penta sodium pentachlorophenate, styrene
45 parts, 35 parts of butyl acrylate, 30 parts of methacrylic acid, hydroxide Ca45 part, 4 parts of magnesium hydride, 0.6 part of phosphoric acid, NaOH 2
Part, 4 parts of paraffin, 40 parts of calcium oxide.
6. the preparation method of a kind of scrubbing resistance calcium carbonate powder interior wall coating according to claim 1, it is characterised in that：Step
Rapid 1）Described in each raw material, 100 parts of calcium carbonate, 3 parts of hydrochloric acid, 3.5 parts of formaldehyde, 90 parts of pure water, 20 parts of penta sodium pentachlorophenate, styrene
40 parts, 30 parts of butyl acrylate, 25 parts of methacrylic acid, 40 parts of calcium hydroxide, 3 parts of magnesium hydride, 0.5 part of phosphoric acid, NaOH
1.5 parts, 3 parts of paraffin, 35 parts of calcium oxide.
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| CN201611260770.5A CN106700748A (en) | 2016-12-30 | 2016-12-30 | Preparation method of scrub-resistant calcium carbonate powder interior wall coating |
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| CN201611260770.5A CN106700748A (en) | 2016-12-30 | 2016-12-30 | Preparation method of scrub-resistant calcium carbonate powder interior wall coating |
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| CN1107170A (en) * | 1994-02-19 | 1995-08-23 | 易发云 | multi-function ceresin wax wall decoration coating |
| CN1201060A (en) * | 1997-06-03 | 1998-12-09 | 冯东林 | Paint for both inner wall and outer wall decoration |
| CN1398932A (en) * | 2002-05-28 | 2003-02-26 | 北京化工大学 | Water-thinned latex paint containing nanometer calcium carbonate for inner wall and its prepn process |
-
2016
- 2016-12-30 CN CN201611260770.5A patent/CN106700748A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85107492A (en) * | 1985-09-23 | 1987-04-01 | 上海华东新型建筑材料厂 | Insecticidal coating and manufacture method thereof |
| CN86102406B (en) * | 1986-04-09 | 1987-06-03 | 浙江工学院 | Anti-polishing inner wall coating |
| CN1107170A (en) * | 1994-02-19 | 1995-08-23 | 易发云 | multi-function ceresin wax wall decoration coating |
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