CN106675753B - Composite glass cutting fluid - Google Patents

Composite glass cutting fluid Download PDF

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Publication number
CN106675753B
CN106675753B CN201611216928.9A CN201611216928A CN106675753B CN 106675753 B CN106675753 B CN 106675753B CN 201611216928 A CN201611216928 A CN 201611216928A CN 106675753 B CN106675753 B CN 106675753B
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cutting fluid
glass cutting
composite glass
polyethylene glycol
glass
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CN106675753A (en
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董恩莲
严定龙
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GUANGDONG WINDSCAPE ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD
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GUANGDONG WINDSCAPE ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a composite glass cutting fluid which comprises the following components in percentage by mass: 4-15% of synthetic lubricant, 5-25% of sorbitol, 0.1-4% of siloxane corrosion inhibitor, 0.5-5% of bactericide and 0.05-0.5% of defoaming agent. The composite glass cutting fluid provided by the invention can not corrode and damage a printed circuit in the composite glass cutting process, so that the glass cutting fluid can ensure the safety of the printed circuit in the cutting process and can also ensure the processing precision and efficiency of glass cutting and the service life of a cutter.

Description

Composite glass cutting fluid
Technical Field
The invention relates to the technical field of material processing, in particular to a composite glass cutting fluid.
Background
Many types of composite glass include, and one of them is called OGS glass, which has attracted attention in recent years. OGS is an abbreviation of "One Glass Solution," and the name "single Glass display Solution" in the literature means that Touch Glass (Touch Sensor) and Cover Glass (Cover Glass) are integrated together, that is, an ITO conductive layer is plated on the inner side of general Cover Glass, so that the single Glass not only has the strength and safety of the Cover Glass, but also has a Touch function. OGS glass is a functional component for touch devices that has appeared in recent years, and is a composite material component formed by integrating ITO conductive layers, metal printed circuits, sensors, and other components on the surface of cover glass. The OGS glass has the advantages of reducing the thickness of a display screen, increasing the transmittance of the screen, reducing the weight of the device, reducing the cost and the like when being applied to intelligent terminal equipment, and has considerable market share in the fields of current smart phones, tablet computers and the like.
The OGS glass contains a printed circuit made of metal materials with poor corrosion resistance, so that the OGS glass has high requirements on corrosion inhibition performance of cutting fluid in the processes of cutting a large piece of glass into small pieces and profiling edging and finishing the small pieces of glass. The prior glass cutting fluid on the market generally uses alcohol amine organic alkali which has strong corrosivity on metals such as copper, aluminum and the like, and has poor corrosion inhibition and protection effects on the metals, so that the problems of strong corrosivity on printed circuits in OGS glass, easy corrosion and discoloration of the printed circuits, electrical property damage and the like exist. Some OGS glass manufacturers use pure water to avoid this problem and ensure the safety of printed circuits, but pure water lacks lubricity, which in turn leads to problems of poor machining precision, low efficiency and short tool life in glass cutting.
Disclosure of Invention
Therefore, it is necessary to provide a composite glass cutting fluid to solve the problem that the conventional glass cutting fluid is easy to corrode a printed circuit in the machining process of OGS glass cutting.
The composite glass cutting fluid comprises the following components in percentage by mass:
Figure BDA0001191999060000021
in one embodiment, the synthetic lubricant is selected from at least one of polyether, polyether ester, polyethylene glycol mono fatty acid ester, glycerol polyoxyethylene ether, polyethylene glycol, and polyvinyl alcohol.
Further, the polyethylene glycol mono-fatty acid ester is at least one selected from polyethylene glycol monooleate, polyethylene glycol monolaurate, polyethylene glycol mono-cocoate, polyethylene glycol monostearate, polyethylene glycol monoisostearate and polyethylene glycol monoricinoleate.
Further, the polyether is a water-soluble polyether.
In one embodiment, the disinfectant also comprises 0.5-5% of a bactericide; preferably, the antimicrobial agent is a food preservative.
Further, the bactericide is selected from sodium benzoate or potassium sorbate.
In one embodiment, the defoamer is a silicone defoamer.
The composite glass cutting fluid provided by the invention does not contain components with corrosion action on copper, aluminum and the like, so that the printed circuit in the composite glass type OGS glass can not be corroded and damaged in the cutting and edging process, the lubricity of the cutting fluid is also improved due to the addition of a proper synthetic lubricant, sorbitol is used as a stabilizer to enable each component additive of the composite glass cutting fluid to play a role stably, a siloxane corrosion inhibitor can perform a complexing action with metal ions generated in the corrosion process of the metal surface, an auxiliary protection effect is achieved, the metal circuit in the OGS glass is effectively separated from the corrosive substances, and the corrosion rate of the solution to the circuit is reduced. Therefore, the matching of the components ensures that the glass cutting fluid not only can ensure the safety of a printed circuit in the cutting process, but also can ensure the processing precision and efficiency of glass cutting and the service life of a cutter.
Detailed Description
The composite glass cutting fluid is further described below by way of specific embodiments.
The composite glass cutting fluid provided by the embodiment of the invention comprises the following components in percentage by mass:
Figure BDA0001191999060000022
Figure BDA0001191999060000031
the synthetic lubricant is selected from the products which can be fully dispersed or even dissolved in water, such as polyether, polyether ester, polyethylene glycol mono fatty acid ester, glycerol polyoxyethylene ether, polyethylene glycol or polyvinyl alcohol, and the synthetic lubricants of the products can be used alone or in a mixture of a plurality of products. The polyether in these synthetic lubricants is soluble in water by changing the proportion of alkylene oxide in its molecule to have water solubility to disperse the lubricant sufficiently in an aqueous solution, and further, the polyether can also be used as a defoaming agent. Sorbitol is a common stabilizer in the food industry, and can not only stabilize additives of various components of the cutting fluid, but also play a role in preventing harm to personnel and environment due to low toxicity. The siloxane corrosion inhibitor has strong affinity with metal ions, can be firmly adsorbed on the metal surface of the OGS glass, and forms a water-insoluble net-shaped film structure through self-crosslinking, so that the metal surface can be effectively isolated from corrosive media, the metal corrosion rate is effectively reduced, and metal parts in the OGS glass are protected from being corroded by the media.
The cutting fluid is a processing operation auxiliary solution which is repeatedly recycled in the processing process, bacteria are easily bred in the cutting fluid, the cutting fluid is in contact with a human body for a long time to influence the health of an operator, the adverse effect can also be exerted on the service life of the cutting fluid, therefore, a proper bactericide is added, various microorganisms are prevented from breeding, and in numerous bactericides, a food preservative is preferably selected, so that the bactericide is safe and mild, a good antibacterial effect is provided, the service life of the composite glass cutting fluid is prolonged, the skin safety of the operator is not stimulated, and the health of the operator is not influenced. The food preservative has more types, more than 30 types are used in China, and sodium benzoate or potassium sorbate is preferably selected, so that the two types of preservatives have the widest application range, and the cutting fluid has low cost while the good preservative effect is ensured.
Preferably, the defoaming agent is an organic silicon defoaming agent, and the defoaming agent has the advantages of small surface tension, high surface activity, strong defoaming force, small using amount, low cost and better thermal stability, and can be used in a wide temperature range of 5-150 ℃.
The following are specific examples.
Example one
The composite glass cutting fluid comprises the following raw materials in percentage by mass:
Figure BDA0001191999060000032
Figure BDA0001191999060000041
the 5% dilution of the composite glass cutting fluid is heated and kept at the constant temperature of 50 +/-2 ℃, an OGS glass workpiece is soaked for 24 hours, and the OGS glass workpiece is taken out for observation, so that a metal printed circuit is bright and has no corrosion and discoloration, and the electrical property is not influenced by testing, which indicates that the composite glass cutting fluid is safe to OGS glass.
Example two
The composite glass cutting fluid comprises the following raw materials in percentage by mass:
Figure BDA0001191999060000042
the 5% dilution of the composite glass cutting fluid is heated and kept at the constant temperature of 50 +/-2 ℃, an OGS glass workpiece is soaked for 24 hours, and the OGS glass workpiece is taken out for observation, so that a metal printed circuit is bright and has no corrosion and discoloration, and the electrical property is not influenced by testing, which indicates that the composite glass cutting fluid is safe to OGS glass.
EXAMPLE III
The composite glass cutting fluid comprises the following raw materials in percentage by mass:
Figure BDA0001191999060000043
the 5% dilution of the composite glass cutting fluid is heated and kept at the constant temperature of 50 +/-2 ℃, an OGS glass workpiece is soaked for 24 hours, and the OGS glass workpiece is taken out for observation, so that a metal printed circuit is bright and has no corrosion and discoloration, and the electrical property is not influenced by testing, which indicates that the composite glass cutting fluid is safe to OGS glass.
Example four
The composite glass cutting fluid comprises the following raw materials in percentage by mass:
Figure BDA0001191999060000051
the 5% dilution of the composite glass cutting fluid is heated and kept at the constant temperature of 50 +/-2 ℃, an OGS glass workpiece is soaked for 24 hours, and the OGS glass workpiece is taken out for observation, so that a metal printed circuit is bright and has no corrosion and discoloration, and the electrical property is not influenced by testing, which indicates that the composite glass cutting fluid is safe to OGS glass.
EXAMPLE five
The composite glass cutting fluid comprises the following raw materials in percentage by mass:
Figure BDA0001191999060000052
the 5% dilution of the composite glass cutting fluid is heated and kept at the constant temperature of 50 +/-2 ℃, an OGS glass workpiece is soaked for 24 hours, and the OGS glass workpiece is taken out for observation, so that a metal printed circuit is bright and has no corrosion and discoloration, and the electrical property is not influenced by testing, which indicates that the composite glass cutting fluid is safe to OGS glass.
EXAMPLE six
The composite glass cutting fluid comprises the following raw materials in percentage by mass:
Figure BDA0001191999060000061
the 5% dilution of the composite glass cutting fluid is heated and kept at the constant temperature of 50 +/-2 ℃, an OGS glass workpiece is soaked for 24 hours, and the OGS glass workpiece is taken out for observation, so that a metal printed circuit is bright and has no corrosion and discoloration, and the electrical property is not influenced by testing, which indicates that the composite glass cutting fluid is safe to OGS glass.
EXAMPLE seven
The composite glass cutting fluid comprises the following raw materials in percentage by mass:
Figure BDA0001191999060000062
the 5% dilution of the composite glass cutting fluid is heated and kept at the constant temperature of 50 +/-2 ℃, an OGS glass workpiece is soaked for 24 hours, and the OGS glass workpiece is taken out for observation, so that a metal printed circuit is bright and has no corrosion and discoloration, and the electrical property is not influenced by testing, which indicates that the composite glass cutting fluid is safe to OGS glass.
Example eight
The composite glass cutting fluid comprises the following raw materials in percentage by mass:
Figure BDA0001191999060000063
Figure BDA0001191999060000071
the 5% dilution of the composite glass cutting fluid is heated and kept at the constant temperature of 50 +/-2 ℃, an OGS glass workpiece is soaked for 24 hours, and the OGS glass workpiece is taken out for observation, so that a metal printed circuit is bright and has no corrosion and discoloration, and the electrical property is not influenced by testing, which indicates that the composite glass cutting fluid is safe to OGS glass.
Although a few exemplary embodiments of the present invention have been shown and described, it would be appreciated by those skilled in the art that changes may be made in these exemplary embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the claims and their equivalents.

Claims (6)

1. The composite glass cutting fluid is applied to OGS glass and comprises the following components in percentage by mass:
Figure FDA0002450204250000011
the balance being water.
2. The composite glass cutting fluid according to claim 1, wherein the synthetic lubricant is at least one selected from the group consisting of polyether, polyether ester, polyethylene glycol mono fatty acid ester, glycerol polyoxyethylene ether, polyethylene glycol, and polyvinyl alcohol.
3. The composite glass cutting fluid according to claim 2, wherein the polyethylene glycol monofatty acid ester is at least one selected from the group consisting of polyethylene glycol monooleate, polyethylene glycol monolaurate, polyethylene glycol monostearate, polyethylene glycol monoisostearate, and polyethylene glycol monoricinoleate.
4. The composite glass cutting fluid according to claim 2, wherein the polyether is a water-soluble polyether.
5. The composite glass cutting fluid according to claim 1, wherein the bactericide is selected from sodium benzoate or potassium sorbate.
6. The composite glass cutting fluid according to claim 1, wherein the defoaming agent is a silicone defoaming agent.
CN201611216928.9A 2016-12-26 2016-12-26 Composite glass cutting fluid Active CN106675753B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102925274A (en) * 2012-11-09 2013-02-13 上海应用技术学院 Optical glass grinding fluid and preparation method thereof
CN103013638A (en) * 2011-09-20 2013-04-03 浙江瑞翌新材料科技有限公司 Water-soluble cooling liquid for fixed abrasive material line cutting, and preparation method thereof
CN103525533A (en) * 2013-10-23 2014-01-22 东莞太平洋博高润滑油有限公司 Full-synthetic glass grinding fluid
CN104450105A (en) * 2014-12-29 2015-03-25 长沙艾森设备维护技术有限公司 Low-odor and low-toxicity glass cutting fluid
CN104479833A (en) * 2014-12-17 2015-04-01 江苏鑫露新材料股份有限公司 High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof
CN104673473A (en) * 2013-11-30 2015-06-03 鸿富锦精密工业（深圳）有限公司 Water-based grinding fluid and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013638A (en) * 2011-09-20 2013-04-03 浙江瑞翌新材料科技有限公司 Water-soluble cooling liquid for fixed abrasive material line cutting, and preparation method thereof
CN102925274A (en) * 2012-11-09 2013-02-13 上海应用技术学院 Optical glass grinding fluid and preparation method thereof
CN103525533A (en) * 2013-10-23 2014-01-22 东莞太平洋博高润滑油有限公司 Full-synthetic glass grinding fluid
CN104673473A (en) * 2013-11-30 2015-06-03 鸿富锦精密工业（深圳）有限公司 Water-based grinding fluid and preparation method thereof
CN104479833A (en) * 2014-12-17 2015-04-01 江苏鑫露新材料股份有限公司 High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof
CN104450105A (en) * 2014-12-29 2015-03-25 长沙艾森设备维护技术有限公司 Low-odor and low-toxicity glass cutting fluid

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