CN106647088A - 一种具有荧光开关和电致变色性能的双功能器件 - Google Patents
一种具有荧光开关和电致变色性能的双功能器件 Download PDFInfo
- Publication number
- CN106647088A CN106647088A CN201611068705.2A CN201611068705A CN106647088A CN 106647088 A CN106647088 A CN 106647088A CN 201611068705 A CN201611068705 A CN 201611068705A CN 106647088 A CN106647088 A CN 106647088A
- Authority
- CN
- China
- Prior art keywords
- solution
- fluorescent switch
- double
- function device
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims abstract description 18
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960003351 prussian blue Drugs 0.000 claims abstract description 14
- 239000013225 prussian blue Substances 0.000 claims abstract description 14
- 239000011521 glass Substances 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 239000000243 solution Substances 0.000 claims description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000003792 electrolyte Substances 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 230000004087 circulation Effects 0.000 claims description 10
- 239000011245 gel electrolyte Substances 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 6
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 6
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- 238000004070 electrodeposition Methods 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229910002538 Eu(NO3)3·6H2O Inorganic materials 0.000 claims description 3
- 229910020350 Na2WO4 Inorganic materials 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims description 3
- LTUDISCZKZHRMJ-UHFFFAOYSA-N potassium;hydrate Chemical compound O.[K] LTUDISCZKZHRMJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 3
- 238000010189 synthetic method Methods 0.000 claims description 3
- 239000000052 vinegar Substances 0.000 claims description 3
- 235000021419 vinegar Nutrition 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
- -1 allyl ester Chemical class 0.000 claims description 2
- 230000005540 biological transmission Effects 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims description 2
- 238000011010 flushing procedure Methods 0.000 claims description 2
- 238000009825 accumulation Methods 0.000 claims 1
- 238000005137 deposition process Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 230000009977 dual effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 3
- HKVGLVBQYVEJRZ-UHFFFAOYSA-N CC=C.O=C=O Chemical group CC=C.O=C=O HKVGLVBQYVEJRZ-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Natural products O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 125000005909 ethyl alcohol group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004984 smart glass Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
- G02F1/1516—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising organic material
- G02F2001/1517—Cyano complex compounds, e.g. Prussian blue
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611068705.2A CN106647088B (zh) | 2016-11-29 | 2016-11-29 | 一种具有荧光开关和电致变色性能的双功能器件 |
Applications Claiming Priority (1)
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CN201611068705.2A CN106647088B (zh) | 2016-11-29 | 2016-11-29 | 一种具有荧光开关和电致变色性能的双功能器件 |
Publications (2)
Publication Number | Publication Date |
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CN106647088A true CN106647088A (zh) | 2017-05-10 |
CN106647088B CN106647088B (zh) | 2019-08-09 |
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CN201611068705.2A Active CN106647088B (zh) | 2016-11-29 | 2016-11-29 | 一种具有荧光开关和电致变色性能的双功能器件 |
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CN (1) | CN106647088B (zh) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5071233A (en) * | 1990-10-29 | 1991-12-10 | General Motors Corporation | Electrochromic device with oxymethylene-polyoxyethylene electrolyte |
KR19990086433A (ko) * | 1998-05-28 | 1999-12-15 | 민혜경 | 전기 변색장치의 제조방법 |
CN1492274A (zh) * | 2003-08-26 | 2004-04-28 | 广州市光机电工程研究开发中心 | 全固态塑料电致变色器件及其制备方法 |
CN1775778A (zh) * | 2005-12-01 | 2006-05-24 | 复旦大学 | 二噻吩乙烯类功能材料及其制备方法和应用 |
JP2009048141A (ja) * | 2007-08-23 | 2009-03-05 | Sony Corp | エレクトロクロミック化合物、中間体化合物、及び、それらの製造方法、並びに、エレクトロクロミック化合物を用いた光学装置 |
CN104375349A (zh) * | 2014-11-18 | 2015-02-25 | 辽宁大学 | 一种基于多酸的纯无机多色彩电致变色膜 |
CN105807525A (zh) * | 2016-03-23 | 2016-07-27 | 辽宁大学 | 一种基于多酸的可以在非水中性电解质中高效变色的电致变色薄膜 |
-
2016
- 2016-11-29 CN CN201611068705.2A patent/CN106647088B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5071233A (en) * | 1990-10-29 | 1991-12-10 | General Motors Corporation | Electrochromic device with oxymethylene-polyoxyethylene electrolyte |
KR19990086433A (ko) * | 1998-05-28 | 1999-12-15 | 민혜경 | 전기 변색장치의 제조방법 |
CN1492274A (zh) * | 2003-08-26 | 2004-04-28 | 广州市光机电工程研究开发中心 | 全固态塑料电致变色器件及其制备方法 |
CN1775778A (zh) * | 2005-12-01 | 2006-05-24 | 复旦大学 | 二噻吩乙烯类功能材料及其制备方法和应用 |
JP2009048141A (ja) * | 2007-08-23 | 2009-03-05 | Sony Corp | エレクトロクロミック化合物、中間体化合物、及び、それらの製造方法、並びに、エレクトロクロミック化合物を用いた光学装置 |
CN104375349A (zh) * | 2014-11-18 | 2015-02-25 | 辽宁大学 | 一种基于多酸的纯无机多色彩电致变色膜 |
CN105807525A (zh) * | 2016-03-23 | 2016-07-27 | 辽宁大学 | 一种基于多酸的可以在非水中性电解质中高效变色的电致变色薄膜 |
Also Published As
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CN106647088B (zh) | 2019-08-09 |
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Effective date of registration: 20201216 Address after: 241100 8 / F, building 5, Wuhu TONGHANG Innovation Park, Wanbi Town, Wuhu City, Anhui Province Patentee after: Wuhu Digital Information Industrial Park Co.,Ltd. Address before: 110000 58 Shenbei New Area Road South, Shenyang, Liaoning. Patentee before: LIAONING University |
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EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20170510 Assignee: ZHEJIANG QIPINTONG NETWORK TECHNOLOGY CO.,LTD. Assignor: Wuhu Digital Information Industrial Park Co.,Ltd. Contract record no.: X2021330000733 Denomination of invention: A dual function device with fluorescent switching and electrochromic properties Granted publication date: 20190809 License type: Common License Record date: 20211109 |
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EC01 | Cancellation of recordation of patent licensing contract | ||
EC01 | Cancellation of recordation of patent licensing contract |
Assignee: ZHEJIANG QIPINTONG NETWORK TECHNOLOGY CO.,LTD. Assignor: Wuhu Digital Information Industrial Park Co.,Ltd. Contract record no.: X2021330000733 Date of cancellation: 20240204 |