CN106635512A - Preparation method for green soaping agent for spinning printing and dyeing - Google Patents
Preparation method for green soaping agent for spinning printing and dyeing Download PDFInfo
- Publication number
- CN106635512A CN106635512A CN201610973017.4A CN201610973017A CN106635512A CN 106635512 A CN106635512 A CN 106635512A CN 201610973017 A CN201610973017 A CN 201610973017A CN 106635512 A CN106635512 A CN 106635512A
- Authority
- CN
- China
- Prior art keywords
- parts
- minutes
- mixture
- preparation
- soaping agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/20—Water-insoluble oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a preparation method for a green soaping agent for spinning printing and dyeing and belongs to the technical field of spinning printing and dyeing. The preparation method provided by the invention comprises the following steps: 1) dissolving 8-12 parts of potassium peroxymonosulfate into 300 parts of deionized water and then adding 28-36 parts of antistatic emulsifying lubricating oil; melting the antistatic emulsifying lubricating oil and then adding 40-50 parts of span 80, stirring for 30-35 minutes, and then adding 38-45 parts of tween 80, stirring for 20-23 minutes, and then adding 8-12 parts of white carbon black and stirring for 40 minutes, thereby acquiring a mixture A; uniformly mixing 1.6 parts of span 80 with 1.6 parts of tween 80, then adding 0.5 part of mixture A, and uniformly mixing, thereby acquiring a mixture B; adding 8 parts of sodium percarbonate into 280 parts of soft water and stirring for 28-30 minutes, and then adding 30 parts of antistatic emulsifying lubricating oil and stirring for 30 minutes; adding 0.6 part of sodium chloride and stirring for 20 minutes; and adding 3.7 parts of mixture B and stirring for 20 minutes, thereby acquiring the green soaping agent. The green soaping agent prepared according to the method is edible, is safe in residual, is harmless and environmentally friendly and is good in soaping effect.
Description
Technical field
The present invention relates to a kind of preparation method of textile printing and dyeing with green soaping agent；Belong to technical field of textile printing.
Background technology
Soap be primarily referred to as print and dye postprocessing working procedures, to fabric Jing after dyeing and printing process, be improve its color fastness with
Gorgeous degree, with soap or detergent solution by the dyestuff on its surface without fixation, dyeing auxiliaries used, concentrator etc. in nearly boiling bar
The processing technology of washing is carried out under part.At present, the kind of the soaping agent for using of soaping has nonionic soaping agent, cation to soap
Agent, anion soaping agent, acid scouring agent etc., their textiles to reactive dyeing has preferably soap soil resistant to imitate
Really.But containing APEO, formaldehyde, benzene, dimethylbenzene, azo, halogen etc. in these soaping agents, biodegradable difference, water-supply source is caused
Severe contamination.During the above-mentioned soaping agent treatment of dyed fabric of textile printing and dyeing production and application, soaping agent can residue in dyed fabric；So as to
Cause to be attached with the chemical substance of harmful to human normal hormonal on dyed fabric, these chemical substances can also discharge environmental hormone,
Ozone depletion material is too big to environment potential hazard.
The content of the invention
It is an object of the invention to provide a kind of efficient, nontoxic, safe and environment-friendly textile printing and dyeing green soaping agent；With
Substitute existing soaping agent, and, even preferably effect suitable with existing soaping agent can be realized.
Technical scheme
A kind of textile printing and dyeing preparation method of green soaping agent, comprises the following steps,
First, mixture A is prepared
300 parts of deionized waters are taken, under conditions of deionized water temperature is kept for 60-70 DEG C following operation is carried out：
（1）8-12 part potassium hydrogen peroxymonosulfates are dissolved in deionized water, the antistatic emulsion type lubricant of 28-36 parts is subsequently adding；
（2）Antistatic emulsion type lubricant adds 40-50 parts sorbester p17 stirring 30-35 minutes after melting, be subsequently adding 38-45 parts and tell
Temperature 80 stirs 20-23 minutes, adds 8-12 parts white carbon and stirs more than 40 minutes；
2nd, mixture B is prepared
0.5 part of mixture A is added after 1.6 parts of sorbester p17s and 1.6 parts of Tween 80s are well mixed, is mixed, obtain mixture B；
3rd, soaping agent is prepared
280 parts of soft water are taken, under conditions of soft water temperature is kept for 80 DEG C following operation is carried out：
Add 8 parts of SODIUM PERCARBONATEs to stir 28-30 minutes in soft water, be subsequently adding 30 parts of antistatic emulsion type lubricants and stir 30 points
Clock, adds 0.6 part of common salt and stirs 20 minutes, then adds 3.7 parts of mixture B and stirs more than 20 minutes, you can；
Described part is weight portion；
The antistatic emulsion type lubricant refers to the patented product of Patent No. 201310653893.5.
The preparation method of the present invention,
The mixing time after SODIUM PERCARBONATE is added, if being shorter than 28 minutes solid particulate matter is produced；If 30min is longer than
The COD that prepared soaping agent can be caused is raised, not environmentally；
The mixing time after antistatic emulsion type lubricant is added, if being shorter than 30 minutes, spawn can be produced；If long
In 30min, then foam can be produced；
Add common salt after mixing time, if being shorter than 20 minutes, there is a problem of dissolving it is insufficient, cause prepared by
Then there is solid particulate matter in defoamer；If being longer than 20 minutes, demulsifying phenomenon occurs, cause water-oil separating.
So, the preparation method of the present invention has carried out considered critical to mixing time.
Under the conditions of the raw material dosage of the present invention, if the temperature of soft water is higher than 80 DEG C, foam can be produced, cause to prepare
Process is not easily controlled.
Above-mentioned preparation method, it is preferred that in step one, with 300 parts of deionized waters, 10 parts of potassium hydrogen peroxymonosulfates, 45 parts of departments
80,40 parts of Tween 80s of disk, 30 parts of antistatic emulsion type lubricants and 10 parts of white carbons are raw material.
Above-mentioned preparation method, it is preferred that in step 3, adds the mixing time after 8 parts of SODIUM PERCARBONATEs to be 28 in soft water
Minute.
The preparation method of the present invention, step one, the charging sequence in two, three can not be overturned, and otherwise prepared product is not
Possesses effect of soaping.
The preparation method of the present invention, the antistatic emulsion type lubricant in raw material can not be with conventional antistatic lubricant emulsion generation
Replace, otherwise prepared product does not possess effect of soaping.
The raw material that the preparation method of the present invention is adopted is food-grade, therefore, prepared soaping agent is edible.
Using the medical material prepared by soaping agent prepared by the method for the present invention, its safe, harmless, environmental protection of residual.
Present invention also offers the soaping agent prepared using said method.
Beneficial effect
（1）Prepare that needed raw material is simple, wide material sources；
（2）Preparation process is simple to operate, easy to control without the need for HTHP；
（3）Prepared soaping agent is safe and harmless, environmental protection, can reach food-grade；Effect of soaping is good.
Specific embodiment
Embodiment 1.1
（1）With 950kg waste oils, 427kg alkali, 21kg aliphatic alcohols emulsifying agent and 23kg methyl alcohol as raw material；92 DEG C of bars of waste oil
31min is stirred under part；Alkali is disposably added, 103min is then stirred, then is warming up to 126 DEG C；Plus emulsifying agent, then stir and protect
Warm 107min；Plus methyl alcohol, continue to be incubated 110min；Obtain final product antistatic emulsion type lubricant, i.e. Patent No. 201310653893.5
Patented product；
（2）Prepared with 300kg deionized waters, 10kg potassium hydrogen peroxymonosulfates, 45kg sorbester p17s, 40kg Tween 80s, 30kg steps 1
Antistatic emulsion type lubricant and 10kg white carbons are raw material；Following behaviour is carried out under conditions of deionized water temperature is kept for 60 DEG C
Make：Potassium hydrogen peroxymonosulfate is dissolved in deionized water, antistatic emulsion type lubricant is subsequently adding；Antistatic emulsion type lubricant melts
Add sorbester p17 to stir after change 30 minutes, be subsequently adding Tween 80 and stir 20 minutes, add white carbon and stir more than 40 minutes
Mixture A can be obtained.
Embodiment 1.2
（1）With 950kg waste oils, 400-450kg alkali, 10-30kg aliphatic alcohols emulsifying agent and 15-35kg methyl alcohol as raw material；Ground
Ditch oil stirs 20-35min under the conditions of 87-98 DEG C；Plus alkali, then stir 60-150min, then it is warming up to 115-136 DEG C；Plus breast
Agent, then stirring is incubated 80-120min；Plus methyl alcohol, continue to be incubated 80-120min, you can obtain antistatic emulsion type lubricant（Specially
Profit number is 201310653893.5 patented product）；
（2）With 300kg deionized waters, 8-12kg potassium hydrogen peroxymonosulfates, 40-50kg sorbester p17s, 38-45kg Tween 80s, 28-36kg
Antistatic emulsion type lubricant and 8-12kg white carbons prepared by step 1 is raw material；In the bar for keeping deionized water temperature to be 60 DEG C
Following operation is carried out under part：Potassium hydrogen peroxymonosulfate is dissolved in deionized water, antistatic emulsion type lubricant is subsequently adding；It is anti-quiet
Electric emulsion type lubricant adds sorbester p17 stirring 30-35 minutes after melting, be subsequently adding Tween 80 stirring 20-23 minutes, adds
White carbon is stirred more than 40 minutes and can obtain mixture A.
Embodiment 2
（1）The mixture A for adding 0.5kg embodiments 1.1 to prepare after 1.6kg sorbester p17s and 1.6kg Tween 80s are well mixed, mixes
It is even, obtain mixture B；
（2）280kg soft water is taken, under conditions of soft water temperature is kept for 80 DEG C following operation is carried out：
Add 8kg SODIUM PERCARBONATEs to stir in soft water 28 minutes, be subsequently adding the antistatic emulsification profit of the preparation of 30kg embodiments 1.1
Lubricating oil stir 30 minutes, add 0.6kg common salts stir 20 minutes, then add 3.7kg mixtures B stir 20 minutes with
On, obtain final product soaping agent.
Embodiment 3
（1）The mixture A for adding 0.5kg embodiments 1.1 to prepare after 1.6kg sorbester p17s and 1.6kg Tween 80s are well mixed, mixes
It is even, obtain mixture B；
（2）280kg soft water is taken, under conditions of soft water temperature is kept for 80 DEG C following operation is carried out：
Add 8kg SODIUM PERCARBONATEs to stir in soft water 30 minutes, be subsequently adding the antistatic emulsification profit of the preparation of 30kg embodiments 1.1
Lubricating oil stir 30 minutes, add 0.6kg common salts stir 20 minutes, then add 3.7kg mixtures B stir 20 minutes with
On, obtain final product soaping agent.
Comparative example 1
（1）The mixture A for adding 0.5kg embodiments 1.1 to prepare after 1.6kg sorbester p17s and 1.6kg Tween 80s are well mixed, mixes
It is even, obtain mixture B；
（2）280kg soft water is taken, under conditions of soft water temperature is kept for 80 DEG C following operation is carried out：
Add 8kg SODIUM PERCARBONATEs to stir in soft water 32 minutes, be subsequently adding the antistatic emulsification profit of the preparation of 30kg embodiments 1.1
Lubricating oil stir 30 minutes, add 0.6kg common salts stir 20 minutes, then add 3.7kg mixtures B stir 20 minutes with
On, obtain final product soaping agent.
Comparative example 2
（1）The mixture A for adding 0.5kg embodiments 1.1 to prepare after 1.6kg sorbester p17s and 1.6kg Tween 80s are well mixed, mixes
It is even, obtain mixture B；
（2）280kg soft water is taken, under conditions of soft water temperature is kept for 80 DEG C following operation is carried out：
Add 8kg SODIUM PERCARBONATEs to stir in soft water 26 minutes, be subsequently adding the antistatic emulsification profit of the preparation of 30kg embodiments 1.1
Lubricating oil stir 30 minutes, add 0.6kg common salts stir 20 minutes, then add 3.7kg mixtures B stir 20 minutes with
On, obtain final product soaping agent.
Comparative example 3
（1）With 300kg deionized waters, 10kg potassium hydrogen peroxymonosulfates, 45kg sorbester p17s, 40kg Tween 80s, the antistatic emulsifications of 30kg
Lubricant（By NaOH, penetrating agent JFC, starch, glue 102, talcum powder according to 6:2:100:4:2 mass ratio composition）
And 10kg white carbons are raw material；Following operation is carried out under conditions of deionized water temperature is kept for 60 DEG C：By hydrogen peroxymonosulfate
Potassium is dissolved in deionized water, is subsequently adding antistatic lubricant emulsion；Antistatic lubricant emulsion adds sorbester p17 after melting
Stirring 30 minutes, is subsequently adding Tween 80 and stirs 20 minutes, adds by white carbon is stirred more than 40 minutes and obtains mixture
A。
（2）0.5kg mixture A are added after 1.6kg sorbester p17s and 1.6kg Tween 80s are well mixed, is mixed, obtain mixture
B；
（3）280kg soft water is taken, under conditions of soft water temperature is kept for 80 DEG C following operation is carried out：
Add 8kg SODIUM PERCARBONATEs to stir in soft water 26 minutes, be subsequently adding the antistatic lubricant emulsions of 30kg and stir 30 minutes,
Add 0.6kg common salts to stir 20 minutes, then add 3.7kg mixtures B and stir more than 20 minutes, obtain final product soaping agent.
Soap effect experimental
（1）Stained clot-h is dyeed using following dyeing conditions：The red B-4BD of dye activity（The 6% of stained clot-h quality）, sulfuric acid
Sodium 80g/L, sodium carbonate 30g/L, bath raio are 1:20th, temperature 60 C, time 60min；
（2）Soaping agent is configured to the liquid of soaping of 1g/L, and liquid of soaping is added in glass container, then stained clot-h is put into bath of soaping
In, bath raio 1：20；Machine is opened, in 98 DEG C of 20min that soap；Test cloth cold rinse 1 time is taken out, with 60 DEG C of drying；Observation
The depth of foot-washing water after dyeing；Test cloth after soaping is tested it according to color fastness to washing experimental technique GB/T 3921-2008
Color fastness；As a result it is as shown in table 1；
（3）Step（1）Stained clot-h 5g and identical adjacent fabric 2.5g, in soaping agent 2g/L, bath raio 1:15th, soap for 60 DEG C
30min；Stained clot-h and adjacent fabric are taken out, with cold rinse 1 time, in 60 DEG C of drying；By adjacent fabric on Computer color testing instrument
Measure K/S value results as shown in table 1；
Table 1
；Blank group：In step（2）、（3）Operating process in without soaping agent.
Different antistatic emulsion type lubricants, mixture A are prepared using the preparation method of embodiment 1.2, is then adopted respectively
Different soaping agents are prepared with the preparation method of embodiment 2-3；Soap effect and the soaping agent of embodiment 2-3 of these soaping agents
Effect compare it is slightly worse, but difference is not obvious.
Claims (4)
1. a kind of textile printing and dyeing preparation method of green soaping agent, it is characterised in that comprise the following steps,
First, mixture A is prepared
300 parts of deionized waters are taken, under conditions of deionized water temperature is kept for 60-70 DEG C following operation is carried out：
8-12 part potassium hydrogen peroxymonosulfates are dissolved in deionized water, the antistatic emulsion type lubricant of 28-36 parts is subsequently adding；
Antistatic emulsion type lubricant adds 40-50 parts sorbester p17 stirring 30-35 minutes after melting, be subsequently adding 38-45 part tweens
8O stirs 20-23 minutes, adds 8-12 parts white carbon and stirs more than 40 minutes；
2nd, mixture B is prepared
0.5 part of mixture A is added after 1.6 parts of sorbester p17s and 1.6 parts of Tween 80s are well mixed, is mixed, obtain mixture B；
3rd, soaping agent is prepared
280 parts of soft water are taken, under conditions of soft water temperature is kept for 80 DEG C following operation is carried out：
Add 8 parts of SODIUM PERCARBONATEs to stir 28-30 minutes in soft water, be subsequently adding 30 parts of antistatic emulsion type lubricants and stir 30 points
Clock, adds 0.6 part of common salt and stirs 20 minutes, then adds 3.7 parts of mixture B and stirs more than 20 minutes, you can；
Described part is weight portion；
The antistatic emulsion type lubricant refers to the patented product of Patent No. 201310653893.5.
2. preparation method according to claim 1, it is characterised in that in step one, with 300 parts of deionized waters, 10 parts of mistakes
One potassium acid sulfate, 45 parts of sorbester p17s, 40 parts of Tween 80s, 30 parts of antistatic emulsion type lubricants and 10 parts of white carbons are raw material.
3. preparation method according to claim 1 and 2, it is characterised in that in step 3, adds 8 parts to cross carbon in soft water
Mixing time after sour sodium is 28 minutes.
4. the soaping agent that prepared by a kind of employing claim 1,2 or 3 methods describeds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610973017.4A CN106635512A (en) | 2016-10-28 | 2016-10-28 | Preparation method for green soaping agent for spinning printing and dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610973017.4A CN106635512A (en) | 2016-10-28 | 2016-10-28 | Preparation method for green soaping agent for spinning printing and dyeing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106635512A true CN106635512A (en) | 2017-05-10 |
Family
ID=58821965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610973017.4A Pending CN106635512A (en) | 2016-10-28 | 2016-10-28 | Preparation method for green soaping agent for spinning printing and dyeing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106635512A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1354233A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Cleaning agent for removing dyeing and printing loose colour |
| CN102424771A (en) * | 2011-10-18 | 2012-04-25 | 浙江华晟化学制品有限公司 | Low temperature soaping powder and preparation method thereof |
| CN102899185A (en) * | 2012-10-25 | 2013-01-30 | 南京大地冷冻食品有限公司 | Method for preparing high-class wool spinning textile printing detergent |
| CN103571654A (en) * | 2013-11-20 | 2014-02-12 | 上海德桑精细化工有限公司 | Novel detergent and preparation method thereof |
| CN103726357A (en) * | 2013-12-09 | 2014-04-16 | 山东济宁锦祥化工有限公司 | Antistatic emulsified lubricating oil |
-
2016
- 2016-10-28 CN CN201610973017.4A patent/CN106635512A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1354233A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Cleaning agent for removing dyeing and printing loose colour |
| CN102424771A (en) * | 2011-10-18 | 2012-04-25 | 浙江华晟化学制品有限公司 | Low temperature soaping powder and preparation method thereof |
| CN102899185A (en) * | 2012-10-25 | 2013-01-30 | 南京大地冷冻食品有限公司 | Method for preparing high-class wool spinning textile printing detergent |
| CN103571654A (en) * | 2013-11-20 | 2014-02-12 | 上海德桑精细化工有限公司 | Novel detergent and preparation method thereof |
| CN103726357A (en) * | 2013-12-09 | 2014-04-16 | 山东济宁锦祥化工有限公司 | Antistatic emulsified lubricating oil |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101709554B (en) | Surfactant for woven fabric dye-bath retreat process and preparation method thereof | |
| CN101435162A (en) | Formula of foam dyeing system and foam dyeing method of base cloth for multifunctional water stabbed superfine fiber leather | |
| CN105648793B (en) | A kind of high chlorine-resistant print paste and preparation method and application | |
| CN103469623A (en) | Method for carrying out salt-free dyeing on un-scoured and unbleached cotton textile by reactive dyes | |
| CN103525571A (en) | Strong degreasing detergent and production method thereof | |
| CN115216961B (en) | Biological-based all-in-one textile scouring agent and preparation method and application thereof | |
| CN106192471A (en) | A kind of natural animal-plant base is combined the preparation method of aldehyde-free colour stabilizer | |
| CN107460728A (en) | A kind of high-effective low foam refining agent and preparation method thereof | |
| KR101577780B1 (en) | Textile dyeing process of cellulosic fibers and their blends and polyester and its blends with recycled dyeing baths | |
| CN109629271A (en) | A kind of anti-staining soaping agent and preparation method thereof | |
| CN103898770B (en) | A kind of silk flosssilk wadding BLENDED FABRIC scouring agent | |
| CN106398903A (en) | Hand-wash laundry detergent capable of achieving rinsing easily and preparation method thereof | |
| CN106635512A (en) | Preparation method for green soaping agent for spinning printing and dyeing | |
| CN101942368B (en) | Wool whitening detergent | |
| CN104818614A (en) | Novel penetrating agent for textile pretreatment | |
| CN107653671A (en) | A kind of environment protection type multifunctional scouring agent and preparation method | |
| CN101831772B (en) | Fabric finishing technique | |
| CN107164982B (en) | Green food-grade detergent for textile printing and dyeing | |
| CN106381693A (en) | Polyester-cotton blended fabric one-bath pretreatment process | |
| CN100549152C (en) | Break compound special for washhouse of hotel | |
| CN104532560A (en) | Refining agent for continuous dyeing | |
| CN113604291A (en) | Dry cleaning agent for stains on down jackets | |
| CN103174019A (en) | Multifunctional chemical system used for scouring and bleaching cotton-polyester blended fabrics and dyeing polyester components in one bath | |
| CN104450232B (en) | A kind of preparation method of jeans scavenger specially | |
| CN108264779B (en) | A kind of active black dye composition and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170510 |