CN103898770B - A kind of silk flosssilk wadding BLENDED FABRIC scouring agent - Google Patents
A kind of silk flosssilk wadding BLENDED FABRIC scouring agent Download PDFInfo
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- CN103898770B CN103898770B CN201410110249.8A CN201410110249A CN103898770B CN 103898770 B CN103898770 B CN 103898770B CN 201410110249 A CN201410110249 A CN 201410110249A CN 103898770 B CN103898770 B CN 103898770B
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- hydrogen peroxide
- scouring agent
- cellulase
- sodium
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- 239000004744 fabric Substances 0.000 title claims abstract description 27
- 238000009991 scouring Methods 0.000 title claims abstract description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 57
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 48
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 108010059892 Cellulase Proteins 0.000 claims abstract description 16
- 229940106157 cellulase Drugs 0.000 claims abstract description 16
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 14
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical group CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 14
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 14
- 239000011734 sodium Substances 0.000 claims abstract description 14
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 12
- 229930182490 saponin Natural products 0.000 claims abstract description 12
- 150000007949 saponins Chemical class 0.000 claims abstract description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000835 fiber Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 229920001277 pectin Polymers 0.000 abstract description 4
- 239000001814 pectin Substances 0.000 abstract description 4
- 235000010987 pectin Nutrition 0.000 abstract description 4
- 238000005187 foaming Methods 0.000 abstract description 2
- 239000004575 stone Substances 0.000 abstract description 2
- 230000004083 survival effect Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 description 15
- 235000011121 sodium hydroxide Nutrition 0.000 description 13
- 239000012535 impurity Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- AEMOLEFTQBMNLQ-BKBMJHBISA-N alpha-D-galacturonic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-BKBMJHBISA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000010977 jade Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000628997 Flos Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of silk flosssilk wadding BLENDED FABRIC scouring agent, component comprises: cellulase, alkaline pectase, fatty alcohol-polyoxyethylene ether, two palmityl ethylene diamine dipropionic acid sodium, sodium hydroxide solution, sodium carbonate, hydrogen peroxide, Tea Saponin, deionized water.Alkaline pectase is added in scouring agent of the present invention, the pectin removing effect of fiber surface can be improved, and add a small amount of cellulase, improve fabric softening, and the fatty alcohol-polyoxyethylene ether added is on the one hand as the promoter of alkaline pectase, improve the heat resistance of cellulase on the other hand, extend its survival half-life, kill two birds with one stone.In addition, the two palmityl ethylene diamine dipropionic acid sodium added in scouring agent are as a kind of novel Gemini surface active, and have excellent alkaline-resisting and resistance to stabilized hydrogen peroxide feature, emulsibility is good, and foaming power is strong, improves scouring result.
Description
Technical field
The present invention relates to a kind of weaving scouring agent, particularly a kind of silk flosssilk wadding BLENDED FABRIC scouring agent.
Background technology
Natural color cotton/silk blend fabric is a kind of novel Green Product.Color cotton can give real silk with color, makes product without the need to chemical staining, meets environmental protection and healthy consumption requirement; Real silk be added in keep COTTON FABRIC natural stype while, gloss and the wearability of cotton product can also be improved.Therefore blending can make two kinds of fibers reach mutual supplement with each other's advantages, and makes the environmental protection characteristic of product more obvious.Colorful cotton fibre and cocoon fiber are environmental protection fiber, with the natural environmental-protective type product of these two kinds of fiber blend exploitations, can significantly improve grade and the class of product.
During cotton fiber growth, there is natural impurity (pectic substance, waxy substance, nitrogen substance etc.) association together.COTTON FABRIC is after destarch, and most of slurry and part natural impurity are removed, but also has a small amount of slurry and most of natural impurity also to remain on fabric.The existence of these impurity, the cloth cover that silk floss is weaved cotton cloth is more yellow, poor permeability.Meanwhile, owing to there being the existence of cotton seed hulls, greatly have impact on the presentation quality of cotton.Therefore need kiering fabric being carried out in the high alkali liquid of high temperature the long period, to remove residual impurity.Kiering utilizes caustic soda and other boiling-off additives and pectic substance, waxy substance, nitrogen substance, cotton seed hulls generation chemical degradation to react or emulsification, Swelling Functions etc., after washing, impurity stripped from fabric.
At present, concise operation adopts NaOH and other auxiliary agent process are cotton and BLENDED FABRIC, remove pectin, cotton wax, cotton seed hulls, protein, grease and the material such as the slurry do not eliminated in destarch operation and impurity in COTTON FABRIC, make fabric obtain good outward appearance and the quality of inherence.No matter be conventional refining process, move back and boil a bleaching two-phase method technique, or one-bath DSB method technique, or cold-pad-batch process etc., all need to add scouring agent, to improve scouring result.
Along with the development of printing and dyeing industry, energy efficient, accelerate refining speed, shortened process is inexorable trend.As the important component part of scouring agent, surfactant must have good wetting, infiltration, emulsification, dispersion, washing performance, also should have the performances such as high temperature resistant, biology is easily degraded, low foam, safety non-toxic.Single surfactant can not have above-mentioned performance concurrently, must be undertaken composite by several surfactant, reaches satisfied scouring result by collaborative and synergistic effect.
Summary of the invention
The object of the invention is to: the defect overcoming above-mentioned prior art, propose a kind of silk flosssilk wadding BLENDED FABRIC scouring agent.
In order to achieve the above object, the present invention propose a kind of silk flosssilk wadding BLENDED FABRIC scouring agent, its component by mass ratio as follows:
Cellulase: 0.3-0.5 part; alkaline pectase: 1.2-1.5 part; fatty alcohol-polyoxyethylene ether: 7-8 part; two palmityl ethylene diamine dipropionic acid sodium: 5-6 part; sodium hydroxide solution: 18-20 part, sodium carbonate: 6-7 part, hydrogen peroxide: 8-10 part; Tea Saponin: 4-5 part, deionized water: 80-110 part.
The further improvement of silk flosssilk wadding BLENDED FABRIC scouring agent of the present invention is:
1, the mass percent concentration of described sodium hydroxide solution is: 17-19%.
2, in described hydrogen peroxide, the concentration of volume percent mark of hydrogen peroxide is 20-24%.
3, its component by mass ratio as follows: cellulase: 0.3 part; alkaline pectase: 1.2 parts; fatty alcohol-polyoxyethylene ether: 7 parts; two palmityl ethylene diamine dipropionic acid sodium: 5 parts; sodium hydroxide solution: 18 parts, sodium carbonate: 6 parts, hydrogen peroxide: 8 parts; Tea Saponin: 4 parts, deionized water: 80 parts.
4, its component by mass ratio as follows: cellulase: 0.5 part; alkaline pectase: 1.5 parts; fatty alcohol-polyoxyethylene ether: 8 parts; two palmityl ethylene diamine dipropionic acid sodium: 6 parts; sodium hydroxide solution: 20 parts, sodium carbonate: 7 parts, hydrogen peroxide: 10 parts; Tea Saponin: 5 parts, deionized water: 110 parts.
5, its component by mass ratio as follows: cellulase: 0.4 part; alkaline pectase: 1.3 parts; fatty alcohol-polyoxyethylene ether: 7.5 parts; two palmityl ethylene diamine dipropionic acid sodium: 5.5 parts; sodium hydroxide solution: 19 parts, sodium carbonate: 6.5 parts, hydrogen peroxide: 9 parts; Tea Saponin: 4.5 parts, deionized water: 100 parts.
Alkaline pectase is added in scouring agent of the present invention, the pectin removing effect of fiber surface can be improved, and add a small amount of cellulase, improve fabric softening, and the fatty alcohol-polyoxyethylene ether added is on the one hand as the promoter of alkaline pectase, improve the heat resistance of cellulase on the other hand, extend its survival half-life, kill two birds with one stone.In addition, the two palmityl ethylene diamine dipropionic acid sodium added in scouring agent are as a kind of novel Gemini surface active, and have excellent alkaline-resisting and resistance to stabilized hydrogen peroxide feature, emulsibility is good, and foaming power is strong, improves scouring result.
Innovation of the present invention, not only in the formation of component, is more the proportioning between component, and the scouring result of silk flosssilk wadding BLENDED FABRIC can be made to reach best.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment one
The present embodiment scouring agent component is by mass ratio as follows:
Cellulase (production of Ningxia jade of the He family Bioisystech Co., Ltd): 0.3 part; alkaline pectase (production of Ningxia jade of the He family Bioisystech Co., Ltd): 1.2 parts; fatty alcohol-polyoxyethylene ether: 7 parts; two palmityl ethylene diamine dipropionic acid sodium: 5 parts; sodium hydroxide solution: 18 parts, sodium carbonate: 6 parts, hydrogen peroxide: 8 parts; Tea Saponin: 4 parts, deionized water: 80 parts.Wherein, the mass percent concentration of sodium hydroxide solution is: 17%.In hydrogen peroxide, the concentration of volume percent mark of hydrogen peroxide is 20%.
Embodiment two
The present embodiment scouring agent component is by mass ratio as follows: cellulase: 0.5 part; alkaline pectase: 1.5 parts; fatty alcohol-polyoxyethylene ether: 8 parts; two palmityl ethylene diamine dipropionic acid sodium: 6 parts; sodium hydroxide solution: 20 parts, sodium carbonate: 7 parts, hydrogen peroxide: 10 parts; Tea Saponin: 5 parts, deionized water: 110 parts.Wherein, the mass percent concentration of sodium hydroxide solution is: 19%.In hydrogen peroxide, the concentration of volume percent mark of hydrogen peroxide is 24%.
Embodiment three
The present embodiment scouring agent component is by mass ratio as follows: cellulase: 0.4 part; alkaline pectase: 1.3 parts; fatty alcohol-polyoxyethylene ether: 7.5 parts, two palmityl ethylene diamine dipropionic acid sodium: 5.5 parts, sodium hydroxide solution: 19 parts; sodium carbonate: 6.5 parts; hydrogen peroxide: 9 parts, Tea Saponin: 4.5 parts, deionized water: 100 parts; wherein, the mass percent concentration of sodium hydroxide solution is: 18%.In hydrogen peroxide, the concentration of volume percent mark of hydrogen peroxide is 22%.
Our experiments show that, use above-mentioned three kinds of scouring agents to participate in the concise of silk flosssilk wadding BLENDED FABRIC as additive, except pectin effect and cleaning effect are all very good, fabric softening is improved.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of application claims.
Claims (4)
1. a silk flosssilk wadding BLENDED FABRIC scouring agent, its component by mass ratio as follows:
Cellulase: 0.3-0.5 part, alkaline pectase: 1.2-1.5 part, fatty alcohol-polyoxyethylene ether: 7-8 part, two palmityl ethylene diamine dipropionic acid sodium: 5-6 part, sodium hydroxide solution: 18-20 part, sodium carbonate: 6-7 part, hydrogen peroxide: 8-10 part, Tea Saponin: 4-5 part, deionized water: 80-110 part; The mass percent concentration of described sodium hydroxide solution is: 17-19%; In described hydrogen peroxide, the concentration of volume percent mark of hydrogen peroxide is 20-24%.
2. silk flosssilk wadding BLENDED FABRIC scouring agent according to claim 1; it is characterized in that: its component by mass ratio as follows: cellulase: 0.3 part; alkaline pectase: 1.2 parts; fatty alcohol-polyoxyethylene ether: 7 parts, two palmityl ethylene diamine dipropionic acid sodium: 5 parts, sodium hydroxide solution: 18 parts; sodium carbonate: 6 parts; hydrogen peroxide: 8 parts, Tea Saponin: 4 parts, deionized water: 80 parts.
3. silk flosssilk wadding BLENDED FABRIC scouring agent according to claim 1; it is characterized in that: its component by mass ratio as follows: cellulase: 0.5 part; alkaline pectase: 1.5 parts; fatty alcohol-polyoxyethylene ether: 8 parts, two palmityl ethylene diamine dipropionic acid sodium: 6 parts, sodium hydroxide solution: 20 parts; sodium carbonate: 7 parts; hydrogen peroxide: 10 parts, Tea Saponin: 5 parts, deionized water: 110 parts.
4. silk flosssilk wadding BLENDED FABRIC scouring agent according to claim 1; it is characterized in that: its component by mass ratio as follows: cellulase: 0.4 part; alkaline pectase: 1.3 parts; fatty alcohol-polyoxyethylene ether: 7.5 parts, two palmityl ethylene diamine dipropionic acid sodium: 5.5 parts, sodium hydroxide solution: 19 parts; sodium carbonate: 6.5 parts; hydrogen peroxide: 9 parts, Tea Saponin: 4.5 parts, deionized water: 100 parts.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410110249.8A CN103898770B (en) | 2014-03-24 | 2014-03-24 | A kind of silk flosssilk wadding BLENDED FABRIC scouring agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410110249.8A CN103898770B (en) | 2014-03-24 | 2014-03-24 | A kind of silk flosssilk wadding BLENDED FABRIC scouring agent |
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| CN103898770A CN103898770A (en) | 2014-07-02 |
| CN103898770B true CN103898770B (en) | 2016-02-10 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104294612A (en) * | 2014-10-20 | 2015-01-21 | 苏州富美纺织科技有限公司 | Scouring agent for silk-cotton blended fabrics |
| CN105155249B (en) * | 2015-10-14 | 2017-10-17 | 吴江市七都镇庙港雅迪针织制衣厂 | A kind of low temperature scouring agent, Its Preparation Method And Use |
| CN107476054A (en) * | 2017-07-26 | 2017-12-15 | 安徽双鑫新纤维科技有限公司 | Acidproof heat-proof cotton fiber preparation method |
| CN109322161A (en) * | 2018-09-15 | 2019-02-12 | 杭州三印染整有限公司 | A kind of cotton-polyester blend fabric scouring agent and its method for refining |
| CN111485419A (en) * | 2020-04-23 | 2020-08-04 | 罗莱生活科技股份有限公司 | Skin-care scouring agent and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN100575593C (en) * | 2008-04-02 | 2009-12-30 | 苏州大学 | Silk broadcloth scouring agent |
| CN103603202B (en) * | 2013-11-14 | 2015-09-23 | 浙江益南纤维科技有限公司 | A kind of weaving refining agent |
| CN103643493A (en) * | 2013-12-09 | 2014-03-19 | 常熟市梦迪安家饰用品有限公司 | Environmental-friendly and alkali-resistant scouring agent |
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