CN103726357A - Antistatic emulsified lubricating oil - Google Patents
Antistatic emulsified lubricating oil Download PDFInfo
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- CN103726357A CN103726357A CN201310653893.5A CN201310653893A CN103726357A CN 103726357 A CN103726357 A CN 103726357A CN 201310653893 A CN201310653893 A CN 201310653893A CN 103726357 A CN103726357 A CN 103726357A
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- antistatic
- methyl alcohol
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Abstract
The invention relates to an antistatic emulsified lubricating oil, and belongs to the technical fields of spinning, printing and dyeing. The antistatic emulsified lubricating oil is prepared by the following materials: 950 parts of gutter oil, 400-450 parts of alkali, 10-30 parts of a fatty alcohol emulgator and 15-35 parts of methyl alcohol, wherein the gutter oil and the alkali are taken as main raw materials, and the fatty alcohol emulgator and the methyl alcohol are taken as auxiliary materials. A specific preparation method is adopted, and a charging sequence, a temperature range and the alkali dropping speed are controlled strictly to ensure interaction among the components, so as to achieve the effects of being antistatic and soft, lubrication, complexing calcium and magnesium ions. Through the adoption of the antistatic emulsified lubricating oil, the average yarn breakage in a beam dyeing process is lower than 7.3 pieces/hour, the average diameter dividing ratio is above 9700 m/h, and surface specific resistance is lower than 4.1*102 ohm; besides, as the gutter oil is taken as a main raw material, the difficulty in utilizing the gutter oil is overcome, and meanwhile, the production cost is reduced.
Description
Technical field
The present invention relates to a kind of antistatic emulsion type lubricant, belong to technical field of textile printing.
Background technology
At present, in printing and dyeing front road (bundle dyes) yarn technique, cowboy exists: the problem that fluffing, yarn glue connection, lubricated, flexibility is poor, easily produce static; Cause in lease making operation, lease making efficiency is low, end breakage rate is high, reduce product quality, increase product cost.For solve yarn fluffing, easily sticky connection, lubricated, flexibility is poor, easily produce the problems such as static, in yarn beam, dye and in process, conventionally add the printing and dyeing assistants such as NaOH, bleeding agent, starch, glue, talcum powder.But above-mentioned printing and dyeing assistant function singleness, cannot solve two and plural technical problem simultaneously.
If bleeding agent, NaOH are the conventional emulsifying agents in this area, can play good effect, but substantially cannot solve electrostatic problem; Alkali, this area is commonly used to do degreaser, but cannot play emulsification and anlistatig effect; Methyl alcohol, this area is commonly used to reduce the intensity of NaOH, but cannot play lubricated and anlistatig effect.
Summary of the invention
The object of the present invention is to provide a kind of antistatic emulsion type lubricant that can simultaneously play emulsification and lubricant effect and antistatic property.
Technical scheme of the present invention
1. an antistatic emulsion type lubricant, its raw material and weight proportion are:
950 parts of waste oils, 400-450 part alkali, 10-30 part aliphatic alcohols emulsifying agent and 15-35 part methyl alcohol;
Its preparation method is:
(1) waste oil stirs 20-35min under 87-98 ℃ of condition;
(2) add alkali, then stir 60-150min, then be warming up to 115-136 ℃;
(3) add emulsifying agent, then stir insulation 80-120min;
(4) add methyl alcohol, continue insulation 80-120min, obtain product.
Described alkali is hydroxide, basic salt, the mixture of hydroxide and basic salt.
The antistatic emulsion type lubricant of the present invention, take waste oil and alkali as main raw material, take aliphatic alcohols emulsifying agent and methyl alcohol as auxiliary material; Adopt specific preparation method, by the rate of addition of strict control charging sequence, temperature range and alkali, make to interact between each component; Thereby played effect antistatic, lubricated, soft, complexing calcium ions and magnesium ions.Use antistatic emulsion type lubricant of the present invention, yarn beam dye in process average end breakage rate 7.3/below h, average mark footpath rate is up to more than 9700m/h, surface specific resistance is at 4.1x10
2below Ω.In addition, take waste oil as main raw material, solve waste oil and utilized difficult problem, reduced the production cost of product simultaneously.
In order further to improve antistatic effect and the stability of product, above-mentioned antistatic emulsion type lubricant, the waste oil that preferential selected fatty acid C chain length is 10-18 is as raw material.
In order to obtain better antistatic, lubricated, emulsifying effectiveness; Above-mentioned antistatic emulsion type lubricant, its raw material optimum ratio is: 950 parts of waste oils, alkali 420-430 part, emulsifying agent 18-23 part, methyl alcohol 20-25 part.
Above-mentioned antistatic emulsion type lubricant, most preferred proportioning is: 950 parts of waste oils, 427 parts, alkali, 21 parts of emulsifying agents, 23 parts of methyl alcohol.Now, the various best performances of product; Surface specific resistance is 1.7x10
2Ω, 6.4/below h, average mark footpath rate is up to more than 9900m/h.
Above-mentioned antistatic emulsion type lubricant, preferably adopts following process conditions:
(1) waste oil stirs 31min under 92 ℃ of conditions;
(2) add alkali, then stir 103min, then be warming up to 126 ℃;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min, obtain product.
Beneficial effect
Raw material is easy to get, with low cost; A kind of nuisanceless application mode of waste oil is provided;
The preparation method of product is simple, pollution-free;
Effect antistatic, lubricated, soft, complexing calcium ions and magnesium ions that product possesses simultaneously;
After using this product, surface specific resistance is down to 4.1x10
2below Ω; In lease making operation, end breakage rate drop to 7.3/below h, more than a point footpath rate is increased to 9700m/h.
The specific embodiment
Embodiment 1-9, comparative example 1-10;
Table 1:
; In table 1, described umber is weight portion, and waste oil used is the aliphatic acid that the C chain length that extracts from waste oil is 10-18; Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3(evidence aliphatic alcohols emulsifying agent, and all can meet requirement of the present invention and effect does not have notable difference, at this, only take AEO-3 as example);
According to table 1, prepare raw material, be prepared by the following method:
(1) waste oil stirs 31min under 92 ℃ of conditions;
(2) adopt dropping mode to add alkali, within 3-6 hour, dropwise rear stirring 103min, then be warming up to 126 ℃;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min; Obtain product.
Embodiment 10
The raw material proportioning that adopts embodiment 1, adopts following step to be prepared:
(1) under 98 ℃ of conditions of waste oil, stir 20min;
(2) adopt dropping mode to add alkali, within 6 hours, dropwise rear stirring 150min, then be warming up to 136 ℃;
(3) add emulsifying agent, then stir insulation 120min;
(4) add methyl alcohol, continue insulation 120min, obtain product;
Waste oil used is the aliphatic acid that the C chain length that extracts from waste oil is 10-18; Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3.
Embodiment 11
The raw material proportioning that adopts embodiment 1, adopts following step to be prepared:
(1) under 87 ℃ of conditions of waste oil, stir 20min;
(2) adopt dropping mode to add alkali, within 3 hours, dropwise rear stirring 60min, then be warming up to 115 ℃;
(3) add emulsifying agent, then stir insulation 80min;
(4) add methyl alcohol, continue insulation 80min, obtain product;
Waste oil used is the aliphatic acid that the C chain length that extracts from waste oil is 10-18; Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3.
Embodiment 12
The raw material proportioning that adopts embodiment 1, adopts following step to be prepared:
(1) under 92 ℃ of conditions of waste oil, stir 31min;
(2) by disposable alkali, add, then stir 103min, then be warming up to 126 ℃;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min; Obtain respectively product;
Waste oil used is the aliphatic acid that the C chain length that extracts from waste oil is 10-18; Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3.
Embodiment 13
(1) waste oil stirs 31min under 92 ℃ of conditions;
(2) adopt dropping mode to add alkali, within 3-6 hour, dropwise rear stirring 103min, then be warming up to 126 ℃;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min; Obtain respectively product;
Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3.
Effect test
In identical bundle dyeing yarn Wiring technology, every 100 grams of polyester cotton blended yarns, add respectively product prepared by equivalent 1g above-described embodiment; Then the yarn of halved tie after dying and the cloth that adopts this yarn to be made into detect, evaluate; Result is as table 2.
Table 2
| Surface specific resistance | Flexibility | Average end breakage rate (root/h) | Average mark footpath rate (m/h) | |
| Embodiment 1 | 1.7x10 2Ω | Excellent | 6.4 | 9900 |
| Embodiment 2 | 2.4x10 2Ω | Excellent | 6.7 | 9800 |
| Embodiment 3 | 2.1x10 2Ω | Excellent | 6.6 | 9800 |
| Embodiment 4 | 2.3x10 2Ω | Excellent | 6.7 | 9700 |
| Embodiment 5 | 2.6x10 2Ω | Excellent | 6.8 | 9800 |
| Embodiment 6 | 3.3x10 2Ω | Excellent | 7.1 | 9700 |
| Embodiment 7 | 3.2x10 2Ω | Excellent | 6.9 | 9700 |
| Embodiment 8 | 3.4x10 2Ω | Excellent | 7.1 | 9700 |
| Embodiment 9 | 3.3x10 2Ω | Excellent | 7.0 | 9800 |
| Embodiment 10 | 3.7x10 2Ω | Excellent | 7.2 | 9800 |
| Embodiment 11 | 4.1x10 2Ω | Excellent | 7.3 | 9700 |
| Embodiment 12 | 9.4x10 5Ω | Good | 8.5 | 9000 |
| Embodiment 13 | 9.3x10 6Ω | Excellent | 8.4 | 9100 |
| Comparative example 1 | 9.1x10 9Ω | Good | 9.1 | 8400 |
| Comparative example 2 | 9.2x10 8Ω | Good | 9.2 | 8300 |
| Comparative example 3 | 9.2x10 7Ω | Excellent | 9.2 | 8400 |
| Comparative example 4 | 9.3x10 8Ω | Good | 9.1 | 8300 |
| Comparative example 5 | 9.1x10 9Ω | Excellent | 9.0 | 8200 |
| Comparative example 6 | 8.8x10 12Ω | Good | 9.0 | 8300 |
| Comparative example 7 | 8.7x10 14Ω | Good | 9.3 | 8200 |
| Comparative example 8 | 8.1x10 15Ω | Excellent | 9.4 | 8100 |
| Comparative example 9 | 7.3x10 14Ω | Good | 9.4 | 8200 |
| Comparative example 10 | 6.x10 15Ω | Excellent | 9.4 | 8100 |
By table 2, can be drawn product effect excellence of the present invention
.
Claims (5)
1. an antistatic emulsion type lubricant, is characterized in that, its raw material and weight proportion are:
950 parts of waste oils, 400-450 part alkali, 10-30 part aliphatic alcohols emulsifying agent and 15-35 part methyl alcohol;
Its preparation method is:
(1) waste oil stirs 20-35min under 87-98 ℃ of condition;
(2) add alkali, then stir 60-150min, then be warming up to 115-136 ℃;
(3) add emulsifying agent, then stir insulation 80-120min;
(4) add methyl alcohol, continue insulation 80-120min, obtain product.
2. antistatic emulsion type lubricant according to claim 1, is characterized in that, the waste oil that selected fatty acid C chain length is 10-18 is as raw material.
3. antistatic emulsion type lubricant according to claim 1 and 2, is characterized in that, its raw material proportioning is: 950 parts of waste oils, alkali 420-430 part, emulsifying agent 18-23 part, methyl alcohol 20-25 part.
4. antistatic emulsion type lubricant according to claim 1 and 2, is characterized in that, its raw material proportioning is: 950 parts of waste oils, 427 parts, alkali, 21 parts of emulsifying agents, 23 parts of methyl alcohol.
5. antistatic emulsion type lubricant according to claim 1 and 2, is characterized in that, adopts following process conditions to be prepared:
(1) waste oil stirs 31min under 92 ℃ of conditions;
(2) add alkali, then stir 103min, then be warming up to 126 ℃;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min, obtain product.
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| CN201310653893.5A CN103726357B (en) | 2013-12-09 | 2013-12-09 | A kind of antistatic emulsion type lubricant |
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| CN201310653893.5A CN103726357B (en) | 2013-12-09 | 2013-12-09 | A kind of antistatic emulsion type lubricant |
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| CN103726357A true CN103726357A (en) | 2014-04-16 |
| CN103726357B CN103726357B (en) | 2016-04-13 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176693A (en) * | 2015-09-23 | 2015-12-23 | 西京学院 | Preparation method for antistatic agent based on polyhydroxyl, gutter oil and quaternary ammonium salt |
| CN106283620A (en) * | 2016-07-29 | 2017-01-04 | 苏州富欧生物科技有限公司 | A kind of emulsifying agent of Environmental-friendantistatic antistatic |
| CN106498696A (en) * | 2016-10-28 | 2017-03-15 | 济宁锦祥化工科技有限公司 | A kind of textile printing and dyeing white preparation method of green solid |
| CN106498781A (en) * | 2016-10-28 | 2017-03-15 | 济宁锦祥化工科技有限公司 | A kind of preparation method of textile printing and dyeing with non-polluted edible level defoamer |
| CN106544165A (en) * | 2016-10-28 | 2017-03-29 | 济宁锦祥化工科技有限公司 | A kind of preparation method of textile printing and dyeing with green deoiling decontaminant |
| CN106635512A (en) * | 2016-10-28 | 2017-05-10 | 济宁锦祥化工科技有限公司 | Preparation method for green soaping agent for spinning printing and dyeing |
| CN106801333A (en) * | 2017-01-23 | 2017-06-06 | 济宁锦祥化工科技有限公司 | A kind of textile printing and dyeing preparation method of green strong high-temperature alkali-resistant penetrant |
| CN112574807A (en) * | 2021-01-20 | 2021-03-30 | 安徽联亚新材料有限公司 | Biodegradable lubricating oil prepared from waste oil and fat and preparation process thereof |
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| CN102276825A (en) * | 2011-06-01 | 2011-12-14 | 夏森林 | Process for manufacturing polyvinyl chloride (PVC) internal lubricant |
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Patent Citations (4)
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| CN101157850A (en) * | 2007-11-20 | 2008-04-09 | 孝英 | Preparation of high temperature resistant lubricant for drilling liquid by animal plant oil |
| CN102276825A (en) * | 2011-06-01 | 2011-12-14 | 夏森林 | Process for manufacturing polyvinyl chloride (PVC) internal lubricant |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176693A (en) * | 2015-09-23 | 2015-12-23 | 西京学院 | Preparation method for antistatic agent based on polyhydroxyl, gutter oil and quaternary ammonium salt |
| CN105176693B (en) * | 2015-09-23 | 2019-03-26 | 西京学院 | A kind of preparation method of the antistatic agent based on polyhydroxy gutter oil quaternary ammonium salt |
| CN106283620A (en) * | 2016-07-29 | 2017-01-04 | 苏州富欧生物科技有限公司 | A kind of emulsifying agent of Environmental-friendantistatic antistatic |
| CN106498696A (en) * | 2016-10-28 | 2017-03-15 | 济宁锦祥化工科技有限公司 | A kind of textile printing and dyeing white preparation method of green solid |
| CN106498781A (en) * | 2016-10-28 | 2017-03-15 | 济宁锦祥化工科技有限公司 | A kind of preparation method of textile printing and dyeing with non-polluted edible level defoamer |
| CN106544165A (en) * | 2016-10-28 | 2017-03-29 | 济宁锦祥化工科技有限公司 | A kind of preparation method of textile printing and dyeing with green deoiling decontaminant |
| CN106635512A (en) * | 2016-10-28 | 2017-05-10 | 济宁锦祥化工科技有限公司 | Preparation method for green soaping agent for spinning printing and dyeing |
| CN106801333A (en) * | 2017-01-23 | 2017-06-06 | 济宁锦祥化工科技有限公司 | A kind of textile printing and dyeing preparation method of green strong high-temperature alkali-resistant penetrant |
| CN112574807A (en) * | 2021-01-20 | 2021-03-30 | 安徽联亚新材料有限公司 | Biodegradable lubricating oil prepared from waste oil and fat and preparation process thereof |
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|---|---|
| CN103726357B (en) | 2016-04-13 |
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Effective date of registration: 20160420 Address after: 272503 Shandong city of Jining province Wenshang County Yin Si Zhen Kong Lou 800 meters north of the village Patentee after: Jining Jinxiang Chemical Technology Co., Ltd. Address before: Shandong province Jining City Xindian 272509 South Wenshang County Patentee before: SHANDONG JINING JINXIANG CHEMICAL CO., LTD. |