CN103726357B - A kind of antistatic emulsion type lubricant - Google Patents
A kind of antistatic emulsion type lubricant Download PDFInfo
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- CN103726357B CN103726357B CN201310653893.5A CN201310653893A CN103726357B CN 103726357 B CN103726357 B CN 103726357B CN 201310653893 A CN201310653893 A CN 201310653893A CN 103726357 B CN103726357 B CN 103726357B
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Abstract
The present invention relates to a kind of antistatic emulsion type lubricant, belong to technical field of textile printing.Antistatic emulsion type lubricant of the present invention, is prepared from by 950 parts of waste oils, 400-450 part alkali, 10-30 part aliphatic alcohols emulsifying agent and 15-35 part methyl alcohol.With waste oil and alkali for main raw material, with aliphatic alcohols emulsifying agent and methyl alcohol for auxiliary material; Adopting specific preparation method, by strictly controlling the rate of addition of charging sequence, temperature range and alkali, making the interphase interaction of each component; Thus serve antistatic, lubrication, softness, complexing calcium ions and magnesium ions effect.Use antistatic emulsion type lubricant of the present invention, in yarn beam dye process, average end breakage rate is at 7.3/below h, and average mark footpath rate is up to more than 9700m/h, and surface specific resistance is at 4.1x10
2below Ω.In addition, be main raw material with waste oil, solve waste oil and utilize difficult problem, reduce the production cost of product simultaneously.
Description
Technical field
The present invention relates to a kind of antistatic emulsion type lubricant, belong to technical field of textile printing.
Background technology
At present, exist in cowboy prints and dyes front road (bundle dye) yarn process: the problem of the electrostatic that fluffs, yarn glues connection, do not lubricate, flexibility is poor, easily produces; Cause in lease making operation, lease making efficiency is low, end breakage rate is high, reduce product quality, increase product cost.In order to solve yarn fluffing, easily stickyly join, does not lubricate, the problem such as flexibility is poor, easy generation electrostatic, in yarn beam dye process, usually add the printing and dyeing assistants such as NaOH, bleeding agent, starch, glue, talcum powder.But above-mentioned printing and dyeing assistant function singleness, cannot solve two and plural technical problem simultaneously.
If bleeding agent, NaOH are the emulsifying agents that this area is commonly used, good effect can be played, but substantially cannot solve electrostatic problem; Alkali, this area is commonly used to do degreaser, but cannot play emulsification and anlistatig effect; Methyl alcohol, this area is commonly used to the intensity reducing NaOH, but cannot play lubrication and anlistatig effect.
Summary of the invention
The object of the present invention is to provide a kind of antistatic emulsion type lubricant that simultaneously can play emulsification and lubricant effect and antistatic property.
Technical scheme of the present invention
1. an antistatic emulsion type lubricant, its raw material and weight proportion are:
950 parts of waste oils, 400-450 part alkali, 10-30 part aliphatic alcohols emulsifying agent and 15-35 part methyl alcohol;
Its preparation method is:
(1) waste oil stirs 20-35min under 87-98 DEG C of condition;
(2) add alkali, then stir 60-150min, then be warming up to 115-136 DEG C;
(3) add emulsifying agent, then stir insulation 80-120min;
(4) add methyl alcohol, continue insulation 80-120min, obtain product.
Described alkali is hydroxide, basic salt, the mixture of hydroxide and basic salt.
The antistatic emulsion type lubricant of the present invention, with waste oil and alkali for main raw material, with aliphatic alcohols emulsifying agent and methyl alcohol for auxiliary material; Adopting specific preparation method, by strictly controlling the rate of addition of charging sequence, temperature range and alkali, making the interphase interaction of each component; Thus serve antistatic, lubrication, softness, complexing calcium ions and magnesium ions effect.Use antistatic emulsion type lubricant of the present invention, in yarn beam dye process, average end breakage rate is at 7.3/below h, and average mark footpath rate is up to more than 9700m/h, and surface specific resistance is at 4.1x10
2below Ω.In addition, be main raw material with waste oil, solve waste oil and utilize difficult problem, reduce the production cost of product simultaneously.
In order to improve antistatic effect and the stability of product further, above-mentioned antistatic emulsion type lubricant, preferential selected fatty acid C chain length is that the waste oil of 10-18 is as raw material.
In order to obtain better antistatic, lubrication, emulsifying effectiveness; Above-mentioned antistatic emulsion type lubricant, its raw material optimum ratio is: waste oil 950 parts, alkali 420-430 part, emulsifying agent 18-23 part, methyl alcohol 20-25 part.
Above-mentioned antistatic emulsion type lubricant, most preferred proportioning is: waste oil 950 parts, 427 parts, alkali, emulsifying agent 21 parts, methyl alcohol 23 parts.Now, the various best performances of product; Surface specific resistance is 1.7x10
2Ω, 6.4/below h, average mark footpath rate is up to more than 9900m/h.
Above-mentioned antistatic emulsion type lubricant, preferably adopts following process conditions:
(1) waste oil stirs 31min under 92 DEG C of conditions;
(2) add alkali, then stir 103min, then be warming up to 126 DEG C;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min, obtain product.
Beneficial effect
Raw material is easy to get, with low cost; Provide a kind of nuisanceless application mode of waste oil;
The preparation method of product is simple, pollution-free;
Product possesses antistatic, lubrication, softness, complexing calcium ions and magnesium ions effect simultaneously;
After using this product, surface specific resistance is down to 4.1x10
2below Ω; In lease making operation, end breakage rate drops to 7.3/below h, and a point footpath rate is increased to more than 9700m/h.
Detailed description of the invention
Embodiment 1-9, comparative example 1-10;
Table 1:
; In table 1, described number is weight portion, and waste oil used is the C chain length extracted from waste oil is the aliphatic acid of 10-18; Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is that AEO-3(test proves aliphatic alcohols emulsifying agent, all can meet requirement of the present invention and effect does not have notable difference, at this, only for AEO-3);
Prepare raw material according to table 1, be prepared by the following method:
(1) waste oil stirs 31min under 92 DEG C of conditions;
(2) adopt dropping mode to add alkali, within 3-6 hour, dropwise rear stirring 103min, then be warming up to 126 DEG C;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min; Obtain product.
Embodiment 10
Adopt the pulp furnish of embodiment 1, adopt following step to be prepared:
(1) 20min is stirred under waste oil 98 DEG C of conditions;
(2) adopt dropping mode to add alkali, within 6 hours, dropwise rear stirring 150min, then be warming up to 136 DEG C;
(3) add emulsifying agent, then stir insulation 120min;
(4) add methyl alcohol, continue insulation 120min, obtain product;
Waste oil used is the C chain length extracted from waste oil is the aliphatic acid of 10-18; Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3.
Embodiment 11
Adopt the pulp furnish of embodiment 1, adopt following step to be prepared:
(1) 20min is stirred under waste oil 87 DEG C of conditions;
(2) adopt dropping mode to add alkali, within 3 hours, dropwise rear stirring 60min, then be warming up to 115 DEG C;
(3) add emulsifying agent, then stir insulation 80min;
(4) add methyl alcohol, continue insulation 80min, obtain product;
Waste oil used is the C chain length extracted from waste oil is the aliphatic acid of 10-18; Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3.
Embodiment 12
Adopt the pulp furnish of embodiment 1, adopt following step to be prepared:
(1) 31min is stirred under waste oil 92 DEG C of conditions;
(2) add disposable for alkali, then stir 103min, then be warming up to 126 DEG C;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min; Obtain product respectively;
Waste oil used is the C chain length extracted from waste oil is the aliphatic acid of 10-18; Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3.
Embodiment 13
(1) waste oil stirs 31min under 92 DEG C of conditions;
(2) adopt dropping mode to add alkali, within 3-6 hour, dropwise rear stirring 103min, then be warming up to 126 DEG C;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min; Obtain product respectively;
Alkali used is the mixture that NaOH and sodium carbonate form according to the weight ratio of 1:1; Emulsifying agent used is AEO-3.
Effect test
In identical bundle dyeing yarn Wiring technology, every 100 grams of polyester cotton blended yarns, add product prepared by equivalent 1g above-described embodiment respectively; Then the yarn after halved tie dye and the cloth adopting this yarn to be made into carry out detecting, evaluating; Result is as table 2.
Table 2
| Surface specific resistance | Flexibility | Average end breakage rate (root/h) | Average mark footpath rate (m/h) | |
| Embodiment 1 | 1.7x10 2Ω | Excellent | 6.4 | 9900 |
| Embodiment 2 | 2.4x10 2Ω | Excellent | 6.7 | 9800 |
| Embodiment 3 | 2.1x10 2Ω | Excellent | 6.6 | 9800 |
| Embodiment 4 | 2.3x10 2Ω | Excellent | 6.7 | 9700 |
| Embodiment 5 | 2.6x10 2Ω | Excellent | 6.8 | 9800 |
| Embodiment 6 | 3.3x10 2Ω | Excellent | 7.1 | 9700 |
| Embodiment 7 | 3.2x10 2Ω | Excellent | 6.9 | 9700 |
| Embodiment 8 | 3.4x10 2Ω | Excellent | 7.1 | 9700 |
| Embodiment 9 | 3.3x10 2Ω | Excellent | 7.0 | 9800 |
| Embodiment 10 | 3.7x10 2Ω | Excellent | 7.2 | 9800 |
| Embodiment 11 | 4.1x10 2Ω | Excellent | 7.3 | 9700 |
| Embodiment 12 | 9.4x10 5Ω | Good | 8.5 | 9000 |
| Embodiment 13 | 9.3x10 6Ω | Excellent | 8.4 | 9100 |
| Comparative example 1 | 9.1x10 9Ω | Good | 9.1 | 8400 |
| Comparative example 2 | 9.2x10 8Ω | Good | 9.2 | 8300 |
| Comparative example 3 | 9.2x10 7Ω | Excellent | 9.2 | 8400 |
| Comparative example 4 | 9.3x10 8Ω | Good | 9.1 | 8300 |
| Comparative example 5 | 9.1x10 9Ω | Excellent | 9.0 | 8200 |
| Comparative example 6 | 8.8x10 12Ω | Good | 9.0 | 8300 |
| Comparative example 7 | 8.7x10 14Ω | Good | 9.3 | 8200 |
| Comparative example 8 | 8.1x10 15Ω | Excellent | 9.4 | 8100 |
| Comparative example 9 | 7.3x10 14Ω | Good | 9.4 | 8200 |
| Comparative example 10 | 6.x10 15Ω | Excellent | 9.4 | 8100 |
Can be drawn by table 2, product excellent effect of the present invention.
Claims (3)
1. an antistatic emulsion type lubricant, is characterized in that, its raw material and weight proportion are:
950 parts of waste oils, 420-430 part alkali, 18-23 part aliphatic alcohols emulsifying agent and 20-25 part methyl alcohol; Described waste oil, its aliphatic acid C chain length is 10-18;
Its preparation method is:
(1) waste oil stirs 20-35min under 87-98 DEG C of condition;
(2) add alkali, then stir 60-150min, then be warming up to 115-136 DEG C;
(3) add emulsifying agent, then stir insulation 80-120min;
(4) add methyl alcohol, continue insulation 80-120min, obtain product.
2. antistatic emulsion type lubricant according to claim 1, is characterized in that, its pulp furnish is: waste oil 950 parts, 427 parts, alkali, emulsifying agent 21 parts, methyl alcohol 23 parts.
3. antistatic emulsion type lubricant according to claim 1, is characterized in that, adopts following process conditions to be prepared:
(1) waste oil stirs 31min under 92 DEG C of conditions;
(2) add alkali, then stir 103min, then be warming up to 126 DEG C;
(3) add emulsifying agent, then stir insulation 107min;
(4) add methyl alcohol, continue insulation 110min, obtain product.
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| CN103726357B true CN103726357B (en) | 2016-04-13 |
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| CN105176693B (en) * | 2015-09-23 | 2019-03-26 | 西京学院 | A kind of preparation method of the antistatic agent based on polyhydroxy gutter oil quaternary ammonium salt |
| CN106283620A (en) * | 2016-07-29 | 2017-01-04 | 苏州富欧生物科技有限公司 | A kind of emulsifying agent of Environmental-friendantistatic antistatic |
| CN106635512A (en) * | 2016-10-28 | 2017-05-10 | 济宁锦祥化工科技有限公司 | Preparation method for green soaping agent for spinning printing and dyeing |
| CN106498696A (en) * | 2016-10-28 | 2017-03-15 | 济宁锦祥化工科技有限公司 | A kind of textile printing and dyeing white preparation method of green solid |
| CN106544165A (en) * | 2016-10-28 | 2017-03-29 | 济宁锦祥化工科技有限公司 | A kind of preparation method of textile printing and dyeing with green deoiling decontaminant |
| CN106498781A (en) * | 2016-10-28 | 2017-03-15 | 济宁锦祥化工科技有限公司 | A kind of preparation method of textile printing and dyeing with non-polluted edible level defoamer |
| CN106801333A (en) * | 2017-01-23 | 2017-06-06 | 济宁锦祥化工科技有限公司 | A kind of textile printing and dyeing preparation method of green strong high-temperature alkali-resistant penetrant |
| CN112574807B (en) * | 2021-01-20 | 2022-07-29 | 上海中器环保科技有限公司 | Biodegradable lubricating oil prepared from waste oil and fat and preparation process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157850A (en) * | 2007-11-20 | 2008-04-09 | 孝英 | Preparation of high temperature resistant lubricant for drilling liquid by animal plant oil |
| CN102276825A (en) * | 2011-06-01 | 2011-12-14 | 夏森林 | Process for manufacturing polyvinyl chloride (PVC) internal lubricant |
| CN103045183A (en) * | 2012-12-07 | 2013-04-17 | 中国石油集团川庆钻探工程有限公司 | Illegal cooking oil lubricant and preparation method thereof |
| CN103320182A (en) * | 2013-07-17 | 2013-09-25 | 汤永华 | Multipurpose low-carbon oil and its production method |
-
2013
- 2013-12-09 CN CN201310653893.5A patent/CN103726357B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157850A (en) * | 2007-11-20 | 2008-04-09 | 孝英 | Preparation of high temperature resistant lubricant for drilling liquid by animal plant oil |
| CN102276825A (en) * | 2011-06-01 | 2011-12-14 | 夏森林 | Process for manufacturing polyvinyl chloride (PVC) internal lubricant |
| CN103045183A (en) * | 2012-12-07 | 2013-04-17 | 中国石油集团川庆钻探工程有限公司 | Illegal cooking oil lubricant and preparation method thereof |
| CN103320182A (en) * | 2013-07-17 | 2013-09-25 | 汤永华 | Multipurpose low-carbon oil and its production method |
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Effective date of registration: 20160420 Address after: 272503 Shandong city of Jining province Wenshang County Yin Si Zhen Kong Lou 800 meters north of the village Patentee after: Jining Jinxiang Chemical Technology Co., Ltd. Address before: Shandong province Jining City Xindian 272509 South Wenshang County Patentee before: SHANDONG JINING JINXIANG CHEMICAL CO., LTD. |