CN106635509A - Vegetable and fruit cleaning agent and preparation method thereof - Google Patents
Vegetable and fruit cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN106635509A CN106635509A CN201611210775.7A CN201611210775A CN106635509A CN 106635509 A CN106635509 A CN 106635509A CN 201611210775 A CN201611210775 A CN 201611210775A CN 106635509 A CN106635509 A CN 106635509A
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- Prior art keywords
- vegetables
- cleaning agent
- fruits
- vegetable
- rice
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/268—Carbohydrates or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
Abstract
The invention belongs to the technical field of daily chemical cleaning agents, and particularly relates to a vegetable and fruit cleaning agent and a preparation method of the vegetable and fruit cleaning agent. The vegetable and fruit cleaning agent comprises the following components in percent by mass: 20-28% of active ionized calcium, 10-14% of starch, 5-10% of a chelating agent, 5-10% of salt and 38-60% of washing water of rice. The vegetable and fruit cleaning agent has the technical advantages that the vegetable and fruit cleaning agent has no side effects, leaves no residues on human skin and fruits after being used in cleaning, is green and environmentally friendly, also cleans up vegetables and fruits, guarantees the hygiene of vegetables and fruits and the eating health of people, and causes no pollution to the environment.
Description
Technical field
The invention belongs to daily use chemicals detergent technical field, and in particular to a kind of vegetables and fruits cleaning agent and preparation method thereof.
Background technology
Various nutriments of the vegetable and fruit rich in needed by human body, with the improvement of people's living standards, to various vegetables
The consumption demand of fruit also more and more higher.Therefore a large amount of planting vegetable fruit also bring huge economic well-being of workers and staff to grower, are
Prevention and elimination of disease and pests improves agricultural product quality to ensure the stable yields of vegetable and fruit, increase production, and agricultural chemicals is also widely used, and afterwards
Still can be widely used in considerably long one period.Although country promulgated successively agricultural chemicals manage and safe handling in terms of phase
Regulation is closed, but still the agricultural chemicals for having many high poison high residues is applied on crops, especially vegetable and fruit.Long-term consumption contains agricultural chemicals
The vegetable and fruit of residual, can bring high risks to health, and it can slowly accumulate in human body, carcinogenic to human body generation,
The slow poisonings such as teratogenesis, mutagenesis；In recent years media also have been reported that repeatly with regard to the event of pesticide poisoning, malicious cowpea, malicious ginger etc..
Certainly, consumer is also improving constantly to the consciousness and demand that remove agricultural chemicals, and the solution of residues of pesticides also can be removed in searching
Method, such as peels and shells, but lost part nutrient, to soil such as use salt solution, the rice washing water that can not remove the peel, starch immersions
Method, but effect is unknown.
Chinese patent application CN103897906A discloses a kind of vegetables and fruits cleaning agent, by fatty acid amide sulfosuccinic acid fat
Disodium, limonene, APES, sodium hypochlorite, sodium gluconate and polyether modified silicon oil composition, lives containing surface
Property agent, surfactant ability of deoiling is stronger, is chemical agent class, pesticidal effects is not only can determine that, and if taking the photograph for a long time
Enter this kind of material, then savings property can may be produced to human body and is poisoned.
Chinese patent application CN105238600A discloses natural vegetables and fruits Cleasing compositions of a kind of powdery and preparation method thereof,
Comprising powder of natural shell, starch, salt, nonionic surfactant and chelating agent, although without anion surfactant safety
Environmental protection still yet suffers from nonionic surfactant.In addition vegetables and fruits cleaning agents many on the market are phosphorous, exist to environment and threaten,
Therefore people earnestly wish to a kind of vegetables and fruits cleaning agent easy to use, safe, effective and professional.
Problem of the prior art is solved, it is current main task to research and develop a kind of safely and efficiently vegetables and fruits cleaning agent.
The content of the invention
There is potential threat to health and ask in the surfactant or other for the existing vegetables and fruits cleaning agent presence of solution
Topic, the present invention provides a kind of vegetables and fruits cleaning agent and preparation method thereof.
A kind of vegetables and fruits cleaning agent, including following components and its mass percent：
Activated ionic calcium 20～28%, starch 10～14%, chelating agent 5～10%, salt 5～10% and rice washing water 38～
60%.
Preferably, described vegetables and fruits cleaning agent, is made up of following components and its mass percent：
Activated ionic calcium 25%, starch 12.5%, chelating agent 7.5%, salt 7.5% and rice washing water 47.5%.
Preferably, described chelating agent is by sodium citrate and the sodium of glutamic acid diacetic acid four in mass ratio 2:3 compositions.
Further preferably, the rice washing water is that rice is placed in water after immersion to filter the metric system and obtain, and with rice and the gross weight of water
On the basis of, the consumption of rice is 10-20%, and the consumption of water is 80-90%.
Additionally, the invention also discloses a kind of preparation method of vegetables and fruits cleaning agent, comprises the following steps：By active ion
Calcium, starch, chelating agent and salt stir in stirred tank, then rice washing water is sprinkled into stirred tank with spray gun, stir
To without particulate matter or caking, obtain final product.
Starch CAS：9005-25-8；Sodium citrate CAS：68-04-2；Four sodium of glutamic acid diacetic acid CAS：
51981-21-6。
Activated ionic calcium is water-soluble powder, meets water and dissolves, and it mainly includes five kinds of main hot spring level Alkaline minerals
Matter, exists with ionic formses, including calcium ion, magnesium ion, potassium ion, sodium ion, germanium ion, can efficiently and effectively decompose vegetables and fruits
Remained on surface agricultural chemicals, chemical fertilizer, wax (oil), additive etc.；Starch insoluble in cold water but be heated to boiling point jointly with water will shape
Into paste-like, with adhesivity, this adhesivity is thought to produce gelatification to the cold recklessly；Sodium citrate and the sodium of glutamic acid diacetic acid four
For chelating agent, the addition of chelating agent makes metal ion generate the diverse chelate of property, is to reduce and control metal ion
The main method of concentration；There is salt sterilizing to act on and safety and environmental protection；Rice washing water is the water after a kind of washed rice, in acid
Property, between 5.5～6, point water of rice washing water can be very good to separate grease, cleaning bowls and chopsticks, removes chopping board peculiar smell, washes off pH
Iron rust on kitchen knife etc., people often outwell rice washing water when cooking, it is believed that it there is not purposes, in fact, in daily life
In work, rice washing water can not only play the part of the natural detergent of multiple player, but also with good medical value.
Compatibility of the present invention is reasonable, science, and each component cooperates, acting synergistically makes the vegetables and fruits cleaning agent ensure to human body
Preferable cleaning performance is kept on the basis of non-hazardous and environmental protection.
Compared with prior art, it is of the invention it is a technical advantage that：Have no side effect, after cleaning to human body skin and fruit not
Residual phenomena can be produced, environmental protection can clean up vegetables and fruits again, it is ensured that the health that the health of vegetables and fruits and people eat,
It is also pollution-free to environment.
Specific embodiment
The present invention is described in further details below by specific embodiment, these embodiments are only used for the mesh of illustration
, it is in no way intended to limit protection scope of the present invention.
Activated ionic calcium is purchased from Guang Jian nutrition Science and Technology Ltd. of Shenzhen.
Embodiment 1-3, comparative example 1-2
The component and mass percent of embodiment 1-3 and comparative example 1-2 vegetables and fruits cleaning agent is as shown in table 1.
The embodiment of table 1 and comparative example vegetables and fruits cleaning agent component and mass percent
Comparative example 1 is with the difference of embodiment 2：Without activated ionic calcium, increase the content of rice washing water.
Comparative example 2 is with the difference of embodiment 2：Chelating agent by sodium citrate and the sodium of glutamic acid diacetic acid four in mass ratio
1:1 composition.
The preparation method of the vegetables and fruits cleaning agent of embodiment 2 is：By activated ionic calcium, starch, chelating agent and salt in stirred tank
In stir, then rice washing water is sprinkled into stirred tank with spray gun, be evenly stirred until without particulate matter or caking, obtain final product.
The preparation method of embodiment 1, embodiment 3 and comparative example 1-2 vegetables and fruits cleaning agent is similar to Example 2.
Properties of product evaluation test
In order to study the effect of the vegetables and fruits cleaning agent of present invention preparation, for vegetables and fruits prepared by above-described embodiment and comparative example
Cleaning agent carries out properties of product evaluation test.
Test example 1：Remove agriculture residual effect fruit test experiments
The experimental technique for removing agriculture residual effect fruit with reference to vegetables and fruits cleaning agent GB GB/T24691-2009, and selected agricultural chemicals is residual
Prestige and cypermethrin are killed, the carrier of selected attachment agricultural chemicals is garden pea.
Experimental procedure：
S1, the certain density pesticidal emulsion of preparation, garden pea are immersed in emulsion after 20min and are taken out, and get rid of surface residual
Drop is stayed, in room temperature shady place 24h is placed, obtain the sample of vegetables containing agricultural chemicals；
S2, the detergent solution that sample concentration is 0.2% is prepared with the hard water of 250ppm, washed according to national standard method；
Liquid chromatograph (HPLC) detection is crossed in vegetable sample Jing homogenate after S3, cleaning, extraction after concentration.
Remove the residual effect of agriculture to be graded by different removal degree, calculated with 0-10 point, concrete grading is as follows：0
Point --- the residual clearance of agriculture is 0-5%；1 point --- the residual clearance of agriculture is 5-15%；2 points --- the residual clearance of agriculture is 15-25%；3
Point --- the residual clearance of agriculture is 25-35%；4 points --- the residual clearance of agriculture is 35-45%；5 points --- the residual clearance of agriculture is 45-55%；
6 points --- the residual clearance of agriculture is 55-65%；7 points --- the residual clearance of agriculture is 65-75%；8 points --- the residual clearance of agriculture is 75-
85%, it is residual that major part removes surface agriculture；9 points --- the residual clearance of agriculture is 85-95%, substantially removes surface agriculture residual；10 points ---
The residual clearance of agriculture is more than 95%, and almost removal surface agriculture completely is residual, as a result as shown in table 2.
Embodiment 1-3 of table 2 removes the residual Contrast on effect of agriculture with comparative example 1-2 vegetables and fruits cleaning agent
| Test sample | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| Remove agriculture residual effect fruit to score | 9 | 10 | 9 | 7 | 6 |
The experiment test residual clearance of agriculture of each embodiment and comparative example vegetables and fruits cleaning agent, from table 2 it can be seen that embodiment
1-3 illustrates that residual removal of agriculture of each component synergy to vegetables and fruits has in the present invention apparently higher than the residual clearance of agriculture of comparative example 1-2
There is preferable effect.
Test example 2：Little cabbage, apple and green vegetables are respectively placed in vegetables and fruits cleaning agent obtained in embodiment and comparative example
After immersion 30min, the impurity on little cabbage, apple and green vegetables is detected, the result for obtaining is as shown in table 3.
Cleaning performance of the embodiment of table 3 from comparative example vegetables and fruits cleaning agent to different vegetables and fruits
As can be seen from Table 3 embodiment 1-3 is more preferable to the cleaning performance of little cabbage, apple and green vegetables compared with comparative example 1-2,
Impurity is visible by naked eyes after washing, is cleaned up.
The above is only the preferred embodiment of the present invention, it is noted that it is right that above-mentioned preferred embodiment is not construed as
The restriction of the present invention, protection scope of the present invention should be defined by claim limited range.For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change
Enter and retouch also to should be regarded as protection scope of the present invention.
Claims (5)
1. a kind of vegetables and fruits cleaning agent, it is characterised in that including following components and its mass percent：
Activated ionic calcium 20～28%, starch 10～14%, chelating agent 5～10%, salt 5～10% and rice washing water 38～
60%.
2. vegetables and fruits cleaning agent according to claim 1, it is characterised in that be made up of following components and its mass percent：
Activated ionic calcium 25%, starch 12.5%, chelating agent 7.5%, salt 7.5% and rice washing water 47.5%.
3. vegetables and fruits cleaning agent according to claim 1 and 2, it is characterised in that described chelating agent is by sodium citrate and paddy
The sodium of propylhomoserin oxalic acid four in mass ratio 2:3 compositions.
4. vegetables and fruits cleaning agent according to claim 1 and 2, it is characterised in that the rice washing water is that rice is placed in water into leaching
The metric system is filtered after bubble 12h to obtain, and on the basis of the gross weight of rice and water, the consumption of rice is 10-20%, and the consumption of water is 80-
90%.
5. the preparation method of the vegetables and fruits cleaning agent according to any one of claim 1-4, it is characterised in that including following step
Suddenly：Activated ionic calcium, starch, chelating agent and salt are stirred in stirred tank, then rice washing water is sprinkled into stirring with spray gun
In kettle, it is evenly stirred until without particulate matter or caking, obtains final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210775.7A CN106635509A (en) | 2016-12-24 | 2016-12-24 | Vegetable and fruit cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210775.7A CN106635509A (en) | 2016-12-24 | 2016-12-24 | Vegetable and fruit cleaning agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106635509A true CN106635509A (en) | 2017-05-10 |
Family
ID=58827715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611210775.7A Pending CN106635509A (en) | 2016-12-24 | 2016-12-24 | Vegetable and fruit cleaning agent and preparation method thereof |
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| Country | Link |
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| CN (1) | CN106635509A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587813A (en) * | 2018-07-11 | 2018-09-28 | 佛山市陵谐环保科技有限公司 | A kind of fruits and vegetables detergent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238600A (en) * | 2014-07-11 | 2016-01-13 | 上海家化联合股份有限公司 | Powdery natural cleaning composition for vegetables and fruits and preparation method thereof |
| CN106047531A (en) * | 2016-06-03 | 2016-10-26 | 芜湖县富园食品有限公司 | Material composition of vegetable and fruit cleaning agent, vegetable and fruit cleaning agent as well as preparation method and application of vegetable and fruit cleaning agent |
-
2016
- 2016-12-24 CN CN201611210775.7A patent/CN106635509A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238600A (en) * | 2014-07-11 | 2016-01-13 | 上海家化联合股份有限公司 | Powdery natural cleaning composition for vegetables and fruits and preparation method thereof |
| CN106047531A (en) * | 2016-06-03 | 2016-10-26 | 芜湖县富园食品有限公司 | Material composition of vegetable and fruit cleaning agent, vegetable and fruit cleaning agent as well as preparation method and application of vegetable and fruit cleaning agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587813A (en) * | 2018-07-11 | 2018-09-28 | 佛山市陵谐环保科技有限公司 | A kind of fruits and vegetables detergent |
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Application publication date: 20170510 |