CN106633232A - Artware and preparation method thereof - Google Patents

Artware and preparation method thereof Download PDF

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Publication number
CN106633232A
CN106633232A CN201611196339.9A CN201611196339A CN106633232A CN 106633232 A CN106633232 A CN 106633232A CN 201611196339 A CN201611196339 A CN 201611196339A CN 106633232 A CN106633232 A CN 106633232A
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China
Prior art keywords
parts
handicraft
latex
gum
powder
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CN201611196339.9A
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CN106633232B (en
Inventor
马爱忠
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Zhangye Danxia Fengyun Tourism Culture Development Co ltd
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Tianjin Welfare Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • C08L7/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • C08L9/08Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/10Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adornments (AREA)

Abstract

The invention discloses artware and a preparation method thereof. The artware comprises the following raw materials in parts by weight: 30-80 parts of mineral powder, 30-100 parts of macromolecular resin, 50-100 parts of resin, 20-30 parts of yellow clay and 50-200 parts of latex. The artware prepared in the invention has the advantages of high waterproof and fireproof properties, high tensile strength and compressive strength, relatively good shaping property, rare deformation after shaping and simple preparation method and is suitable for large-scale industrial production.

Description

A kind of handicraft and preparation method thereof
Technical field
The present invention relates to handicraft Technical Development Area, more particularly to a kind of handicraft and preparation method thereof.
Background technology
Handicraft is requisite articles for use in life.The species of modern crafts product is various, there is ceramics, plastics work Skill product, tendril handicraft, metal handicrafts etc., the preparation method of various handicrafts is varied, and metal handicrafts cost is high, system Preparation Method is complicated, and the energy consumption of preparation is higher, and tendril handicraft generally requires hand woven, and cost of labor is high, and plastic crafts are produced Raw offensive odour, unfavorable to health, ceramics prepares difficulty, and yield rate is low, needs to fire, energy consumption It is higher.
Patent 201310001678.7 discloses a kind of handicraft and preparation method thereof., including the raw material of following weight portion: 1000 parts of resin, 2~7 parts of accelerator, 3~10 parts of curing agent.The technology overcomes the shadow that temperature and humidity is molded to handicraft Ring, it is to avoid be also easy to produce bubble in the handicraft that brings because of humidity, because of the handicraft easy fracture layering that temperature band is come, or be difficult into The problem of type.It is the smooth smooth, uniform in color of obtained handicraft, transparent, original aesthetic feeling of various decorative patterns can be embodied, give people to regard Enjoyment in feel.But, the quality of the handicraft depends on the quality of natural peach shell, the product quality heterogeneity of preparation.Patent 201110419590.8 a kind of fragrant high-hardness gypsum artwork and preparation method thereof is disclosed, by the raw material system of following weight ratio Into:Land plaster CaSO4-2H2O 74.5%, water 20.5-21%, sinter kaolin 3%, and siloxane aqueous dispersant 1%, DH is high Molecular modification resin 0.5-1%.The range of application of the handicraft is narrow.
The content of the invention
The present invention be in order to overcome above-mentioned prior art in defect, propose a kind of handicraft and preparation method thereof.
A kind of handicraft, including the raw material of following parts by weight:Mineral powder 30-80 parts, macromolecule resin 30-100 parts, tree Glue 50-100 parts, yellow clay 20-30 parts, latex 50-200 parts.
The mineral powder be sepiolite powder, pyrophyllite powder, iron ore powder, talcum powder, the one kind or one kind in silica flour with On.
The macromolecule resin be epoxy resin, acrylic resin, SBS, benzene Ethene-isoprene-styrene block copolymer, one kind in styrene-ethylene-butylene-styrene block copolymer or More than kind.
The natural gum is peach gum, bassora gum, ghatti gum, karaya gum, one or more in tamarind gum.
The latex be natural emulsion, polybutadiene latex, butadiene-styrene latex, the one kind or one kind in carboxylic acrylonitrile butadiene rubber latex glue More than.
Also contain 1-3 part gold sodium sulfides in the handicraft.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, gummy 50-100 parts are taken, is heated to 70-100 DEG C, add mineral powder 30-80 parts, Huang is glutinous Native 20-30 parts, stir;
(2) temperature is risen to into 110-130 DEG C, adds macromolecule resin 30-100 parts, stirred;
(3) room temperature is cooled the temperature to, latex 50-200 parts are added, is stirred, be poured over die for molding, dried naturally Or drying is made
Compared with prior art, the present invention has the advantages that:Handicraft prepared by the present invention, waterproof and fire line Can be high, tension and compression strength are high, it is moulding preferably, it is moulding after do not allow yielding, preparation method is simple, is adapted to heavy industrialization Production.
Specific embodiment
The specific embodiment of the present invention is described in detail below, it is to be understood that protection scope of the present invention is not Limited by specific embodiment.
Embodiment 1
A kind of handicraft, including the raw material of following parts by weight:50 parts of sepiolite powder, 60 parts of epoxy resin, 70 parts of peach gum, 25 parts of yellow clay, 100 parts of natural emulsion.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 70 parts of peach gum is taken, is heated to 80 DEG C, add 50 parts of sepiolite powder, 25 parts of yellow clay to stir Mix uniform;
(2) temperature is risen to into 120 DEG C, adds 60 parts of epoxy resin, stirred;
(3) room temperature is cooled the temperature to, 100 parts of natural emulsion is added, is stirred, be poured over die for molding, dried in the air naturally Dry or drying is made.
Embodiment 2
A kind of handicraft, including the raw material of following parts by weight:30 parts of pyrophyllite powder, 30 parts of acrylic resin, bassora gum 50 parts, 20 parts of yellow clay, 50 parts of polybutadiene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 50 parts of bassora gum is taken, is heated to 70 DEG C, add 30 parts of pyrophyllite powder, 20 parts of yellow clay, Stir;
(2) temperature is risen to into 110 DEG C, adds 30 parts of acrylic resin, stirred;
(3) room temperature is cooled the temperature to, 50 parts of polybutadiene latex is added, is stirred, be poured over die for molding, it is natural Dry or dry and make.
Embodiment 3
A kind of handicraft, including the raw material of following parts by weight:80 parts of iron ore powder, s-B-S is embedding 00 part of copolymer 1 of section, 100 parts of ghatti gum, 30 parts of yellow clay, 200 parts of butadiene-styrene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 100 parts of ghatti gum is taken, is heated to 100 DEG C, add 80 parts of iron ore powder, yellow clay 30 Part, stir;
(2) temperature is risen to into 130 DEG C, adds 100 parts of SBS, stirred;
(3) room temperature is cooled the temperature to, 200 parts of butadiene-styrene latex is added, is stirred, be poured over die for molding, dried in the air naturally Dry or drying is made.
Embodiment 4
A kind of handicraft, including the raw material of following parts by weight:45 parts of talcum powder, styrene-isoprene-phenylethene is embedding 56 parts of copolymer of section, 65 parts of karaya gum, 22 parts of yellow clay, 55 parts of carboxylic acrylonitrile butadiene rubber latex glue.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 65 parts of karaya gum is taken, is heated to 76 DEG C, add 45 parts of talcum powder, 23 parts of yellow clay, Stir;
(2) temperature is risen to into 115 DEG C, adds 56 parts of SIS, stirred;
(3) room temperature is cooled the temperature to, 65 parts of karaya gum is added, is stirred, be poured over die for molding, dried naturally Or drying is made.
Embodiment 5
A kind of handicraft, including the raw material of following parts by weight:66 parts of silica flour, styrene-ethylene-butylene-styrene 66 parts of block copolymer, 55 parts of tamarind gum, 22 parts of yellow clay, 78 parts of polybutadiene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 55 parts of tamarind gum is taken, is heated to 78 DEG C, add 66 parts of silica flour, 22 parts of yellow clay, Stir;
(2) temperature is risen to into 118 DEG C, adds 66 parts of styrene-ethylene-butylene-styrene block copolymer, stirring is equal It is even;
(3) room temperature is cooled the temperature to, 78 parts of polybutadiene latex is added, is stirred, be poured over die for molding, it is natural Dry or dry and make.
Embodiment 6
A kind of handicraft, including the raw material of following parts by weight:66 parts of silica flour, styrene-ethylene-butylene-styrene 66 parts of block copolymer, 55 parts of tamarind gum, 22 parts of yellow clay, 78 parts of polybutadiene latex, 2 parts of gold sodium sulfide.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 55 parts of tamarind gum is taken, is heated to 78 DEG C, add 66 parts of silica flour, 22 parts of yellow clay, 2 parts of gold sodium sulfide, stirs;
(2) temperature is risen to into 118 DEG C, adds 66 parts of styrene-ethylene-butylene-styrene block copolymer, stirring is equal It is even;
(3) room temperature is cooled the temperature to, 78 parts of polybutadiene latex is added, is stirred, be poured over die for molding, it is natural Dry or dry and make.
Embodiment 7
A kind of handicraft, including the raw material of following parts by weight:50 parts of sepiolite powder, 60 parts of epoxy resin, 70 parts of peach gum, 25 parts of yellow clay, 100 parts of natural emulsion, 3- (4,4,5,5- tetramethyl -1, the ring -2- bases of 3,2- dioxy boron penta) ethyl benzoate 2 Part.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 70 parts of peach gum is taken, is heated to 80 DEG C, add 50 parts of sepiolite powder, 25 parts of yellow clay to stir Mix uniform;
(2) temperature is risen to into 120 DEG C, adds 60 parts of epoxy resin, stirred;
(3) room temperature is cooled the temperature to, 100 parts of natural emulsion, 3- (4,4,5,5- tetramethyl -1,3,2- dioxy boron penta are added Ring -2- bases) 2 parts of ethyl benzoate, stir, die for molding is poured over, dry naturally or dry and make.
Embodiment 8
A kind of handicraft, including the raw material of following parts by weight:30 parts of pyrophyllite powder, 30 parts of acrylic resin, bassora gum 50 parts, 20 parts of yellow clay, 50 parts of polybutadiene latex, to 2 parts of isopropoxy methyl benzoate.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 50 parts of bassora gum is taken, is heated to 70 DEG C, add 30 parts of pyrophyllite powder, 20 parts of yellow clay, Stir;
(2) temperature is risen to into 110 DEG C, adds 30 parts of acrylic resin, stirred;
(3) cool the temperature to room temperature, add 50 parts of polybutadiene latex, to 2 parts of isopropoxy methyl benzoate, stirring is equal It is even, die for molding is poured over, dry naturally or dry and make.
Comparative example 1
A kind of handicraft, including the raw material of following parts by weight:80 parts of iron ore powder, s-B-S is embedding 00 part of copolymer 1 of section, 30 parts of yellow clay, 200 parts of butadiene-styrene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 80 parts of iron ore powder is taken, 30 parts of yellow clay stirs;
(2) temperature is risen to into 130 DEG C, adds 100 parts of SBS, stirred;
(3) room temperature is cooled the temperature to, 200 parts of butadiene-styrene latex is added, is stirred, be poured over die for molding, dried in the air naturally Dry or drying is made.
Comparative example 2
A kind of handicraft, including the raw material of following parts by weight:45 parts of talcum powder, 65 parts of karaya gum, 22 parts of yellow clay, 55 parts of carboxylic acrylonitrile butadiene rubber latex glue.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps:
(1) according to parts by weight, 65 parts of karaya gum is taken, is heated to 76 DEG C, add 45 parts of talcum powder, 23 parts of yellow clay, Stir;
(2) room temperature is cooled the temperature to, 65 parts of karaya gum is added, is stirred, be poured over die for molding, dried naturally Or drying is made.
Performance test:Using universal testing machine, the speed specified by GB/T228-2002 standards allows testing machine to mark Quasi- tension sample is stretched, and surveys tensile strength, and using compression test machine compression strength is surveyed, and the results are shown in Table 1:
Table 1
Detection object Tensile strength Mpa Compression strength Mpa
Embodiment 1 145 221
Embodiment 2 135 222
Embodiment 3 136 221
Embodiment 4 137 212
Embodiment 5 135 221
Embodiment 6 187 251
Embodiment 7 188 260
Embodiment 8 189 253
Comparative example 1 98 133
Comparative example 2 97 132
The embodiment of above formulation ratio and technique simply elaborates the general principle and characteristic of the present invention, and the present invention is not Limited by the enforcement of above-mentioned technique and proportioning, without departing from the spirit and scope of the invention, the present invention can also make various Modification and conversion.Therefore these changes and change is belonged in the scope of the invention.

Claims (7)

1. a kind of handicraft, it is characterised in that including the raw material of following parts by weight:Mineral powder 30-80 parts, macromolecule resin 30-100 parts, gummy 50-100 parts, yellow clay 20-30 parts, latex 50-200 parts.
2. handicraft according to claim 1, it is characterised in that the mineral powder is sepiolite powder, pyrophyllite powder, iron ore Stone flour, talcum powder, one or more in silica flour.
3. handicraft according to claim 1, it is characterised in that the macromolecule resin is epoxy resin, acrylic acid tree Fat, SBS, SIS, styrene-second One or more in alkene-butylene-styrene block copolymer.
4. handicraft according to claim 1, it is characterised in that the natural gum is peach gum, bassora gum, ghatti gum, OK a karaoke club Refined glue, one or more in tamarind gum.
5. handicraft according to claim 1, it is characterised in that the latex is natural emulsion, polybutadiene latex, fourth Atrolactamide, one or more in carboxylic acrylonitrile butadiene rubber latex glue.
6. handicraft according to claim 1, it is characterised in that also contain 1-3 part gold sodium sulfides in the handicraft.
7. the preparation method of the handicraft described in claim 1, it is characterised in that carry out in accordance with the following steps:
(1) according to parts by weight, gummy 50-100 parts are taken, is heated to 70-100 DEG C, add mineral powder 30-80 parts, yellow clay 20- 30 parts, stir;
(2) temperature is risen to into 110-130 DEG C, adds macromolecule resin 30-100 parts, stirred;
(3) cool the temperature to room temperature, add latex 50-200 parts, stir, be poured over die for molding, dry naturally or Drying is made.
CN201611196339.9A 2016-12-22 2016-12-22 A kind of craftwork and preparation method thereof Active CN106633232B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109438785A (en) * 2018-11-27 2019-03-08 青岛金瑞纳橡胶科技有限公司 A kind of vulcanized rubber powder wet process rubber compound and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1510075A (en) * 2002-12-25 2004-07-07 上海三和科技合作公司 Artist clay material and production thereof
CN101928468A (en) * 2010-08-31 2010-12-29 常熟市恒升工艺品有限公司 Bogus carved-bone artware and manufacturing process thereof
CN104497487A (en) * 2014-12-18 2015-04-08 无锡伊诺永利文化创意有限公司 Environment-friendly artware raw material formula
CN106080006A (en) * 2016-07-13 2016-11-09 叶安生 A kind of high imitative ivory carving and manufacturing process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1510075A (en) * 2002-12-25 2004-07-07 上海三和科技合作公司 Artist clay material and production thereof
CN101928468A (en) * 2010-08-31 2010-12-29 常熟市恒升工艺品有限公司 Bogus carved-bone artware and manufacturing process thereof
CN104497487A (en) * 2014-12-18 2015-04-08 无锡伊诺永利文化创意有限公司 Environment-friendly artware raw material formula
CN106080006A (en) * 2016-07-13 2016-11-09 叶安生 A kind of high imitative ivory carving and manufacturing process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中国农业百科全书总编辑委员会森林工业卷编辑委员会: "《中国农业百科全书 森林工业卷》", 31 March 1993, 农业出版社出版 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109438785A (en) * 2018-11-27 2019-03-08 青岛金瑞纳橡胶科技有限公司 A kind of vulcanized rubber powder wet process rubber compound and preparation method thereof

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