CN108147712A - A kind of diatom ooze integrated wall plate and preparation method thereof - Google Patents

A kind of diatom ooze integrated wall plate and preparation method thereof Download PDF

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Publication number
CN108147712A
CN108147712A CN201711459416.XA CN201711459416A CN108147712A CN 108147712 A CN108147712 A CN 108147712A CN 201711459416 A CN201711459416 A CN 201711459416A CN 108147712 A CN108147712 A CN 108147712A
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China
Prior art keywords
wall plate
integrated wall
diatom ooze
resin
coupling agent
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CN201711459416.XA
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Chinese (zh)
Inventor
李广东
闫浩
彭勇
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Hainan Institute of Science and Technology
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Hainan Institute of Science and Technology
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Priority to CN201711459416.XA priority Critical patent/CN108147712A/en
Publication of CN108147712A publication Critical patent/CN108147712A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/242Moulding mineral aggregates bonded with resin, e.g. resin concrete
    • B29C67/245Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of indefinite length
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/045Polyalkenes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing halogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/776Walls, e.g. building panels
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Molding Of Porous Articles (AREA)

Abstract

The invention discloses a kind of diatom ooze integrated wall plates and preparation method thereof, are related to building material technical field, which includes following raw material:Diatomite miberal powder 50 70%, resin 15 35%, processing aid 3 10%, stabilizer 3 8%, in-lubricant 0.5 2%, PE waxes 0.5 2%, coupling agent 0.1 2%, foaming agent 0.5 3% and bamboo and woods fiber mixture 10 20%.Its production method be after more than component is mixed by extruding machine extrusioning shaping after, semi-finished product skinning surfaces are polished wire drawing with special-shaped grinding machine and wire drawing machine, surface is presented irregular micropore, forms diatom ooze integrated wall plate.This kind of diatom ooze integrated wall plate have waterproof, it is fire-retardant, go formaldehyde, heat preservation and soundproof effect apparent, while also there is dehumidifying, deodorization, purifies the air of a room, preparation is simply, convenient material drawing, low production cost is suitable for industrialized development, is excellent environment-friendly type indoor and outdoor decoration material.

Description

A kind of diatom ooze integrated wall plate and preparation method thereof
Technical field
The present invention relates to building material technical fields more particularly to a kind of diatom ooze integrated wall plate and preparation method thereof.
Background technology
According to Chinese interior decoration association environment measuring center, the national dead people as caused by indoor decoration pollution every year For number up to 11.1 ten thousand, this number is surprising.Wherein, formaldehyde is to cause one of main source of indoor environmental pollution, The materials such as artificial board, adhesive, wallpaper are typically derived from, are universally acknowledged potential carcinogens, and it can also cause fetus Deformity.However, formaldehyde pollutants caused by how eliminating interior decoration, the administering method that there is no at present.Windowing ventilation can only The concentration of formaldehyde pollutants is temporarily reduced, and cannot many times be opened a window for a long time, it is often more important that, formaldehyde pollution source exists again Formaldehyde is constantly released, indoor pollution is caused to be difficult to effect a radical cure.Integrated wall plate is widely used as industrial building, and inhabitation is built It builds, the non-load bearing inner partition wall of public building, application of the integrated wall plate especially in modern Decoration Industry is most, miscellaneous collection Meet different human needs into wallboard.
Therefore, only thoroughly set about from the source of formaldehyde pollution, research and develop a kind of environment-friendly type interior decoration material that can remove formaldehyde Material could fundamentally effect a radical cure formaldehyde pollution.However, existing indoor decoration board is unable to reach the effect effect of formaldehyde at all Fruit, it is impossible to meet requirement of the people to living environment well.Therefore, how to develop with formaldehyde remove function environment-friendly type Indoor decoration wall panel is those skilled in the art's urgently problem to be solved.
Invention content
In view of the problems of the existing technology, the present invention provides a kind of diatom ooze integrated wall plates and preparation method thereof, should Kind of integrated wall plate have waterproof, it is fire-retardant, go formaldehyde, heat preservation and soundproof effect apparent, while also there is dehumidifying, deodorization, in clean room The effects that air is excellent environment-friendly type indoor and outdoor decoration material.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of diatom ooze integrated wall plate, including following raw material by weight percentage:Diatomite miberal powder 50-70%, resin 15- 35%th, processing aid 3-10%, stabilizer 3-8%, in-lubricant 0.5-2%, PE wax 0.5-2%, coupling agent 0.1-2%, foaming Agent 0.5-3% and the sum of bamboo and woods fiber mixture 10-20%, above-mentioned each component content is 100%.
Further, the integrated wall plate includes following raw material by weight percentage:Diatomite miberal powder 58%, resin 18%th, processing aid 4.5%, stabilizer 3.5%, in-lubricant 1.0%, PE waxes 0.8%, coupling agent 0.7%, 0.5% and of foaming agent Bamboo and woods fiber mixture 13%.
Further, the diatomite miberal powder is made by following steps:Using the high-quality diatom containing 80%-90%SiO2 After drying, crushing, drying, burning forging is carried out using rotary kiln, is finely divided using classification and sorting machine after calcining for native ore It is formed after choosing.
Preferentially, the resin is one kind of ABS resin, PS resins, polyvinyl chloride resin.
Preferentially, the coupling agent is in Silane coupling agent KH550, titanate esters or gamma-aminopropyl-triethoxy-silane It is a kind of.
Preferentially, the foaming agent is the combination of one or both of azodicarbonamide, sodium bicarbonate.
Preferentially, the stabilizer is calcium-zinc composite stabilizing agent, and the main component of the calcium-zinc composite stabilizing agent has tristearin Sour calcium, ricinoleic acid calcium, zinc stearate, zinc ricinate and epoxidized soybean oil, ultra-violet absorber.
A kind of production method of above-mentioned diatom ooze integrated wall plate, follows the steps below:
(1)Above-mentioned raw material are mixed successively, and is put into powder mixer and stirs, and heat 20-30 minutes simultaneously, then Cooling and stirring machine is put under conditions of 120-125 DEG C of temperature, mixed powder is made;
(2)Mixed powder is added in into Bitruder, micro- hair is extruded by mold under conditions of 150-190 DEG C of temperature The special-shaped plank of bubble, cools down by vacuum forming mould and cuts into semi-finished product;
(3)By manufactured semi-finished product be placed in humidity be 80%-90%, maintenance processing 3-6h in the environment of temperature is 35-45 DEG C;
(4)With special-shaped grinding machine and wire drawing machine by the polishing wire drawing of semi-finished product skinning surfaces, surface is presented irregular micropore, forms silicon Algal gel integrated wall plate.
The present invention has following advantageous effect:
(1)The diatom ooze integrated wall plate of the present invention is improved and optimizated by the raw material to production and processing and technique, adds diatom The ingredients such as native miberal powder, bamboo and woods fiber, resin cooperate with the function affect of outer adding assistant so that finished product integrated wall plate with waterproof, It is fire-retardant, go formaldehyde, heat preservation and soundproof effect apparent, while also there is dehumidifying, deodorization, purify the air of a room, be excellent Environment-friendly type indoor and outdoor decoration material meets requirement of the people for living environment environment protection health.
(2)The diatom ooze integrated wall plate of the present invention is prepared simply, and convenient material drawing, the diatomite miberal powder used is the list of diatom By the accumulational stage of tens thousand of years after cellular plant death, a kind of diatom cumulose soil mineral deposit of fossil of formation, production cost is low It is honest and clean, it is suitable for industrialized development.
Specific embodiment
The specific embodiment of the present invention is further described with reference to embodiment, following embodiment is only used for more clear Illustrate to Chu technical scheme of the present invention, and be not intended to limit the protection scope of the present invention and limit the scope of the invention.
Embodiment 1
A kind of diatom ooze integrated wall plate, is mainly matched by weight percentage by following component:Diatomite miberal powder 56%, resin 25%th, processing aid 5%, stabilizer 1%, in-lubricant 0.5%, PE waxes 0.5%, coupling agent 1%, foaming agent 1% and bamboo and woods fiber Mixture 10%.
The diatomite miberal powder is made by following steps:Using the high-quality diatomite ore containing 80%SiO2, through overdrying After dry, crushing, drying, burning forging is carried out using rotary kiln, using classification and sorting machine form after finely sorting after calcining.
Wherein, above-mentioned resin uses ABS resin;Coupling agent uses Silane coupling agent KH550;Foaming agent uses azo two Formamide.
A kind of production method of above-mentioned diatom ooze integrated wall plate, follows the steps below:
(1)Above-mentioned raw material are mixed successively, and is put into powder mixer and stirs, and are heated 20 minutes simultaneously, then in temperature Cooling and stirring machine is put under conditions of 120 DEG C of degree, mixed powder is made;
(2)Mixed powder is added in into Bitruder, it is different by mold to be extruded into fretting map under conditions of 150 DEG C of temperature Based plate cools down by vacuum forming mould and cuts into semi-finished product;
(3)By manufactured semi-finished product be placed in humidity be 80%, maintenance processing 3h in the environment of temperature is 35 DEG C;
(4)With special-shaped grinding machine and wire drawing machine by the polishing wire drawing of semi-finished product skinning surfaces, surface is presented irregular micropore, forms silicon Algal gel integrated wall plate.
Embodiment 2
A kind of diatom ooze integrated wall plate, is mainly matched by weight percentage by following component:Diatomite miberal powder 60%, PS trees Fat 15%, processing aid 5%, stabilizer 4.5%, in-lubricant 1%, PE waxes 1%, coupling agent 0.5%, foaming agent 0.5% and bamboo Wood-fibred mixture 12.5%.
The diatomite miberal powder is made by following steps:Using the high-quality diatomite ore containing 90%SiO2, through overdrying After dry, crushing, drying, burning forging is carried out using rotary kiln, using classification and sorting machine form after finely sorting after calcining.
Wherein, above-mentioned resin uses PS resins;Coupling agent uses titanate esters;Foaming agent uses sodium bicarbonate.
A kind of production method of above-mentioned diatom ooze integrated wall plate, follows the steps below:
(1)Above-mentioned raw material are mixed successively, and is put into powder mixer and stirs, and are heated 25 minutes simultaneously, then in temperature Cooling and stirring machine is put under conditions of 125 DEG C of degree, mixed powder is made;
(2)Mixed powder is added in into Bitruder, it is different by mold to be extruded into fretting map under conditions of 160 DEG C of temperature Based plate cools down by vacuum forming mould and cuts into semi-finished product;
(3)By manufactured semi-finished product be placed in humidity be 85%, maintenance processing 5h in the environment of temperature is 40 DEG C;
(4)With special-shaped grinding machine and wire drawing machine by the polishing wire drawing of semi-finished product skinning surfaces, surface is presented irregular micropore, forms silicon Algal gel integrated wall plate.
Embodiment 3
A kind of diatom ooze integrated wall plate, is mainly matched by weight percentage by following component:Diatomite miberal powder 58%, resin 18%th, processing aid 4.5%, stabilizer 3.5%, in-lubricant 1.0%, PE waxes 0.8%, coupling agent 0.7%, 0.5% and of foaming agent Bamboo and woods fiber mixture 13%.
The diatomite miberal powder is made by following steps:Using the high-quality diatomite ore containing 90%SiO2, through overdrying After dry, crushing, drying, burning forging is carried out using rotary kiln, using classification and sorting machine form after finely sorting after calcining.
Wherein, above-mentioned resin uses polyvinyl chloride resin;Coupling agent uses gamma-aminopropyl-triethoxy-silane;Foaming agent uses Azodicarbonamide.
A kind of production method of above-mentioned diatom ooze integrated wall plate, follows the steps below:
(1)Above-mentioned raw material are mixed successively, and is put into powder mixer and stirs, and are heated 30 minutes simultaneously, then in temperature Cooling and stirring machine is put under conditions of 125 DEG C of degree, mixed powder is made;
(2)Mixed powder is added in into Bitruder, it is different by mold to be extruded into fretting map under conditions of 180 DEG C of temperature Based plate cools down by vacuum forming mould and cuts into semi-finished product;
(3)By manufactured semi-finished product be placed in humidity be 90%, maintenance processing 4h in the environment of temperature is 45 DEG C;
(4)With special-shaped grinding machine and wire drawing machine by the polishing wire drawing of semi-finished product skinning surfaces, surface is presented irregular micropore, forms silicon Algal gel integrated wall plate.
Embodiment 4
A kind of diatom ooze integrated wall plate, is mainly matched by weight percentage by following component:Diatomite miberal powder 50%, resin 18%th, processing aid 3%, stabilizer 7%, in-lubricant 1%, PE waxes 1%, coupling agent 1%, foaming agent 1% and bamboo and woods fiber mixing Object 18%.
The diatomite miberal powder is made by following steps:Using the high-quality diatomite ore containing 85%SiO2, through overdrying After dry, crushing, drying, burning forging is carried out using rotary kiln, using classification and sorting machine form after finely sorting after calcining.
Wherein, above-mentioned resin uses polyvinyl chloride resin;Coupling agent uses Silane coupling agent KH550;Foaming agent uses bicarbonate Sodium.
A kind of production method of above-mentioned diatom ooze integrated wall plate, follows the steps below:
(1)Above-mentioned raw material are mixed successively, and is put into powder mixer and stirs, and are heated 30 minutes simultaneously, then in temperature Cooling and stirring machine is put under conditions of 120 DEG C of degree, mixed powder is made;
(2)Mixed powder is added in into Bitruder, fretting map abnormal shape is extruded by mold under conditions of 190 DEG C of temperature Plank cools down by vacuum forming mould and cuts into semi-finished product;
(3)By manufactured semi-finished product be placed in humidity be 86%, maintenance processing 6h in the environment of temperature is 45 DEG C;
(4)With special-shaped grinding machine and wire drawing machine by the polishing wire drawing of semi-finished product skinning surfaces, surface is presented irregular micropore, forms silicon Algal gel integrated wall plate.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality Example is applied the present invention is described in detail, it for those skilled in the art, still can be to aforementioned each implementation Technical solution recorded in example modifies or which part technical characteristic is replaced on an equal basis.All essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (8)

1. a kind of diatom ooze integrated wall plate, which is characterized in that including following raw material by weight percentage:Diatomite miberal powder 50-70%, resin 15-35%, processing aid 3-10%, stabilizer 3-8%, in-lubricant 0.5-2%, PE wax 0.5-2%, coupling Agent 0.1-2%, foaming agent 0.5-3% and the sum of bamboo and woods fiber mixture 10-20%, above-mentioned each component content are 100%.
2. a kind of diatom ooze integrated wall plate according to claim 1, which is characterized in that including it is following by weight percentage Raw material:Diatomite miberal powder 58%, resin 18%, processing aid 4.5%, stabilizer 3.5%, in-lubricant 1.0%, PE waxes 0.8%th, coupling agent 0.7%, foaming agent 0.5% and bamboo and woods fiber mixture 13%.
3. a kind of diatom ooze integrated wall plate according to claim 1, which is characterized in that the diatomite miberal powder passes through following Step is made:Using the high-quality diatomite ore containing 80%-90%SiO2, after drying, crushing, drying, using rotary kiln Burning forging is carried out, using classification and sorting machine form after finely sorting after calcining.
4. a kind of diatom ooze integrated wall plate according to claim 1, which is characterized in that the resin is ABS resin, PS trees One kind of fat, polyvinyl chloride resin.
5. a kind of diatom ooze integrated wall plate according to claim 1, which is characterized in that the coupling agent is silane coupling agent One kind in KH550, titanate esters or gamma-aminopropyl-triethoxy-silane.
6. a kind of diatom ooze integrated wall plate according to claim 1, which is characterized in that the foaming agent is two formyl of azo The combination of one or both of amine, sodium bicarbonate.
7. a kind of diatom ooze integrated wall plate according to claim 1, which is characterized in that the stabilizer is steady for Ca Zn composite Determine agent, the main component of the calcium-zinc composite stabilizing agent have calcium stearate, ricinoleic acid calcium, zinc stearate, zinc ricinate, with And epoxidized soybean oil, ultra-violet absorber.
8. a kind of its production method of diatom ooze integrated wall plate, which is characterized in that include the following steps:
(1)Above-mentioned raw material are mixed successively, and is put into powder mixer and stirs, and heat 20-30 minutes simultaneously, then Cooling and stirring machine is put under conditions of 120-125 DEG C of temperature, mixed powder is made;
(2)Mixed powder is added in into Bitruder, micro- hair is extruded by mold under conditions of 150-190 DEG C of temperature The special-shaped plank of bubble, cools down by vacuum forming mould and cuts into semi-finished product;
(3)By manufactured semi-finished product be placed in humidity be 80%-90%, maintenance processing 3-6h in the environment of temperature is 35-45 DEG C;
(4)With special-shaped grinding machine and wire drawing machine by the polishing wire drawing of semi-finished product skinning surfaces, surface is presented irregular micropore, forms silicon Algal gel integrated wall plate.
CN201711459416.XA 2017-12-28 2017-12-28 A kind of diatom ooze integrated wall plate and preparation method thereof Pending CN108147712A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109266036A (en) * 2018-09-10 2019-01-25 湖南荣兴环保装饰材料有限公司 A kind of environment friendly decorative material and its preparation method and application
CN112408854A (en) * 2020-11-16 2021-02-26 蓝天豚绿色建筑新材料有限公司 Diatom composite fiber board and preparation method thereof

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CN103467892A (en) * 2013-09-26 2013-12-25 吉林吉瑞莱板材科技有限公司 Diatomite calcium plastic panel as well as production method thereof
KR101680527B1 (en) * 2016-09-23 2016-11-29 이경택 A Manufacturing Method Of Mortar With Agar

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CN103467892A (en) * 2013-09-26 2013-12-25 吉林吉瑞莱板材科技有限公司 Diatomite calcium plastic panel as well as production method thereof
KR101680527B1 (en) * 2016-09-23 2016-11-29 이경택 A Manufacturing Method Of Mortar With Agar

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109266036A (en) * 2018-09-10 2019-01-25 湖南荣兴环保装饰材料有限公司 A kind of environment friendly decorative material and its preparation method and application
CN112408854A (en) * 2020-11-16 2021-02-26 蓝天豚绿色建筑新材料有限公司 Diatom composite fiber board and preparation method thereof

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Application publication date: 20180612